DE2139686A1 - Feinteilige expandierbare styrolpolymerisate - Google Patents
Feinteilige expandierbare styrolpolymerisateInfo
- Publication number
- DE2139686A1 DE2139686A1 DE2139686A DE2139686A DE2139686A1 DE 2139686 A1 DE2139686 A1 DE 2139686A1 DE 2139686 A DE2139686 A DE 2139686A DE 2139686 A DE2139686 A DE 2139686A DE 2139686 A1 DE2139686 A1 DE 2139686A1
- Authority
- DE
- Germany
- Prior art keywords
- expandable styrene
- expandable
- coating
- styrene polymers
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims description 62
- 229920000642 polymer Polymers 0.000 claims description 32
- 239000011248 coating agent Substances 0.000 claims description 19
- 238000000576 coating method Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims 2
- 125000003917 carbamoyl group Chemical class [H]N([H])C(*)=O 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 17
- 150000001408 amides Chemical class 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 239000006260 foam Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 229920006248 expandable polystyrene Polymers 0.000 description 6
- -1 aliphatic acid amide Chemical class 0.000 description 4
- 150000003857 carboxamides Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- DJWFNQUDPJTSAD-UHFFFAOYSA-N n-octadecyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)CCCCCCCCCCCCCCCCC DJWFNQUDPJTSAD-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004604 Blowing Agent Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 238000010097 foam moulding Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- QPUQNFRDMXWYKM-QZOPMXJLSA-N (z)-octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O.CCCCCCCC\C=C/CCCCCCCC(N)=O QPUQNFRDMXWYKM-QZOPMXJLSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical class C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- RRSRZEGDMPXJOX-UHFFFAOYSA-N N-dodecyldocosanamide Chemical compound C(CCCCCCCCCCC)NC(CCCCCCCCCCCCCCCCCCCCC)=O RRSRZEGDMPXJOX-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000000181 anti-adherent effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- AFYPFACVUDMOHA-UHFFFAOYSA-N chlorotrifluoromethane Chemical compound FC(F)(F)Cl AFYPFACVUDMOHA-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000013518 molded foam Substances 0.000 description 1
- PECBPCUKEFYARY-ZPHPHTNESA-N n-[(z)-octadec-9-enyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCCCCCCC\C=C/CCCCCCCC PECBPCUKEFYARY-ZPHPHTNESA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- SVCKESZOKLIWKX-UHFFFAOYSA-N n-octadecyldocosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)NCCCCCCCCCCCCCCCCCC SVCKESZOKLIWKX-UHFFFAOYSA-N 0.000 description 1
- PCPVQTNQMJCULF-UHFFFAOYSA-N n-octadecyloctanamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)CCCCCCC PCPVQTNQMJCULF-UHFFFAOYSA-N 0.000 description 1
- ZKNMQGPYNVQBAL-UHFFFAOYSA-N n-octadecyltetradecanamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)CCCCCCCCCCCCC ZKNMQGPYNVQBAL-UHFFFAOYSA-N 0.000 description 1
- ZJZAMUXTFNFFAA-UHFFFAOYSA-N n-octylhexadecanamide Chemical compound CCCCCCCCCCCCCCCC(=O)NCCCCCCCC ZJZAMUXTFNFFAA-UHFFFAOYSA-N 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- KWYAAIXBHVHNLN-SVMKZPJVSA-N octadecanamide;(z)-octadec-9-enamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O.CCCCCCCC\C=C/CCCCCCCC(N)=O KWYAAIXBHVHNLN-SVMKZPJVSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/224—Surface treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE787273D BE787273A (fr) | 1971-08-07 | Polymeres de styrene expansibles finement divises | |
| DE2139686A DE2139686A1 (de) | 1971-08-07 | 1971-08-07 | Feinteilige expandierbare styrolpolymerisate |
| US00276129A US3817879A (en) | 1971-08-07 | 1972-07-28 | Particulate expandable styrene polymers coated with a carboxamide |
