DE2435989C2 - Verfahren zur Herstellung eines verschleißfesten, beschichteten Hartmetallkörpers für Zerspanungszwecke - Google Patents
Verfahren zur Herstellung eines verschleißfesten, beschichteten Hartmetallkörpers für ZerspanungszweckeInfo
- Publication number
- DE2435989C2 DE2435989C2 DE2435989A DE2435989A DE2435989C2 DE 2435989 C2 DE2435989 C2 DE 2435989C2 DE 2435989 A DE2435989 A DE 2435989A DE 2435989 A DE2435989 A DE 2435989A DE 2435989 C2 DE2435989 C2 DE 2435989C2
- Authority
- DE
- Germany
- Prior art keywords
- hard metal
- hard
- base body
- surface layer
- material surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 31
- 239000002184 metal Substances 0.000 title claims description 31
- 238000000034 method Methods 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000003754 machining Methods 0.000 title description 2
- 239000000463 material Substances 0.000 claims description 25
- 239000002344 surface layer Substances 0.000 claims description 12
- 239000010941 cobalt Substances 0.000 claims description 8
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 150000001247 metal acetylides Chemical class 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- 239000001307 helium Substances 0.000 claims description 2
- 229910052734 helium Inorganic materials 0.000 claims description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 150000004767 nitrides Chemical class 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 230000001681 protective effect Effects 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 230000007423 decrease Effects 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 239000010955 niobium Substances 0.000 claims 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 1
- 229910052715 tantalum Inorganic materials 0.000 claims 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 239000010410 layer Substances 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 238000003801 milling Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000007792 gaseous phase Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000005019 vapor deposition process Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12007—Component of composite having metal continuous phase interengaged with nonmetal continuous phase
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12021—All metal or with adjacent metals having metal particles having composition or density gradient or differential porosity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12146—Nonmetal particles in a component
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Powder Metallurgy (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Chemical Vapour Deposition (AREA)
- Physical Vapour Deposition (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2435989A DE2435989C2 (de) | 1974-07-26 | 1974-07-26 | Verfahren zur Herstellung eines verschleißfesten, beschichteten Hartmetallkörpers für Zerspanungszwecke |
| US05/594,224 US3999954A (en) | 1974-07-26 | 1975-07-09 | Hard metal body and its method of manufacture |
| FR7522969A FR2279853A1 (fr) | 1974-07-26 | 1975-07-23 | Element en metal dur, notamment pour la realisation d'outils |
| JP50091019A JPS5917191B2 (ja) | 1974-07-26 | 1975-07-25 | 耐摩耗性被覆を有する切削工具用超硬合金体の製法 |
| GB31302/75A GB1510684A (en) | 1974-07-26 | 1975-07-25 | Hard metal body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2435989A DE2435989C2 (de) | 1974-07-26 | 1974-07-26 | Verfahren zur Herstellung eines verschleißfesten, beschichteten Hartmetallkörpers für Zerspanungszwecke |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2435989A1 DE2435989A1 (de) | 1976-02-05 |
| DE2435989C2 true DE2435989C2 (de) | 1982-06-24 |
Family
ID=5921590
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2435989A Expired DE2435989C2 (de) | 1974-07-26 | 1974-07-26 | Verfahren zur Herstellung eines verschleißfesten, beschichteten Hartmetallkörpers für Zerspanungszwecke |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3999954A (enExample) |
| JP (1) | JPS5917191B2 (enExample) |
| DE (1) | DE2435989C2 (enExample) |
| FR (1) | FR2279853A1 (enExample) |
