DE2536359C3 - Verfahren und Vorrichtung zur kontinuierlichen Polymerisation von Äthylen - Google Patents
Verfahren und Vorrichtung zur kontinuierlichen Polymerisation von ÄthylenInfo
- Publication number
- DE2536359C3 DE2536359C3 DE2536359A DE2536359A DE2536359C3 DE 2536359 C3 DE2536359 C3 DE 2536359C3 DE 2536359 A DE2536359 A DE 2536359A DE 2536359 A DE2536359 A DE 2536359A DE 2536359 C3 DE2536359 C3 DE 2536359C3
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- monomer
- pressure
- autoclave
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006116 polymerization reaction Methods 0.000 title claims description 27
- 238000000034 method Methods 0.000 title claims description 25
- 230000008569 process Effects 0.000 title claims description 17
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 14
- 239000005977 Ethylene Substances 0.000 title claims description 14
- 239000003054 catalyst Substances 0.000 claims description 43
- 239000000178 monomer Substances 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 11
- 238000002347 injection Methods 0.000 claims description 10
- 239000007924 injection Substances 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 7
- 238000010276 construction Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 239000011953 free-radical catalyst Substances 0.000 claims 1
- 239000002685 polymerization catalyst Substances 0.000 claims 1
- 230000002787 reinforcement Effects 0.000 claims 1
- 125000006850 spacer group Chemical group 0.000 claims 1
- 238000013459 approach Methods 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 4
- 239000012190 activator Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical compound CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- -1 propylene, butylene, hexene Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000004043 responsiveness Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/02—Feed or outlet devices therefor
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/497,977 US4002813A (en) | 1974-08-16 | 1974-08-16 | Injection of catalysts into a polymerization autoclave |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2536359A1 DE2536359A1 (de) | 1976-02-26 |
| DE2536359B2 DE2536359B2 (de) | 1980-02-28 |
| DE2536359C3 true DE2536359C3 (de) | 1980-11-06 |
Family
ID=23979113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2536359A Expired DE2536359C3 (de) | 1974-08-16 | 1975-08-14 | Verfahren und Vorrichtung zur kontinuierlichen Polymerisation von Äthylen |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4002813A (enExample) |
| JP (1) | JPS5855963B2 (enExample) |
| CA (1) | CA1065100A (enExample) |
| DE (1) | DE2536359C3 (enExample) |
| FR (1) | FR2281787A1 (enExample) |
| GB (2) | GB1512267A (enExample) |
| NO (1) | NO147188C (enExample) |
| SE (1) | SE7509176L (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4173697A (en) * | 1977-09-21 | 1979-11-06 | Gulf Oil Corporation | Continuous high pressure mass processes for the polymerization of ethylene |
| JPS5834811A (ja) * | 1981-08-22 | 1983-03-01 | Mitsubishi Petrochem Co Ltd | エチレンの重合法 |
| JPS60191358U (ja) * | 1984-05-25 | 1985-12-18 | ユニオンケミカ−株式会社 | インクリボンカ−トリツジ |
| JPS6265255U (enExample) * | 1985-10-14 | 1987-04-23 | ||
| JPH07179009A (ja) * | 1993-12-22 | 1995-07-18 | Kao Corp | インクリボンカセット |
| JPH07304240A (ja) * | 1994-05-10 | 1995-11-21 | Kao Corp | インクリボンカセット |
| JPH07304239A (ja) * | 1994-05-10 | 1995-11-21 | Kao Corp | インクリボンカセット |
| JPH07304238A (ja) * | 1994-05-10 | 1995-11-21 | Kao Corp | インクリボンカセット |
| PL2725052T3 (pl) * | 2012-10-23 | 2019-07-31 | Uhde Inventa-Fischer Gmbh | Urządzenie do repolimeryzacji |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3450800A (en) * | 1964-01-31 | 1969-06-17 | Phillips Petroleum Co | Dispersing gases into liquids |
| US3405115A (en) * | 1964-02-26 | 1968-10-08 | Koppers Co Inc | Liquid catalyst injection |
| US3399185A (en) * | 1965-03-01 | 1968-08-27 | Koppers Co Inc | Preparation of polyethylene having improved optical properties |
| US3577224A (en) * | 1968-09-09 | 1971-05-04 | Sinclair Koppers Co | Apparatus for production of high pressure polyethylene |
| NL6912911A (enExample) * | 1969-08-25 | 1971-03-01 | ||
| NL160292C (nl) * | 1969-09-19 | 1979-10-15 | Stamicarbon | Werkwijze en reactor voor het continu polymeriseren van etheen. |
| US3745658A (en) * | 1971-01-25 | 1973-07-17 | P Raneses | Apparatus for determining earthwork volumes |
| DE2116374A1 (de) * | 1971-04-03 | 1972-10-19 | Friedrich Uhde Gmbh, 4600 Dortmund | Verfahren zur Durchführung von Gasphasenreaktionen |
| US3876602A (en) * | 1971-11-26 | 1975-04-08 | Union Carbide Corp | Particulate catalyst injection method in polyolefin production |
| NL7312804A (nl) * | 1973-09-18 | 1975-03-20 | Stamicarbon | Werkwijze voor het polymeriseren van etheen onder hoge druk en temperatuur. |
-
1974
- 1974-08-16 US US05/497,977 patent/US4002813A/en not_active Expired - Lifetime
-
1975
- 1975-08-01 CA CA232,708A patent/CA1065100A/en not_active Expired
- 1975-08-08 GB GB53015/77A patent/GB1512267A/en not_active Expired
- 1975-08-08 GB GB33234/75A patent/GB1512266A/en not_active Expired
- 1975-08-14 DE DE2536359A patent/DE2536359C3/de not_active Expired
- 1975-08-14 FR FR7525455A patent/FR2281787A1/fr active Granted
- 1975-08-15 NO NO752846A patent/NO147188C/no unknown
- 1975-08-15 SE SE7509176A patent/SE7509176L/ not_active Application Discontinuation
- 1975-08-15 JP JP50099438A patent/JPS5855963B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1512267A (en) | 1978-05-24 |
| NO752846L (enExample) | 1976-02-17 |
| CA1065100A (en) | 1979-10-23 |
| DE2536359A1 (de) | 1976-02-26 |
| SE7509176L (sv) | 1976-02-17 |
| NO147188B (no) | 1982-11-08 |
| FR2281787A1 (fr) | 1976-03-12 |
| NO147188C (no) | 1983-02-16 |
| DE2536359B2 (de) | 1980-02-28 |
| FR2281787B1 (enExample) | 1979-05-11 |
| GB1512266A (en) | 1978-05-24 |
| US4002813A (en) | 1977-01-11 |
| JPS5855963B2 (ja) | 1983-12-13 |
| JPS5146386A (enExample) | 1976-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |