DE2151397A1 - PROCESS FOR THE MANUFACTURING OF COMPRESSED LAMINATED PANELS FROM HARD PAPER PROVIDED WITH DECORATED SHEETS - Google Patents
PROCESS FOR THE MANUFACTURING OF COMPRESSED LAMINATED PANELS FROM HARD PAPER PROVIDED WITH DECORATED SHEETSInfo
- Publication number
- DE2151397A1 DE2151397A1 DE19712151397 DE2151397A DE2151397A1 DE 2151397 A1 DE2151397 A1 DE 2151397A1 DE 19712151397 DE19712151397 DE 19712151397 DE 2151397 A DE2151397 A DE 2151397A DE 2151397 A1 DE2151397 A1 DE 2151397A1
- Authority
- DE
- Germany
- Prior art keywords
- sheets
- impregnated
- decorative
- press
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B29/005—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/0469—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/10—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/06—Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B43/00—Operations specially adapted for layered products and not otherwise provided for, e.g. repairing; Apparatus therefor
- B32B43/006—Delaminating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/06—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/028—Paper layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/10—Fibres of continuous length
- B32B2305/18—Fabrics, textiles
- B32B2305/188—Woven fabrics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2315/00—Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
- B32B2315/08—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/02—Cork
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/12—Paper, e.g. cardboard
- B32B2317/125—Paper, e.g. cardboard impregnated with thermosetting resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/16—Wood, e.g. woodboard, fibreboard, woodchips
Landscapes
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
Description
OZ 71099OZ 71099
DYNAMIT NOBEL AKTIENGESELLSCHAFT Troisdorf Bez. KölnDYNAMIT NOBEL AKTIENGESELLSCHAFT Troisdorf Bez. Cologne
Terfahren zur Herstellung von Schichtpreßstoffplatten aus mitTerfahren for the production of laminated panels from with
■ ■ Dekorbögen versehenen Hartpapieren.■ ■ hard paper with decorative sheets.
Der Gegenstand der Erfindung bezieht sich auf ein Verfahren zur Herstellung von Schichtpreßstoffplatten aus mit an der oberen ; Seite mit Dekorbögen versehenen Hartpapieren mit rauher Oberfläche auf der Basis von mit Vorkondensaten von Duroplasten impräg-,nierten Cellulosebahnen durch Heißverpressen in einer Presse, wobei als Dekorbögen solche nach Art von Rauhfasertapeten verwenidet werden und zwei Schichtfolgen des herzustellenden Hartpapiers spiegelbildlich mit den später oberen Seiten gegeneinander in die Presse eingelegt werden, und die Schichtfolgen durch, einen bis 'drei Trennbögen voneinander isoliert sind und wobei die Rauhung der Dekorbögen aus Holz-, Glas-, Stroh-, Metall-, Kork- oder Textilfaserteilchen oder Geweben besteht, nach Patent ........The object of the invention relates to a method for the production of laminated panels from with at the top ; Side with decorative sheets provided with hard paper with a rough surface on the basis of impregnated with precondensates of thermosets Cellulose webs by hot pressing in a press, with decorative sheets such as woodchip wallpaper being used and two layer sequences of the hard paper to be produced are mirror images with the later upper sides against each other in the Press are inserted, and the layer sequences are isolated from one another by 'one to' three separating sheets and the roughening the decor sheets consists of wood, glass, straw, metal, cork or textile fiber particles or fabrics, according to patent ........
(Patentanmeldung P 20 14 952.4).(Patent application P 20 14 952.4).
Bei der Herstellung von Hartpapier in Gestalt von Schichtpreßstoff platten, die durch Heißverpressen von mehreren Lagen aus mit Vorkondensaten von Duroplasten imprägnierten Oellulosebahnen hergestellt werden, ist es bekannt, als Deckschicht auf der Ober' seite einen Dekorbogen einzulegen. Als Dekorbogen kommen z.B« mit Melaminharg getränkte Cellulosebahnen in Jrage, die versohle«In the manufacture of hard paper in the form of laminate Sheets that are made by hot pressing of several layers with precondensates of thermosetting plastics it is known as a top layer on the top ' side to insert a decal sheet. As a decal sheet come e.g. cellulose sheets impregnated with melamine harg in jrage, the sole "
3Q9817/QSU3Q9817 / QSU
j -2- 215139?j -2- 215139?
