DE1907369C3 - Vorrichtung zur Bestimmung von Wasserstoff in Gasen, insbesondere in Chlor - Google Patents
Vorrichtung zur Bestimmung von Wasserstoff in Gasen, insbesondere in ChlorInfo
- Publication number
- DE1907369C3 DE1907369C3 DE1907369A DE1907369A DE1907369C3 DE 1907369 C3 DE1907369 C3 DE 1907369C3 DE 1907369 A DE1907369 A DE 1907369A DE 1907369 A DE1907369 A DE 1907369A DE 1907369 C3 DE1907369 C3 DE 1907369C3
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen
- gas
- diffusion
- membrane
- analyzed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000001257 hydrogen Substances 0.000 title claims description 45
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 45
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 38
- 239000007789 gas Substances 0.000 title claims description 33
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims description 9
- 239000000460 chlorine Substances 0.000 title claims description 9
- 229910052801 chlorine Inorganic materials 0.000 title claims description 9
- 239000012528 membrane Substances 0.000 claims description 43
- 238000009792 diffusion process Methods 0.000 claims description 31
- 239000012159 carrier gas Substances 0.000 claims description 13
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 9
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 8
- 238000005259 measurement Methods 0.000 claims description 8
- -1 polypropylene Polymers 0.000 claims description 8
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 5
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 239000001307 helium Substances 0.000 claims description 2
- 229910052734 helium Inorganic materials 0.000 claims description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 239000011148 porous material Substances 0.000 claims description 2
- 239000010970 precious metal Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 239000000956 alloy Substances 0.000 claims 2
- 229910045601 alloy Inorganic materials 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 230000004888 barrier function Effects 0.000 claims 1
- 150000001805 chlorine compounds Chemical class 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 230000008901 benefit Effects 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- DHZSIQDUYCWNSB-UHFFFAOYSA-N chloroethene;1,1-dichloroethene Chemical compound ClC=C.ClC(Cl)=C DHZSIQDUYCWNSB-UHFFFAOYSA-N 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- WJGVWFOXHWYCHL-UHFFFAOYSA-N 1,1-dichloroethene;methyl prop-2-enoate Chemical compound ClC(Cl)=C.COC(=O)C=C WJGVWFOXHWYCHL-UHFFFAOYSA-N 0.000 description 1
- UEISCBZSYPKMGC-UHFFFAOYSA-N CC(C(OCC1OC1)=O)=C.Cl Chemical compound CC(C(OCC1OC1)=O)=C.Cl UEISCBZSYPKMGC-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- YZIPEAHOHOYNCE-UHFFFAOYSA-N chloroethene;1,1-dichloroethene;prop-2-enenitrile Chemical compound ClC=C.C=CC#N.ClC(Cl)=C YZIPEAHOHOYNCE-UHFFFAOYSA-N 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N7/00—Analysing materials by measuring the pressure or volume of a gas or vapour
- G01N7/10—Analysing materials by measuring the pressure or volume of a gas or vapour by allowing diffusion of components through a porous wall and measuring a pressure or volume difference
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
- B01D71/301—Polyvinylchloride
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N13/00—Investigating surface or boundary effects, e.g. wetting power; Investigating diffusion effects; Analysing materials by determining surface, boundary, or diffusion effects
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/14—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of an electrically-heated body in dependence upon change of temperature
- G01N27/18—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of an electrically-heated body in dependence upon change of temperature caused by changes in the thermal conductivity of a surrounding material to be tested
