DE102005026035A1 - Cosmetic preparations containing a special aniseed extract and fillers - Google Patents

Abstract

Cosmetic composition containing DOLLAR A (a) an aqueous extract of aniseed fruit (Pimpinella anis fruit extract), under the trade name Bioxilift from SILAB, St. Viance, France, obtainable DOLLAR A (b) and one or more fillers.

Description

The The present invention relates to cosmetic preparations containing an aqueous one Fruit extract from anise (Pimpinella anis fruit extract), under which Trade name Bioxilift in the company SILAB, St. Viance, France, available and one or more fillers.

Under Cosmetics can take all measures to summarize the aesthetic establish changes on the skin and hair or for body cleansing. Cosmetics means, therefore, the external appearance too cultivate, improve and beautify, in order to be visible, tangible and smelling way to please fellow human beings as well as oneself. Thousands of years ago, man made cosmetics for this purpose applied. One dyed Lips and face, anointed with precious oils and bathed in fragrant Water.

Nice For a long time the professional world has been searching for cosmetic Preparations effective against wrinkles or cellulite.

A for the Consumers very essential, but difficult to quantitative measurable Property of cosmetic products is a particular invigorating and / or smooth skin feel as well as the smoothness of the skin after its application.

A rosy skin color (such as the stay available in fresh air is considered healthy by consumers accordingly desirable whereas a pale complexion is usually not as desirable.

task The present invention was to skin care preparations and Preparations for the care of naturally aged skin to disposal to provide, the preparations care for the body and embellish and simultaneously reduce skin wrinkles and eliminate cellulite.

It has surprisingly that a cosmetic preparation containing (a) an aqueous one Fruit extract from anise (Pimpinella anis fruit extract), under which Trade name Bioxilift in the company SILAB, St. Viance, France, available and (b) one or more fillers remedies the disadvantages of the prior art. Such a preparation has the significant advantage over preparations of the state The technique that by adding the fillers an "immediate" physical wrinkle reduction by Fill up the wrinkles with microparticles takes place. Furthermore, by Addition of fillers a discoloration the emulsion due to the intrinsic color of the drug or by Decreasing degradation processes.

Furthermore has such a preparation the following additional benefits: It promotes the natural Regeneration process and Cellular metabolism of the skin, activates the skin's own protective systems and makes the skin more resistant to stressors, counteracts (first) signs of aging, reducing lines and facial lines, Refines pores and visibly firms and smoothes the complexion, Deeply activates the skin's own production of components connective tissue such as collagens, elastic fibers and proteoglycans hyaluronic acids, among others) This effectively counteracts the formation of new wrinkles through energy deposits / reserves filled and the skin / cell regeneration is improved, contributes to the rejuvenation of the inner skin structure by improving the epidermal-dermal interlocking (Papillae), which refines facial and skin contours and tightened, firming and visibly firming the skin and improving the skin Skin elasticity.

at Bioxilift is an aqueous fruit extract Anise (Pimpinella anis fruit extract). The extract has an amber-like Color up and has a characteristic anise smell.

Of the Extract is rich in inorganic minerals like sodium and magnesium ions, but especially of potassium ions. The recorded spectra provide no clue for the identification of individual lead structures or principles of action. Rather, the spectra represent "typical" plant extract spectra represents.

The specific composition is:
Dry matter: 40-60 g / l
Mineral ashes 11-18 g / l
Total protein 12-20 g / l
pH 4.5-5.5

Of the Extract is preserved with butylene glycol 0.36% and parabens 0.14% and is in ethanol up to a ratio of 40/60 ethanol / water (v / v) soluble.

at During production, the aniseed fruits are solubilized in water and enzymatically hydrolyzed. The ratio of raw material to extract is ½. Soluble and insoluble Phases are separated and then filtered or afterwards sterile filtered. Bioxilift is produced by the company SILAB, France offered.

fillers within the meaning of the present invention are particulate substances, which usually has no color effect in the cosmetic formulation generate in which they are used. Furthermore, fillers of the invention usually have a low refractive index resulting in no or a very low opacity.

