DE2527582A1 - Composite floor- or wall-cover - contg non-woven hydrophobic top layer, hydrophilic intermediate- and hydrophobic bottom layer - Google Patents

Composite floor- or wall-cover - contg non-woven hydrophobic top layer, hydrophilic intermediate- and hydrophobic bottom layer

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Publication number
DE2527582A1
DE2527582A1 DE19752527582 DE2527582A DE2527582A1 DE 2527582 A1 DE2527582 A1 DE 2527582A1 DE 19752527582 DE19752527582 DE 19752527582 DE 2527582 A DE2527582 A DE 2527582A DE 2527582 A1 DE2527582 A1 DE 2527582A1
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Germany
Prior art keywords
layer
fibers
fleece
cover
composite
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Pending
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DE19752527582
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German (de)
Inventor
Gerhard Baumgartner
Walter Six
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Bunzl and Biach AG
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Bunzl and Biach AG
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Publication of DE2527582A1 publication Critical patent/DE2527582A1/en
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • D04H1/4258Regenerated cellulose series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282Addition polymers
    • D04H1/43Acrylonitrile series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/4334Polyamides
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/435Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4374Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/48Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/498Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres entanglement of layered webs
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/593Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives to layered webs
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00Other non-woven fabrics

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

Impregnated composite material, contg. >=1 cover-layer of non-woven fabric needle with >=1 bottom-layer of non-woven- and/or woven fabric, consists of a non-woven fabric top layer esp. of water-repellent fibres and a lower stratum of esp. water-repellent fibres, with an intermediate pre-bonded non-woven fabric, esp. of hydrophilic fibres, e.g. cellulose fibres. Material has improved opaqueness and higher strength and tread-resistance. Absorbency of intermediate layer improves printing.

Description

Verbundstoff, insbesondere für Boden-oder Wandbeläge.Composite material, in particular for floor or wall coverings.

Die vorliegende Erfindung bezieht sich auf einen imprägnierten Verbundstoff, insbesondere'für Bodenbeläge, mit wenigstens einer Deckvliesschicht sowie wenigstens einer weiteren Vlies- und/oder Gewebe- bzw. Gewirkelage als Unterschicht, die miteinander vernadelt sind; weiters bezieht sich die Erfindung auf ein Verfahren zur Herstellung eines derartigen Verbundstoffes. The present invention relates to an impregnated composite, in particular for floor coverings, with at least one non-woven cover layer and at least a further nonwoven and / or woven or knitted layer as a lower layer, which with each other are needled; The invention also relates to a method of production such a composite.

Es ist bereits bekannt, bei der Herstellung von Verbundstoffen mit wenigstens einer Deckvliesschicht sowie einer Unterschicht Kunstfaserabfälle für die Unterschicht zu verwenden; da derartige, im allgemeinen bunte Kunstfaserabfälle billig sind, kann dadurch der Herstellungspreis reduziert werden. It is already known to use in the manufacture of composites at least one top layer and a lower layer of synthetic fiber waste for to use the underlayer; because such, generally colored synthetic fiber waste are cheap, the manufacturing price can be reduced.

Um jedoch ein Durchscheinen oder Durchschlagen der Farbe der bunten Kunstfaser der Unterschicht durch die Deckvliesschicht möglichst zu vfflhindern, muß ein derartiger Verbundstoff im allgemeinen mit einer relativ dicken Deckvliesschicht hergestellt werden, wodurch die Herstellungskosten noch immer verhältnismäßig hoch sind.However, in order to show through or bleed through the color of the brightly colored To prevent synthetic fibers of the lower layer by the cover fleece layer as much as possible, Such a composite must generally have a relatively thick nonwoven facing layer are manufactured, whereby the manufacturing costs are still relatively high are.

Es sind ferner Verbundstoffe für Bodenbeläge bekannt, bei welchen eine Vlieslage mit einer weiteren Vlies schicht vernadelt ist. Die durch die Nadelung vereinigten Schichten sind weiters durch Imprägnierung mit einem Bindemittel verfestigt (saturiert oder einseitig imprägniert). Dabei wird durch die für eine bessere Haltbarkeit des Bodenbelages notwendige Imprägnierung mit dem Kunststoffbindemittel zunächst der textile Charakter der Belagsoberfläche verändert. Auch wird durch die Imprägnierung die den Fasern ursprünglich innewohnende Elastizität durch das Bindemittel merklich unterdrückt. There are also known composites for floor coverings in which a fleece layer is needled with another fleece layer. The one through the needling The combined layers are further solidified by impregnation with a binder (saturated or impregnated on one side). This is done by for a better shelf life Impregnation of the floor covering with the plastic binder is necessary first the textile character of the covering surface changes. Even will through the impregnation, the elasticity originally inherent in the fibers the binder is noticeably suppressed.

