DE102010033844B4 - Verfahren zur Gewinnung von Di-Trimethylolpropan und mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung - Google Patents

Verfahren zur Gewinnung von Di-Trimethylolpropan und mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung Download PDF

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Publication number
DE102010033844B4
DE102010033844B4 DE102010033844A DE102010033844A DE102010033844B4 DE 102010033844 B4 DE102010033844 B4 DE 102010033844B4 DE 102010033844 A DE102010033844 A DE 102010033844A DE 102010033844 A DE102010033844 A DE 102010033844A DE 102010033844 B4 DE102010033844 B4 DE 102010033844B4
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DE
Germany
Prior art keywords
trimethylolpropane
aqueous solution
acidic
distillation
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE102010033844A
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German (de)
English (en)
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DE102010033844A1 (de
DE102010033844A8 (de
Inventor
Dr. Kreickmann Thorsten
Dr. Frey Guido D.
Norman Nowotny
Dr. Strutz Heinz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oxea GmbH
Original Assignee
OQ Chemicals GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE102010033844A priority Critical patent/DE102010033844B4/de
Application filed by OQ Chemicals GmbH filed Critical OQ Chemicals GmbH
Priority to JP2013523514A priority patent/JP5697220B2/ja
Priority to EP11748262.0A priority patent/EP2603482B1/de
Priority to PCT/EP2011/003788 priority patent/WO2012019714A1/de
Priority to US13/810,723 priority patent/US8987523B2/en
Priority to KR1020137003267A priority patent/KR101802136B1/ko
Priority to CN201180037940.2A priority patent/CN103052616B/zh
Priority to TW100128270A priority patent/TWI403496B/zh
Publication of DE102010033844A1 publication Critical patent/DE102010033844A1/de
Publication of DE102010033844A8 publication Critical patent/DE102010033844A8/de
Application granted granted Critical
Publication of DE102010033844B4 publication Critical patent/DE102010033844B4/de
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/88—Separation; Purification; Use of additives, e.g. for stabilisation by treatment giving rise to a chemical modification of at least one compound
    • C07C29/90—Separation; Purification; Use of additives, e.g. for stabilisation by treatment giving rise to a chemical modification of at least one compound using hydrogen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/22—Trihydroxylic alcohols, e.g. glycerol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/34—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/34—Separation; Purification; Stabilisation; Use of additives
    • C07C41/40—Separation; Purification; Stabilisation; Use of additives by change of physical state, e.g. by crystallisation
    • C07C41/42—Separation; Purification; Stabilisation; Use of additives by change of physical state, e.g. by crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/34—Separation; Purification; Stabilisation; Use of additives
    • C07C41/44—Separation; Purification; Stabilisation; Use of additives by treatments giving rise to a chemical modification

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE102010033844A 2010-08-11 2010-08-11 Verfahren zur Gewinnung von Di-Trimethylolpropan und mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung Expired - Fee Related DE102010033844B4 (de)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE102010033844A DE102010033844B4 (de) 2010-08-11 2010-08-11 Verfahren zur Gewinnung von Di-Trimethylolpropan und mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
EP11748262.0A EP2603482B1 (de) 2010-08-11 2011-07-28 Verfahren zur gewinnung von di-trimethylolpropan und mit trimethylolpropan angereicherten produktströmen aus den nebenströmen der trimethylolpropanherstellung
PCT/EP2011/003788 WO2012019714A1 (de) 2010-08-11 2011-07-28 Verfahren zur gewinnung von di-trimethylolpropan und mit trimethylolpropan angereicherten produktströmen aus den nebenströmen der trimethylolpropanherstellung
US13/810,723 US8987523B2 (en) 2010-08-11 2011-07-28 Method for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the side-streams in trimethylolpropane production
JP2013523514A JP5697220B2 (ja) 2010-08-11 2011-07-28 トリメチロールプロパン製造の副流からジトリメチロールプロパンとトリメチロールプロパンが富化された生成物流とを製造するための方法
KR1020137003267A KR101802136B1 (ko) 2010-08-11 2011-07-28 트리메틸올프로판 제조시 사이드-스트림으로부터 트리메틸올프로판-풍부 생성물 스트림 및 디트리메틸올프로판을 수득하는 방법
CN201180037940.2A CN103052616B (zh) 2010-08-11 2011-07-28 由三羟甲基丙烷制备中的侧流得到二-三羟甲基丙烷和富三羟甲基丙烷产物流的方法
TW100128270A TWI403496B (zh) 2010-08-11 2011-08-09 雙三羥甲基丙烷和富含三羥甲基丙烷的生成物流之製造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102010033844A DE102010033844B4 (de) 2010-08-11 2010-08-11 Verfahren zur Gewinnung von Di-Trimethylolpropan und mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung

Publications (3)

Publication Number Publication Date
DE102010033844A1 DE102010033844A1 (de) 2012-02-16
DE102010033844A8 DE102010033844A8 (de) 2012-04-26
DE102010033844B4 true DE102010033844B4 (de) 2013-01-03

Family

ID=44509168

Family Applications (1)

Application Number Title Priority Date Filing Date
DE102010033844A Expired - Fee Related DE102010033844B4 (de) 2010-08-11 2010-08-11 Verfahren zur Gewinnung von Di-Trimethylolpropan und mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung

Country Status (8)

