DE2137499B2 - Verfahren zur Herstellung von Chlormethanen durch thermische Chlorierung - Google Patents
Verfahren zur Herstellung von Chlormethanen durch thermische ChlorierungInfo
- Publication number
- DE2137499B2 DE2137499B2 DE19712137499 DE2137499A DE2137499B2 DE 2137499 B2 DE2137499 B2 DE 2137499B2 DE 19712137499 DE19712137499 DE 19712137499 DE 2137499 A DE2137499 A DE 2137499A DE 2137499 B2 DE2137499 B2 DE 2137499B2
- Authority
- DE
- Germany
- Prior art keywords
- gas
- chlorine
- reactor
- temperature
- chlorination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical class ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 title claims description 57
- 238000000034 method Methods 0.000 title claims description 35
- 238000005660 chlorination reaction Methods 0.000 title claims description 32
- 230000008569 process Effects 0.000 title claims description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000007789 gas Substances 0.000 description 72
- 239000000460 chlorine Substances 0.000 description 71
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 58
- 229910052801 chlorine Inorganic materials 0.000 description 55
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 50
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 36
- 239000000203 mixture Substances 0.000 description 32
- 238000006243 chemical reaction Methods 0.000 description 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 13
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 13
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 13
- 238000000926 separation method Methods 0.000 description 10
- 238000012546 transfer Methods 0.000 description 10
- 229910052759 nickel Inorganic materials 0.000 description 8
- 239000004071 soot Substances 0.000 description 8
- 239000011261 inert gas Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 230000032050 esterification Effects 0.000 description 5
- 238000005886 esterification reaction Methods 0.000 description 5
- 239000013529 heat transfer fluid Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000005253 cladding Methods 0.000 description 4
- 239000000571 coke Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 3
- 229960001701 chloroform Drugs 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- JQCVPZXMGXKNOD-UHFFFAOYSA-N 1,2-dibenzylbenzene Chemical class C=1C=CC=C(CC=2C=CC=CC=2)C=1CC1=CC=CC=C1 JQCVPZXMGXKNOD-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000010943 off-gassing Methods 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MHCVCKDNQYMGEX-UHFFFAOYSA-N 1,1'-biphenyl;phenoxybenzene Chemical group C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1OC1=CC=CC=C1 MHCVCKDNQYMGEX-UHFFFAOYSA-N 0.000 description 1
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- JNRLEMMIVRBKJE-UHFFFAOYSA-N 4,4'-Methylenebis(N,N-dimethylaniline) Chemical compound C1=CC(N(C)C)=CC=C1CC1=CC=C(N(C)C)C=C1 JNRLEMMIVRBKJE-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 101150107341 RERE gene Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 239000000374 eutectic mixture Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 210000000003 hoof Anatomy 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- AGDRDFJCYMPNFZ-UHFFFAOYSA-N methane;methanol Chemical compound C.OC AGDRDFJCYMPNFZ-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE786848D BE786848A (fr) | 1971-07-27 | Procede de preparation de methanes chlores par chloration thermique | |
| DE19712137499 DE2137499B2 (de) | 1971-07-27 | 1971-07-27 | Verfahren zur Herstellung von Chlormethanen durch thermische Chlorierung |
| NL7210116A NL7210116A (enExample) | 1971-07-27 | 1972-07-21 | |
| ES405032A ES405032A1 (es) | 1971-07-27 | 1972-07-21 | Procedimiento para la obtencion de clorometanos por colora-cion termica. |
| IT2739472A IT963342B (it) | 1971-07-27 | 1972-07-25 | Procedimento per la preparazione di clorometani mediante clorurazione termica |
| CA147,975A CA989878A (en) | 1971-07-27 | 1972-07-26 | Process for the manufacture of chloromethanes by thermal chlorination |
| FR7226876A FR2147207B1 (enExample) | 1971-07-27 | 1972-07-26 | |
| GB3496572A GB1400855A (en) | 1971-07-27 | 1972-07-26 | Process for the manufacture of chloromethanes by thermal chlorination |
| BR504072A BR7205040D0 (pt) | 1971-07-27 | 1972-07-27 | Processo para a preparacao de clorometanos atraves de cloracao termica |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712137499 DE2137499B2 (de) | 1971-07-27 | 1971-07-27 | Verfahren zur Herstellung von Chlormethanen durch thermische Chlorierung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2137499A1 DE2137499A1 (de) | 1973-02-08 |
| DE2137499B2 true DE2137499B2 (de) | 1975-08-14 |
Family
ID=5814944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712137499 Withdrawn DE2137499B2 (de) | 1971-07-27 | 1971-07-27 | Verfahren zur Herstellung von Chlormethanen durch thermische Chlorierung |
Country Status (9)
| Country | Link |
|---|---|
| BE (1) | BE786848A (enExample) |
| BR (1) | BR7205040D0 (enExample) |
| CA (1) | CA989878A (enExample) |
| DE (1) | DE2137499B2 (enExample) |
| ES (1) | ES405032A1 (enExample) |
| FR (1) | FR2147207B1 (enExample) |
| GB (1) | GB1400855A (enExample) |
| IT (1) | IT963342B (enExample) |
| NL (1) | NL7210116A (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2933691B1 (fr) * | 2008-07-10 | 2012-11-09 | Arkema France | Hydro(chloro)fluoroolefines et leur procede de preparation |
-
0
- BE BE786848D patent/BE786848A/xx unknown
-
1971
- 1971-07-27 DE DE19712137499 patent/DE2137499B2/de not_active Withdrawn
-
1972
- 1972-07-21 ES ES405032A patent/ES405032A1/es not_active Expired
- 1972-07-21 NL NL7210116A patent/NL7210116A/xx not_active Application Discontinuation
- 1972-07-25 IT IT2739472A patent/IT963342B/it active
- 1972-07-26 GB GB3496572A patent/GB1400855A/en not_active Expired
- 1972-07-26 FR FR7226876A patent/FR2147207B1/fr not_active Expired
- 1972-07-26 CA CA147,975A patent/CA989878A/en not_active Expired
- 1972-07-27 BR BR504072A patent/BR7205040D0/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR7205040D0 (pt) | 1973-07-03 |
| DE2137499A1 (de) | 1973-02-08 |
| GB1400855A (en) | 1975-07-16 |
| NL7210116A (enExample) | 1973-01-30 |
| FR2147207B1 (enExample) | 1977-08-26 |
| IT963342B (it) | 1974-01-10 |
| CA989878A (en) | 1976-05-25 |
| FR2147207A1 (enExample) | 1973-03-09 |
| BE786848A (fr) | 1973-01-29 |
| ES405032A1 (es) | 1975-07-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8230 | Patent withdrawn |