Dadurch ist ein derartiger Fußbodenbelag beispielsweise viel steifer als ein bloß gewebter, genadelter oder andersartig hergestellter Bodenbelag, welcher keine Kunststoffimprägnierung aufweist.As a result, such a floor covering is, for example, much stiffer as a merely woven, needled or otherwise manufactured floor covering, which has no plastic impregnation.

Es ist ein Ziel der vorliegenden Erfindung, einen Verbundstoff der eingangs erwähnten Art zu schaffen, bei dem die oben angeführten Nachteile vermieden sind. Insbesondere bezweckt die Erfindung die Schaffung eines Verbundstoffes, welcher einerseits eine verbesserte Opazität, insbesondere im Falle eines Bodenbelages gute mechanische Eigenschaften, vor allem bezüglich der Begehung, sowie eine hohe Trittfestigkeit aufweist; andererseits soll der erfindungsgemäße Verbundstoff auch billig hergestellt werden können. It is an object of the present invention to provide a composite of To create the type mentioned at the beginning, in which the above-mentioned disadvantages are avoided are. In particular, the invention aims to provide a composite which on the one hand, an improved opacity, particularly good in the case of a floor covering mechanical properties, especially with regard to walking, as well as high resistance to treading having; on the other hand, the composite according to the invention should also be produced cheaply can be.

Der erfindungsgemäße Verbundstoff der eingangs angeführten Art ist dadurch gekennzeichnet, daß zwischen der Deckvliesschicht aus vorzugsweise hydrophoben Fasern und der Unterschicht aus vorzugsweise hydrophoben Fasern ein vorgebundenes Vlies als Zwischenlage, vorzugsweise aus hydrophilen Fasern, beispielsweise Zellulosefasern, vorgesehen ist. Unter einem vorgebundenen Vlies wird dabei ein nach irgendeinem bekannten Vliesverfestigungsverfahren - etwa Verschmelzen oder Verkleben -und nicht durch bloße Nadelung gebundenes Vlies verstanden; beispielsweise kann auch ein Wellvlies oder aber Papier, insbesondere langfaseriges Papier, für die Zwischenlage verwendet werden. The composite according to the invention of the type mentioned is characterized in that between the non-woven cover layer of preferably hydrophobic Fibers and the lower layer of preferably hydrophobic fibers a pre-bonded Fleece as an intermediate layer, preferably made of hydrophilic fibers, for example cellulose fibers, is provided. Under a pre-bonded fleece there is one after any known nonwoven bonding processes - such as fusing or gluing - and not understood fleece bound by mere needling; for example, a corrugated fleece can also be used or paper, especially long-fiber paper, for the intermediate layer be used.

Der erfindungsgemäße Verbundstoff kann dabei vorzugsweise dadurch hagetellt werden, daß zunächst die Unterschicht, die vorgebundene Zwischenlage und die Deckvliesschicht durch Nadeln miteinander verbunden werden, wonach der Verbundstoff mit wässerigen Kunstharzdispersionen bzw. -lösungen behandelt bzw. imprägniert und schließlich - etwa durch Hindurchführen zwischen zwei Walzen - abgequetscht wird. The composite according to the invention can thereby preferably be hagetellt that first the lower layer, the pre-bonded intermediate layer and the non-woven cover layer are connected to each other by needles, after which the composite material treated or impregnated with aqueous synthetic resin dispersions or solutions and finally - is squeezed off - for example by passing it through between two rollers.