- G01N27/185—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of an electrically-heated body in dependence upon change of temperature caused by changes in the thermal conductivity of a surrounding material to be tested using a catharometer
Landscapes
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Sampling And Sample Adjustment (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE55458 | 1968-03-07 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1907369A1 DE1907369A1 (de) | 1969-10-09 |
| DE1907369B2 DE1907369B2 (de) | 1977-10-13 |
| DE1907369C3 true DE1907369C3 (de) | 1978-06-08 |
Family
ID=3840914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1907369A Expired DE1907369C3 (de) | 1968-03-07 | 1969-02-14 | Vorrichtung zur Bestimmung von Wasserstoff in Gasen, insbesondere in Chlor |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3619986A (enExample) |
| AT (1) | AT296659B (enExample) |
| BE (1) | BE711789A (enExample) |
| CH (1) | CH498391A (enExample) |
| DE (1) | DE1907369C3 (enExample) |
| ES (1) | ES364427A1 (enExample) |
| FI (1) | FI54030C (enExample) |
| FR (1) | FR2003377A1 (enExample) |
| NL (1) | NL6903539A (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3721065A (en) * | 1971-01-27 | 1973-03-20 | Int Paper Co | Barrier attachment for gas chromatograph |
| US3926561A (en) * | 1974-05-13 | 1975-12-16 | Meloy Lab | Gas analysis employing semi-permeable membrane |
| DE3017286C2 (de) * | 1980-05-06 | 1982-01-21 | Horst 1000 Berlin Lampertz | Sicherungsraum oder -schrank für Dokumente |
| AU676789B2 (en) * | 1993-11-19 | 1997-03-20 | Greenspan Technology Pty Ltd | Diffusion cell |
| EP0734516A4 (en) * | 1993-11-19 | 1997-11-19 | Commw Scient Ind Res Org | DIFFUSION CELL |
| AUPM707494A0 (en) * | 1994-07-26 | 1994-08-18 | Crc For Waste Management And Pollution Control Limited | A method and apparatus for environmental monitoring of low concentration levels of organic compounds |
| US6129973A (en) * | 1994-07-29 | 2000-10-10 | Battelle Memorial Institute | Microchannel laminated mass exchanger and method of making |
| JP2969075B2 (ja) * | 1996-02-26 | 1999-11-02 | ジャパンゴアテックス株式会社 | 脱気装置 |
| US5888275A (en) * | 1996-02-26 | 1999-03-30 | Japan Gore-Tex, Inc. | Assembly for deaeration of liquids |
| US6875247B2 (en) * | 2000-06-06 | 2005-04-05 | Battelle Memorial Institute | Conditions for fluid separations in microchannels, capillary-driven fluid separations, and laminated devices capable of separating fluids |
| US6666909B1 (en) | 2000-06-06 | 2003-12-23 | Battelle Memorial Institute | Microsystem capillary separations |
| KR100715103B1 (ko) * | 2001-10-26 | 2007-05-07 | 에스케이 주식회사 | 수소정제모듈 |
| US8367413B2 (en) * | 2008-12-16 | 2013-02-05 | Halliburton Energy Services, Inc. | Determining formation fluid composition |
| WO2019039242A1 (ja) * | 2017-08-21 | 2019-02-28 | 東京応化工業株式会社 | 気体分離方法、及び気体分離膜 |
| CN114577669A (zh) * | 2022-01-19 | 2022-06-03 | 淄博火炬能源有限责任公司 | 铅酸蓄电池析氢测定方法及装置 |
-
1968
- 1968-03-07 BE BE711789D patent/BE711789A/xx unknown
-
1969
- 1969-02-14 DE DE1907369A patent/DE1907369C3/de not_active Expired
- 1969-02-25 FR FR6905047A patent/FR2003377A1/fr not_active Withdrawn
- 1969-02-26 CH CH288069A patent/CH498391A/fr not_active IP Right Cessation
- 1969-02-28 FI FI626/69A patent/FI54030C/fi active
- 1969-03-06 ES ES364427A patent/ES364427A1/es not_active Expired
- 1969-03-07 NL NL6903539A patent/NL6903539A/xx not_active Application Discontinuation
- 1969-03-07 US US805250A patent/US3619986A/en not_active Expired - Lifetime
- 1969-03-07 AT AT230169A patent/AT296659B/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE1907369B2 (de) | 1977-10-13 |
| AT296659B (de) | 1972-02-25 |
| CH498391A (fr) | 1970-10-31 |
| DE1907369A1 (de) | 1969-10-09 |
| FI54030B (fi) | 1978-05-31 |
| NL6903539A (enExample) | 1969-09-09 |
| FR2003377A1 (enExample) | 1969-11-07 |
| US3619986A (en) | 1971-11-16 |
| BE711789A (enExample) | 1968-09-09 |
| FI54030C (fi) | 1978-09-11 |
| ES364427A1 (es) | 1971-02-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| EHJ | Ceased/non-payment of the annual fee |