DE102013009635A1 - Titandioxid-haltige und Carbonat-haltige Kompositpigmente und Verfahren zu ihrer Herstellung - Google Patents
Titandioxid-haltige und Carbonat-haltige Kompositpigmente und Verfahren zu ihrer Herstellung Download PDFInfo
- Publication number
- DE102013009635A1 DE102013009635A1 DE102013009635.9A DE102013009635A DE102013009635A1 DE 102013009635 A1 DE102013009635 A1 DE 102013009635A1 DE 102013009635 A DE102013009635 A DE 102013009635A DE 102013009635 A1 DE102013009635 A1 DE 102013009635A1
- Authority
- DE
- Germany
- Prior art keywords
- titanium dioxide
- particles
- composite pigment
- carbonate
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 136
- 239000000049 pigment Substances 0.000 title claims abstract description 112
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 61
- 239000002131 composite material Substances 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 34
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 title claims description 14
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000002245 particle Substances 0.000 claims abstract description 106
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 56
- 239000011575 calcium Substances 0.000 claims abstract description 26
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 24
- 239000000945 filler Substances 0.000 claims abstract description 24
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 20
- 239000011256 inorganic filler Substances 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000012766 organic filler Substances 0.000 claims abstract description 11
- 238000000576 coating method Methods 0.000 claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 239000004033 plastic Substances 0.000 claims abstract description 5
- 229920003023 plastic Polymers 0.000 claims abstract description 5
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 5
- 239000000725 suspension Substances 0.000 claims description 30
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 13
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical class [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 13
- -1 oxides Chemical class 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 9
- 239000007900 aqueous suspension Substances 0.000 claims description 7
- 238000011065 in-situ storage Methods 0.000 claims description 7
- 239000001095 magnesium carbonate Substances 0.000 claims description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 6
- CXUJOBCFZQGUGO-UHFFFAOYSA-F calcium trimagnesium tetracarbonate Chemical compound [Mg++].[Mg++].[Mg++].[Ca++].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O CXUJOBCFZQGUGO-UHFFFAOYSA-F 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 6
- 229910000515 huntite Inorganic materials 0.000 claims description 6
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 5
- 150000007514 bases Chemical class 0.000 claims description 4
- 239000010459 dolomite Substances 0.000 claims description 4
- 229910000514 dolomite Inorganic materials 0.000 claims description 4
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 4
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 3
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 150000004679 hydroxides Chemical class 0.000 claims description 3
- 235000011160 magnesium carbonates Nutrition 0.000 claims description 3
- 235000019362 perlite Nutrition 0.000 claims description 3
- 235000021317 phosphate Nutrition 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- 150000004760 silicates Chemical class 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- XBVLXSQOCZMOFV-UHFFFAOYSA-N carbonic acid oxygen(2-) titanium(4+) Chemical compound [O--].[O--].[Ti+4].OC(O)=O XBVLXSQOCZMOFV-UHFFFAOYSA-N 0.000 claims description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 239000010451 perlite Substances 0.000 claims description 2
- 239000004606 Fillers/Extenders Substances 0.000 abstract description 15
- 239000006185 dispersion Substances 0.000 abstract description 10
- 238000001556 precipitation Methods 0.000 abstract description 6
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract description 5
- 238000000149 argon plasma sintering Methods 0.000 abstract description 4