Wenn die Zwischenlage aus hydrophilen Kunst fasern hergestellt wird, kann eine hohe Konzentration des Bindemittels bzw. Imprägniermittels in der Zwischenlage auch nach dem Abquetschen des Verbundstoffes erhalten werden; andererseits verbleibt bei Verwendung von hydrophoben Kunstfasern für die äußeren Vlieslagen wenig Bindemittel oder Imprägniermittel in diesen Vlieslagen. Dadurch kann ein bezüglich Begehung elastischer und weicher Bodenbelag erhalten werden, der aber trotzdem eine hohe mechanische Festigkeit und insbesondere eine hohe Trittfestigkeit aufweist. Als hydrophobe Fasern eigenen sich dabei insbesondere Kunstfasern aus Polyamid, Polyester, Polyacryl oder Polyolefinen. Für die Herstellung der Unterschicht werden dabei zweckmäßig billige Kunstfaserabfälle verwendet. If the intermediate layer is made of hydrophilic synthetic fibers, can have a high concentration of the binding agent or impregnating agent in the intermediate layer also obtained after squeezing the composite; on the other hand remains when using hydrophobic synthetic fibers for the outer fleece layers, little binding agent or impregnating agents in these fleece layers. This allows a regarding inspection elastic and soft flooring can be obtained, but still a high has mechanical strength and, in particular, high resistance to treading. as hydrophobic fibers are particularly suitable synthetic fibers made of polyamide, polyester, Polyacrylic or polyolefins. For the production of the underlayer it is useful used cheap synthetic fiber waste.

Die Zwischenlage aus einem vorgebundenen Vlies, beispielsweise aus Zellulosefasern, insbesondere Zellwollefasern, oder aber - etwa für die Verwendung des erfindungsgemäßen Verbundstoffes als Wandbelag - auch aus Polyamidfasern, verhindert ein optisches Durchschlagen der Färbung der buten Kunstfaserabfälle, die für die Herstellung der Unterschicht verwendet werden können, da die Fasern beim Vernadeln der drei Schichten oder Lagen trotz gleicher Verfestigung nicht so tief eingenadelt müssen werden7; hiefür ist es wesentlich, daß das Zwischenlage-Vlies imprägniert oder auf andere Weise verfestigt oder vorgebunden ist, da dann die Fasern des Zwischenvlieses beim Nadelprozeß praktisch in der horizontalen Lage bleiben und praktisch keine Fasern dieses Zwischenvlieses in die Unterschicht eingezogen werden. Daher ist es möglich, eine relativ dünne Ober- oder Deckvliesschicht vorzusehen. Dadurch werden die Gestehungskosten eines derartigen Verbundstoffes beträchtlich reduziert, da ja die - verhältnismäßig dünne - Zwischenlage etwa aus Zellulosefasern bereits vom Material bzw. von der Herstellung her billig ist, während die Herstellung der Unterschicht infolge der Möglichkeit der Verwendung von Kunstfaserabfällen noch preiswerter ist. The intermediate layer made from a pre-bonded fleece, for example from Cellulose fibers, especially rayon fibers, or else - for example for use of the composite according to the invention as wall covering - also made of polyamide fibers, prevents the color of the synthetic fiber waste from showing through, which can be used for the manufacture of the underlayer as the fibers not so when the three layers or plies are needled despite the same level of consolidation need to be deeply needled7; for this it is essential that the intermediate layer fleece impregnated or otherwise consolidated or pre-bonded, since then the fibers of the intermediate fleece practically remain in the horizontal position during the needling process and practically no fibers of this intermediate fleece are drawn into the lower layer will. It is therefore possible to provide a relatively thin top or cover fleece layer. This makes the production costs of such a composite considerable reduced, since the - relatively thin - intermediate layer, for example, made of cellulose fibers is already cheap from the material or from the production, while the production the lower layer due to the possibility of using synthetic fiber waste is cheaper.

Die Deckvliesschicht ist im allgemeinen weiß bzw. - etwa uni-färbig - bedruckt; es ist daher von Vorteil, wenn die Zwischenlage aus weißen Fasern oder aber aus entsprechend der Deckvliesschicht gefärbten Fasern besteht, sodaß die Stärke der Deckvliesschicht weiter reduziert werden kann. Beim Druckprozeß wirkt die Zwischenlage, wenn sie aus hydrophilen Fasern hergestellt ist, ferner saugend und erhöht somit die Sicherheit bei komplizierten Bedruckungsprozessen, etwa mit übereinanderliegenden Farben. Auch ermöglicht das Zwischenlage-Vlies eine konzentrierte Chemikalienspeicherung dicht unterhalb der Oberfläche und begünstigt den Feuchtigkeitshaushalt der Oberschicht oder Trittfläche, bedingt durch die hydrophile Faser (antistatische Eigenschaft). The non-woven cover layer is generally white or, for example, uni-colored - printed; It is therefore advantageous if the intermediate layer is made of white fibers or but consists of fibers dyed according to the non-woven cover layer, so that the strength the non-woven cover layer can be further reduced. During the printing process, the intermediate layer acts if it is made of hydrophilic fibers, it is also absorbent and thus increases the security in complicated printing processes, for example with one on top of the other Colours. The intermediate layer fleece also enables concentrated storage of chemicals just below the surface and favors the moisture balance of the top layer or step surface, due to the hydrophilic fiber (antistatic property).