Of the The prior art knows a number of fillers, which z. B. as support materials in the formulation of powders or as a viscosity and Sensors modulators in emulsions or anhydrous formulations. such fillers become common also used to achieve mattifying effects on the skin or to absorb sebum.

Furthermore affected the use of fillers in general also the distributability of customary formulations the skin as well as the uniformity of a possible Color effect.

The fillers within the meaning of the present invention are advantageously selected from the group the inorganic fillers selected for example, from the group of silicates.

Silicates are salts and esters (silicic acid esters) of orthosilicic acid [Si (OH) ₄ ] and their condensation products. The silicates are not only the most species-rich class of minerals, but also extremely important geologically and technically. Over 80% of the earth's crust is made up of silicates.

For the purposes of the present invention, for example, phyllosilicates are advantageous. Layer silicates (phyllosilicates, leaf silicates) are (ideally) silicate structures with two-dimensionally infinite layers of [SiO ₄ ] ⁴ tetrahedra, each tetrahedron being connected via 3 bridging oxygens to neighboring tetrahedra.

Chemical formulas can only be approximated for phyllosilicates because they have a high ion exchange capacity and silicon can be exchanged for aluminum and this in turn for magnesium, Fe ²⁺ , Fe ³⁺ , Zn and the like. The resulting possibly negative charge of the layers is usually compensated by cations, in particular by Na ⁺ and Ca ²⁺ in interlayer positions.

phyllosilicates can by reversible storage of water (in the 2- to 7-fold amount) and others Substances such. As alcohols, glycols and the like swell. Their use as thickeners in cosmetic products is accordingly known per se. However, the state of the art could do not point the way to the present invention.

advantageous Phyllosilicates, which are used in the context of the present invention can be for example, those whose largest expansion direction in the unmodified and unswollen state a mean length of less than 10 μm Has. For example, you can the average dimensions of the modified sheet silicate particles used at 1000 nm × 100 nm × 1 nm and below. The effective size of modified sheet silicate particles in a cosmetic or dermatological formulation of course depends on the amount of stored substances.

According to the invention advantageous (Layer) silicates are in particular:

• Talc: Mg ₃ [Si ₄ O ₁₀ ] (ON) ₂ ,
• Kaolin: Al ₂ [Si ₂ O ₅ ] (ON) ₄
• - montmorillonite: M ⁺ Al [Si ₂ O ₅ ] (OH), also called smectite. These include: • Bentonite = montmorillonite with Ca (Fuller earth) or Na (Wyoming bentonite) Hectorites: M ⁺ _0.3 (Mg _2,7 Li _0.3 ) [Si ₄ O ₁₀ (OH) ₂ ], where M ^{+ is} usually Na ⁺ ,
• - Mica, an aluminosilicate that is easily fissile and is present in tabular crystals. Mica is transparent to translucent and has pearlescence. The most important form is muscovite: KAl ₂ [AlSi ₃ O ₁₀ ] (OH, F) ₂ . Sericite is a special form of mica that has smaller platelets than muscovite.

Magnesium silicate Mg ₂ [Si ₄ O ₁₀ ]

Advantageous are z. As available by addition of dimethylsilyl groups Silica dimethyl silylates such as Aerosil R972 (Degussa Sleeve) Aerosil R974 (Degussa Hüls), CAB-O-SIL TS-610 (Cabot), CAB-O-SIL TS-720 (Cabot), Wacker HDK N15 (Wacker-Chemie), Wacker HDK H18 (Wacker-Chemie) and / or Wacker HDK H20 (Wacker chemistry).

Further advantageous are those obtainable by addition of trimethylsilyl groups Silica silylates (eg Aerosil R 812 (Degussa Huls), CAB-O-SIL TS-530 (Cabot), Sipernat D 17 (Degussa Hüls), Wacker HDK H2000 (Wacker-Chemie)).

