DE310789C - - Google Patents
Info
- Publication number
- DE310789C DE310789C DENDAT310789D DE310789DA DE310789C DE 310789 C DE310789 C DE 310789C DE NDAT310789 D DENDAT310789 D DE NDAT310789D DE 310789D A DE310789D A DE 310789DA DE 310789 C DE310789 C DE 310789C
- Authority
- DE
- Germany
- Prior art keywords
- parts
- nitration product
- weight
- nitration
- explosive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000006396 nitration reaction Methods 0.000 claims description 9
- 239000002360 explosive Substances 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 230000002745 absorbent Effects 0.000 claims description 2
- 239000002250 absorbent Substances 0.000 claims description 2
- -1 B. ethylene Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- SNIOPGDIGTZGOP-UHFFFAOYSA-N 1,2,3-propanetrioltrinitrate Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229960003711 glyceryl trinitrate Drugs 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000020 Nitrocellulose Substances 0.000 description 2
- 239000000006 Nitroglycerin Substances 0.000 description 2
- 229940014995 Nitroglycerin Drugs 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 239000001828 Gelatine Substances 0.000 description 1
- 210000002268 Wool Anatomy 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000001264 neutralization Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001698 pyrogenic Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B43/00—Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Preparation (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Description
Läßt man gasförmige ungesättigte Kohlenwasserstoffe, wie z. B. Äthylen, auf ein Gemisch von Schwefelsäure und Salpetersäure einwirken, so erhält man als Nitrierungsprodukt ein neutrales, gelblich gefärbtes öl.Leaving gaseous unsaturated hydrocarbons, such as. B. ethylene, on a mixture When sulfuric acid and nitric acid act, the nitration product is obtained a neutral, yellowish colored oil.
Es zeigte sich nun, daß man dieses Nitrierungsprodukt als Sprengöl benutzen kann, wenn man es der Initialzündung unterwirft.It has now been shown that this nitration product can be used as an explosive oil, if one subjects it to the initial spark.
Das neue Sprengöl steht dem Nitroglyzerin ίο an Explosivkraft nicht nach, übertrifft es sogar zum Teil. Es kann überhaupt das Nitroglyzerin ersetzen, indem es sowohl mit Aufsaugungsmitteln und Zumischpulvern zu dynamitähnlichen Produkten verarbeitet, als auch mit Nitrozellulose gelatiniert werden kann.The new explosive oil is not inferior to nitroglycerin ίο in terms of explosive power, it even surpasses it partly. It can replace the nitroglycerin at all by using both absorbents and admixture powders are processed into dynamite-like products, as well as gelatinized with nitrocellulose can.
Dem Nitroglyzerin gegenüber ist das neue Sprengöl bezüglich der Herstellung überlegen, weil es durch direkte Nitrierung der bei der pyrogenen Zersetzung organischer Stoffe entstehenden ungesättigten gasförmigen Kohlenwasserstoffe gewonnen werden kann.Compared to nitroglycerine, the new explosive oil is superior in terms of production, because it is the result of direct nitration of the unsaturated gaseous formed during the pyrogenic decomposition of organic substances Hydrocarbons can be obtained.
I. Herstellung des Nitrierungsproduktes. I. Preparation of the nitration product.
In ein gekühltes Gemisch von 50 Raurnteilen Salpetersäure und 76 Raumteilen .Schwefelsäure, welches Ungefähr ein spezifisches Gewicht von 1,735 bis 1,785 haben soll, leitet man unter guter Durchmischung Äthylengas ein. Nach einiger Zeit scheidet sich oberhalb der Säure ein gelblich gefärbtes Öl aus, welches neutralisiert, gewaschen und getrocknet wird. Es hat ein spezifisches Gewicht von 1,489 und ist nahezu wasserunlöslich. Bezüglich seiner Sprengeigenschaften verhält es sich vollständig analog dem Nitroglyzerin.In a cooled mixture of 50 parts by volume nitric acid and 76 parts by volume Sulfuric acid, which have a specific gravity of approximately 1.735 to 1.785 ethylene gas is introduced with thorough mixing. After a while, parting A yellowish colored oil emerges above the acid, which neutralizes, washed and is dried. It has a specific weight of 1.489 and is almost insoluble in water. With regard to its explosive properties, it behaves completely analogously to nitroglycerine.
II. Herstellung von Dynamit aus · dem Nitrierungsprodukt.II. Manufacture of dynamite from the nitration product.
75 Gewichtsteile Nitrierungsprodukt werden mit 251 Gewichtsteilen Kieselgur! vermischt. Hierbei wird ein kittartiger Gurdynamit von bekannter Qualität erhalten.75 parts by weight of nitration product are mixed with 25 1 parts by weight of kieselguhr! mixed. A putty-like gurdynamite of known quality is obtained here.
III. Herstellung von Sprenggelatine. III. Production of blasting gelatine.
Da das Nitrierungsprodukt sehr hohes Lösungsvermögen für Nitrozellulose besitzt, kann man durch Auflösen von 8 Gewichtsteilen Kollodiumwolle in 92 Gewichtsteilen Nitrierungsprodukt eine Sprenggelatine von bester Qualität herstellen.Since the nitration product has a very high dissolving power for nitrocellulose, can be obtained by dissolving 8 parts by weight of collodion wool in 92 parts by weight Nitration product to produce a blasting gelatin of the best quality.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE310789C true DE310789C (en) |
Family
ID=563818
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT310789D Active DE310789C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE310789C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2712989A (en) * | 1947-02-01 | 1955-07-12 | Aerojet General Co | Propellant composition comprising nitroparaffin gel |
| DE1019229B (en) * | 1954-09-16 | 1957-11-07 | Franzoesische Republik Vertret | Process for the production of Sprengoel by the nitration of ethylene |
-
0
- DE DENDAT310789D patent/DE310789C/de active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2712989A (en) * | 1947-02-01 | 1955-07-12 | Aerojet General Co | Propellant composition comprising nitroparaffin gel |
| DE1019229B (en) * | 1954-09-16 | 1957-11-07 | Franzoesische Republik Vertret | Process for the production of Sprengoel by the nitration of ethylene |
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