I den eingefärbt sein können. Solche Dekorbögen ermöglichen jedoch inur eine glatte Oberfläche. Eine rauhe Oberfläche konnte bisher ' lediglich durch Verwendung bzw. Einsatz einer mit einer entspre-I can be colored. Such decals make it possible, however in only a smooth surface. A rough surface could so far '' only by using or deploying one with a corresponding
! chenden Struktur ausgebildeten Preßplatte erzeugt werden.! corresponding structure formed press plate are generated.
j In dem Hauptpatent ..... (Patentanmeldung P 20 14 952.4) ist nunj In the main patent ..... (patent application P 20 14 952.4) is now
I ein Verfahren beschrieben, wonach strukturierte, d.h. rauhe Oberflächen von geschichteten Hartpapieren ohne Einsatz von strukturgebenden Preßplatten hergestellt werden können. Dieses Verfahren geht davon aus, daß zwei Schichtpreßstoffplatten spiegelbildlich in einem Arbeitsgang zwischen zwei Preßplatten einer Presse hergestellt werden, wobei die die Struktur enthaltenden Dekorbögen auf der die Oberseite der Schichtpreßstoffplatte bildenden Seite mittels Trennbögen spiegelbildlich aufeinander folgen.I described a method according to which structured, i.e. rough surfaces can be produced from layered hard papers without the use of structuring press plates. This method assumes that two laminate plates are produced in mirror image in one operation between two pressing plates of a press the decor sheets containing the structure on the side forming the top of the laminate follow one another in mirror image using separating sheets.
Die vorliegende Erfindung befaßt sich mit der WeiterentwicklungThe present invention is concerned with further development
j 'j '
' des in dem Hauptpatent .... (Patentanmeldung P 20 14 952.4) vorgeschlagenen Verfahrens zur Herstellung mit strukturierter'in the main patent .... (patent application P 20 14 952.4) proposed method for manufacturing with structured
i Oberfläche ausgestatteter Schichtpreßstoffplatten. Erfindungsge-i Surface of equipped laminate panels. Inventive
j maß wird vorgeschlagen, daß die die Rauhung bewirkenden Struktureinlagen getrennt von dem die Oberseite bildenden aus mitj measure it is proposed that the roughening effecting structural inlays separated from the one forming the top with
beispielsweise Melaminharz getränkten Gellulosebahnen bestehenden Dekorbögen innerhalb der Schichtpreßstoffplatte angeordnet , werden. Auf diese Y/eise ist es möglich, die Struktur unabhängig von den die Oberseite, d.h. die Deckfläche bildenden Dekcrbogen und dessen Eigenschaften, wie Farbmusterung usw., zu gestalten. Der wesentliche Vorteil des erfindungsgemäßen Verfahrens ist u.a. darin zu sehen, daß die Strukturierung der Oberfläche der Schicht-for example melamine resin impregnated cellulose sheets Decorative sheets are arranged within the laminate sheet. In this way it is possible to make the structure independent of the decorative arches forming the upper side, i.e. the top surface, and its properties, such as color patterns, etc. The main advantage of the method according to the invention is, among other things, that the structuring of the surface of the layer
309817/0947309817/0947
preßstoffplatte von innen her, d.h. durch den Schichtaufbau, erfolgt und nicht, wie bei den bekannten Verfahren durch Aufdrücken eines Musters von außen. Dies hat auch zur Folge, daß die Struktur weichere Übergänge durch die darüberliegende Schicht bzw. Schichten auf der Oberfläche erzeugt.pressed board from the inside, i.e. through the layer structure and not, as in the known methods, by printing on a pattern from the outside. This also has the consequence that the structure softer transitions produced by the overlying layer or layers on the surface.