Further advantageous for the purposes of the present invention are by hydrolysis and condensation reactions available from methyltrimethoxysilanes Polymethylsilsesquioxanes, which also have a round shape and their particle size distribution can be controlled by the manufacture.

preferred For example, polymethylsilsesquioxanes are trade names Tospearl 2000 B from GE Bayer Silikones, Tospearl 145A from Toshiba, AEC Silicone Resin Spheres from A & E Connock and Wacker - Belsil PMS MK offered by Wacker-Chemie.

Another advantageous filler For the purposes of the present invention is boron nitride. Boron nitride is isoelectronic with carbon (i.e., it is graphite and diamond form possible). Boron nitride is characterized by its chemical inertness.

For the purposes of the present invention, for example, the boron nitrides listed below are advantageous: trade name Available at: Boron Nitride Powder Advanced Ceramics Boron Nitride Powder Sintec ceramics Ceram Blanche Kawasaki HCST Boron Nitride strongly Très BN ^® Carborundum Wacker boron nitride BNP Wacker-Chemie

Further advantageous fillers in the context of the present invention are carbonates, such as. As magnesium carbonate (MgCO ₃ ) and calcium carbonate (CaCO ₃ ). It is particularly advantageous for the purposes of the present invention to use the carbonates as fillers in dry powders.

The fillers In the context of the present invention, moreover, advantageous the group of organic fillers selected.

According to the invention advantageous organic fillers are z. Natural Polymers such as silk powder, microcrystalline cellulose and / or zinc stearates.

advantageous organic fillers are also strength and starch derivatives, as:

• - cornstarch Zea Mays (Amidon De Mais MST (Wackherr), Argo Brand Corn Starch (Corn Products), Pure-Dent (Grain Processing), Purity 21C (National Starch)),
• - Rice starch (D.S.A. 7 (Agrana strength), Oryzapearl (Ichimaru Pharcos)),
• - Distarch Phosphates (Corn PO4 (Agrana starch), Corn PO4 (Tri-K)),
• - Sodium Corn Starch Octenylsuccinate (C * EmCap - Instant 12639 (Cerestar USA)),
• Aluminum Starch Octenylsuccinate (Covafluid AMD (Wackherr), Dry Flo-PC (National Starch), Dry Flo Pure (National Starch), Fluidamide DF 12 (Roquette)),

According to the invention preferred organic fillers are also synthetic polymers, d. H. Polymer particles, which in the preparation in the form of solids, such as Polycarbonates, polyethers, polyethylene, polypropylene, polyvinyl chloride, Polystyrene, polyamides, polyurethanes, polyacrylates and the like more. Particularly advantageous is z. As the substance with the INCI name HDI / trimethylol Hexyllactone Crosspolymer, which is called BPD-500 / Plastic Powder D available from Kobo is.

Also advantageous for the purposes of the present invention is nylon (polyamide 6 and polyamide 12), for example microfine polyamide particles, in particular those available under the trade name SP-500 from TORAY. Also advantageous are polyamide 6 (also: nylon 6), or polyamide 12 (also: nylon 12), particles. Polyamide 6 is the polyamide [poly (ε-caprolactam)] composed of ε-aminocaproic acid (6-aminohexanoic acid), or ε-caprolactam, and polyamide 12 is a poly (ε-laurolactam) derived from ε-laurolactam. Advantageous for the purposes of the present invention are, for example Orgasol ^® 1002 (polyamide 6), and Orgasol ^® 2002 (polyamide 12) from ELF ATOCHEM.

