DE2834699C2 - Verfahren zur Herstellung von Äthylen - Google Patents

Verfahren zur Herstellung von Äthylen

Info

Publication number
DE2834699C2
DE2834699C2 DE2834699A DE2834699A DE2834699C2 DE 2834699 C2 DE2834699 C2 DE 2834699C2 DE 2834699 A DE2834699 A DE 2834699A DE 2834699 A DE2834699 A DE 2834699A DE 2834699 C2 DE2834699 C2 DE 2834699C2
Authority
DE
Germany
Prior art keywords
reactor
ethyl alcohol
catalyst
ethylene
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE2834699A
Other languages
German (de)
English (en)
Other versions
DE2834699A1 (de
Inventor
Ruy Coutinho Rio de Janeiro Assis de
Helcio Valladares Niteroi Rio de Janeiro Barrocas
Joao Baptista Ilha do Governador Rio de Janeiro Castro M. da Silva de
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Petroleo Brasileiro SA Petrobras
Original Assignee
Petroleo Brasileiro SA Petrobras
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=4006904&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE2834699(C2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Petroleo Brasileiro SA Petrobras filed Critical Petroleo Brasileiro SA Petrobras
Publication of DE2834699A1 publication Critical patent/DE2834699A1/de
Application granted granted Critical
Publication of DE2834699C2 publication Critical patent/DE2834699C2/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
    • C07C2527/173—Phosphoric acid or other acids with the formula Hn+2PnO3n+1
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE2834699A 1977-08-09 1978-08-08 Verfahren zur Herstellung von Äthylen Expired DE2834699C2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BR7705256A BR7705256A (pt) 1977-08-09 1977-08-09 Processo e preparacao de eteno

Publications (2)

Publication Number Publication Date
DE2834699A1 DE2834699A1 (de) 1979-02-22
DE2834699C2 true DE2834699C2 (de) 1986-11-06

Family

ID=4006904

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2834699A Expired DE2834699C2 (de) 1977-08-09 1978-08-08 Verfahren zur Herstellung von Äthylen

Country Status (13)

Country Link
US (1) US4232179A (enExample)
JP (1) JPS5919927B2 (enExample)
AR (1) AR215330A1 (enExample)
AU (1) AU524261B2 (enExample)
BE (1) BE869500A (enExample)
BR (1) BR7705256A (enExample)
DE (1) DE2834699C2 (enExample)
FR (1) FR2399992B1 (enExample)
GB (1) GB2002416B (enExample)
IN (1) IN150493B (enExample)
KE (1) KE3366A (enExample)
MX (1) MX147969A (enExample)
ZA (1) ZA784321B (enExample)