In Weiterführung der Erfindung wird vorgeschlagen, die Struktureinlage zwischen dem Dekorbogen und den Kernpapierbögen einzulegen. Nach einem v/eiteren Vorschlag der Erfindung wird so verfahren, daß zwischen der Struktureinlage und dem Dekorbogen ein oder mehrere Kernpapierbögen vorgesehen werden. Je tiefer die Struktureinlage in dem Schichtpreßstoffplattenaufbau eingesetzt wird, desto schwächer wird einerseits die vermittelte Oberflächenstruktur, da sich die eingebauten Strukturkörper weniger stark durchdrücken können, andererseits wirkt dabei die Oberfläche weich und harmonisch, ohne allzu starke Dehnung. Es ist jedoch möglich, relativ starke Strukturkörper einzubauen, die je nach Tiefe des Einbaus eine mehr oder weniger starke Strukturierung erzeugen. In a further development of the invention, it is proposed that the structural insert to be inserted between the decal sheet and the core paper sheets. According to a further proposal of the invention, the procedure is that between the structural insert and the decal sheet or several core paper sheets are provided. The deeper the structural insert is used in the laminate structure on the one hand, the weaker the conveyed surface structure becomes, as the built-in structural bodies cannot push themselves through as much, on the other hand, the surface has an effect soft and harmonious, without excessive stretching. However, it is possible to build in relatively strong structural bodies, depending on the Depth of the installation produce a more or less strong structure.
Die für den Einbau in die Schichtpreßstoffplatte verwendeten Struktureinlagen können entweder in ihrem naturbelassenen Zustand oder aber beharzt, z.B. mit Melaminharz imprägniert, eingesetzt werden.The structural inserts used for installation in the laminate board can either be left in their natural state or with a resin, e.g. impregnated with melamine resin.
Die Erfindung ist in der Zeichnung in Ausführungsbeispielen dargestellt und wird anhand dieser näher erläutert. Es zeigen:The invention is shown in the drawing in exemplary embodiments and is explained in more detail on the basis of this. Show it:
309817/09Λ7309817 / 09Λ7
Pig. I und Pig. II Verschiedene Schichtaufbauten zum Herstellen von Hartpapier nach dem erfindungsgemäßen Verfahren.Pig. I and Pig. II Different layer structures for the production of hard paper according to the invention Procedure.
Zwischen zwei nicht dargestellten Preßplatten einer Mehretagenpresse zum Verpressen der Bögen su einer Schichtpreßstoffplatte werden nacheinander folgende Schichten aufgebracht: Pünf Kernpapierbögen 1a bis 1e z.B. aus Hatron-Kraftpapier, das mit Phenolharz imprägniert ist, darauf wird die Struktureinlage 2, beispielsweise ein grobes Textilgewebe, gelegt, abschließend folgt dann der Dekorbogen 3 au3 einer mit Melaminharz getränkten CeI-lulosebahn, die die Oberseite der fertigen Schichtpreßstoffplatte bilden soll. Spiegelbildlich ist darauffolgend unter Zwischenlage der Trenneinlage 4, z.B. einer Cellulosebahn, die mit einem Trennmittel, wie Türkischrotöl, Seife oder einem Siliconöl oder einem Siliconharz imprägniert ist, aufgebaut. Nach dem Heißverpressen in der Hehretagenpresse werden die Schichtpreßstoffplatten aus der Presse entfernt und die Trenneinlage 4 wird entfernt. Die so mittels eines Preßvorganges erhaltenen zwei Schichtpreßstoffplatten v/eisen auf ihrer Oberseite 3 eine entsprechend der Struktureinlage 2 ausgebildete Oberfläche auf.Between two press plates, not shown, of a multi-daylight press For pressing the sheets on a laminate sheet, the following layers are applied one after the other: Five core paper sheets 1a to 1e e.g. made of Hatron Kraft paper with phenolic resin is impregnated, the structural insert 2, for example a coarse textile fabric, is placed on it, and finally follows Then the decal sheet 3 consists of a melamine resin-soaked cellulose sheet, which is the top of the finished laminate board should form. The mirror image is then with the interposition of the separating insert 4, e.g. a cellulose web with a Release agent, such as Turkish red oil, soap or a silicone oil or a silicone resin is impregnated. After hot pressing The laminate panels are in the high-floor press removed from the press and the separator 4 is removed. The two laminated panels obtained in this way by means of a pressing process On its upper side 3, iron has a surface configured in accordance with the structural insert 2.