• – PMMA: Polymethylmethacrylate
• – Polyethylene Spheres
• – Polyurethane
• – Silikon Resins: Trimethylsiloxysilicate (z. B. SR 1000 GE Bayer Silicones)
• – Silikonelastomere

Further advantageous organic fillers are:

• PMMA: polymethyl methacrylates
• - Polyethylene spheres
• - Polyurethanes
• - Silicone Resins: Trimethylsiloxysilicate (eg SR 1000 GE Bayer Silicones)
• - silicone elastomers

So it may be z. B. be of considerable advantage to use such silicone elastomers in preparations according to the present invention, as described for example in the US patents US 4980167 or US 4742142 to be discribed. Advantageous silicone elastomers are also z. For example, those sold under the names KSG6 by Shin Etsu, Tefil E-505C or Trefil E-506C by Dow Corning, Gransil by Grant Industries (SR-CYC, SR-DMF10, SR-DC556), as well as those known in the art in the form of preformed gels (such as KSG15, KSG17, KSG16, KSG18 from Shin Etsu, Gransil SP 5CYC gel, Gransil SR DMF 10 gel, Gransil SR DC 556 gel, Gransil GCM, Gransil PM gel, Gransil DMG -5, SF 1204 and JK 113 from Gereral Electric). Further advantageous silicone elastomers can be selected from the group of vinyl dimethicone crosspolymers, such as. Dow Corning 9506 Cosmetic Powder from Dow Coming (INCI: Dimethicone / Vinyl Dimethicone Crosspolymer).

Farther can be used advantageously so-called silicone resins, e.g. KSP-100, KSP-200 or KSP-300 by Shin Etsu, also under the INCI name Dimethicone / Vinyl Dimethicone crosspolymer led or SR 1000 from GE Bayer Silicones, which is the INCI name Trimethylsiloxy carries silicates Also preferred is lauroyl lysine, which is under the name Amihope LL is sold by Ajinomoto.

The Total amount of at least one filler in the finished cosmetic or dermatological preparations will be beneficial in the field from 0.05 to 20.0 Wt .-%, preferably 0.5 - 10.0 % By weight selected, based on the total weight of the preparations.

According to the invention preferred fillers come from the group of inorganic or organic silicon compounds.

From the inorganic silicon compounds are particularly preferred the phyllosilicates. Of these, kaolin, talc are particularly preferred and mica.

Farther belong to the preferred inorganic silicon compounds and the Surface organic modified spherical Particle.

From these are particularly preferably the polymethylsilsesquioxanes and hydrophobically modified aerosils, e.g. Aerosil R 972.

To The organic silicon compounds include the siloxane elastomers and siloxane resins. Of these, particularly preferred are the CSP types by Shin Etsu, as well as the trimethylsiloxysilicate.

Further inventively preferred fillers come from the group of spherical particles. Particularly preferably, the average particle diameter is less than 30 microns. Furthermore, it is preferred chosen spherical particles of organic origin. Particularly preferred is the BPD-500 marketed by Kobo.

Furthermore are preferably spherical Particles with a mean particle diameter smaller than 10 μm. From that particularly preferred are nylon-12, the e.g. sold as SP-501 or SP-500 by the company Kobo. Further preferred are polymethyl methacrylates, e.g. under sold under the trade name Covabead LH 85 by LCW.

Farther can preferably be used Lauroyl lysine, bismuth oxychloride or boron nitride.

All In general, it is particularly preferred if the particle diameter the fillers 5-100 microns, esp. 10-60μm amount.

It is also advantageous in the context of the present invention, cosmetic Preparing preparations whose main purpose is not protection is sunlight, but still contains a content of other UV-protective substances contain. So z. In day creams or make-up products usually Incorporated UV-A or UV-B filter substances. Also, UV protectors, as well as antioxidants and, if desired, preservatives, effective protection of the preparations themselves against spoilage. Cheap are also cosmetic preparations in the form of a sunscreen available.

Accordingly contain the preparations for the purposes of the present invention preferably at least one further UV-A, UV-B and / or broadband filter substance. The formulations can, although not necessary, optionally also one or more organic and / or inorganic pigments as UV filter substances, which may be present in the water and / or the oil phase.

The Preparations according to the present invention Invention can furthermore advantageously also in the form of so-called oil-free cosmetic emulsions which are a water phase and at least one at room temperature liquid UV filter substance as a further phase and which in particular can also be advantageous free of other oil components.