- 239000011246 composite particle Substances 0.000 abstract description 4
- 229910052749 magnesium Inorganic materials 0.000 abstract description 4
- 230000003287 optical effect Effects 0.000 abstract description 4
- 229910052814 silicon oxide Inorganic materials 0.000 abstract description 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 235000010216 calcium carbonate Nutrition 0.000 description 21
- 229910010413 TiO 2 Inorganic materials 0.000 description 16
- 239000000203 mixture Substances 0.000 description 16
- 239000003973 paint Substances 0.000 description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000843 powder Substances 0.000 description 7
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 7
- 125000006850 spacer group Chemical group 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000000123 paper Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 239000001110 calcium chloride Substances 0.000 description 3
- 229910001628 calcium chloride Inorganic materials 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 239000006259 organic additive Substances 0.000 description 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 239000010954 inorganic particle Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000004579 marble Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- GGMMWVHTLAENAS-UHFFFAOYSA-M (1,1-diethylpyrrolidin-1-ium-3-yl) 2-hydroxy-2,2-diphenylacetate;bromide Chemical compound [Br-].C1[N+](CC)(CC)CCC1OC(=O)C(O)(C=1C=CC=CC=1)C1=CC=CC=C1 GGMMWVHTLAENAS-UHFFFAOYSA-M 0.000 description 1
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 241000276425 Xiphophorus maculatus Species 0.000 description 1
- 150000008043 acidic salts Chemical class 0.000 description 1
- 239000003619 algicide Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- BAJCNPGPHMFYJP-UHFFFAOYSA-L calcium oxygen(2-) titanium(4+) carbonate Chemical group [O-2].[O-2].[Ca+2].[Ti+4].[O-]C([O-])=O BAJCNPGPHMFYJP-UHFFFAOYSA-L 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- XFVGXQSSXWIWIO-UHFFFAOYSA-N chloro hypochlorite;titanium Chemical compound [Ti].ClOCl XFVGXQSSXWIWIO-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- AKMZSNOVSFMEQQ-UHFFFAOYSA-K dialuminum oxygen(2-) phosphate Chemical compound [O-2].[Al+3].[Al+3].[O-]P([O-])([O-])=O AKMZSNOVSFMEQQ-UHFFFAOYSA-K 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical class O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
- C09C1/0084—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound containing titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3653—Treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/002—Tissue paper; Absorbent paper
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/62—L* (lightness axis)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/64—Optical properties, e.g. expressed in CIELAB-values b* (yellow-blue axis)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102013009635.9A DE102013009635A1 (de) | 2012-06-28 | 2013-06-10 | Titandioxid-haltige und Carbonat-haltige Kompositpigmente und Verfahren zu ihrer Herstellung |
| PCT/EP2013/001828 WO2014000874A1 (de) | 2012-06-28 | 2013-06-20 | Titandioxid-haltige und carbonat-haltige kompositpigmente und verfahren zu ihrer herstellung |
| HK15107307.6A HK1206769B (zh) | 2012-06-28 | 2013-06-20 | 含二氧化钛及含碳酸盐的复合色素及其制造方法 |
| IN2664MUN2014 IN2014MN02664A (https=) | 2012-06-28 | 2013-06-20 | |
| EP13734330.7A EP2877539B1 (de) | 2012-06-28 | 2013-06-20 | Titandioxid-haltige und carbonat-haltige kompositpigmente und verfahren zu ihrer herstellung |
| CN201380031741.XA CN104411779B (zh) | 2012-06-28 | 2013-06-20 | 含二氧化钛及含碳酸盐的复合色素及其制造方法 |
| BR112014029961-7A BR112014029961B1 (pt) | 2012-06-28 | 2013-06-20 | Pigmento composto que contém dióxido de titânio e carbonato, processo para a produção e uso de partículas de pigmento composto |
| ES13734330.7T ES2687980T3 (es) | 2012-06-28 | 2013-06-20 | Pigmentos compuestos que contienen dióxido de titanio y carbonato y procedimiento para su producción |
| US13/930,188 US8858701B2 (en) | 2012-06-28 | 2013-06-28 | Composite pigments comprising titanium dioxide and carbonate and method for producing |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102012012899 | 2012-06-28 | ||