Families Citing this family (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR8101487A (pt) * 1981-03-13 1982-10-26 Petroleo Brasileiro Sa Processo de desidratacao de um alcool de baixo peso molecular
JPS57190650A (en) * 1981-05-15 1982-11-24 Agency Of Ind Science & Technol Porous crystalline catalyst for olefin synthesis
US4404414A (en) * 1982-09-28 1983-09-13 Mobil Oil Corporation Conversion of methanol to gasoline
US4590320A (en) * 1984-08-31 1986-05-20 Mobil Oil Corporation Conversion of methanol to olefins in a tubular reactor with light olefin co-feeding
JPS6434929A (en) * 1987-07-30 1989-02-06 Jgc Corp Method for dehydrating reaction of ethanol
US4885405A (en) * 1987-12-10 1989-12-05 Horst Dornhagen Process for the production of pure dimethylether and a catalyst used in the process
JPH11217343A (ja) 1998-01-30 1999-08-10 Sangi Co Ltd 化学工業原料及びハイオク燃料の合成法
US20050175519A1 (en) * 2004-02-06 2005-08-11 Rogers William A.Jr. Microchannel compression reactor
CN101304963A (zh) * 2005-11-14 2008-11-12 三井化学株式会社 含有来源于生物有机体的碳的丙烯的制造方法
EP1792885A1 (en) * 2005-11-29 2007-06-06 BP Chemicals Limited Process for producing ethylene
EP1790627A1 (en) * 2005-11-29 2007-05-30 BP Chemicals Limited Process for producing olefins
EP1792886A1 (en) * 2005-11-29 2007-06-06 BP Chemicals Limited Process for producing propylene
BRPI0601803A (pt) * 2006-05-18 2008-02-19 Helcio Valladares Barrocas processo para produção de eteno a partir de álcool etìlico
JP2010030902A (ja) * 2006-11-21 2010-02-12 Mitsui Chemicals Inc エチレンの製造方法
EP1992601A1 (en) * 2007-05-11 2008-11-19 Ineos Europe Limited Dehydration of alcohols over supported heteropolyacids
EP2050730A1 (en) * 2007-10-17 2009-04-22 BP Chemicals Limited Process for preparing ethene
ATE528329T1 (de) * 2007-12-05 2011-10-15 Braskem Sa Integriertes verfahren zur herstellung eines ethylen-butylen-copolymers, ethylen-butylen- copolymer und verwendung von ethylen und 1- butylen als aus erneuerbaren natürlichen rohmaterialien gewonnene comonomere
EP2108637A1 (en) * 2008-04-11 2009-10-14 Total Petrochemicals Research Feluy Process to make olefins from ethanol.
EP2108636A1 (en) * 2008-04-11 2009-10-14 Total Petrochemicals Research Feluy Dehydration of alcohols in the presence of an inert component.
KR101217957B1 (ko) * 2008-02-07 2013-01-02 토탈 리서치 앤드 테크놀로지 펠루이 결정질 실리케이트 상에서의 알코올의 탈수
AU2009211370A1 (en) * 2008-02-07 2009-08-13 Total Petrochemicals Research Feluy Dehydration of alcohols in the presence of an inert component
EP2238092A1 (en) * 2008-02-07 2010-10-13 Total Petrochemicals Research Feluy Process to make olefins from ethanol
EP2090561A1 (en) 2008-02-07 2009-08-19 Total Petrochemicals Research Feluy Dehydration of alcohols on crystalline silicates
KR101227221B1 (ko) * 2008-02-07 2013-01-28 토탈 리서치 앤드 테크놀로지 펠루이 에탄올로부터의 올레핀의 제조 방법
EP2108634A1 (en) 2008-04-11 2009-10-14 Total Petrochemicals Research Feluy Dehydration of alcohols on crystalline silicates
EP2108635A1 (en) 2008-04-11 2009-10-14 Total Petrochemicals Research Feluy Process to make olefins from ethanol
FR2934599B1 (fr) * 2008-07-29 2012-12-21 Arkema France Fabrication de polyethylene a partir de matieres renouvelables, polyethylene obtenu et utilisations
JP2010042343A (ja) * 2008-08-12 2010-02-25 National Institute Of Advanced Industrial & Technology 低級オレフィン製造用触媒、その製造方法及びこれを用いた低級オレフィンの製造方法
EP2192101A1 (en) 2008-11-28 2010-06-02 Total Petrochemicals Research Feluy Purification of alcohols prior to their use in the presence of an acid catalyst
MX2011005459A (es) 2008-11-28 2011-06-16 Total Petrochemicals Res Feluy Purificacion de alcoholes antes de su uso en presencia de un catalizador acido.
US9242919B2 (en) 2009-07-01 2016-01-26 Dow Global Technologies Llc Process to prepare olefins from aliphatic alcohols
CN102884026B (zh) 2010-02-24 2014-10-29 英国石油有限公司 制备烯烃的方法
ES2699724T3 (es) 2010-02-24 2019-02-12 Technip E & C Ltd Procedimiento para la preparación de un alqueno
FR2959751B1 (fr) 2010-05-06 2012-06-08 Inst Francais Du Petrole Procede de production de base pour carburants a partir d'une charge ethylenique mettant en oeuvre au moins une etape d'oligomerisation en presence d'un systeme catalytique homogene.
FR2959752B1 (fr) 2010-05-06 2012-06-08 Inst Francais Du Petrole Procede flexible de transformation de l'ethanol en distillats moyens mettant en oeuvre un systeme catalytique homogene et un systeme catalytique heterogene.
FR2959750B1 (fr) 2010-05-06 2013-02-15 Inst Francais Du Petrole Procede de production de kerosene a partir de bio-ethanol.
CN102381927B (zh) * 2010-09-01 2014-04-30 中国石油化工股份有限公司 一种由乙醇合成乙苯的方法
CN102381922B (zh) * 2010-09-01 2014-04-30 中国石油化工股份有限公司 一种由乙醇合成乙烯的方法
WO2013004544A1 (en) * 2011-07-07 2013-01-10 Ineos Europe Ag Process and apparatus for producing olefins with heat transfer from steam cracking to alcohol dehydration process.
FR2978146B1 (fr) 2011-07-21 2013-08-30 IFP Energies Nouvelles Procede de deshydratation de l'ethanol en ethylene a basse consommation energetique