• • Phenylen-1,4-bis-(2-benzimidazyl)-3,3'-5,5'-tetrasulfonsäure und ihre Salze, besonders die entsprechenden Natrium-, Kalium- oder Triethanolammonium-Salze, insbesondere das Phenylen-1,4-bis-(2-benzirnidazyl)-3,3'-5,5'-tetrasulfonsäure-bis-natriumsalz mit der INCI-Bezeichnung Disodium Phenyl Dibenzimidazol Tetrasulfonat (CAS-Nr.: 180898-37-7), welches beispielsweise unter der Handelsbezeichnung Neo Heliopan AP bei Symrise erhältlich ist;
• • Salze der 2-Phenylbenzimidazol-5-sulfonsäure, wie ihr Natrium-, Kalium- oder ihr Triethanolammonium-Salz sowie die Sulfonsäure selbst mit der INCI Bezeichnung Phenylbenzimidazole Sulfonsäure (CAS.-Nr. 27503-81-7), welches beispielsweise unter der Handelsbezeichnung Eusolex 232 bei Merck oder unter Neo Heliopan Hydro bei Symrise erhältlich ist;
• • 1,4-di(2-oxo-10-Sulfo-3-bornylidenmethyl)-Benzol (auch: 3,3'-(1,4-Phenylendimethylene)-bis-(7,7-dimethyl-2-oxo-bicyclo-[2.2.1]hept-1-ylmethan Sulfonsäure) und dessen Salze (besonders die entprechenden 10-Sulfato-verbindungen, insbesondere das entsprechende Natrium-, Kalium- oder Triethanolammonium-Salz), das auch als Benzol-1,4-di(2-oxo-3-bornylidenmethyl-10-sulfonsäure) bezeichnet wird. Benzol-1,4-di(2-oxo-3-bornylidenmethyl-10-sulfonsäure) hat die INCI-Bezeichnung Terephtalidene Dicampher Sulfonsäure (CAS.-Nr.: 90457-82-2) und ist beispielsweise unter dem Handelsnamen Mexoryl SX von der Fa. Chimex erhältlich;
• • Sulfonsäure-Derivate des 3-Benzylidencamphers, wie z. B. 4-(2-Oxo-3-bornylidenmethyl)benzolsulfonsäure, 2-Methyl-5-(2-oxo-3-bornylidenmethyl)sulfonsäure und deren Salze.
• • Benzoxazol-Derivate, wie z. B. das 2,4-bis-[5-1(dimethylpropyl)benzoxazol-2-yl-(4-phenyl)-imino]-6-(2-ethylhexyl)-imino-1,3,5-triazin mit der CAS Nr. 288254-16-0, welches bei 3V Sigma unter der Handelsbezeichnung Uvasorb^® K2A erhältlich ist.
• • Hydroxybenzophenone, z. B. der 2-(4 -Diethylamino-2 -hydoxybenzoyl)-benzoesäurehexylester (auch: Aminobenzophenon), welcher unter der Handelsbezeichnung Uvinul A Plus bei der Fa. BASF erhältlich ist.
• • Triazinderivate, wie z. B. 2,4-Bis-{[4-(2-Ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazin (INCI: Bis-Ethylhexyloxylphenol Methoxyphenyl Triazin), welches unter der Handelsbezeichnung Tinosorb^® S bei der CIBA-Chemikalien GmbH erhältlich ist; Dioctylbutylamidotriazon (INCI: Diethylhexyl Butamido Triazone), welches unter der Handelsbezeichnung UVASORB HEB bei Sigma 3V erhältlich ist; 4,4',4 -(1,3,5-Triazin-2,4,6-triyltriimino)-tris-benzoesäure-tris(2-ethylhexylester), auch: 2,4,6-Tris-[anilino-(p-carbo-2-ethyl-1 -hexyloxy)]-1,3,5-triazin (INCI: Ethylhexyl Triazone), welches von der BASF Aktiengesellschaft unter der Warenbezeichnung UVI-NUL^® T 150 vertrieben wird; 2-[4,6-Bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)phenol (CAS Nr.: 2725-22-6).
• • Benzotriazole, wie z. B. 2,2'-Methylen-bis-(6-(2N-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)-phenol) (INCI: Methylene Bis-Benztriazolyl Tetramethylbutylphenol), welches z. B. unter der Handelsbezeichnung Tinosorb^® M bei der CIBA-Chemikalien GmbH erhältlich ist.
• • 3-Benzylidencampher-Derivate, vorzugsweise 3-(4-Methylbenzyliden)campher, 3-Benzylidencampher;
• • 4-Aminobenzoesäure-Derivate, vorzugsweise 4-(Dimethylamino)-benzoesäure(2-ethylhexyl)ester, 4-(Dimethylamino)benzoesäureamylester;
• • Ester der Benzalmalonsäure, vorzugsweise 4-Methoxybenzalmalonsäuredi(2-ethylhexyl)ester;
• • Ester der Zimtsäure, vorzugsweise 4-Methoxyzimtsäure(2-ethylhexyl)ester, 4-Methoxyzimtsäureisopentylester;
• • Derivate des Benzophenons, vorzugsweise 2-Hydroxy-4-methoxybenzophenon, 2-Hydroxy-4-methoxy-4-methylbenzophenon, 2,2-Dihydroxy-4-methoxybenzophenon sowie
• • an Polymere gebundene UV-Filter
• • Ethylhexyl-2-cyano-3,3-diphenylacrylat (Octocrylen), welches von BASF unter der Bezeichnung Uvinul N 539 T erhältlich ist.

