DE1493269C - - Google Patents
Info
- Publication number
- DE1493269C DE1493269C DE1493269C DE 1493269 C DE1493269 C DE 1493269C DE 1493269 C DE1493269 C DE 1493269C
- Authority
- DE
- Germany
- Prior art keywords
- acid
- alkylation
- olefin
- sulfuric acid
- absorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002253 acid Substances 0.000 claims description 66
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 58
- 150000001336 alkenes Chemical class 0.000 claims description 36
- 238000005804 alkylation reaction Methods 0.000 claims description 34
- 239000012535 impurity Substances 0.000 claims description 24
- 150000008050 dialkyl sulfates Chemical class 0.000 claims description 23
- 150000002430 hydrocarbons Chemical class 0.000 claims description 22
- 239000004215 Carbon black (E152) Substances 0.000 claims description 19
- 239000003054 catalyst Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 13
- 239000010410 layer Substances 0.000 claims description 12
- 239000012044 organic layer Substances 0.000 claims description 12
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 10
- 230000002152 alkylating Effects 0.000 claims description 10
- 230000002378 acidificating Effects 0.000 claims description 9
- 238000000605 extraction Methods 0.000 claims description 8
- 238000004821 distillation Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000002250 absorbent Substances 0.000 claims description 5
- 230000002745 absorbent Effects 0.000 claims description 5
- 238000007792 addition Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 description 31
- 239000000203 mixture Substances 0.000 description 18
- NNPPMTNAJDCUHE-UHFFFAOYSA-N Isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 14
- 239000001282 iso-butane Substances 0.000 description 14
- 239000012074 organic phase Substances 0.000 description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000000926 separation method Methods 0.000 description 8
- 239000005977 Ethylene Substances 0.000 description 7
- 125000005907 alkyl ester group Chemical group 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 239000000356 contaminant Substances 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N activated carbon Substances [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 5
- 238000010790 dilution Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- NMCUIPGRVMDVDB-UHFFFAOYSA-L Iron(II) chloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- JYCKNDWZDXGNBW-UHFFFAOYSA-N dipropyl sulfate Chemical compound CCCOS(=O)(=O)OCCC JYCKNDWZDXGNBW-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 235000013844 butane Nutrition 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910052570 clay Inorganic materials 0.000 description 2
- 230000000875 corresponding Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000004508 fractional distillation Methods 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- -1 propylene, butylenes Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N Isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N Octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- HOWJQLVNDUGZBI-UHFFFAOYSA-N butane;propane Chemical compound CCC.CCCC HOWJQLVNDUGZBI-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atoms Chemical group C* 0.000 description 1
- 238000003442 catalytic alkylation reaction Methods 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000005591 charge neutralization Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- WMWXXXSCZVGQAR-UHFFFAOYSA-N dialuminum;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3] WMWXXXSCZVGQAR-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-M ethyl sulfate Chemical group CCOS([O-])(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-M 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atoms Chemical class [H]* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000001264 neutralization Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000717 retained Effects 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229940080313 sodium starch Drugs 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 238000009489 vacuum treatment Methods 0.000 description 1
Family
ID=
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69301579T2 (de) | Verbessertes Verfahren zur Gleichzeitigen Herstellung von Propylenoxid und Styrolmonomer | |
CH631693A5 (de) | Feste phosphorsaeure-katalysierte alkylierung von aromatischen kohlenwasserstoffen. | |
DE2752111C2 (US06373033-20020416-M00035.png) | ||
DE69214884T2 (de) | Verfahren zur Herstellung von Alkylbenzol | |
DE69302245T2 (de) | Regenerierung eines Alkylierungskatalysators | |
DE1493269C (US06373033-20020416-M00035.png) | ||
DE69303992T2 (de) | Regenerierung eines ALkylierungskatalysators | |
US3227774A (en) | Sulfuric alkylation acid recovery | |
DE69403512T2 (de) | Verfahren zur Rückgewinnung verbrauchter fluorierter Sulfansäure-Katalysatoren für ein Alkylierungsverfahren | |
DE1493269B (de) | Verfahren zur Alkylierung von Iso Paraffinen | |
DE1443346C3 (de) | Verfahren zur kontinuierlichen Alkylierung von Monohydroxyarylverbindungen | |
DE1443648B2 (de) | Verfahren zur kontinuierlichen herstellung von monoalkylbenzolen durch zweistufige alkylierung | |
CH479504A (de) | Verfahren zur Alkylierung eines Isoparaffins | |
DE1493269A1 (de) | Verfahren zur Alkylierung von Isoparaffinen | |
DE2149331C3 (de) | Verfahren zur Alkylierung von Isoparaffinen mit Olefinen in Gegenwart eines Schwefelsäure-Katalysators | |
DE1668741A1 (de) | Alkylierungsverfahren | |
DE1768021C3 (de) | Verfahren zur Herstellung alkylaromatischer Kohlenwasserstoffe | |
DE1593597C3 (de) | Verfahren zum Alkylieren eines Isoparaffins | |
DE1593599C3 (de) | Verfahren zur Alkylierung eines Isoparaffins | |
AT214424B (de) | Verfahren zur kontinuierlichen Alkylierung aromatischer Kohlenwasserstoffe | |
AT338219B (de) | Verfahren zur herstellung eines alkylierungsproduktes | |
DE1618911C3 (de) | Verfahren zur Herstellung eines zu waschaktiven Substanzen sulfonierbaren Alkylats | |
DE1935750B2 (de) | Verfahren zur Herstellung von Alkylbenzolen | |
CH479505A (de) | Verfahren zur Alkylierung von Paraffinkohlenwasserstoffen | |
AT206090B (de) | Verfahren zur Herstellung von Benzinkohlenwasserstoffen von hohem Antiklopfwert |