DE1758923C3 - Oberflächennitrierte, abriebbeständige Werkstücke, insbesondere Schneidwerkzeuge - Google Patents
Oberflächennitrierte, abriebbeständige Werkstücke, insbesondere SchneidwerkzeugeInfo
- Publication number
- DE1758923C3 DE1758923C3 DE1758923A DE1758923A DE1758923C3 DE 1758923 C3 DE1758923 C3 DE 1758923C3 DE 1758923 A DE1758923 A DE 1758923A DE 1758923 A DE1758923 A DE 1758923A DE 1758923 C3 DE1758923 C3 DE 1758923C3
- Authority
- DE
- Germany
- Prior art keywords
- titanium
- metal alloy
- molybdenum
- tungsten
- tantalum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005520 cutting process Methods 0.000 title claims description 84
- 238000005299 abrasion Methods 0.000 title claims description 6
- 239000010936 titanium Substances 0.000 claims description 295
- 239000010955 niobium Substances 0.000 claims description 166
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 153
- 229910052719 titanium Inorganic materials 0.000 claims description 153
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 105
- 229910052750 molybdenum Inorganic materials 0.000 claims description 104
- 229910052758 niobium Inorganic materials 0.000 claims description 104
- 229910052721 tungsten Inorganic materials 0.000 claims description 104
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 98
- 239000011733 molybdenum Substances 0.000 claims description 98
- 229910052715 tantalum Inorganic materials 0.000 claims description 98
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 97
- 239000010937 tungsten Substances 0.000 claims description 97
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 95
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 93
- 229910052720 vanadium Inorganic materials 0.000 claims description 91
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 90
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 83
- 229910052751 metal Inorganic materials 0.000 claims description 51
- 239000002184 metal Substances 0.000 claims description 51
- 229910052757 nitrogen Inorganic materials 0.000 claims description 50
- 150000002739 metals Chemical class 0.000 claims description 41
- 230000007423 decrease Effects 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 description 182
- 239000000956 alloy Substances 0.000 description 182
- 239000000203 mixture Substances 0.000 description 73
- 238000005121 nitriding Methods 0.000 description 57
- 238000010586 diagram Methods 0.000 description 28
- 239000000463 material Substances 0.000 description 25
- 229910000831 Steel Inorganic materials 0.000 description 22
- 239000010959 steel Substances 0.000 description 22
- 238000000034 method Methods 0.000 description 18
- 238000006396 nitration reaction Methods 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 17
- 230000008569 process Effects 0.000 description 15
- 239000007858 starting material Substances 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 239000002344 surface layer Substances 0.000 description 10
- 238000010521 absorption reaction Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000003754 machining Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 230000004584 weight gain Effects 0.000 description 4
- 235000019786 weight gain Nutrition 0.000 description 4
- 229910000952 Be alloy Inorganic materials 0.000 description 3
- 229910000760 Hardened steel Inorganic materials 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 2
- OFHSNVAJKODVJF-UHFFFAOYSA-N [Ta].[Ti].[Mo] Chemical compound [Ta].[Ti].[Mo] OFHSNVAJKODVJF-UHFFFAOYSA-N 0.000 description 2
- ZTJWUVMPZRLXAB-UHFFFAOYSA-N [Ta].[Ti].[W] Chemical compound [Ta].[Ti].[W] ZTJWUVMPZRLXAB-UHFFFAOYSA-N 0.000 description 2
- QDNARMPMTMJYMK-UHFFFAOYSA-N [W].[Ti].[Nb] Chemical compound [W].[Ti].[Nb] QDNARMPMTMJYMK-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 229910002056 binary alloy Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000001427 coherent effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- BWDUFCSALZHSPQ-UHFFFAOYSA-N molybdenum niobium titanium Chemical compound [Ti][Nb][Mo] BWDUFCSALZHSPQ-UHFFFAOYSA-N 0.000 description 2