| DE102012012899.1 | 2012-06-28 | ||
| DE102013009635.9A DE102013009635A1 (de) | 2012-06-28 | 2013-06-10 | Titandioxid-haltige und Carbonat-haltige Kompositpigmente und Verfahren zu ihrer Herstellung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102013009635A1 true DE102013009635A1 (de) | 2014-05-22 |
Family
ID=48747504
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102013009635.9A Withdrawn DE102013009635A1 (de) | 2012-06-28 | 2013-06-10 | Titandioxid-haltige und Carbonat-haltige Kompositpigmente und Verfahren zu ihrer Herstellung |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8858701B2 (https=) |
| EP (1) | EP2877539B1 (https=) |
| CN (1) | CN104411779B (https=) |
| BR (1) | BR112014029961B1 (https=) |
| DE (1) | DE102013009635A1 (https=) |
| ES (1) | ES2687980T3 (https=) |
| IN (1) | IN2014MN02664A (https=) |
| WO (1) | WO2014000874A1 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2883917A1 (de) | 2013-12-13 | 2015-06-17 | Kronos International, Inc. | Calciumphosphat-haltige Kompositpigmente und Verfahren zu ihrer Herstellung |
| EP2886613A1 (de) | 2013-12-17 | 2015-06-24 | Kronos International, Inc. | Verfahren zur Herstellung von Kompositpartikeln |
| EP3081602A1 (de) | 2015-04-17 | 2016-10-19 | Kronos International, Inc. | Aluminiumhydroxid-haltige kompositpigmente und verfahren zu ihrer herstellung |
| ES2848113T3 (es) * | 2015-03-10 | 2021-08-05 | Kronos Int Inc | Pigmentos compuestos que contienen hidróxido de aluminio y procedimiento para su preparación |
| DE102015002946A1 (de) | 2015-03-10 | 2016-09-15 | Kronos International, Inc. | Aluminiumhydroxid-haltige Kompositpigmente und Verfahren zu ihrer Herstellung |
| CN104893364A (zh) * | 2015-06-03 | 2015-09-09 | 安徽省铜陵县牛山矿业有限责任公司 | 矿物/TiO2复合颗粒材料生产工艺及生产线 |
| WO2016200945A1 (en) * | 2015-06-09 | 2016-12-15 | Imerys Pigments, Inc. | Compositions and methods for reducing or extending titanium dioxide in paper |
| EP3202858A1 (de) * | 2016-02-02 | 2017-08-09 | Kronos International, Inc. | Herstellung von matten lacken und druckfarben |
| EP3985073A1 (en) | 2016-03-16 | 2022-04-20 | Swimc, LLC | Opacifying clusters for use in paint compositions |
| CN106189369A (zh) * | 2016-07-11 | 2016-12-07 | 滁州格锐矿业有限责任公司 | 一种钛白复合粉制备方法 |
| KR102562875B1 (ko) * | 2016-10-24 | 2023-08-02 | 이시하라 산교 가부시끼가이샤 | 복합 안료 및 이의 제조 방법, 복합 안료를 함유하는 페인트 조성물, 및 코팅 필름 |
| CN109651851A (zh) * | 2019-01-15 | 2019-04-19 | 上海崇明木棉花开手工社 | 天然植物来源的有机-无机杂化纳米颜料及制法和应用 |
| TW202042781A (zh) * | 2019-05-03 | 2020-12-01 | 瑞士商歐米亞國際公司 | 在口腔保健組成物中作為白色顏料的經表面處理之含鎂離子材料 |
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- 2013-06-20 WO PCT/EP2013/001828 patent/WO2014000874A1/de not_active Ceased
- 2013-06-20 IN IN2664MUN2014 patent/IN2014MN02664A/en unknown
- 2013-06-20 EP EP13734330.7A patent/EP2877539B1/de active Active
- 2013-06-20 CN CN201380031741.XA patent/CN104411779B/zh active Active
- 2013-06-20 ES ES13734330.7T patent/ES2687980T3/es active Active
- 2013-06-20 BR BR112014029961-7A patent/BR112014029961B1/pt active IP Right Grant
- 2013-06-28 US US13/930,188 patent/US8858701B2/en active Active
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| DE1792118A1 (de) | 1967-07-24 | 1971-10-21 | Du Pont | Verfahren zur Herstellung von Titandioxidpigmenten |
| EP0861299B1 (en) | 1995-11-13 | 2000-04-05 | E.I. Du Pont De Nemours And Company | TiO2-PIGMENT COATED WITH SMALL INORGANIC PARTICLES |
| EP0956316B1 (en) | 1996-03-04 | 2004-05-26 | FP-Pigments Oy | Pigment particles coated with precipitated calcium carbonate and a process for the preparation thereof |
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Also Published As
| Publication number | Publication date |
|---|---|
| US20140000484A1 (en) | 2014-01-02 |
| IN2014MN02664A (https=) | 2015-08-28 |
| US8858701B2 (en) | 2014-10-14 |
| ES2687980T3 (es) | 2018-10-30 |
| CN104411779A (zh) | 2015-03-11 |
| BR112014029961A2 (pt) | 2017-06-27 |
| CN104411779B (zh) | 2019-03-15 |
| EP2877539B1 (de) | 2018-07-18 |
| HK1206769A1 (en) | 2016-01-15 |
| WO2014000874A1 (de) | 2014-01-03 |
| BR112014029961B1 (pt) | 2021-08-31 |
| EP2877539A1 (de) | 2015-06-03 |
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