DE1543108B - - Google Patents
Info
- Publication number
- DE1543108B DE1543108B DE1543108B DE 1543108 B DE1543108 B DE 1543108B DE 1543108 B DE1543108 B DE 1543108B
- Authority
- DE
- Germany
- Prior art keywords
- dichloroethane
- reaction
- ethylene
- liquid
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 41
- 238000006243 chemical reaction Methods 0.000 claims description 37
- 239000005977 Ethylene Substances 0.000 claims description 23
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 21
- 239000007789 gas Substances 0.000 claims description 20
- 239000000460 chlorine Substances 0.000 claims description 17
- 229910052801 chlorine Inorganic materials 0.000 claims description 17
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 229910001510 metal chloride Inorganic materials 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- RBTARNINKXHZNM-UHFFFAOYSA-K Iron(III) chloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000003208 petroleum Substances 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- NMCUIPGRVMDVDB-UHFFFAOYSA-L Iron(II) chloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 3
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 3
- 238000005336 cracking Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 239000000047 product Substances 0.000 claims description 2
- 238000004227 thermal cracking Methods 0.000 claims description 2
- 230000001105 regulatory Effects 0.000 claims 5
- 239000000498 cooling water Substances 0.000 claims 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-Trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000006227 byproduct Substances 0.000 claims 1
- 239000000571 coke Substances 0.000 claims 1
- 238000004821 distillation Methods 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 230000002349 favourable Effects 0.000 claims 1
- 239000008246 gaseous mixture Substances 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 238000007259 addition reaction Methods 0.000 description 5
- 239000012429 reaction media Substances 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 4
- 238000007086 side reaction Methods 0.000 description 4
- HRYZWHHZPQKTII-UHFFFAOYSA-N Chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- 229960003750 ethyl chloride Drugs 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- DKQVJMREABFYNT-UHFFFAOYSA-N C=C.C=C Chemical group C=C.C=C DKQVJMREABFYNT-UHFFFAOYSA-N 0.000 description 1
- WBLXMRIMSGHSAC-UHFFFAOYSA-N [Cl].[Cl] Chemical compound [Cl].[Cl] WBLXMRIMSGHSAC-UHFFFAOYSA-N 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 230000001771 impaired Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3700132C2 (xx) | ||
| DE3327274A1 (de) | Verfahren zur herstellung von phosgen unter gleichzeitiger erzeugung von dampf | |
| DE2447551C3 (de) | Verfahren zur Herstellung von Methylchlorid | |
| DE2805933C2 (de) | Verfahren zur Abspaltung von Chlorwasserstoff aus Lösungen von Aminhydrochloriden | |
| EP0225617B1 (de) | Verbessertes Verfahren zur Herstellung von Vinylchlorid durch thermische Spaltung von 1,2-Dichlorethan | |
| DE2427045A1 (de) | Verfahren zur herstellung von aethylendichlorid | |
| DE2626133A1 (de) | Zyklisches verfahren zur herstellung von aethylendichlorid | |
| DE1543108A1 (de) | Verfahren zum Herstellen von 1,2-Dichloraethan | |
| DE3519161A1 (de) | Verfahren zur reinigung von 1,2-dichlorethan | |
| DE1543108C (xx) | ||
| DE3604968A1 (de) | Verfahren zur herstellung von dichlorethan | |
| DE3044854A1 (de) | "verfahren zur herstellung von 1,2-dichlorethan" | |
| DE1543108B (xx) | ||
| DE2530306A1 (de) | Verfahren zur behandlung eines chlorierten kohlenwasserstoff enthaltenden gasfoermigen ausgangsprodukts | |
| EP0142016A2 (de) | Verfahren zur Herstellung von 1,2-Dichlorethan aus Ethylen und Chlorgas | |
| DE1242594B (de) | Verfahren zur Herstellung von Vinylchlorid durch unvollstaendige thermische Spaltung von 1, 2-Dichloraethan | |
| DE2733502B2 (de) | Verfahren zur Herstellung von 1,2-Dichloräthan aus Äthylen enthaltenden Restgasen, die aus einer Oxychlorierung stammen | |
| DE1567575B2 (de) | Verfahren zur Herstellung von Chlor | |
| DE1518969B2 (de) | Verfahren zur oxydation von cycloalkanen mit vier bis acht kohlenstoffatomen | |
| DE3225732A1 (de) | Verfahren zur herstellung und reinigung von 1,2-dichlorethan | |
| DE2652332A1 (de) | Verfahren zur herstellung von 1,2-dichloraethan | |
| WO1996003361A1 (de) | Verfahren und vorrichtung zur herstellung von 1,2-dichlorethan durch direktchlorierung unter abgasrückführung | |
| DE1271705B (de) | Verfahren zur Herstellung von Tetrachlorkohlenstoff und Perchloraethylen | |
| DE1806988A1 (de) | Verfahren zur Chlorierung von Kohlenwasserstoffen | |
| DE975968C (de) | Verfahren zur kontinuierlichen Herstellung von Gemischen aus Essigsaeure und Methylacetat |