Der erfindungsgemäße Verbundstoff kann weiters, falls dies gewünscht wird, an seiner Oberfläche durch Prägung usw. veredelt werden, wobei die Prägung beispielsweise kalt oder heiß durch Kalandern aufgebracht werden kann; es kann jedoch auch im HF-Feld geprägt werden. Ferner ist es möglich, durch schichtweise Ausbildung der Deckvliesschicht beliebige Farbmusterungen vorzusehen, etwa durch streifige od.dgl. Ausbildung der Deckvliesschicht. The composite of the present invention can further be used if so desired will be refined on its surface by embossing, etc., the embossing can for example be applied cold or hot by calendering; however, it can can also be embossed in the HF field. It is also possible by training in layers to provide any color patterns for the non-woven cover layer, for example by streaky ones or the like. Formation of the cover fleece layer.

Bei der Ausbildung des erfindungsgemäßen Verbundstoffes als Wandbelagsstoff ermöglicht die Vlieszwischenlage, die dann vorzugsweise aus Polyamidfaser hergestellt wird, eine außerordentlich dünne Ober- oder Deckvliesschicht, beispielsweise ebenfalls aus Polyamidfasern. Dabei kann beim Druckprozeß die Zwischenlage aus Polyamidfasern durch die Deckvliesschicht hindurch mit gleicher Echtheit angedruckt werden. In the formation of the composite material according to the invention as a wall covering material allows the fleece intermediate layer, which is then preferably made of polyamide fiber is, an extremely thin top or cover fleece layer, for example also made of polyamide fibers. The intermediate layer made of polyamide fibers can be used during the printing process be printed through the cover fleece layer with the same authenticity.

Die folgenden Beispiele dienen zur weiten Erläuterung der Erfindung, ohne daß diese jedoch hierauf beschränkt ist. The following examples serve to further illustrate the invention, but without this being restricted to this.

B e i s p i e 1 1: Eine Deckvlies- oder Trittschicht aus weißen Polyamidfasern mit 300 bis 350 g/m2 wird mit einer Unterschicht aus bunten Polyester-Faserabfällen mit 300 bis 350 g/m2 unter Zwischenlage eines weißen Zellwollvlieses von 50 g/m2 durch Nadeln verbunden. Danach wird der so erhaltene Verbundstoff mit einer Acrylharzdispersion als Bindemittel beidseits imprägniert und zwischen zwei Walzen abgequetscht, wobei in der hydrophilen Zellwollvlies-Zwischenlage eine hohe Konzentration des Bindemittels und damit eine gute Bindung der genadelten Fasern und hiebei auch eine innige Verankerung der in die Zwischenlage im 7.uge der Vernadelung eingeführten Fasern der Deckvliesschicht erhalten wird. Dabei wird gegenüber vergleichbaren 7Meischichtigen Verbundstoffen für Bodenbeläge eine Gewichtsersparnis von ca. 100 g/m2 in der - teuren - weißen Deckvliesschicht erzielt, wobei dennoch die Farbe der Unterschicht nicht an de Oberfläche durchschlägt.Example 1 1: A cover fleece or tread layer made of white polyamide fibers with 300 to 350 g / m2 is made with an underlayer of colored polyester fiber waste with 300 to 350 g / m2 with a white cellulose fleece of 50 g / m2 in between by Needles connected. The composite material thus obtained is then coated with an acrylic resin dispersion Impregnated as a binder on both sides and squeezed between two rollers, whereby a high concentration of the binder in the hydrophilic cellulose fleece intermediate layer and with it a good binding of the needled fibers and also an intimate anchoring of the fibers of the nonwoven layer introduced into the intermediate layer in the 7th eye of the needling is obtained. Compared to comparable 7-layer composites for floor coverings a weight saving of approx. 100 g / m2 in the - expensive - white Top layer achieved, although the color of the lower layer is not on the surface hits through.