| GB (1) | GB1510684A (enExample) |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT336905B (de) * | 1975-02-10 | 1977-06-10 | Plansee Metallwerk | Verschleissteil fur die spanabhebende und spanlose formgebung |
| JPS5819736B2 (ja) * | 1975-10-14 | 1983-04-19 | 日本特殊陶業株式会社 | 切削工義用焼結合金 |
| DE2620197C3 (de) * | 1976-05-07 | 1980-08-07 | Maschinenfabrik Augsburg-Nuernberg Ag, 8000 Muenchen | Verfahren zur Wärmebehandlung von Bauteilen aus hochwarmfesten Werkstoffen |
| US4150195A (en) * | 1976-06-18 | 1979-04-17 | Sumitomo Electric Industries, Ltd. | Surface-coated cemented carbide article and a process for the production thereof |
| JPS5328505A (en) * | 1976-08-31 | 1978-03-16 | Fuji Dies Kk | Superhard alloy product and process for production thereof |
| US4120719A (en) * | 1976-12-06 | 1978-10-17 | Sumitomo Electric Industries, Ltd. | Cemented carbonitride alloys containing tantalum |
| DE2717842C2 (de) * | 1977-04-22 | 1983-09-01 | Fried. Krupp Gmbh, 4300 Essen | Verfahren zur Oberflächenbehandlung von gesinterten Hartmetallkörpern |
| DE2722271C3 (de) * | 1977-05-17 | 1979-12-06 | Thyssen Edelstahlwerke Ag, 4000 Duesseldorf | Verfahren zur Herstellung von Werkzeugen durch Verbundsinterung |
| SE406090B (sv) | 1977-06-09 | 1979-01-22 | Sandvik Ab | Belagd hardmetallkropp samt sett att framstalla en dylik kropp |
| JPS546803A (en) * | 1977-06-20 | 1979-01-19 | Amada Co Ltd | Punch |
| US4239536A (en) * | 1977-09-09 | 1980-12-16 | Sumitomo Electric Industries, Ltd. | Surface-coated sintered hard body |
| SE415199B (sv) * | 1977-09-28 | 1980-09-15 | Sandvik Ab | Med borerad ytzon forsedd sintrad hardmetallkropp |
| JPS5823353B2 (ja) * | 1978-05-17 | 1983-05-14 | 住友電気工業株式会社 | 切削工具用焼結体とその製造法 |
| CH632944A5 (fr) * | 1978-06-22 | 1982-11-15 | Stellram Sa | Piece d'usure en metal dur. |
| DE2851584B2 (de) * | 1978-11-29 | 1980-09-04 | Fried. Krupp Gmbh, 4300 Essen | Verbundkörper |
| CA1119850A (en) * | 1978-12-04 | 1982-03-16 | William M. Stoll | Roll for hot forming steel rod |
| SE417618B (sv) * | 1979-01-22 | 1981-03-30 | Sandvik Ab | Hardmetallkropp med slitstarkt ytskikt |
| US4268582A (en) * | 1979-03-02 | 1981-05-19 | General Electric Company | Boride coated cemented carbide |
| GB2063922A (en) * | 1979-11-20 | 1981-06-10 | Metallurg Inc | Sintered hard metals |
| US4359335A (en) * | 1980-06-05 | 1982-11-16 | Smith International, Inc. | Method of fabrication of rock bit inserts of tungsten carbide (WC) and cobalt (Co) with cutting surface wear pad of relative hardness and body portion of relative toughness sintered as an integral composite |
| USRE34180E (en) * | 1981-03-27 | 1993-02-16 | Kennametal Inc. | Preferentially binder enriched cemented carbide bodies and method of manufacture |
| US4610931A (en) * | 1981-03-27 | 1986-09-09 | Kennametal Inc. | Preferentially binder enriched cemented carbide bodies and method of manufacture |
| GB2116584A (en) * | 1982-03-11 | 1983-09-28 | Metallurg Inc | Sintered hardmetals |
| CA1216197A (en) * | 1982-12-29 | 1987-01-06 | Mark F. Mosser | Surface modified powder metal parts and methods for making same |
| US4497874A (en) * | 1983-04-28 | 1985-02-05 | General Electric Company | Coated carbide cutting tool insert |
| US4784923A (en) * | 1985-08-19 | 1988-11-15 | Carboloy Inc. | Hard metal alloy with surface region enriched with tantalum, niobium, vanadium or combinations thereof and methods of making the same |
| CA1313762C (en) * | 1985-11-19 | 1993-02-23 | Sumitomo Electric Industries, Ltd. | Hard sintered compact for a tool |
| SE453202B (sv) * | 1986-05-12 | 1988-01-18 | Sandvik Ab | Sinterkropp for skerande bearbetning |
| USRE35538E (en) * | 1986-05-12 | 1997-06-17 | Santrade Limited | Sintered body for chip forming machine |
| DE3630429C2 (de) * | 1986-09-06 | 1994-07-21 | Metallgesellschaft Ag | Wandelement für Sicherheitsaufbauten |
| US4722405A (en) * | 1986-10-01 | 1988-02-02 | Dresser Industries, Inc. | Wear compensating rock bit insert |
| JPS63125602A (ja) * | 1986-11-12 | 1988-05-28 | Sumitomo Electric Ind Ltd | 工具用硬質合金 |
