DE299028C - - Google Patents
Info
- Publication number
- DE299028C DE299028C DENDAT299028D DE299028DA DE299028C DE 299028 C DE299028 C DE 299028C DE NDAT299028 D DENDAT299028 D DE NDAT299028D DE 299028D A DE299028D A DE 299028DA DE 299028 C DE299028 C DE 299028C
- Authority
- DE
- Germany
- Prior art keywords
- explosive
- explosives
- nitro
- trinitrotoluene
- hexamethylenetetramine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002360 explosive Substances 0.000 claims description 12
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- VKYKSIONXSXAKP-UHFFFAOYSA-N Hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 2
- 229960004011 Methenamine Drugs 0.000 claims description 2
- 238000005474 detonation Methods 0.000 claims description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 2
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000006396 nitration reaction Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 description 3
- 239000000015 trinitrotoluene Substances 0.000 description 3
- 230000002349 favourable Effects 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000001828 Gelatine Substances 0.000 description 1
- 229960004321 Pentaerithrityl tetranitrate Drugs 0.000 description 1
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N Picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000000802 nitrating Effects 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229940114148 picric acid Drugs 0.000 description 1
- 229950002929 trinitrophenol Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
- C06B25/34—Compositions containing a nitrated organic compound the compound being a nitrated acyclic, alicyclic or heterocyclic amine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Air Bags (AREA)
Description
Der durch die Patentschrift 104280, Kl. 12, bekannte und durch Nitrieren von Hexamethylentetramin gewonnene Nitrokörper hat bisher in der Sprengtechnik keine Anwendung' gefunden.The patent specification 104280, class 12, known nitro bodies obtained by nitrating hexamethylenetetramine have so far not been used in blasting technology ' found.
Es hat sich nun bei der sprengstofftechnischen Prüfung dieses Körpers ergeben, daß in ihm ein Sprengstoff von außerordentlich günstigen Eigenschaften vorliegt. Bezüglich der Sprengleistung im Trauzlblock kommt dieser Nitrokörper den stärksten Sprengstoffen, wie Sprenggelatine, Nitropentaerythrit, gleich (10 g gaben 520 ecm netto), während er hinsichtlich seiner Schlagempfindlichkeit dem Tetranitromethylanilin nähesteht. Unter dem 2-kg-Fallhammer explodierten - beide Stoffe bei 30 cm Fallhöhe. Das Verhältnis zwischen Empfindlichkeit und Sprengleistung gestaltet sich bei diesem Körper infolgedessen außerordentlich günstig.The explosives test of this body has now shown that in it an explosive with extremely favorable properties is present. Regarding the explosive power In the Trauzl block this nitro body comes from the strongest explosives, such as explosive gelatine, Nitropentaerythritol, equal (10 g gave 520 ecm net), while he was with regard to his Impact sensitivity is close to that of tetranitromethylaniline. Under the 2 kg drop hammer exploded - both fabrics at a height of 30 cm. The relationship between sensitivity and As a result, explosive power is extremely favorable with this body.
Die Dichte des Körpers in kristallisiertem
Zustande übertrifft die aller anderen nur Sauerstoff, Wasserstoff und Kohlenstoff enthaltenden
Nitroverbindungen. Sie wurde zu 1,76 bestimmt. Sie ist sprengstofftechnisch wichtig,
weil der Körper, selbst bis zur Höchstdichte gepreßt, noch mit Leichtigkeit zur Detonation
gebracht werden kann.
Überhaupt ist die leichte Detonierbarkeit des Sprengstoffs und seine Fähigkeit, die Detonation
vorzüglich zu übertragen, eine bemerkenswerte Eigenschaft. Sb wurde festgestellt,
daß ein Zusatz von 5 Prozent zugegossenem Trinitrotoluol, das bekanntlich freiliegend
nur schwer und nur mit außerordentlich starken Initialladungen zur Detonation zu
bringen ist, genügt, um das Trinitrotoluol bei Verwendung von nur 9 g gepreßter Pikrinsäure
als Übertragungsladung freiliegend zur vollständigen Detonation zu bringen. Setzt man
dem Trinitrotoluol größere Mengen (bis 50 Pro-■zent) des Nitrokörpers zu, so erhält man sehr
brisante gießbare Sprengstoffe.The density of the body in the crystallized state exceeds that of all other nitro compounds containing only oxygen, hydrogen and carbon. It was determined to be 1.76. It is important in terms of explosives because the body can be detonated with ease, even when compressed to the highest possible density.
In general, the easy detonability of the explosive and its ability to transfer the detonation excellently is a remarkable property. Sb it was found that an addition of 5 percent poured trinitrotoluene, which is known to be difficult to detonate when exposed and only with extraordinarily strong initial charges, is sufficient to completely detonate the trinitrotoluene when only 9 g of pressed picric acid is used as a transfer charge bring. If larger amounts (up to 50 percent) of the nitro body are added to the trinitrotoluene, very explosive castable explosives are obtained.
Auch die Stabilität des Körpers ist ausgezeichnet. Proben von 5 g, die mehrere Monate bei 75 ° gelagert waren, zeigten keine Gewichts-Veränderung. The stability of the body is also excellent. Samples of 5 g that lasted several months were stored at 75 °, showed no change in weight.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE299028C true DE299028C (en) |
Family
ID=553169
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT299028D Active DE299028C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE299028C (en) |
-
0
- DE DENDAT299028D patent/DE299028C/de active Active
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