Particularly advantageous UV filter substances which are liquid at room temperature for the purposes of the present invention are homomenthylsalicylate (INCI: homosalates), 2-ethylhexyl-2-cyano-3,3-diphenylacrylate (INCI: octocrylene), 2-ethylhexyl-2-hydroxybenzoate (2 Ethylhexyl salicylate, octyl salicylate, INCI: ethylhexyl salicylate) and esters of cinnamic acid, preferably 4-methoxycinnamic acid (2-ethylhexyl) ester (2-ethylhexyl-4-methoxycinnamate, INCI: ethylhexyl methoxycinnamate) and isopentyl 4-methoxycinnamate (isopentyl-4-methoxycinnamate, INCI : isoamyl p-Methoxycinnamate), 3- (4- (2,2-bis ethoxycarbonylvinyl) phenoxy) propenyl) -methoxysiloxan / dimethylsiloxane - copolymer which is obtainable for example from Hoffmann La Roche under the trade name Parsol ^® SLX. Advantageous UV filter substances in the context of the present invention are also:

• Phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid and its salts, especially the corresponding sodium, potassium or triethanolammonium salts, especially the phenylene-1,4 bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid bis-sodium salt with the INCI name Disodium Phenyl Dibenzimidazole Tetrasulfonate (CAS No .: 180898-37-7), which is available, for example, under the Trade name Neo Heliopan AP available at Symrise;
• Salts of 2-phenylbenzimidazole-5-sulfonic acid, such as its sodium, potassium or triethanolammonium salt, and the sulfonic acid itself with the INCI name phenylbenzimidazole sulfonic acid (CAS No. 27503-81-7), which is available, for example, from Trade name Eusolex 232 available from Merck or Neo Heliopan Hydro from Symrise;
• 1,4-di (2-oxo-10-sulfo-3-bornylidenemethyl) benzene (also: 3,3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxo) bicyclo [2.2.1] hept-1-ylmethane sulfonic acid) and its salts (especially the corresponding 10-sulfato compounds, in particular the corresponding sodium, potassium or triethanolammonium salt), which is also known as benzene-1,4- benzene-1,4-di (2-oxo-3-bomylidenemethyl-10-sulfonic acid) has the INCI name Terephtalidene Dicampher Sulfonic Acid (CAS.No. : 90457-82-2) and is available, for example, under the trade name Mexoryl SX from Chimex;
• Sulfonic acid derivatives of 3-Benzylidencamphers, such as. B. 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid, 2-methyl-5- (2-oxo-3-bomylidenemethyl) sulfonic acid and salts thereof.
• Benzoxazole derivatives, such as. B. the 2,4-bis- [5-1 (dimethylpropyl) benzoxazol-2-yl- (4-phenyl) -imino] -6- (2-ethylhexyl) -imino-1,3,5-triazine with the CAS No. 288254-16-0, which at 3V Sigma under the Han dels designation Uvasorb® ^® K2A is available.
• Hydroxybenzophenones, e.g. B. 2- (4-diethylamino-2-hydroxybenzoyl) -benzoesäurehexylester (also: aminobenzophenone), which is available under the trade name Uvinul A Plus in the company. BASF.
