DE2305149A1 - Verfahren zur herstellung von trinatrium- bzw. trikaliumcitrat - Google Patents
Verfahren zur herstellung von trinatrium- bzw. trikaliumcitratInfo
- Publication number
- DE2305149A1 DE2305149A1 DE2305149A DE2305149A DE2305149A1 DE 2305149 A1 DE2305149 A1 DE 2305149A1 DE 2305149 A DE2305149 A DE 2305149A DE 2305149 A DE2305149 A DE 2305149A DE 2305149 A1 DE2305149 A1 DE 2305149A1
- Authority
- DE
- Germany
- Prior art keywords
- citrate
- alkaline earth
- solution
- citric acid
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 239000001508 potassium citrate Substances 0.000 title description 11
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 title description 11
- 229960002635 potassium citrate Drugs 0.000 title description 2
- 235000011082 potassium citrates Nutrition 0.000 title description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 78
- 239000003513 alkali Substances 0.000 claims description 20
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 18
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 12
- 238000000855 fermentation Methods 0.000 claims description 9
- 230000004151 fermentation Effects 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- -1 alkaline earth metal citrate Chemical class 0.000 claims description 8
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 claims description 8
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 6
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 6
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 6
- 235000011181 potassium carbonates Nutrition 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 229940072033 potash Drugs 0.000 claims description 5
- 235000015320 potassium carbonate Nutrition 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims 2
- 239000004020 conductor Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 35
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 15
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 12
- 239000001354 calcium citrate Substances 0.000 description 12
- 235000013337 tricalcium citrate Nutrition 0.000 description 12
- 150000001860 citric acid derivatives Chemical class 0.000 description 10
- 239000001509 sodium citrate Substances 0.000 description 10
- 235000015870 tripotassium citrate Nutrition 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- 239000006227 byproduct Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 5
- 229940038773 trisodium citrate Drugs 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000007900 aqueous suspension Substances 0.000 description 4
- 235000010216 calcium carbonate Nutrition 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 239000013067 intermediate product Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- DBERGLNNXHLATL-UHFFFAOYSA-N [Ba].[C] Chemical compound [Ba].[C] DBERGLNNXHLATL-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- YFPHTCQIAVMAJR-UHFFFAOYSA-L azanium;calcium;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [NH4+].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YFPHTCQIAVMAJR-UHFFFAOYSA-L 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229940006612 barium citrate Drugs 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- PAVWOHWZXOQYDB-UHFFFAOYSA-H barium(2+);2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O PAVWOHWZXOQYDB-UHFFFAOYSA-H 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000020438 lemon syrup Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- HRJXMHAOFRMRCR-UHFFFAOYSA-J tetrasodium 2-hydroxypropane-1,2,3-tricarboxylate hydroxide Chemical compound [OH-].[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRJXMHAOFRMRCR-UHFFFAOYSA-J 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT90672A AT315817B (de) | 1972-02-04 | 1972-02-04 | Verfahren zur Herstellung von Trinatrium- bzw. Trikaliumzitraten |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2305149A1 true DE2305149A1 (de) | 1973-08-09 |
| DE2305149B2 DE2305149B2 (enrdf_load_stackoverflow) | 1979-08-30 |
Family
ID=3502562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2305149A Ceased DE2305149A1 (de) | 1972-02-04 | 1973-02-02 | Verfahren zur herstellung von trinatrium- bzw. trikaliumcitrat |
Country Status (12)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0694937A2 (de) | 1994-07-29 | 1996-01-31 | Siemens Aktiengesellschaft | Verfahren zur Bestimmung der Restlebensdauer von Kontakten in Schaltgeräten und zugehörige Anordnung |
| EP0747340A1 (de) * | 1995-06-06 | 1996-12-11 | Jungbunzlauer Ges.m.b.H. | Wasserfreies Trinatriumcitrat, Verfahren zu seiner Herstellung und seine Verwendung als Trägermaterial |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4400535A (en) * | 1980-01-17 | 1983-08-23 | Dr. Madaus & Co. | Acidic alkali citrate and compositions for adjusting the pH of urine |
| CN105061196B (zh) * | 2015-09-15 | 2017-05-17 | 安徽丰原发酵技术工程研究有限公司 | 一种从柠檬酸钾末道母液中提纯柠檬酸钾的方法 |
| CN111909032B (zh) * | 2020-08-07 | 2023-04-14 | 日照金禾博源生化有限公司 | 一种不合格柠檬酸钠母液的处理方法 |
-
0
- BE BE794726D patent/BE794726A/xx not_active IP Right Cessation
-
1972
- 1972-02-04 AT AT90672A patent/AT315817B/de not_active IP Right Cessation
-
1973
- 1973-01-29 GB GB442173A patent/GB1384194A/en not_active Expired
- 1973-01-30 CH CH130673A patent/CH570352A5/xx not_active IP Right Cessation
- 1973-01-31 CA CA162,508A patent/CA997782A/en not_active Expired
- 1973-02-02 US US00329240A patent/US3819696A/en not_active Expired - Lifetime
- 1973-02-02 FR FR7303817A patent/FR2170235B1/fr not_active Expired
- 1973-02-02 JP JP1365673A patent/JPS544930B2/ja not_active Expired
- 1973-02-02 NL NL7301519A patent/NL7301519A/xx unknown
- 1973-02-02 BR BR73826A patent/BR7300826D0/pt unknown
- 1973-02-02 DE DE2305149A patent/DE2305149A1/de not_active Ceased
- 1973-02-05 IT IT734806Q patent/IT977199B/it active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0694937A2 (de) | 1994-07-29 | 1996-01-31 | Siemens Aktiengesellschaft | Verfahren zur Bestimmung der Restlebensdauer von Kontakten in Schaltgeräten und zugehörige Anordnung |
| DE4427006A1 (de) * | 1994-07-29 | 1996-02-01 | Siemens Ag | Verfahren zur Bestimmung der Restlebensdauer von Kontakten in Schaltgeräten und zugehörige Anordnung |
| EP0747340A1 (de) * | 1995-06-06 | 1996-12-11 | Jungbunzlauer Ges.m.b.H. | Wasserfreies Trinatriumcitrat, Verfahren zu seiner Herstellung und seine Verwendung als Trägermaterial |
Also Published As
| Publication number | Publication date |
|---|---|
| AT315817B (de) | 1974-06-10 |
| FR2170235A1 (enrdf_load_stackoverflow) | 1973-09-14 |
| US3819696A (en) | 1974-06-25 |
| FR2170235B1 (enrdf_load_stackoverflow) | 1976-05-14 |
| JPS4881815A (enrdf_load_stackoverflow) | 1973-11-01 |
| JPS544930B2 (enrdf_load_stackoverflow) | 1979-03-12 |
| IT977199B (it) | 1974-09-10 |
| BR7300826D0 (pt) | 1973-09-20 |
| BE794726A (fr) | 1973-05-16 |
| GB1384194A (en) | 1975-02-19 |
| CA997782A (en) | 1976-09-28 |
| AU5163273A (en) | 1974-08-01 |
| NL7301519A (enrdf_load_stackoverflow) | 1973-08-07 |
| DE2305149B2 (enrdf_load_stackoverflow) | 1979-08-30 |
| CH570352A5 (enrdf_load_stackoverflow) | 1975-12-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8235 | Patent refused |