| CA148,480A CA982750A (en) | 1971-08-07 | 1972-08-01 | Coated particulate expandable styrene polymers |
| GB3649872A GB1396949A (en) | 1971-08-07 | 1972-08-04 | Particulate expandable styrene polymers |
| JP47077776A JPS4826248A (enExample) | 1971-08-07 | 1972-08-04 | |
| IT52015/72A IT961888B (it) | 1971-08-07 | 1972-08-05 | Polimerizzati stirolici espandi bili finemente suddivisi |
| ES405582A ES405582A1 (es) | 1971-08-07 | 1972-08-05 | Procedimiento para la obtencion de masas moldeables expan- dibles. |
| NL7210793A NL7210793A (enExample) | 1971-08-07 | 1972-08-07 | |
| FR7228424A FR2149950A5 (enExample) | 1971-08-07 | 1972-08-07 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2139686A DE2139686A1 (de) | 1971-08-07 | 1971-08-07 | Feinteilige expandierbare styrolpolymerisate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2139686A1 true DE2139686A1 (de) | 1973-02-15 |
Family
ID=5816134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2139686A Pending DE2139686A1 (de) | 1971-08-07 | 1971-08-07 | Feinteilige expandierbare styrolpolymerisate |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3817879A (enExample) |
| JP (1) | JPS4826248A (enExample) |
| BE (1) | BE787273A (enExample) |
| CA (1) | CA982750A (enExample) |
| DE (1) | DE2139686A1 (enExample) |
| ES (1) | ES405582A1 (enExample) |
| FR (1) | FR2149950A5 (enExample) |
| GB (1) | GB1396949A (enExample) |
| IT (1) | IT961888B (enExample) |
| NL (1) | NL7210793A (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1409336A (en) * | 1973-04-13 | 1975-10-08 | Shell Int Research | Coated expandable polymers of vinylidene aromatic compounds |
| US3944265A (en) * | 1974-11-15 | 1976-03-16 | Donaldson Company, Inc. | Exhaust system connector seal |
| US4359538A (en) * | 1979-03-20 | 1982-11-16 | Labofina, S.A. | Fire-retardant polystyrenic compositions |
| JPS55145879A (en) * | 1979-05-01 | 1980-11-13 | Mitsutoyo Gomu Kk | Pipe joint |
| JPS5653047A (en) * | 1980-04-04 | 1981-05-12 | Badische Yuka Co Ltd | Production of foamed resin molding |
| US4312957A (en) * | 1980-10-01 | 1982-01-26 | Atlantic Richfield Company | Fast-cooling styrene polymer foams |
| US4278730A (en) * | 1980-10-01 | 1981-07-14 | Arco Polymers, Inc. | Fast-cooling styrene polymer foams |
| US4304797A (en) * | 1980-10-01 | 1981-12-08 | Arco Polymers, Inc. | Fast-cooling styrene polymer foams |
| US4304796A (en) * | 1980-10-01 | 1981-12-08 | Arco Polymers, Inc. | Fast-cooling styrene polymer foams |
| US4278731A (en) * | 1980-10-01 | 1981-07-14 | Arco Polymers, Inc. | Fast-cooling styrene polymer foams |
| CA1203950A (en) * | 1982-12-23 | 1986-04-29 | Harold S. Cox | Anti-static articles |
| US4556680A (en) * | 1983-08-30 | 1985-12-03 | Basf Wyandotte Corporation | Method of producing antistatic expandable polystyrene products |
-
0
- BE BE787273D patent/BE787273A/xx unknown
-
1971
- 1971-08-07 DE DE2139686A patent/DE2139686A1/de active Pending
-
1972
- 1972-07-28 US US00276129A patent/US3817879A/en not_active Expired - Lifetime
- 1972-08-01 CA CA148,480A patent/CA982750A/en not_active Expired
- 1972-08-04 GB GB3649872A patent/GB1396949A/en not_active Expired
- 1972-08-04 JP JP47077776A patent/JPS4826248A/ja active Pending
- 1972-08-05 ES ES405582A patent/ES405582A1/es not_active Expired
- 1972-08-05 IT IT52015/72A patent/IT961888B/it active
- 1972-08-07 NL NL7210793A patent/NL7210793A/xx unknown
- 1972-08-07 FR FR7228424A patent/FR2149950A5/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US3817879A (en) | 1974-06-18 |
| IT961888B (it) | 1973-12-10 |
| CA982750A (en) | 1976-01-27 |
| FR2149950A5 (enExample) | 1973-03-30 |
| GB1396949A (en) | 1975-06-11 |
| BE787273A (fr) | 1973-02-07 |
| ES405582A1 (es) | 1975-08-01 |
| NL7210793A (enExample) | 1973-02-09 |
| JPS4826248A (enExample) | 1973-04-06 |
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