Das Ausführungsbeispiel nach 3?ig. II zeigt den Schichtaufbau zwischen zwei nicht gezeigten Preßplatten, wobei die Struktureinlage 2 tiefer innerhalb der gesamten Schichtpreßstoffplatte zwischen den Kernpapiereinlagen 1b und 1c angeordnet ist. Auf diese Weise lassen sich je nach Wunsch mehr oder weniger starkThe exemplary embodiment according to FIG. 3. II shows the layer structure between two press plates, not shown, the structural insert 2 being deeper within the entire laminate plate is arranged between the core paper inlays 1b and 1c. In this way you can be more or less strong depending on your preference
303817/0947303817/0947
strukturierte Oberflächen von Schichtpreßstoffplatten erzielen. Die Struktureinlage kann je nach Y/unsch beharzt oder unbeharzt eingesetzt v/erden.achieve structured surfaces of laminated panels. The structural insert can be used with or without resin, depending on the Y /.
309817/0 94309817/0 94
Claims (4)
OZ 71099 MG/RoTroisdorf, the October 8, 1971
OZ 71099 MG / Ro
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19712151397 DE2151397A1 (en) | 1971-10-15 | 1971-10-15 | PROCESS FOR THE MANUFACTURING OF COMPRESSED LAMINATED PANELS FROM HARD PAPER PROVIDED WITH DECORATED SHEETS |
IT53310/72A IT966290B (en) | 1971-10-15 | 1972-10-11 | PROCEDURE FOR THE PRODUCTION OF LAMINATE PANELS CONSISTING OF STRONG PAPER FITTED WITH ORNAMENTAL SHEETS |
GB4747772A GB1407052A (en) | 1971-10-15 | 1972-10-13 | Laminated board production |
FR7236257A FR2156320B1 (en) | 1971-10-15 | 1972-10-13 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19712151397 DE2151397A1 (en) | 1971-10-15 | 1971-10-15 | PROCESS FOR THE MANUFACTURING OF COMPRESSED LAMINATED PANELS FROM HARD PAPER PROVIDED WITH DECORATED SHEETS |
Publications (1)
Publication Number | Publication Date |
---|---|
DE2151397A1 true DE2151397A1 (en) | 1973-04-26 |
Family
ID=5822435
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19712151397 Pending DE2151397A1 (en) | 1971-10-15 | 1971-10-15 | PROCESS FOR THE MANUFACTURING OF COMPRESSED LAMINATED PANELS FROM HARD PAPER PROVIDED WITH DECORATED SHEETS |
Country Status (4)
Country | Link |
---|---|
DE (1) | DE2151397A1 (en) |
FR (1) | FR2156320B1 (en) |
GB (1) | GB1407052A (en) |
IT (1) | IT966290B (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1983002256A1 (en) * | 1981-12-24 | 1983-07-07 | William Duncan Baggett | Method of mounting photographic prints |
DE4407620A1 (en) * | 1993-11-13 | 1995-05-18 | Roemmler H Resopal Werk Gmbh | Laminated sheet |
SE516696C2 (en) | 1999-12-23 | 2002-02-12 | Perstorp Flooring Ab | Process for producing surface elements comprising an upper decorative layer as well as surface elements produced according to the method |
SE0101620D0 (en) | 2001-05-10 | 2001-05-10 | Pergo Ab | Embossed decorative boards |
SE527472C2 (en) * | 2003-11-25 | 2006-03-14 | Pergo Europ Ab | Process for making decorative surface elements with a surface structure |
EP2189298B8 (en) * | 2008-11-25 | 2013-01-23 | Cleaf S.p.A. | A method of producing decorative panels or laminates with fabrics |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1047020A (en) * | 1963-06-28 | 1966-11-02 | Formica Int | Separation of laminated products |
-
1971
- 1971-10-15 DE DE19712151397 patent/DE2151397A1/en active Pending
-
1972
- 1972-10-11 IT IT53310/72A patent/IT966290B/en active
- 1972-10-13 FR FR7236257A patent/FR2156320B1/fr not_active Expired
- 1972-10-13 GB GB4747772A patent/GB1407052A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR2156320B1 (en) | 1976-05-21 |
FR2156320A1 (en) | 1973-05-25 |
IT966290B (en) | 1974-02-11 |
GB1407052A (en) | 1975-09-24 |
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