DE1542642A1 - Verfahren zur Herstellung von Calciumperoxyd - Google Patents
Verfahren zur Herstellung von CalciumperoxydInfo
- Publication number
- DE1542642A1 DE1542642A1 DE19651542642 DE1542642A DE1542642A1 DE 1542642 A1 DE1542642 A1 DE 1542642A1 DE 19651542642 DE19651542642 DE 19651542642 DE 1542642 A DE1542642 A DE 1542642A DE 1542642 A1 DE1542642 A1 DE 1542642A1
- Authority
- DE
- Germany
- Prior art keywords
- peroxide
- calcium
- hydrogen peroxide
- hydrogen
- anthraquinone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004343 Calcium peroxide Substances 0.000 title claims description 72
- 235000019402 calcium peroxide Nutrition 0.000 title claims description 72
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 title claims description 68
- 238000000034 method Methods 0.000 title claims description 39
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 129
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 26
- 239000000920 calcium hydroxide Substances 0.000 claims description 26
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 26
- -1 calcium peroxide octahydrate Chemical class 0.000 claims description 26
- 239000013078 crystal Substances 0.000 claims description 22
- 239000002244 precipitate Substances 0.000 claims description 22
- PTKWYSNDTXDBIZ-UHFFFAOYSA-N 9,10-dioxoanthracene-1,2-disulfonic acid Chemical class C1=CC=C2C(=O)C3=C(S(O)(=O)=O)C(S(=O)(=O)O)=CC=C3C(=O)C2=C1 PTKWYSNDTXDBIZ-UHFFFAOYSA-N 0.000 claims description 21
- 239000007864 aqueous solution Substances 0.000 claims description 20
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 13
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 11
- JAJIPIAHCFBEPI-UHFFFAOYSA-N 9,10-dioxoanthracene-1-sulfonic acid Chemical class O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)O JAJIPIAHCFBEPI-UHFFFAOYSA-N 0.000 claims description 10
- 150000002978 peroxides Chemical class 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 229940043430 calcium compound Drugs 0.000 claims description 4
- 150000001674 calcium compounds Chemical class 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 3
- OKONMFPEKSWGEU-UHFFFAOYSA-N 9,10-dioxoanthracene-2,7-disulfonic acid Chemical compound C1=C(S(O)(=O)=O)C=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 OKONMFPEKSWGEU-UHFFFAOYSA-N 0.000 claims description 3
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003729 cation exchange resin Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000012452 mother liquor Substances 0.000 claims description 2
- 230000002745 absorbent Effects 0.000 claims 1
- 239000002250 absorbent Substances 0.000 claims 1
- 229940105847 calamine Drugs 0.000 claims 1
- 238000011109 contamination Methods 0.000 claims 1
- 229910052864 hemimorphite Inorganic materials 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000011787 zinc oxide Substances 0.000 claims 1
- 235000014692 zinc oxide Nutrition 0.000 claims 1
- 239000000243 solution Substances 0.000 description 31
- 239000011575 calcium Substances 0.000 description 24
- 239000000047 product Substances 0.000 description 23
- 238000001556 precipitation Methods 0.000 description 16
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 14
- 229910052791 calcium Inorganic materials 0.000 description 14
- 239000007787 solid Substances 0.000 description 11
- 159000000000 sodium salts Chemical class 0.000 description 10
- 238000000926 separation method Methods 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 150000004056 anthraquinones Chemical class 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000012266 salt solution Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 150000004689 octahydrates Chemical class 0.000 description 3
- 230000001376 precipitating effect Effects 0.000 description 3
- 238000002255 vaccination Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 244000104547 Ziziphus oenoplia Species 0.000 description 2
