DE10347673A1 - Shoe, especially boots, with ABC protection - Google Patents
Shoe, especially boots, with ABC protection Download PDFInfo
- Publication number
- DE10347673A1 DE10347673A1 DE10347673A DE10347673A DE10347673A1 DE 10347673 A1 DE10347673 A1 DE 10347673A1 DE 10347673 A DE10347673 A DE 10347673A DE 10347673 A DE10347673 A DE 10347673A DE 10347673 A1 DE10347673 A1 DE 10347673A1
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- Prior art keywords
- layer
- membrane
- adsorption
- activated carbon
- shoe according
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/07—Linings therefor
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B7/00—Footwear with health or hygienic arrangements
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D5/00—Composition of materials for coverings or clothing affording protection against harmful chemical agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/16—Layered products comprising a layer of natural or synthetic rubber comprising polydienes homopolymers or poly-halodienes homopolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/18—Layered products comprising a layer of natural or synthetic rubber comprising butyl or halobutyl rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
- B32B9/025—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch comprising leather
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/728—Hydrophilic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/10—Natural fibres, e.g. wool, cotton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2375/00—Polyureas; Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
- B32B2437/02—Gloves, shoes
Abstract
Description
Die vorliegende Erfindung betrifft einen Schuh, insbesondere einen Stiefel, mit Schutzfunktion gegenüber chemischen Giften, insbesondere chemischen Kampfstoffen, nach dem Oberbegriff des Anspruchs 1, insbesondere für den militärischen Einsatz oder für den ABC-Einsatz.The The present invention relates to a shoe, in particular a boot, with protective function opposite chemical poisons, especially chemical warfare agents, according to the The preamble of claim 1, in particular for military use or for ABC use.
Es gibt eine Reihe von Stoffen, die von der Haut aufgenommen werden und zu schweren körperlichen Schäden führen. Als Beispiele seien das blasenziehende Lost (Gelbkreuz) und das Nervengift Sarin erwähnt. Menschen, die mit solchen Giften in Kontakt kommen können, müssen eine geeignete Schutzausrüstung tragen bzw. durch geeignete Schutzmaterialien gegen diese Gifte geschützt werden.It There are a number of substances that are absorbed by the skin and too heavy physical damage to lead. Examples are the blistering Lost (yellow cross) and the Nerve poison sarin mentioned. People who can come into contact with such poisons need one suitable protective equipment wear or by suitable protective materials against these toxins protected become.
Zum Schutz des Körpers, insbesondere der Extremitäten und des Rumpfes, gibt es entsprechende Schutzanzüge. Zum Schutz des Kopfes, insbesondere des Gesichtes, sowie der Atemwege werden in der Regel Gasmasken (ABC-Schutzmasken), gegebenenfalls zusammen mit Kapuzen, getragen.To the Protection of the body, especially the extremities and the hull, there are appropriate protective suits. To protect the head, especially the face, as well as the respiratory tract are usually Gas masks (ABC protective masks), optionally worn with hoods.
Des weiteren ist aber auch darauf zu achten, daß auch die Füße mit einem ausreichenden Schutz gegenüber solchen Giften ausgestattet sind. Insbesondere muß ein solches schützendes Schuhwerk für den militärischen Einsatz oder den ABC-Einsatz geeignet sein.Of Another is also to make sure that the feet with a adequate protection against equipped with such poisons. In particular, such must protective Footwear for the military Use or ABC use be suitable.
Zu diesem Zweck werden gemäß dem Stand der Technik für den militärischen Einsatz bzw. den ABC-Einsatz Überschuhe mit ABC-Schutz eingesetzt, die über das eigentliche Schuhwerk übergezogen werden. Dies hat den entscheidenden Nachteil, daß das Schuhwerk mit zusätzlichem Gewicht belastet wird und zudem der Tragekomfort aufgrund des ABC-Überschuhs drastisch reduziert wird. Schließlich ist bei der Verwendung des ABC-Überschuhs keine effiziente abdichtende Verbindung mit dem ABC-Schutzanzug möglich, so daß chemische Gifte, z. B. Kampfstoffe, den Übergang von ABC-Überschuh und ABC-Schutzanzug passieren und auf den Träger des ABC-Schutzanzugs einwirken können.To For this purpose, according to the state of Technology for the military Use or the ABC use overshoes used with ABC protection over the actual footwear is pulled over become. This has the significant disadvantage that the footwear with additional Weight is burdened and also the wearing comfort due to the ABC overshoe drastically reduced. Finally, in use of the ABC overshoe no efficient sealing connection with the ABC protective suit possible, so that chemical Poisons, z. As warfare agents, the transition from ABC overshoe and ABC protective suit and act on the wearer of the ABC protective suit can.
Die alternative Verwendung von ABC-Schutzsocken, die z. B. in herkömmlichen Militärstiefeln getragen werden können, ist gleichermaßen wenig effizient, da diese zum einen nicht das Eindringen von Giften in das eigentliche Schuhwerk verhindern können und zum anderen der Tragekomfort nicht sehr groß ist. Auch hier besteht das Problem der mangelnden Abdichtung des Übergangs zum ABC-Schutzanzug.The alternative use of ABC protective socks, e.g. B. in conventional Military boots can be worn is alike not very efficient, as these do not prevent the ingress of toxins in the actual footwear can prevent and on the other hand, the comfort is very big. Again, there is the problem of lack of sealing of the transition to the ABC protective suit.
Es ist daher die Aufgabe der vorliegenden Erfindung, einen Schuh, insbesondere einen Stiefel, mit Schutzfunktion gegenüber chemischen Giften, insbesondere chemischen Kampfstoffen, bereitzustellen, welcher sich insbesondere für den militärischen Einsatz oder den ABC-Einsatz eignet und die zuvor geschilderten Nachteile des Standes der Technik zumindest teilweise vermeidet.It is therefore the object of the present invention, a shoe, in particular a boot, with protection against chemical toxins, in particular chemical warfare agents, which in particular for the military Use or the ABC use and the previously described Disadvantages of the prior art at least partially avoids.
Zur Lösung der zuvor geschilderten Aufgabe schlägt die vorliegende Erfindung ein Schuh, insbesondere einen Stiefel (z. B. Militärstiefel oder ABC-Schutzstiefel), gemäß Anspruch 1 vor. Weitere, vorteilhafte Ausgestaltungen des erfindungsgemäßen Schuhs sind Gegenstand der Unteransprüche.to solution The object described above proposes the present invention a shoe, in particular a boot (eg military boots or NBC protective boots), according to claim 1 ago. Further, advantageous embodiments of the shoe according to the invention are the subject of the dependent claims.
Die grundlegende Idee der vorliegenden Erfindung besteht darin, einen Schuh, insbesondere einen Stiefel, mit mehrschichtigem Schichtaufbau, welcher einen im Tragezustand vom Fuß abgewandte Außenschicht und eine der Außenschicht zugeordnete, im Tragezustand dem Fuß zugewandte Innenschicht, insbesondere ein Schuhinnenfutter, aufweist, dadurch mit einer Schutzfunktion gegenüber chemischen Giften, insbesondere chemischen Kampfstoffen, auszurüsten, daß zwischen der Außenschicht und der Innenschicht zusätzlich eine Adsorptionsschicht auf Basis eines chemische Gifte adsorbierenden Adsorptionsmaterials, insbesondere Aktivkohle, angeordnet bzw. vorgesehen ist.The basic idea of the present invention is a Shoe, in particular a boot, with a multilayer layer structure, which in the wearing state facing away from the foot outer layer and one of the outer layer associated, in the wearing state the foot-facing inner layer, in particular a shoe lining, having, thereby with a protective function towards chemical Poisons, especially chemical warfare agents, equip that between the outer layer and the inner layer in addition an adsorption layer based on a chemical poisons adsorbing Adsorption, in particular activated carbon, arranged or provided is.
Auf diese Weise wird erreicht, daß gegebenenfalls durch die Außenschicht des Schuhs eingedrungene chemische Gifte, insbesondere chemische Kampfstoffe, nicht mit dem Fuß in Kontakt kommen können, da sie vom Adsorptionsmaterial, insbesondere Aktivkohle, der Adsorptionsschicht aufgenommen bzw. adsorbiert und auf diese Weise unschädlich gemacht werden können.On this way is achieved, if necessary through the outer layer penetrated by the shoe chemical poisons, especially chemical warfare agents, not with your foot in Can come in contact, because of the adsorption material, in particular activated carbon, the adsorption layer absorbed or adsorbed and rendered harmless in this way can be.
Die Schutzfunktion der Adsorptionsschicht bzw. letztendlich des Schuhs kann noch dadurch gesteigert werden, daß der erfindungsgemäße Schuh zusätzlich mit mindestens einer Membran ausgestattet wird, die gegenüber chemischen Giften, insbesondere chemischen Kampfstoffen, zumindest im wesentlichen undurchlässig ist oder deren Durchtritt zumindest verzögert. Grundsätzlich kann die Membran entweder zwischen der Außenschicht und der Adsorptionsschicht oder aber zwischen der Innenschicht und der Adsorptionsschicht angeordnet sein. Vorteilhafterweise ist die Membran aber zwischen der Außenschicht und der Adsorptionsschicht angeordnet, so daß gegebenenfalls eingedrungene chemische Gifte, insbesondere chemische Kampfstoffe, die Adsorptionsschicht nicht oder zumindest zu einem überwiegenden Teil gar nicht erst erreichen, so daß die Adsorptionskapazität der Adsorptionsschicht quasi unerschöpflich bleibt. Durch das Vorsehen der zusätzlichen Membran wird gleichzeitig eine gute Dekontaminierbarkeit und Regenerierbarkeit des erfindungsgemäßen Schuhs erreicht.The protective function of the adsorption layer or ultimately of the shoe can be increased even further by providing the shoe according to the invention with at least one membrane which is at least substantially impermeable to chemical poisons, in particular chemical warfare agents, or at least delays their passage. In principle, the membrane can be arranged either between the outer layer and the adsorption layer or between the inner layer and the adsorption layer. Advantageously, however, the membrane is arranged between the outer layer and the adsorption layer, so that any penetrated chemical poisons, especially chemical warfare agents, the adsorption or not at least for the most part not reach, so that the adsorption capacity of the adsorption remains almost inexhaustible. By providing the additional membrane a good decontamination and regenerability of the shoe according to the invention is achieved at the same time.
Weitere Vorteile, Eigenschaften, Aspekte und Merkmale der vorliegenden Erfindung ergeben sich aus der folgenden Beschreibung eines in der Zeichnung dargestellten, bevorzugten Ausführungsbeispiels. Es zeigt:Further Advantages, characteristics, aspects and features of the present invention will be apparent from the following description of one in the drawing illustrated, preferred embodiment. It shows:
Wie
aus den
Des
weiteren kann vorgesehen sein, daß zwischen der Innenschicht
Im
allgemeinen sind die einzelnen Schichten
Die
einzelnen Schichten
Gemäß einer
alternativen Ausführungsform erstrecken
sich die einzelnen Schichten
Damit
chemische Gifte, insbesondere Kampfstoffe, nicht über die
Sohle
Was
die Außenschicht
Was
das Material für
die Innenschicht
Was
die Adsorptionsschicht
Die
guten Trageeigenschaften des erfindungsgemäßen Schuhs
Im
allgemeinen ist die Adsorptionsschicht
Gemäß einer
besonderen, in den
Gemäß einer
alternativen Ausführungsform kann
die Adsorptionsschicht
Gleichermaßen ist
es auch möglich,
als Adsorptionsmaterial
Zur
Erhöhung
der Adsorptionseffizienz bzw. Adsorptionsleistung besteht die Möglichkeit,
das Adsorptionsmaterial
Was
die gegebenenfalls vorgesehene Membran
Die
Membran
Die
gegebenenfalls vorgesehene Membran
Die
gegebenenfalls vorhandene Membran
Gemäß einer
besonderen Ausführungsform kann
die gegebenenfalls vorhandene Membran
Um
die Stabilität
der gegebenenfalls vorhandenen Membran
Zur
Erhöhung
der des Tragekomforts einerseits und zur Erzielung einer guten Verschleißbeständigkeit
andererseits ist es vorteilhaft, wenn die Membran
Gemäß einer
besonderen, in den
Der erfindungsgemäße Schuh bietet einen effizienten Schutz gegenüber chemischen Giften, insbesondere chemischen Kampfstoffen, bei gleichzeitig hohem Tragekomfort. Der entscheidende Vorteil des Schuhs nach der vorliegenden Erfindung besteht darin, daß die Schutzfunktion gegenüber chemischen Giften in den Schuh selbst integriert ist und kein zusätzlicher Ausrüstungsgegenstand (z. B. Überschuh, Socke etc.) erforderlich ist. Dadurch werden – im Vergleich zu den zuvor geschilderten Methoden des Standes der Technik – nicht nur eine beträchtliche Gewichtseinsparung und ein erhöhter Tragekomfort erreicht, sondern es wird zudem die Möglichkeit einer effizienten abdichtenden Verbindung des Übergangs zu einem ABC-Schutzanzug eröffnet, so daß chemische Gifte, z. B. Kampfstoffe, den Übergang von Schuhwerk/Schutzanzug nicht bzw. nicht ohne weiteres passieren können. Aufgrund dieser Eigenschaften eignet sich der Schuh nach der vorliegenden Erfindung insbesondere für den militärischen Einsatz oder den ABC-Einsatz (z. B. in der Form eines Militärstiefels oder ABC-Schutzstiefels).Of the shoe according to the invention provides efficient protection against chemical toxins, in particular chemical warfare agents, combined with high wearing comfort. Of the decisive advantage of the shoe according to the present invention is that the Protective function chemical poisons is integrated into the shoe itself and no additional Of equipment (eg overshoe, Sock etc.) is required. This will - compared to the previous ones described methods of the prior art - not only a considerable Weight saving and an increased Comfort is achieved, but it is also the possibility an efficient sealing connection of the transition to an ABC protective suit opened, so that chemical Poisons, z. As warfare agents, the transition of footwear / protective suit not or not readily happen can. Because of these properties, the shoe is suitable for the present Invention especially for the military mission or the ABC deployment (eg in the form of a military boot or ABC protective boot).
Infolge der hohen Effizienz der Schutzfunktion der Adsorptionsschicht, die bedarfsweise durch die Verwendung einer Membran gegebenenfalls erhöht werden kann, lassen sich auch atmungsaktive Schuhaußenmaterialen, wie z. B. Leder, einsetzen, so daß sich auf diese Weise der Tragekomfort noch erhöhen läßt, ohne daß der Träger des Schuhs einer erhöhten Gefährdung durch die Verwendung eines atmungsaktiven Schuhaußenmaterials ausgesetzt ist.As a result the high efficiency of the protective function of the adsorption layer, the if necessary, be increased by the use of a membrane can also be breathable Schuhaußenmaterialen, such. Leather, insert, so that in this way, the wearing comfort can be increased without the wearer of the shoe increased risk of the use of a breathable shoe outer material is exposed.
Aufgrund der guten Biegsamkeit der einzelnen Schichten des erfindungsgemäßen Schuhs bzw. des Schichtaufbaus insgesamt wird nicht nur ein guter Tragekomfort erreicht, sondern außerdem auch eine gute Verschleißbeständigkeit des erfindungsgemäßen Schuhs.Due to the good flexibility of the single NEN layers of the shoe according to the invention or of the layer structure overall not only a good wearing comfort is achieved, but also also a good wear resistance of the shoe according to the invention.
Durch die erfindungsgemäße Ausgestaltung des Schuhs nach der vorliegenden Erfindung wird eine ausgezeichnete Barrierewirkung gegenüber chemischen Kampfstoffen erreicht. Die Barrierewirkung gegenüber chemischen Kampfstoffen, insbesondere Bis-[2-chlorethyl]sulfid (synonym auch als Senfgas, Lost oder Gelbkreuz bezeichnet), gemessen nach CRDEC-SP-84010, Methode 2.2, beträgt höchstens 4 μg/cm2 pro 24 h, insbesondere höchstens 3,5 μg/cm2 pro 24 h, vorzugsweise höchstens 3,0 μg/cm2 pro 24 h, besonders bevorzugt höchstens 2,5 μg/cm2 pro 24 h.By the inventive design of the shoe according to the present invention, an excellent barrier effect against chemical warfare agents is achieved. The barrier effect against chemical warfare agents, in particular bis [2-chloroethyl] sulfide (also referred to as mustard gas, lost or yellow cross), measured according to CRDEC-SP-84010, Method 2.2, is at most 4 μg / cm 2 per 24 h, in particular at most 3.5 μg / cm 2 per 24 h, preferably at most 3.0 μg / cm 2 per 24 h, more preferably at most 2.5 μg / cm 2 per 24 h.
Die Herstellung des erfindungsgemäßen Schuhs kann in an sich bekannter Weise erfolgen. Dies ist dem mit der Herstellung von Schuhwerk befaßten Fachmann bestens bekannt, so daß es diesbezüglich keiner weitergehenden Ausführungen bedarf.The Production of the shoe according to the invention can be done in a conventional manner. This is the one with the production of footwear Professional well known, so that it in this regard no further comments requirement.
Weitere Ausgestaltungen, Abwandlungen und Variationen der vorliegenden Erfindung sind für den Fachmann beim Lesen der Beschreibung ohne weiteres erkennbar und realisierbar, ohne daß er dabei den Rahmen der vorliegenden Erfindung verläßt.Further Embodiments, modifications and variations of the present invention are for the Person skilled in the reading of the description readily apparent and realizable without him while leaving the scope of the present invention.
Claims (24)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10347673A DE10347673B4 (en) | 2003-10-09 | 2003-10-09 | Shoe, especially boots, with ABC protection |
US10/834,776 US8176659B2 (en) | 2003-10-09 | 2004-04-28 | Protective footwear |
EP07016528A EP1852026A1 (en) | 2003-10-09 | 2004-07-28 | Shoe, in particular boot, with ABC protection |
DE502004005812T DE502004005812D1 (en) | 2003-10-09 | 2004-07-28 | Shoe, especially boots, with ABC protection |
AT04017790T ATE382274T1 (en) | 2003-10-09 | 2004-07-28 | SHOE, ESPECIALLY BOOTS, WITH ABC PROTECTION |
EP07016529.5A EP1852027B1 (en) | 2003-10-09 | 2004-07-28 | Shoe, in particular boot, with CBN protection |
EP04017790A EP1522229B1 (en) | 2003-10-09 | 2004-07-28 | Shoe, in particular boot, with ABC protection |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10347673A DE10347673B4 (en) | 2003-10-09 | 2003-10-09 | Shoe, especially boots, with ABC protection |
Publications (2)
Publication Number | Publication Date |
---|---|
DE10347673A1 true DE10347673A1 (en) | 2005-06-09 |
DE10347673B4 DE10347673B4 (en) | 2012-01-12 |
Family
ID=34306391
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE10347673A Expired - Fee Related DE10347673B4 (en) | 2003-10-09 | 2003-10-09 | Shoe, especially boots, with ABC protection |
DE502004005812T Active DE502004005812D1 (en) | 2003-10-09 | 2004-07-28 | Shoe, especially boots, with ABC protection |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE502004005812T Active DE502004005812D1 (en) | 2003-10-09 | 2004-07-28 | Shoe, especially boots, with ABC protection |
Country Status (4)
Country | Link |
---|---|
US (1) | US8176659B2 (en) |
EP (3) | EP1852027B1 (en) |
AT (1) | ATE382274T1 (en) |
DE (2) | DE10347673B4 (en) |
Cited By (3)
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2003
- 2003-10-09 DE DE10347673A patent/DE10347673B4/en not_active Expired - Fee Related
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2004
- 2004-04-28 US US10/834,776 patent/US8176659B2/en active Active
- 2004-07-28 EP EP07016529.5A patent/EP1852027B1/en active Active
- 2004-07-28 EP EP04017790A patent/EP1522229B1/en active Active
- 2004-07-28 EP EP07016528A patent/EP1852026A1/en not_active Withdrawn
- 2004-07-28 AT AT04017790T patent/ATE382274T1/en not_active IP Right Cessation
- 2004-07-28 DE DE502004005812T patent/DE502004005812D1/en active Active
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7465490B2 (en) | 2003-10-22 | 2008-12-16 | Blucher Gmbh | Protective clothing providing nbc protection |
EP3128203A1 (en) * | 2015-08-07 | 2017-02-08 | tremco illbruck Produktion GmbH | Damping element for air springs |
DE102015113023A1 (en) * | 2015-08-07 | 2017-02-09 | Tremco Illbruck Produktion Gmbh | Damping element for air springs |
EP3731939B1 (en) | 2017-12-26 | 2022-04-06 | Paul Boye Technologies | Improved nrbc protective garment |
Also Published As
Publication number | Publication date |
---|---|
EP1522229A1 (en) | 2005-04-13 |
DE502004005812D1 (en) | 2008-02-14 |
EP1522229B1 (en) | 2008-01-02 |
EP1852026A1 (en) | 2007-11-07 |
US20050076541A1 (en) | 2005-04-14 |
EP1852027A1 (en) | 2007-11-07 |
ATE382274T1 (en) | 2008-01-15 |
DE10347673B4 (en) | 2012-01-12 |
EP1852027B1 (en) | 2016-07-06 |
US8176659B2 (en) | 2012-05-15 |
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