DE2454002A1 - Thermoplastische polybutylenterephthalat-formmassen mit erhoehter zaehigkeit - Google Patents
Thermoplastische polybutylenterephthalat-formmassen mit erhoehter zaehigkeitInfo
- Publication number
- DE2454002A1 DE2454002A1 DE19742454002 DE2454002A DE2454002A1 DE 2454002 A1 DE2454002 A1 DE 2454002A1 DE 19742454002 DE19742454002 DE 19742454002 DE 2454002 A DE2454002 A DE 2454002A DE 2454002 A1 DE2454002 A1 DE 2454002A1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- polybutylene terephthalate
- parts
- unsaturated carboxylic
- polymerizable unsaturated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- -1 POLYBUTYLENE TEREPHTHALATE Polymers 0.000 title claims description 17
- 229920001707 polybutylene terephthalate Polymers 0.000 title claims description 14
- 229920001169 thermoplastic Polymers 0.000 title claims description 6
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 6
- 238000000465 moulding Methods 0.000 title description 12
- 150000001875 compounds Chemical class 0.000 title description 4
- 229920001577 copolymer Polymers 0.000 claims description 16
- 229920000578 graft copolymer Polymers 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 150000001735 carboxylic acids Chemical class 0.000 claims description 10
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 8
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 claims description 6
- 229920001567 vinyl ester resin Polymers 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000003365 glass fiber Substances 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 4
- 239000002318 adhesion promoter Substances 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- 235000007575 Calluna vulgaris Nutrition 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- WRVRNZNDLRUXSW-UHFFFAOYSA-N acetic acid;prop-2-enoic acid Chemical compound CC(O)=O.OC(=O)C=C WRVRNZNDLRUXSW-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012765 fibrous filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742454002 DE2454002A1 (de) | 1974-11-14 | 1974-11-14 | Thermoplastische polybutylenterephthalat-formmassen mit erhoehter zaehigkeit |
| GB44315/75A GB1514300A (en) | 1974-11-14 | 1975-10-28 | Thermoplastic polybutylene terephthalate moulding compositions showing high impact resistance |
| SE7512659A SE7512659L (sv) | 1974-11-14 | 1975-11-11 | Termoplastisk polybutylenteteftalatformmassa med hog seghet |
| FR7534884A FR2291249A1 (fr) | 1974-11-14 | 1975-11-14 | Matiere a mouler thermoplastique a base de polyterephtalate de butylene de resilience accrue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742454002 DE2454002A1 (de) | 1974-11-14 | 1974-11-14 | Thermoplastische polybutylenterephthalat-formmassen mit erhoehter zaehigkeit |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2454002A1 true DE2454002A1 (de) | 1976-05-26 |
Family
ID=5930815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19742454002 Withdrawn DE2454002A1 (de) | 1974-11-14 | 1974-11-14 | Thermoplastische polybutylenterephthalat-formmassen mit erhoehter zaehigkeit |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE2454002A1 (enExample) |
| FR (1) | FR2291249A1 (enExample) |
| GB (1) | GB1514300A (enExample) |
| SE (1) | SE7512659L (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2726256A1 (de) * | 1976-06-09 | 1977-12-22 | Rohm & Haas | Poly(alkylenterephthalat)-zusammensetzung |
| DE102008019804A1 (de) | 2008-04-15 | 2009-10-22 | Kometra Kunststoff-Modifikatoren Und -Additiv Gmbh | Funktionalisierte Ethylenpolymere mit hohem Haftvermögen und Verfahren zu ihrer Herstellung |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2902468A1 (de) * | 1979-01-23 | 1980-07-31 | Bayer Ag | Thermoplastische polyesterformmassen mit hoher zaehigkeit |
| BR8900992A (pt) * | 1988-03-16 | 1989-10-24 | Polyplastics Co | Processo para producao de resina de poliester termoplastico aperfeicoada e resina de poliester termoplastico produzida |
-
1974
- 1974-11-14 DE DE19742454002 patent/DE2454002A1/de not_active Withdrawn
-
1975
- 1975-10-28 GB GB44315/75A patent/GB1514300A/en not_active Expired
- 1975-11-11 SE SE7512659A patent/SE7512659L/xx unknown
- 1975-11-14 FR FR7534884A patent/FR2291249A1/fr active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2726256A1 (de) * | 1976-06-09 | 1977-12-22 | Rohm & Haas | Poly(alkylenterephthalat)-zusammensetzung |
| DE102008019804A1 (de) | 2008-04-15 | 2009-10-22 | Kometra Kunststoff-Modifikatoren Und -Additiv Gmbh | Funktionalisierte Ethylenpolymere mit hohem Haftvermögen und Verfahren zu ihrer Herstellung |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2291249B3 (enExample) | 1978-08-18 |
| GB1514300A (en) | 1978-06-14 |
| FR2291249A1 (fr) | 1976-06-11 |
| SE7512659L (sv) | 1976-05-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0002761B1 (de) | Schlagzähe Polyamidformmassen | |
| DE2454770C2 (de) | Thermoplastische Formmassen mit erhöhter Schlagzähigkeit | |
| DE69408832T2 (de) | Lackierbare olefin-interpolymer zusammensetzungen | |
| DE2242324C3 (de) | Verfahren zur Herstellung von glasverstärkten Polyolefinmassen | |
| EP0001241B1 (de) | Schlagzähe Polyamidmasse und deren Verwendung in Formkörpern | |
| DE69311223T2 (de) | Formbare kristalline Polyesterzusammensetzung | |
| DE2920246A1 (de) | Polyestermasse fuer die herstellung von formkoerpern und die daraus hergestellten formkoerper | |
| DE3877026T2 (de) | Verfahren zur herstellung einer polymerkomposition auf basis eines polyamidharzes. | |
| DE2926778A1 (de) | Mit fasern verstaerkte polyamid-formmassen | |
| DE3238228A1 (de) | Thermoplastische formmasse | |
| DE3780708T2 (de) | Copolyester und zusammensetzungen die diesen enthalten. | |
| CH630657A5 (de) | Hochschlagzaehe thermoplastische formmasse. | |
| DE69118498T2 (de) | Thermoplastische Zusammensetzungen mit verbesserten Entformungseigenschaften | |
| DE2612011A1 (de) | Verfahren zur herstellung von schlagzaehen thermoplastischen formmassen | |
| DE3002985A1 (de) | Modifizierte polyester-zusammensetzungen | |
| DE2740115A1 (de) | Polyestermassen | |
| DE69223410T2 (de) | Polymergemisch | |
| DE29621057U1 (de) | Thermoplastische Formmassen zum Spritzgießen von Formteilen und Spritzguß-Formteil daraus | |
| DE2934763C2 (enExample) | ||
| DE2757296A1 (de) | Verstaerkte thermoplastische zusammensetzungen aus polyesterharzen und glasfasern in kombination mit fein gemahlenem glimmer | |
| DE2454002A1 (de) | Thermoplastische polybutylenterephthalat-formmassen mit erhoehter zaehigkeit | |
| DE69824700T2 (de) | Schlagzähe spritzgussteile aus polyester | |
| DE3248709A1 (de) | Thermoplastische formmasse | |
| DE3040999A1 (de) | Thermoplastische formmassen | |
| DE2703416A1 (de) | Gefuellte polyamidformmassen mit erhoehter zaehigkeit |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8141 | Disposal/no request for examination |