• Triazine derivatives, such as. For example, 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine (INCI: bis-ethylhexyloxy-phenol methoxyphenyl , which is available under the trade name Tinosorb ^® S from CIBA-Chemikalien GmbH triazine); Dioctylbutylamidotriazone (INCI: Diethylhexyl Butamido Triazone), which is available under the trade name UVASORB HEB from Sigma 3V; 4,4 ', 4 - (1,3,5-triazine-2,4,6-triyltriimino) tris-benzoic acid tris (2-ethylhexyl ester), also: 2,4,6-tris [anilino ( p-carbo-2-ethyl-1 -hexyloxy)] - 1,3,5-triazine (INCI: ethylhexyl Triazone), which is sold by BASF Aktiengesellschaft under the trade name UVI-NUL ^® T 150; 2- [4,6-bis (2,4-dimethylphenyl) -1,3,5-triazin-2-yl] -5- (octyloxy) phenol (CAS No .: 2725-22-6).
• Benzotriazoles, such as. 2,2'-methylene-bis- (6- (2N-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) -phenol) (INCI: Methylene bis-benztriazolyl tetramethylbutylphenol), which z. B. under the trade name Tinosorb ^® M is available from CIBA-Chemikalien GmbH.
• 3-benzylidene camphor derivatives, preferably 3- (4-methylbenzylidene) camphor, 3-benzylidene camphor;
• 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 4- (dimethylamino) benzoic acid amyl ester;
• Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzalmalonate;
• Esters of cinnamic acid, preferably 4-methoxycinnamic acid (2-ethylhexyl) ester, 4-methoxycinnamic acid isopentyl ester;
• Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4-methylbenzophenone, 2,2-dihydroxy-4-methoxybenzophenone and
• • polymer-bound UV filters
• Ethylhexyl 2-cyano-3,3-diphenylacrylate (octocrylene), which is available from BASF under the name Uvinul N 539 T.

Especially advantageous preparations according to the present invention, which are characterized by a high or very high UV-A protection, contained in addition to the filter substance (s) according to the invention) further UV-A and / or broadband filters, in particular Dibenzoylmethanderivate [for example, 4- (tert-butyl) -4'-methoxydibenzoylmethane] and / or the 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine and / or phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid bis-sodium salt each individually or in any combination with each other.

The List of said UV filters, for the purposes of the present invention can be used Of course not limiting.

The Total amount of filter substances is from the range of 0.1 to 30 wt .-%, preferably 0.5 to 10 wt .-%, in particular 1.0 to 6.0 wt .-% - respectively based on the total weight of the preparations - chosen to cosmetic preparations to disposal to put the hair or the skin in front of the entire area protect the ultraviolet radiation.

Further it is preferred if the preparation additionally contains inorganic pigments, preferably coated titanium dioxide.

Inorganic pigments within the meaning of the invention are metal oxides and / or other sparingly water-soluble or insoluble metal compounds, in particular oxides of titanium (TiO ₂ ), zinc (ZnO), iron (eg Fe ₂ O ₃ ), zirconium (ZrO ₂ ) , Silicon (SiO ₂ ), manganese (for example MnO), aluminum (Al ₂ O ₃ ), cerium (for example Ce ₂ O ₃ ), mixed oxides of the corresponding metals and mixtures of such oxides and the sulfate of barium (BaSO ₄ ).