Country Link
US (1) US8987523B2 (enExample)
EP (1) EP2603482B1 (enExample)
JP (1) JP5697220B2 (enExample)
KR (1) KR101802136B1 (enExample)
CN (1) CN103052616B (enExample)
DE (1) DE102010033844B4 (enExample)
TW (1) TWI403496B (enExample)
WO (1) WO2012019714A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009073140A1 (en) 2007-11-30 2009-06-11 Celanese International Corporation Addditive composition for mortars, cements and joint compounds and cementitious compositions made therefrom
DE102011118956A1 (de) * 2011-11-19 2013-05-23 Oxea Gmbh Verfahren zur Gewinnung von Di-Trimethylolpropan und mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
DE102011118993A1 (de) 2011-11-19 2013-05-23 Oxea Gmbh Verfahren zur Gewinnung von Di-Trimethylpropan und mit Trimethylpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
DE102011118953B4 (de) * 2011-11-19 2014-06-05 Oxea Gmbh Destillatives Verfahren zur Gewinnung von Di-Trimethylolpropan
DE102011122356A1 (de) 2011-12-23 2013-06-27 Oxea Gmbh Verfahren zur Gewinnung von mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
WO2014042768A1 (en) * 2012-09-17 2014-03-20 Oxea Bishop, Llc Recovery of trimethylolpropane from purification residue
US8921618B2 (en) 2012-09-17 2014-12-30 Oxea Bishop Llc Recovery of trimethylolpropane from purification residue
US8759593B2 (en) 2012-09-17 2014-06-24 Oxea Bishop Llc Recovery of alcohols from purification residue
US9108911B1 (en) 2014-03-26 2015-08-18 Oxea Bishop Llc Process for the manufacture of di-TMP
CN106589333B (zh) * 2016-12-19 2018-08-31 江西高信有机化工有限公司 一种基于tmp精馏重质残液为原料制备醇酸树脂的方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1768348B1 (de) * 1967-05-05 1971-12-09 Commercial Solvents Corp Verfahren zur Herstellung von Gemischen zweier verschiedener Polymethylolalkane

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JPS509B1 (enExample) * 1969-11-28 1975-01-06
JPS4924044B1 (enExample) 1969-11-29 1974-06-20
SE377923B (enExample) 1972-11-23 1975-08-04 Autochem Instrument Ab
SE370388B (enExample) * 1972-11-23 1974-10-14 Perstorp Ab
US5603835A (en) 1994-01-19 1997-02-18 Hoechst Celanese Corporation Trimethylolpropane color improvement
DE19542036A1 (de) 1995-11-10 1997-05-15 Basf Ag Verfahren zur Herstellung von Polyalkoholen
DE19653093A1 (de) 1996-12-20 1998-06-25 Basf Ag Verfahren zur Herstellung von Polyalkoholen
US5948943A (en) 1997-10-16 1999-09-07 Celanese International Corporation Process improvement to produce low color trimethylolpropane
DE19840276C2 (de) * 1998-09-04 2002-10-31 Perstorp Specialty Chem Ab Verfahren zur reduzierenden Spaltung von linearen und cyclischen Acetalen, insbesondere Formalen
DE19963435A1 (de) 1999-12-28 2001-07-05 Basf Ag Verfahren zur Reinigung von durch Hydrierung hergestelltem Trimethylolpropan durch kontinuierliche Destillation
DE19963437A1 (de) * 1999-12-28 2001-07-05 Basf Ag Verfahren zur Zersetzung von bei der Synthese mehrwertiger Alkohole gebildeter hochsiedender Nebenprodukte
JP2002047234A (ja) * 2000-08-03 2002-02-12 Mitsubishi Gas Chem Co Inc ジトリメチロールプロパンの回収方法
DE10058303A1 (de) 2000-11-24 2002-05-29 Basf Ag Verfahren zur Reinigung von durch Hydrierung hergestelltem Trimethylolpropan durch Kombination einer kontinuierlichen Destillation mit einer Ionentauscherbehandlung
DE10160180A1 (de) 2001-12-07 2003-06-18 Basf Ag Verfahren zur Isolierung von Trimethylolpropan aus einem Reaktionsgemisch
DE10234016A1 (de) * 2002-07-26 2004-02-05 Basf Ag Verfahren zur Ausbeuteerhöhung bei der Herstellung von mehrwertigen Alkoholen durch Spaltung acetalhaltiger Nebenprodukte
EP1491521A1 (en) 2003-06-13 2004-12-29 Mitsubishi Gas Chemical Company, Inc. Method for producing ditrimethylolpropane
DE102008038021A1 (de) 2008-08-16 2010-02-18 Lanxess Deutschland Gmbh Verfahren zur Isolierung von Di-Trimethylolpropan

Patent Citations (1)

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DE1768348B1 (de) * 1967-05-05 1971-12-09 Commercial Solvents Corp Verfahren zur Herstellung von Gemischen zweier verschiedener Polymethylolalkane

Also Published As

Publication number Publication date
CN103052616B (zh) 2015-04-08
EP2603482A1 (de) 2013-06-19
WO2012019714A1 (de) 2012-02-16
JP2013536184A (ja) 2013-09-19
CN103052616A (zh) 2013-04-17
US8987523B2 (en) 2015-03-24
DE102010033844A1 (de) 2012-02-16
JP5697220B2 (ja) 2015-04-08
US20130131391A1 (en) 2013-05-23
EP2603482B1 (de) 2014-10-01
DE102010033844A8 (de) 2012-04-26
KR101802136B1 (ko) 2017-11-28
TWI403496B (zh) 2013-08-01
TW201213286A (en) 2012-04-01
KR20130096237A (ko) 2013-08-29

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R018 Grant decision by examination section/examining division
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Effective date: 20130404

R119 Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee