DE2428929B2 - Verfahren zur Behandlung von wäßrigen Suspensionen - Google Patents
Verfahren zur Behandlung von wäßrigen SuspensionenInfo
- Publication number
- DE2428929B2 DE2428929B2 DE2428929A DE2428929A DE2428929B2 DE 2428929 B2 DE2428929 B2 DE 2428929B2 DE 2428929 A DE2428929 A DE 2428929A DE 2428929 A DE2428929 A DE 2428929A DE 2428929 B2 DE2428929 B2 DE 2428929B2
- Authority
- DE
- Germany
- Prior art keywords
- particles
- added
- suspension
- ppm
- flocculant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims description 25
- 239000007900 aqueous suspension Substances 0.000 title claims description 4
- 239000002245 particle Substances 0.000 claims description 75
- 239000007787 solid Substances 0.000 claims description 40
- 239000000725 suspension Substances 0.000 claims description 31
- 239000007788 liquid Substances 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 11
- 239000008394 flocculating agent Substances 0.000 claims description 10
- 239000003153 chemical reaction reagent Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 6
- 239000008187 granular material Substances 0.000 claims description 5
- 238000005345 coagulation Methods 0.000 claims description 4
- 230000015271 coagulation Effects 0.000 claims description 4
- 230000005484 gravity Effects 0.000 claims description 4
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 4
- 150000004692 metal hydroxides Chemical class 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 2
- 239000012141 concentrate Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 44
- 238000005469 granulation Methods 0.000 description 15
- 230000003179 granulation Effects 0.000 description 15
- 239000011361 granulated particle Substances 0.000 description 14
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 230000002093 peripheral effect Effects 0.000 description 8
- 238000001556 precipitation Methods 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000010802 sludge Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 229920002401 polyacrylamide Polymers 0.000 description 6
- 239000004576 sand Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 229940037003 alum Drugs 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- 239000010419 fine particle Substances 0.000 description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 3
- 238000005352 clarification Methods 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 3
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000012798 spherical particle Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000005189 flocculation Methods 0.000 description 2
- 230000016615 flocculation Effects 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000014413 iron hydroxide Nutrition 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 2
- 229940085991 phosphate ion Drugs 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- -1 acrylamido Chemical group 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 208000001848 dysentery Diseases 0.000 description 1
- 229960004887 ferric hydroxide Drugs 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- GBSRRQISIWGCNC-UHFFFAOYSA-N methyl propane-1-sulfonate Chemical compound CCCS(=O)(=O)OC GBSRRQISIWGCNC-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/0018—Separation of suspended solid particles from liquids by sedimentation provided with a pump mounted in or on a settling tank
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/01—Separation of suspended solid particles from liquids by sedimentation using flocculating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/02—Settling tanks with single outlets for the separated liquid
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5281—Installations for water purification using chemical agents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Removal Of Specific Substances (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4077974A JPS5244753B2 (US07608600-20091027-C00054.png) | 1974-04-10 | 1974-04-10 | |
JP4078074A JPS5215471B2 (US07608600-20091027-C00054.png) | 1974-04-10 | 1974-04-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE2428929A1 DE2428929A1 (de) | 1975-10-23 |
DE2428929B2 true DE2428929B2 (de) | 1980-03-27 |
Family
ID=26380295
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE2428929A Withdrawn DE2428929B2 (de) | 1974-04-10 | 1974-06-15 | Verfahren zur Behandlung von wäßrigen Suspensionen |
Country Status (10)
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2739715A1 (de) * | 1976-09-03 | 1978-03-16 | Elf Aquitaine | Verfahren zur behandlung von schlammrueckstaenden von erdbohrungen |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2721298C3 (de) * | 1977-05-12 | 1979-10-25 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zum Reinigen phosphathaltiger Abwasser |
NL187312C (nl) * | 1978-05-18 | 1991-08-16 | Dhv Raadgevend Ing | Werkwijze voor het defosfateren van water. |
NL7905111A (nl) * | 1979-06-30 | 1981-01-05 | Stamicarbon | Werkwijze voor het chemisch verwijderen van fosfor- verbindingen uit afvalwater en werkwijze voor het zuiveren van afvalwater. |
US4382864A (en) * | 1980-08-08 | 1983-05-10 | Kurita Water Industries Ltd. | Process for dewatering sludges |
US4507206A (en) * | 1982-07-19 | 1985-03-26 | Hughes Geoffrey F | Method for restoring and maintaining eutrophied natural bodies of waters |
IT1184932B (it) * | 1985-03-27 | 1987-10-28 | Luigi Verde | Procedimento perfezionato per la depurazione delle acque mediante chiariflocculazione |
NL8700498A (nl) * | 1987-02-27 | 1988-09-16 | Dhv Raadgevend Ing | Werkwijze voor de verwijdering van zware metalen uit afvalwater. |
BE1004101A3 (nl) * | 1990-12-05 | 1992-09-22 | Treat Tech For Sludges N V Afg | Werkwijze voor het verwerken van drijfmest tot een vast produkt. |
US5302295A (en) * | 1992-12-29 | 1994-04-12 | Ywc Technologies | Method of sludge removal |
EP0728705A3 (en) * | 1995-02-22 | 1997-04-09 | Calgon Corp | Method of using new polymer compositions with high solid content as flocculating agents |
US5993663A (en) * | 1998-07-09 | 1999-11-30 | Ona Electro-Erosion, S.A. | Liquid filtering system in machine tools |
JP5700080B2 (ja) * | 2013-07-02 | 2015-04-15 | 栗田工業株式会社 | カチオン界面活性剤含有排水の処理方法及び処理装置 |
CA3035940A1 (en) * | 2016-09-26 | 2018-03-29 | Heritage Research Group, Llc | Treatment of sludges and flocculants using insoluble mineral colloidal suspensions |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3171800A (en) * | 1962-10-23 | 1965-03-02 | Gen Services Company | Process for removing iron and manganese from water |
US3403096A (en) * | 1963-10-02 | 1968-09-24 | Ceskoslovenska Akademie Ved | Method and device for separation of a suspension |
US3388060A (en) * | 1964-07-29 | 1968-06-11 | Parsons Brinckerhoff Quade & D | Process and composition for purification of water supplies and aqueous wastes |
US3350302A (en) * | 1964-09-16 | 1967-10-31 | Nikex Nehezipari Kulkere | Clarification of surface waters |
US3377274A (en) * | 1965-01-05 | 1968-04-09 | Nalco Chemical Co | Method of coagulation of low turbidity water |
US3481868A (en) * | 1967-10-31 | 1969-12-02 | Pall Corp | Water clarifier and water clarification method |
JPS4626272Y1 (US07608600-20091027-C00054.png) * | 1968-08-26 | 1971-09-09 | ||
US3579443A (en) * | 1969-07-31 | 1971-05-18 | Russell J Horst | Formation of dense precipitates |
US3637491A (en) * | 1969-11-03 | 1972-01-25 | Monsanto Co | Clarification of water |
US3660284A (en) * | 1970-04-09 | 1972-05-02 | Kreske Walter J | Method for water and wastewater treatment |
US3642619A (en) * | 1970-08-31 | 1972-02-15 | Calgon Corp | Conditioning sewage waste sludges for dewatering |
CA962386A (en) * | 1971-04-13 | 1975-02-04 | Canadair Limited | Liquid treatment plant and process particularly for waste water |
-
1974
- 1974-06-12 ES ES427238A patent/ES427238A1/es not_active Expired
- 1974-06-12 GB GB2610074A patent/GB1478345A/en not_active Expired
- 1974-06-14 NL NL7407986A patent/NL7407986A/xx not_active Application Discontinuation
- 1974-06-14 IT IT23990/74A patent/IT1017016B/it active
- 1974-06-14 CA CA202,508A patent/CA1039865A/en not_active Expired
- 1974-06-14 FR FR7420843A patent/FR2267141B1/fr not_active Expired
- 1974-06-14 HU HU74EA136A patent/HU178514B/hu unknown
- 1974-06-14 CH CH820474A patent/CH604839A5/xx not_active IP Right Cessation
- 1974-06-15 DE DE2428929A patent/DE2428929B2/de not_active Withdrawn
-
1976
- 1976-05-13 US US05/686,195 patent/US4046683A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2739715A1 (de) * | 1976-09-03 | 1978-03-16 | Elf Aquitaine | Verfahren zur behandlung von schlammrueckstaenden von erdbohrungen |
Also Published As
Publication number | Publication date |
---|---|
AU6960374A (en) | 1975-12-04 |
NL7407986A (nl) | 1975-10-14 |
DE2428929A1 (de) | 1975-10-23 |
ES427238A1 (es) | 1976-09-16 |
US4046683A (en) | 1977-09-06 |
GB1478345A (en) | 1977-06-29 |
FR2267141A1 (US07608600-20091027-C00054.png) | 1975-11-07 |
CA1039865A (en) | 1978-10-03 |
CH604839A5 (US07608600-20091027-C00054.png) | 1978-09-15 |
FR2267141B1 (US07608600-20091027-C00054.png) | 1980-09-12 |
IT1017016B (it) | 1977-07-20 |
HU178514B (en) | 1982-05-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
OI | Miscellaneous see part 1 | ||
OI | Miscellaneous see part 1 | ||
8230 | Patent withdrawn |