- DLCOPLYGCSRNAY-UHFFFAOYSA-N molybdenum titanium vanadium Chemical compound [Ti][Mo][V] DLCOPLYGCSRNAY-UHFFFAOYSA-N 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- WKXHZKXPFJNBIY-UHFFFAOYSA-N titanium tungsten vanadium Chemical compound [Ti][W][V] WKXHZKXPFJNBIY-UHFFFAOYSA-N 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- 101150030072 CNTF gene Proteins 0.000 description 1
- 101100457849 Caenorhabditis elegans mon-2 gene Proteins 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241000040428 Heterodera iri Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- 229910001257 Nb alloy Inorganic materials 0.000 description 1
- 229910001370 Se alloy Inorganic materials 0.000 description 1
- 229910001362 Ta alloys Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 239000007875 V-40 Substances 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 238000005255 carburizing Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- KVMWOOXRTBUMIS-UHFFFAOYSA-N molybdenum zirconium Chemical compound [Zr].[Mo].[Mo] KVMWOOXRTBUMIS-UHFFFAOYSA-N 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229910002058 ternary alloy Inorganic materials 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/24—Nitriding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
- B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
- B23B27/148—Composition of the cutting inserts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C16/00—Alloys based on zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/16—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on nitrides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66551067A | 1967-09-05 | 1967-09-05 | |
| US75565868A | 1968-08-27 | 1968-08-27 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1758923A1 DE1758923A1 (de) | 1972-04-13 |
| DE1758923B2 DE1758923B2 (de) | 1977-01-13 |
| DE1758923C3 true DE1758923C3 (de) | 1978-09-14 |
Family
ID=27099221
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1758923A Expired DE1758923C3 (de) | 1967-09-05 | 1968-09-04 | Oberflächennitrierte, abriebbeständige Werkstücke, insbesondere Schneidwerkzeuge |
Country Status (11)
| Country | Link |
|---|---|
| AT (1) | AT291611B (enExample) |
| BE (1) | BE720398A (enExample) |
| DE (1) | DE1758923C3 (enExample) |
| FI (1) | FI49435C (enExample) |
| FR (1) | FR1584635A (enExample) |
| GB (1) | GB1239941A (enExample) |
| IL (1) | IL30661A (enExample) |
| LU (2) | LU56819A1 (enExample) |
| NL (1) | NL149544B (enExample) |
| NO (1) | NO125397B (enExample) |
| SE (1) | SE363514B (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3830670A (en) * | 1970-12-18 | 1974-08-20 | Surface Technology Corp | Graded multiphase carburized materials |
| US4026730A (en) * | 1973-01-18 | 1977-05-31 | Surface Technology Corporation | Nitrided materials |
| US4799977A (en) * | 1987-09-21 | 1989-01-24 | Fansteel Inc. | Graded multiphase oxycarburized and oxycarbonitrided material systems |
| AT401778B (de) | 1994-08-01 | 1996-11-25 | Plansee Ag | Verwendung von molybdän-legierungen |
-
1968
- 1968-09-04 GB GB41954/68A patent/GB1239941A/en not_active Expired
- 1968-09-04 LU LU56819D patent/LU56819A1/xx unknown
- 1968-09-04 NO NO3428/68A patent/NO125397B/no unknown
- 1968-09-04 BE BE720398D patent/BE720398A/xx unknown
- 1968-09-04 FI FI682488A patent/FI49435C/fi active
- 1968-09-04 AT AT859968A patent/AT291611B/de not_active IP Right Cessation
- 1968-09-04 IL IL30661A patent/IL30661A/en unknown
- 1968-09-04 LU LU56821D patent/LU56821A1/xx unknown
- 1968-09-04 DE DE1758923A patent/DE1758923C3/de not_active Expired
- 1968-09-04 FR FR1584635D patent/FR1584635A/fr not_active Expired
- 1968-09-04 NL NL686812592A patent/NL149544B/xx unknown
- 1968-09-04 SE SE11913/68A patent/SE363514B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE720398A (enExample) | 1969-03-04 |
| NL149544B (nl) | 1976-05-17 |
| NL6812592A (enExample) | 1969-03-07 |
| FR1584635A (enExample) | 1969-12-26 |
| DE1758923A1 (de) | 1972-04-13 |
| LU56819A1 (enExample) | 1970-03-04 |
| GB1239941A (en) | 1971-07-21 |
| NO125397B (enExample) | 1972-09-04 |
| IL30661A (en) | 1972-07-26 |
| FI49435C (fi) | 1975-06-10 |
| IL30661A0 (en) | 1968-12-26 |
| LU56821A1 (enExample) | 1970-09-03 |
| SE363514B (enExample) | 1974-01-21 |
| FI49435B (enExample) | 1975-02-28 |
| DE1758923B2 (de) | 1977-01-13 |
| AT291611B (de) | 1971-07-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| EHJ | Ceased/non-payment of the annual fee |