b e i s p i e 1 1 Auf ähnliche Weise wie In Beispiel 1 ein Verbundstoff aus einer Deckvliesschicht aus weißen Polyamidfasern mit 250 g/m², einer Zwischenlage aus einem vorgebundenen weißen cellwollvlies mit 100 gim und aus einer Unterschicht aus buntem Acrylfasernregenerat mit 350 g/m² hergestellt. Auch dieser Verbundstoff weist eine gute Festigkeit und eine textile Oberfläche auf, wobei dennoch, obwohl noch weniger Material für die weiße Oberschicht verwendet wird, ein Durchschlagen der Farbe der Unterschicht verhindert ist.e i s p i e 1 1 In a manner similar to Example 1, a composite from a cover fleece layer made of white polyamide fibers with 250 g / m², an intermediate layer from a pre-bonded white cellular wool fleece with 100 gim and from a lower layer made of colored acrylic fiber regenerated with 350 g / m². This composite too has good strength and a textile surface, but, though Even less material is used for the white top layer, a strike through the color of the underlayer is prevented.

Ebenso wie der Verbundstoff gemäß Beispiel 1 kann dieser Verbundstoff anschließend bedruckt werden.Just like the composite according to Example 1, this composite can can then be printed.

B e i s v e 3 3: Eine melé-goldfarbige Deckvliesschicht aus Polyami@@asern mit 250 g/m2 wird mit einer melé-goldfarbigen Zellwollvlies-Zwischenschicht mit 100 g/m2 und einer Unterschicht aus bunten Polyesterfasern (Neuabgang) mit 350 g/m2 vernadelt; der erhaltene Verbundstoff wird imprägniert und abgequetscht, wonach das Imprägniermittel bzw. Bindemittel vernetzt. Auch hier wird ein optisches Durchschlagen des bunten Fasermaterials der Unterschicht zur Oberfläche verhindert und eine gleichmäßige melé-goldfarbige Farbtönung der Oberfläche des Bodenbelages bzw. Verbundstoffes erhalten.B e i s v e 3 3: A melé-gold colored cover fleece made of polyami @@ asern with 250 g / m2, a melé-gold colored Cellulose fleece intermediate layer with 100 g / m2 and a bottom layer of colored polyester fibers (new disposal) with 350 g / m2 needled; the composite obtained is impregnated and squeezed, after which the impregnating agent or binding agent is crosslinked. Here, too, there is an optical strike through of the colored fiber material of the lower layer to the surface prevents and a uniform Melé-gold-colored tint of the surface of the floor covering or composite material obtain.

B e i s p i e 1 4: Zur Herstellung von Verbundstoffen für Wandbeläge wurden verschiedene Deckvliesschichten aus Nylonfasern im Bereich von 160 bis 200 g/m², 7 bis 15 den, unter Zwischenlage eines Vollbad-imprängnierten Längsvlieses aus Nylonfasern mit 50 g/m 4 bis 7 den, mit einer Unterschicht aus weißen bzw. gefärbten Polyesterfasern (original oder Regenerat) mit 200 g/m2, 6 bis 12 den, durch Nadeln verbunden und anschließend durch Imprägnieren verfestigt. Die erhaltenen Verbundstoffe zeigten trotz der dünnen Deckvliesschicht eine gute Opazität.B e i s p i e 1 4: For the production of composite materials for wall coverings different cover layers of nylon fibers in the range from 160 to 200 g / m², 7 to 15 denier, with a full bath-impregnated longitudinal fleece in between from nylon fibers with 50 g / m 4 to 7 den, with an underlayer of white or colored Polyester fibers (original or regenerated) with 200 g / m2, 6 to 12 den, through needles connected and then solidified by impregnation. The composites obtained showed a good opacity despite the thin cover fleece layer.

B e i s p i e 1 5: Auf ähnliche Weise wie in Beispiel 4 werden Verbundstoffe für Wandbeläge hergestellt, wobei jedoch für die Zwischenlage oder Trennschicht ein vorgebundenes Zellwollvlies, wiederum mit 50 g/m2, verwendet wird. Auch hier wird u.a. ein Durch n der Färbung der Unterschicht zur Oberfläche wirksam verhindert.EXAMPLE 1 5: In a manner similar to Example 4, composites are made Manufactured for wall coverings, however, for the intermediate layer or separating layer a pre-bonded cellulose fleece, again with 50 g / m2, is used. Here too inter alia, a through n the coloring of the underlayer to the surface is effectively prevented.