FR2981065B1 (fr) * 2011-10-07 2014-03-14 IFP Energies Nouvelles Procede de deshydratation de l'ethanol dilue en ethylene a basse consommation energetique sans recyclage de l'eau.
EP2594547A1 (en) 2011-11-17 2013-05-22 Solvay Sa Process for the manufacture of at least one ethylene derivative compound from bioethanol
US20170266635A1 (en) * 2012-01-09 2017-09-21 Petron Scientech, Inc. Reactor and process for the dehydration of ethanol to ethylene
US20130178674A1 (en) * 2012-01-09 2013-07-11 Hassan Taheri Reactor and process for dehydration of ethanol to ethylene
US20150265992A1 (en) * 2014-03-20 2015-09-24 Petron Scientec Inc. Reactor and process for dehydration of ethanol to ethylene
US9738575B2 (en) 2012-05-16 2017-08-22 China Petroleum & Chemical Corporation Apparatus for producing ethylene and a producing method thereof
FR2998568B1 (fr) * 2012-11-27 2015-01-23 IFP Energies Nouvelles Procede de deshydratation de l'ethanol en ethylene a basse consommation
FR2998567B1 (fr) 2012-11-27 2014-12-26 IFP Energies Nouvelles Procede de deshydratation d'ethanol en ethylene mettant en oeuvre un pretraitement de la charge
EP2740718A1 (de) 2012-12-04 2014-06-11 Linde Aktiengesellschaft Verfahren zur katalytischen Dehydratisierung von Olefinen
FR3001968B1 (fr) 2013-02-12 2015-02-27 IFP Energies Nouvelles Procede de production d'oxyde d'ethylene a partir d'un flux d'ethanol thermo-mecaniquement integre
FR3001969B1 (fr) 2013-02-12 2015-08-21 IFP Energies Nouvelles Procede de production d'oxyde d'ethylene a partir d'un flux d'ethanol thermiquement integre
BR112016011768B1 (pt) 2013-12-13 2020-11-24 Dow Global Technologies Llc Processo adiabatico
HUE063804T2 (hu) * 2014-12-16 2024-02-28 Technip E & C Ltd Eljárás és berendezés etanol dehidratálására
US10472300B2 (en) 2014-12-31 2019-11-12 Total Research & Technology Feluy Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of sulfur containing compounds
EP3126313B1 (en) 2014-12-31 2017-10-18 Total Research & Technology Feluy Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of organic acids
FI129508B (fi) * 2018-04-20 2022-03-31 Jani Karvanen Kaatopää ja menetelmä pienpuun korjaamiseen
US11260367B2 (en) 2018-12-12 2022-03-01 Instituto Nacional De Tecnologia Catalytic system and process for the production of light olefins from ethanol
FR3089973B1 (fr) 2018-12-14 2020-12-25 Ifp Energies Now Procédé de déshydratation de l'éthanol en éthylène à basse consommation énergétique
US11905396B2 (en) 2019-09-30 2024-02-20 Enlightened Product Solutions, LLC Renewably-sourced biodegradable polyolefin packaging, utensils, and containers
WO2023145941A1 (ja) * 2022-01-31 2023-08-03 旭化成株式会社 エタノールの変換方法、及びその他炭化水素の製造方法
JP2024121026A (ja) * 2022-08-30 2024-09-06 旭化成株式会社 エタノール及びエチレンの変換方法、プロピレンの製造方法、芳香族化合物の製造方法、並びに、エタノール及びエチレンの変換装置
US20240182801A1 (en) * 2022-08-30 2024-06-06 Uop Llc Steam integration in ethanol to jet fuel process
US20240190794A1 (en) * 2022-08-30 2024-06-13 Uop Llc Radial flow reactor for an ethanol dehydration process
US12479779B2 (en) * 2022-08-30 2025-11-25 Uop Llc Steam integration in ethanol to jet fuel process
US20240076249A1 (en) * 2022-08-30 2024-03-07 Uop Llc Radial flow reactor for an ethanol dehydration process
JPWO2024070182A1 (enExample) * 2022-09-30 2024-04-04
WO2024089255A1 (en) 2022-10-28 2024-05-02 Basf Se Process for the manufacture of an ethylene-derived chemical of interest, in particular styrene, from renewably-sourced ethanol
WO2024089252A1 (en) 2022-10-28 2024-05-02 Basf Se Process for the manufacture of a propylene-derived chemical of interest, in particular an acrylic ester, from renewably-sourced ethanol
EP4638400A1 (en) 2022-12-20 2025-10-29 Basf Se Manufacture of an ethylene-derived chemical of interest, in particular acrylic acid, in combination with generation of heated steam
WO2024133082A1 (en) 2022-12-20 2024-06-27 Basf Se Manufacture of an ethylene-derived chemical of interest in combination with production of thermal energy
FR3153613B1 (fr) 2023-09-29 2025-10-10 Ifp Energies Now Procede de production de distillats moyens en particulier de kerosene a partir d’une charge alcoolique
WO2025078353A1 (en) 2023-10-09 2025-04-17 Basf Se Manufacture of ethylene-derived chemicals having a bio-based carbon content from pyrolysis oil
WO2025078362A1 (en) 2023-10-09 2025-04-17 Basf Se Process for the manufacture of styrene acrylic copolymers having a renewably-sourced carbon content
WO2025078359A1 (en) 2023-10-09 2025-04-17 Basf Se Manufacture of ethylene-derived chemicals having a bio-based carbon content from bio-naphtha
WO2025224042A1 (en) 2024-04-23 2025-10-30 Basf Se Process for the manufacture of renewably-sourced n-butanol or 2-ethylhexanol
FR3163379A1 (fr) 2024-06-18 2025-12-19 IFP Energies Nouvelles Procédé d’hydrogénation des oléfines contenues dans une charge oléfinique de type distillats moyens en présence d’un catalyseur de nickel cuivre
WO2026002694A1 (en) 2024-06-26 2026-01-02 Basf Se Manufacture of propylene-based chemical(s) from ethylene obtained from ethanol dehydration