- 235000005505 Ziziphus oenoplia Nutrition 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 241001233037 catfish Species 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- UZVGFAUPMODEBR-UHFFFAOYSA-L disodium;9,10-dioxoanthracene-1,2-disulfonate Chemical compound [Na+].[Na+].C1=CC=C2C(=O)C3=C(S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=C3C(=O)C2=C1 UZVGFAUPMODEBR-UHFFFAOYSA-L 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
- 239000012716 precipitator Substances 0.000 description 2
- 244000292411 Excoecaria agallocha Species 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- XYMSPSSMUWBDBW-UHFFFAOYSA-N O.O.O.O.O.O.O.O.[Ca] Chemical compound O.O.O.O.O.O.O.O.[Ca] XYMSPSSMUWBDBW-UHFFFAOYSA-N 0.000 description 1
- RZYLEYVRIYPFSP-UHFFFAOYSA-M O.O.O.O.O.O.O.O.[OH-].[K+] Chemical compound O.O.O.O.O.O.O.O.[OH-].[K+] RZYLEYVRIYPFSP-UHFFFAOYSA-M 0.000 description 1
- 241001387976 Pera Species 0.000 description 1
- 206010035148 Plague Diseases 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/04—Metal peroxides or peroxyhydrates thereof; Metal superoxides; Metal ozonides; Peroxyhydrates thereof
- C01B15/043—Metal peroxides or peroxyhydrates thereof; Metal superoxides; Metal ozonides; Peroxyhydrates thereof of alkali metals, alkaline earth metals or magnesium or beryllium or aluminium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/04—Metal peroxides or peroxyhydrates thereof; Metal superoxides; Metal ozonides; Peroxyhydrates thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA896578 | 1964-02-26 | ||
| CA896577 | 1964-02-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1542642A1 true DE1542642A1 (de) | 1970-06-04 |
Family
ID=25673483
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19651542642 Pending DE1542642A1 (de) | 1964-02-26 | 1965-02-25 | Verfahren zur Herstellung von Calciumperoxyd |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3318663A (en, 2012) |
| BE (1) | BE660354A (en, 2012) |
| DE (1) | DE1542642A1 (en, 2012) |
| FR (1) | FR1433624A (en, 2012) |
| GB (1) | GB1108302A (en, 2012) |
| NL (1) | NL6502264A (en, 2012) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0043551A1 (de) * | 1980-07-07 | 1982-01-13 | Peroxid-Chemie GmbH | Verfahren zur Herstellung von Peroxiden zweiwertiger Metalle |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3163044D1 (en) * | 1980-05-15 | 1984-05-17 | Interox Chemicals Ltd | The production of alkali metal or alkaline earth metal peroxides and peroxides when so produced |
| CN102976386B (zh) * | 2012-12-05 | 2014-05-21 | 同济大学 | 一种用于去除水体中甲苯的纳米级过氧化钙的制备方法 |
| CL2021001192A1 (es) * | 2020-05-28 | 2021-11-19 | Evonik Operations Gmbh | Dispositivo y proceso para producir peróxido de hidrógeno mediante un proceso de antraquinona |
| CN114634165B (zh) * | 2022-01-20 | 2023-08-29 | 常熟理工学院 | 一种利用垃圾焚烧飞灰制备过氧化钙的方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA673355A (en) * | 1963-10-29 | R. Lusby George | Manufacture of hydrogen peroxide | |
| US2695217A (en) * | 1952-05-22 | 1954-11-23 | Shell Dev | Purification of hydrogen peroxide |
-
1965
- 1965-02-03 US US430176A patent/US3318663A/en not_active Expired - Lifetime
- 1965-02-23 NL NL6502264A patent/NL6502264A/xx unknown
- 1965-02-25 GB GB5767/65A patent/GB1108302A/en not_active Expired
- 1965-02-25 DE DE19651542642 patent/DE1542642A1/de active Pending
- 1965-02-26 FR FR7278A patent/FR1433624A/fr not_active Expired
- 1965-02-26 BE BE660354D patent/BE660354A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0043551A1 (de) * | 1980-07-07 | 1982-01-13 | Peroxid-Chemie GmbH | Verfahren zur Herstellung von Peroxiden zweiwertiger Metalle |
Also Published As
| Publication number | Publication date |
|---|---|
| BE660354A (en, 2012) | 1965-08-26 |
| US3318663A (en) | 1967-05-09 |
| FR1433624A (fr) | 1966-04-01 |
| GB1108302A (en) | 1968-04-03 |
| NL6502264A (en, 2012) | 1965-08-27 |
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