DE3021878A1 - Verfahren zur herstellung von aethylenglycol durch katalytische hydrierung - Google Patents
Verfahren zur herstellung von aethylenglycol durch katalytische hydrierungInfo
- Publication number
- DE3021878A1 DE3021878A1 DE3021878A DE3021878A DE3021878A1 DE 3021878 A1 DE3021878 A1 DE 3021878A1 DE 3021878 A DE3021878 A DE 3021878A DE 3021878 A DE3021878 A DE 3021878A DE 3021878 A1 DE3021878 A1 DE 3021878A1
- Authority
- DE
- Germany
- Prior art keywords
- ester
- hydrogenation
- catalyst
- glycolic acid
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US5251579A | 1979-06-27 | 1979-06-27 | |
US06/132,916 US4366333A (en) | 1979-06-27 | 1980-03-24 | Process of prolonging the life of ester hydrogenation catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
DE3021878A1 true DE3021878A1 (de) | 1981-01-22 |
DE3021878C2 DE3021878C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-08-03 |
Family
ID=26730696
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE3021878A Granted DE3021878A1 (de) | 1979-06-27 | 1980-06-11 | Verfahren zur herstellung von aethylenglycol durch katalytische hydrierung |
Country Status (7)
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020077269A1 (en) * | 2000-10-27 | 2002-06-20 | Whitehouse Robert S. | Alkanoic acid ester monomer compositions and methods of making same |
US9227896B2 (en) | 2010-08-18 | 2016-01-05 | Eastman Chemical Company | Process for the separation and purification of a mixed diol stream |
US8466328B2 (en) | 2010-08-18 | 2013-06-18 | Eastman Chemical Company | Method for recovery and recycle of ruthenium homogeneous catalysts |
US8829248B2 (en) | 2010-08-18 | 2014-09-09 | Eastman Chemical Company | Method for recovery and recycle of ruthenium homogeneous catalysts |
US8709376B2 (en) | 2010-09-23 | 2014-04-29 | Eastman Chemical Company | Process for recovering and recycling an acid catalyst |
US8785686B2 (en) | 2010-09-23 | 2014-07-22 | Eastman Chemical Company | Process for recovering and recycling an acid catalyst |
US8703999B2 (en) | 2012-03-27 | 2014-04-22 | Eastman Chemical Company | Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst |
US8927766B2 (en) | 2012-03-27 | 2015-01-06 | Eastman Chemical Company | Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst |
US8829234B2 (en) | 2012-03-27 | 2014-09-09 | Eastman Chemical Company | Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and heterogeneous catalyst |
US8765999B2 (en) | 2012-03-27 | 2014-07-01 | Eastman Chemical Company | Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst |
US9040748B2 (en) | 2012-06-08 | 2015-05-26 | Eastman Chemical Company | Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration |
US10544077B2 (en) | 2017-08-02 | 2020-01-28 | Eastman Chemical Company | Process for making formic acid utilizing higher-boiling formate esters |
US10570081B2 (en) | 2017-08-02 | 2020-02-25 | Eastman Chemical Company | Process for making formic acid utilizing lower-boiling formate esters |
US10435349B2 (en) | 2017-08-02 | 2019-10-08 | Eastman Chemical Company | Iron-catalyzed cross-coupling of methanol with secondary or tertiary alcohols to produce formate esters |
US10266466B2 (en) | 2017-08-02 | 2019-04-23 | Eastman Chemical Company | Iron-catalyzed transfer hydrogenation of esters to alcohols |
US10266467B2 (en) | 2017-08-02 | 2019-04-23 | Eastman Chemical Company | Synthesis of glycols via transfer hydrogenation of alpha-functional esters with alcohols |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2285448A (en) * | 1937-10-30 | 1942-06-09 | Du Pont | Preparation of polyhydric alcohols |
US2654786A (en) * | 1949-12-08 | 1953-10-06 | Du Pont | Polyethylene glycols from etherestes of glycolic acid |
US4087470A (en) * | 1976-06-23 | 1978-05-02 | Chevron Research Company | Process for the production of ethylene glycol |
-
1980
- 1980-03-24 US US06/132,916 patent/US4366333A/en not_active Expired - Lifetime
- 1980-06-05 CA CA000353393A patent/CA1150317A/en not_active Expired
- 1980-06-11 DE DE3021878A patent/DE3021878A1/de active Granted
- 1980-06-16 NL NL8003491A patent/NL8003491A/nl not_active Application Discontinuation
- 1980-06-19 GB GB8020094A patent/GB2054564B/en not_active Expired
- 1980-06-20 FR FR8013742A patent/FR2459790A1/fr active Granted
- 1980-06-26 IT IT23090/80A patent/IT1131398B/it active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2285448A (en) * | 1937-10-30 | 1942-06-09 | Du Pont | Preparation of polyhydric alcohols |
US2654786A (en) * | 1949-12-08 | 1953-10-06 | Du Pont | Polyethylene glycols from etherestes of glycolic acid |
US4087470A (en) * | 1976-06-23 | 1978-05-02 | Chevron Research Company | Process for the production of ethylene glycol |
Also Published As
Publication number | Publication date |
---|---|
CA1150317A (en) | 1983-07-19 |
GB2054564B (en) | 1983-08-10 |
FR2459790B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1984-04-20 |
FR2459790A1 (fr) | 1981-01-16 |
NL8003491A (nl) | 1980-12-30 |
GB2054564A (en) | 1981-02-18 |
IT8023090A0 (it) | 1980-06-26 |
US4366333A (en) | 1982-12-28 |
IT1131398B (it) | 1986-06-18 |
DE3021878C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-08-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8128 | New person/name/address of the agent |
Representative=s name: DEUFEL, P., DIPL.-WIRTSCH.-ING. DR.RER.NAT. SCHOEN |
|
8110 | Request for examination paragraph 44 | ||
D2 | Grant after examination | ||
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |