DE102014100996B4 - Verfahren zur Herstellung von Neopentylglykol - Google Patents

Verfahren zur Herstellung von Neopentylglykol Download PDF

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Publication number
DE102014100996B4
DE102014100996B4 DE102014100996.7A DE102014100996A DE102014100996B4 DE 102014100996 B4 DE102014100996 B4 DE 102014100996B4 DE 102014100996 A DE102014100996 A DE 102014100996A DE 102014100996 B4 DE102014100996 B4 DE 102014100996B4
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DE
Germany
Prior art keywords
isobutyraldehyde
neopentyl glycol
formaldehyde
takes place
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE102014100996.7A
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German (de)
English (en)
Other versions
DE102014100996A1 (de
Inventor
Matthias Eisenacher
Kurt Schalapski
Heinz Strutz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oxea GmbH
Original Assignee
OQ Chemicals GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE102014100996.7A priority Critical patent/DE102014100996B4/de
Application filed by OQ Chemicals GmbH filed Critical OQ Chemicals GmbH
Priority to PCT/EP2015/051466 priority patent/WO2015113928A1/de
Priority to EP15707553.2A priority patent/EP3099656B1/de
Priority to JP2016536163A priority patent/JP6373385B2/ja
Priority to US15/037,346 priority patent/US20160326073A1/en
Priority to CN201580002718.7A priority patent/CN105764879B/zh
Priority to KR1020167011714A priority patent/KR101846755B1/ko
Publication of DE102014100996A1 publication Critical patent/DE102014100996A1/de
Application granted granted Critical
Publication of DE102014100996B4 publication Critical patent/DE102014100996B4/de
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/862—Iron and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/866—Nickel and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C07C29/84—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by extractive distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/94—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/75—Reactions with formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/19—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen containing hydroxy groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE102014100996.7A 2014-01-28 2014-01-28 Verfahren zur Herstellung von Neopentylglykol Expired - Fee Related DE102014100996B4 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE102014100996.7A DE102014100996B4 (de) 2014-01-28 2014-01-28 Verfahren zur Herstellung von Neopentylglykol
EP15707553.2A EP3099656B1 (de) 2014-01-28 2015-01-26 Verfahren zur herstellung von neopentylglykol
JP2016536163A JP6373385B2 (ja) 2014-01-28 2015-01-26 ネオペンチルグリコールの製造方法
US15/037,346 US20160326073A1 (en) 2014-01-28 2015-01-26 Process for producing neopentyl glycol
PCT/EP2015/051466 WO2015113928A1 (de) 2014-01-28 2015-01-26 Verfahren zur herstellung von neopentylglykol
CN201580002718.7A CN105764879B (zh) 2014-01-28 2015-01-26 生产新戊二醇的方法
KR1020167011714A KR101846755B1 (ko) 2014-01-28 2015-01-26 네오펜틸 글리콜의 제조방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102014100996.7A DE102014100996B4 (de) 2014-01-28 2014-01-28 Verfahren zur Herstellung von Neopentylglykol

Publications (2)

Publication Number Publication Date
DE102014100996A1 DE102014100996A1 (de) 2015-07-30
DE102014100996B4 true DE102014100996B4 (de) 2018-11-15

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
DE102014100996.7A Expired - Fee Related DE102014100996B4 (de) 2014-01-28 2014-01-28 Verfahren zur Herstellung von Neopentylglykol

Country Status (7)

Country Link
US (1) US20160326073A1 (enExample)
EP (1) EP3099656B1 (enExample)
JP (1) JP6373385B2 (enExample)
KR (1) KR101846755B1 (enExample)
CN (1) CN105764879B (enExample)
DE (1) DE102014100996B4 (enExample)
WO (1) WO2015113928A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3747855B1 (de) * 2019-06-04 2024-01-10 OQ Chemicals GmbH Verfahren zur kontinuierlichen herstellung von diolen aus aldehyden mittels raney-cobalt katalyse
KR102690122B1 (ko) * 2019-09-27 2024-07-30 주식회사 엘지화학 네오펜틸글리콜의 제조방법
KR102680195B1 (ko) * 2020-10-16 2024-06-28 주식회사 엘지화학 네오펜틸 글리콜의 제조방법
KR20250042393A (ko) * 2023-09-20 2025-03-27 주식회사 엘지화학 네오펜틸 글리콜의 제조 방법

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10317545A1 (de) * 2003-04-16 2004-11-04 Basf Ag Verfahren zur Herstellung von Neopentylglykol und Hydroxypivalinsäureneopentylglykolester
WO2008107333A1 (de) * 2007-03-02 2008-09-12 Basf Se Verfahren zur herstellung von hydroxypivalinaldehyd und neopentylglykol
WO2010000382A2 (de) * 2008-07-02 2010-01-07 Oxea Deutschland Gmbh Verfahren zur herstellung von neopentylglykol
WO2012143309A1 (de) * 2011-04-19 2012-10-26 Basf Se Verfahren zur herstellung von neopentylglykol

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5118928A (ja) * 1974-08-08 1976-02-14 Aikoh Co Uwatsugizokaiyoyumenhifukuban
DE2827795A1 (de) * 1978-06-24 1980-01-10 Huels Chemische Werke Ag Verfahren zur gewinnung von reinem neopentylglykol
FI108029B (fi) * 1997-12-30 2001-11-15 Neste Oy Menetelmä neopentyyliglykolin valmistamiseksi
US7230150B2 (en) * 2001-04-18 2007-06-12 Grt, Inc. Zone reactor
US7851645B2 (en) * 2008-02-11 2010-12-14 Catalytic Distillation Technologies Process for continuous production of organic carbonates or organic carbamates and solid catalysts therefore
US8884076B2 (en) * 2008-12-09 2014-11-11 Basf Se Method for preparing polymethylols
TW201247618A (en) * 2011-04-19 2012-12-01 Basf Se Process for preparing neopentyl glycol
CN102391068A (zh) * 2011-07-29 2012-03-28 淇县彤邦化工有限公司 一种蒸馏水连续运行新工艺

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10317545A1 (de) * 2003-04-16 2004-11-04 Basf Ag Verfahren zur Herstellung von Neopentylglykol und Hydroxypivalinsäureneopentylglykolester
WO2008107333A1 (de) * 2007-03-02 2008-09-12 Basf Se Verfahren zur herstellung von hydroxypivalinaldehyd und neopentylglykol
WO2010000382A2 (de) * 2008-07-02 2010-01-07 Oxea Deutschland Gmbh Verfahren zur herstellung von neopentylglykol
WO2012143309A1 (de) * 2011-04-19 2012-10-26 Basf Se Verfahren zur herstellung von neopentylglykol

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DPMAinformativ (Version 2.8.1 – 5/2015) [https://www.dpma.de/ponline/ipia/dpmainformativ_03.pdf] *

Also Published As

Publication number Publication date
KR20160114040A (ko) 2016-10-04
CN105764879B (zh) 2017-09-08
US20160326073A1 (en) 2016-11-10
CN105764879A (zh) 2016-07-13
EP3099656B1 (de) 2018-03-14
JP6373385B2 (ja) 2018-08-15
KR101846755B1 (ko) 2018-05-18
WO2015113928A1 (de) 2015-08-06
DE102014100996A1 (de) 2015-07-30
EP3099656A1 (de) 2016-12-07
JP2017510543A (ja) 2017-04-13

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