| US4745033A (en) * | 1987-03-24 | 1988-05-17 | Amax Inc. | Oxidation resistant coatings for molybdenum |
| CA1319497C (en) * | 1988-04-12 | 1993-06-29 | Minoru Nakano | Surface-coated cemented carbide and a process for the production of the same |
| US5310605A (en) * | 1992-08-25 | 1994-05-10 | Valenite Inc. | Surface-toughened cemented carbide bodies and method of manufacture |
| US5368628A (en) * | 1992-12-21 | 1994-11-29 | Valenite Inc. | Articles of ultra fine grained cemented carbide and process for making same |
| US5510193A (en) * | 1994-10-13 | 1996-04-23 | General Electric Company | Supported polycrystalline diamond compact having a cubic boron nitride interlayer for improved physical properties |
| US6478887B1 (en) | 1998-12-16 | 2002-11-12 | Smith International, Inc. | Boronized wear-resistant materials and methods thereof |
| US6638474B2 (en) | 2000-03-24 | 2003-10-28 | Kennametal Inc. | method of making cemented carbide tool |
| ES2280353T3 (es) * | 2000-03-24 | 2007-09-16 | Kennametal Inc. | Herramienta de carburo cementado y metodo de fabricacion. |
| SE0101241D0 (sv) * | 2001-04-05 | 2001-04-05 | Sandvik Ab | Tool for turning of titanium alloys |
| WO2004046262A2 (en) * | 2002-11-15 | 2004-06-03 | University Of Utah | Integral titanium boride coatings on titanium surfaces and associated methods |
| US7163657B2 (en) * | 2003-12-03 | 2007-01-16 | Kennametal Inc. | Cemented carbide body containing zirconium and niobium and method of making the same |
| US7459105B2 (en) * | 2005-05-10 | 2008-12-02 | University Of Utah Research Foundation | Nanostructured titanium monoboride monolithic material and associated methods |
| CN101233256A (zh) * | 2005-08-02 | 2008-07-30 | 本田技研工业株式会社 | 层状铁基合金及其制造方法 |
| US8608592B2 (en) * | 2007-05-16 | 2013-12-17 | Taylor Made Golf Company, Inc. | Coated golf club head/component |
| US20100176339A1 (en) * | 2009-01-12 | 2010-07-15 | Chandran K S Ravi | Jewelry having titanium boride compounds and methods of making the same |
| US8834594B2 (en) | 2011-12-21 | 2014-09-16 | Kennametal Inc. | Cemented carbide body and applications thereof |
| US10336654B2 (en) | 2015-08-28 | 2019-07-02 | Kennametal Inc. | Cemented carbide with cobalt-molybdenum alloy binder |
| DE102019110950A1 (de) | 2019-04-29 | 2020-10-29 | Kennametal Inc. | Hartmetallzusammensetzungen und deren Anwendungen |
| AT522605B1 (de) * | 2019-05-23 | 2021-02-15 | Boehlerit Gmbh & Co Kg | Hartmetalleinsatz |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2765227A (en) * | 1950-12-16 | 1956-10-02 | Sintercast Corp America | Titanium carbide composite material |
| US3171192A (en) * | 1961-09-22 | 1965-03-02 | Vitro Corp Of America | Article and method of fabricating same |
| US3147542A (en) * | 1962-12-13 | 1964-09-08 | Kennametal Inc | Shaping cemented hard metal carbide compositions |
| GB1042711A (enExample) * | 1964-02-10 | |||
| US3647576A (en) * | 1967-12-26 | 1972-03-07 | Suwa Seikosha Kk | Method of hardening sintered cemented carbide compositions by boronizing |
| GB1332451A (en) * | 1969-07-28 | 1973-10-03 | Metro Cutanit Ltd | Cemented carbide materials |
| US3736107A (en) * | 1971-05-26 | 1973-05-29 | Gen Electric | Coated cemented carbide product |
| DE2139738C3 (de) * | 1971-08-07 | 1974-03-07 | Deutsche Edelstahlwerke Gmbh, 4150 Krefeld | Dichtelement |
-
1974
- 1974-07-26 DE DE2435989A patent/DE2435989C2/de not_active Expired
-
1975
- 1975-07-09 US US05/594,224 patent/US3999954A/en not_active Expired - Lifetime
- 1975-07-23 FR FR7522969A patent/FR2279853A1/fr active Granted
- 1975-07-25 GB GB31302/75A patent/GB1510684A/en not_active Expired
- 1975-07-25 JP JP50091019A patent/JPS5917191B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5917191B2 (ja) | 1984-04-19 |
| GB1510684A (en) | 1978-05-10 |
| JPS5137808A (enExample) | 1976-03-30 |
| US3999954A (en) | 1976-12-28 |
| DE2435989A1 (de) | 1976-02-05 |
| FR2279853B1 (enExample) | 1981-08-07 |
| FR2279853A1 (fr) | 1976-02-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| D2 | Grant after examination | ||
| 8363 | Opposition against the patent | ||
| 8330 | Complete disclaimer |