B e i s p i e 1 6: ähnlich wie in Beispiel 4 und 5 wird ein Verbundstoff aus einer Polyamid-Deckvliesschicht mit 200 g/m2 und einer Unterschicht aus gefärbten Polyesterfasern mit 200 g/m2, jedoch mit einer Trennschicht aus drei Lagen von 16 g-Tissue-Papier als Zwischenschicht, hergestellt. Neben der guten Opazität zeigt auch dieser Verbundstoff eine Oberfläche mit textilem Charakter sowie eine gute Festigkeit.Example 1 6: similar to example 4 and 5, a composite material is used made of a polyamide cover layer with 200 g / m2 and an underlayer made of colored Polyester fibers with 200 g / m2, but with a separating layer of three layers of 16 g-tissue paper as an intermediate layer. In addition to showing good opacity This composite also has a surface with a textile character and a good one Strength.

Claims (4)

P a t e n t a n s p r ü c h e P a t e n t a n s p r ü c h e e ImprAgnierter Verbundstoff, insbesondere für Bodenbeläge, wobei wenigstens eine Deckvliesschicht mit wenigstens einer weiteren Vlies- und/oder Gewebe- bzw. Gewirkelage als Unterschicht vernadelt ist, dadurch gekennzeichnet, daß zwischen der Deckvliesschicht aus vorzugsweise hydrophoben Fasern und der Unterschicht aus vorzugsweise hydrophoben Fasern ein vorgebundenes Vlies als Zwischenlage, vorzugsweise aus hydrophilen Fasern, beispielsweise Zellulosefasern, vorgesehen ist.e Impregnated composite, especially for floor coverings, where at least one cover fleece layer with at least one further fleece and / or fabric or knitted layer is needled as a lower layer, characterized in that between the top layer of preferably hydrophobic fibers and the bottom layer preferably hydrophobic fibers, a pre-bonded fleece as an intermediate layer, preferably made of hydrophilic fibers, for example cellulose fibers, is provided. 2. Verbundstoff nach Anspruch 1, dadurch gekennzeichnet, daß die Zwischenlage aus weißen Fasern besteht.2. Composite according to claim 1, characterized in that the intermediate layer consists of white fibers. 3. Verbundstoff nach Anspruch 1, dadurch gekennzeichnet, daß die Zwischenlage aus entsprechend der Deckvliesschicht gefärbten Fasern besteht.3. Composite according to claim 1, characterized in that the intermediate layer consists of fibers dyed according to the non-woven cover layer. 4. Verfahren zur Herstellung eines Verbundstoffes nach Anspruch,1, dadurch gekennzeichnet, daß zunächst die Unterschicht, die Zwischenlage und die Deckvliesschicht durch Nadeln miteinander verbunden werden, wonach der so erhaltene Verbundstoff mit einem Imprägniermittel bzw. Bindemittel behandelt und schließlich abgequetscht wird, wobei eine höhere Konzentration des Imprägniermittels bzw. Bindemittels in der Zwischenlage als in der Deckvliesschicht und in der Unterschicht herbeigeführt wird.4. A method for producing a composite according to claim 1, characterized in that initially the underlayer, the intermediate layer and the Cover fleece layer are connected to each other by needles, after which the so obtained Composite treated with an impregnating agent or binding agent and finally is squeezed, with a higher Concentration of the impregnating agent or binder in the intermediate layer than in the top layer and in the lower layer is brought about.
DE19752527582 1974-07-10 1975-06-20 Composite floor- or wall-cover - contg non-woven hydrophobic top layer, hydrophilic intermediate- and hydrophobic bottom layer Pending DE2527582A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2490551A1 (en) * 1980-09-20 1982-03-26 Uni Charm Corp NONWOVEN MATERIALS AND PROCESS FOR THEIR MANUFACTURE

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2490551A1 (en) * 1980-09-20 1982-03-26 Uni Charm Corp NONWOVEN MATERIALS AND PROCESS FOR THEIR MANUFACTURE

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