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1909356A (en) * 1928-02-27 1933-05-16 Selden Co Catalytic dehydration of alcohols
DE501198C (de) * 1928-11-10 1930-06-28 Chem Fab Dr Hugo Stoltzenberg Vorrichtung zur Entwicklung von AEthylen
US2377026A (en) * 1940-10-01 1945-05-29 Air Reduction Method of dehydrating alcohols
NL63902C (enExample) * 1944-12-04
US2949493A (en) * 1958-10-03 1960-08-16 Happel John Production of divinyl acetylenes by the dehydration of vinyl acetylenic alcohols in the presence of steam
US4052479A (en) * 1973-08-09 1977-10-04 Mobil Oil Corporation Conversion of methanol to olefinic components
US4025576A (en) * 1975-04-08 1977-05-24 Mobil Oil Corporation Process for manufacturing olefins

Also Published As

Publication number Publication date
FR2399992A1 (fr) 1979-03-09
US4232179A (en) 1980-11-04
IN150493B (enExample) 1982-10-23
GB2002416B (en) 1982-03-03
KE3366A (en) 1984-02-03
GB2002416A (en) 1979-02-21
AU3873278A (en) 1980-02-14
MX147969A (es) 1983-02-17
BE869500A (fr) 1978-12-01
AU524261B2 (en) 1982-09-09
BR7705256A (pt) 1979-04-03
DE2834699A1 (de) 1979-02-22
FR2399992B1 (fr) 1985-08-09
US4232179B1 (enExample) 1987-12-08
AR215330A1 (es) 1979-09-28
JPS5436203A (en) 1979-03-16
ZA784321B (en) 1979-07-25
JPS5919927B2 (ja) 1984-05-09

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Legal Events

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Representative=s name: JUNG, E., DIPL.-CHEM. DR.PHIL. SCHIRDEWAHN, J., DI

8110 Request for examination paragraph 44
D2 Grant after examination
8364 No opposition during term of opposition