The Pigments can advantageous in the context of the present invention also in the form of a commercial available oily or aqueous predispersions come into use. These predispersions may advantageously dispersants and / or solubilization promoters may be added.

According to the invention, the pigments may advantageously be surface-treated ("coated"), whereby, for example, a hydrophilic, amphiphilic or hydrophobic character is to be formed or retained.This surface treatment may consist in using a thin hydrophilic and hydrophilic pigment according to methods known per se In the sense of the present invention, the various surface coatings may also contain water consist of alumina (Al ₂ O ₃ ), aluminum hydroxide Al (OH) ₃ , or alumina hydrate (also: alumina, CAS No .: 1333-84-2), sodium hexametaphosphate (NaPO ₃ ) ₆ , sodium metaphosphate (NaPO ₃ ) _n , Silica (SiO ₂ ) (also: silica, CAS No .: 7631-86-9), or iron oxide (Fe ₂ O ₃ ). These inorganic surface coatings may be present alone, in combination and / or in combination with organic coating materials.

organic surface coatings For the purposes of the present invention may consist of vegetable or animal aluminum stearate, vegetable or animal stearic acid, lauric acid, dimethylpolysiloxane (also: dimethicone), methylpolysiloxane (methicone), simethicone (a mixture of dimethylpolysiloxane with an average chain length from 200 to 350 dimethylsiloxane units and silica gel) or alginic acid.

Suitable titanium dioxide particles and predispersions of titanium dioxide particles are available from the following companies under the following trade names:

Zinc oxide particles which are suitable according to the invention and predispersions of zinc oxide particles are obtainable from the following companies under the following commercial names:

Further it is preferred if in the preparation additionally contain alpha-hydroxy acids are. Furthermore, it is preferred if in the preparation additionally glycerol is included. Furthermore, it is preferred if the preparation has a Emulsion, preferably an O / W emulsion or an O / W hydrodispersion, represents. Further, it is preferred if as coated titanium dioxide Substances with a particle diameter of 10-250 nm, preferably 10-100 nm, chosen become. Further, it is preferred if the alpha-hydroxy acid, lactic acid, citric acid, malic acid or tartaric acid is. Further, it is preferred if the preparation has a pH of 3 to 10, preferably from 4 to 8.

The The invention also encompasses the use of a preparation according to the invention against wrinkles and / or to increase skin elasticity.

• • der Fettalkoholethoxylate
• • der ethoxylierten Wollwachsalkohole,
• • der Polyethylenglycolether der allgemeinen Formel R-O-(-CH₂-CH₂-O-)_n R',
• • der Fettsäureethoxylate der allgemeinen Formel R-COO-(-CH₂-CH₂-O-)_n-H,
• • der veretherten Fettsäureethoxylate der allgemeinen Formel R-COO-(-CH₂-CH₂-O-)_n-R',
• • der veresterten Fettsäureethoxylate der allgemeinen Formel R-COO-(-CH₂-CH₂-O-)_n-C(O)-R',
• • der Polyethylenglycolglycerinfettsäureester
• • der ethoxylierten Sorbitanester
• • der Cholesterinethoxylate
• • der ethoxylierten Triglyceride
• • der Alkylethercarbonsäuren der allgemeinen Formel R-O-(-CH₂-CH₂-0-)_n-CH₂-COOH nd n eine Zahl von 5 bis 30 darstellen,
• • der Polyoxyethylensorbitolfettsäureester,
• • der Alkylethersulfate der allgemeinen Formel R-O-(-CH₂-CH₂-O-)_n-SO₃-H
• • der Fettalkoholpropoxylate der allgemeinen Formel R-O-(-CH₂-CH(CH₃)-O-)_n-H,
• • der Polypropylenglycolether der allgemeinen Formel R-O-(-CH₂-CH(CH₃)-O-)_n-R',
• • der propoxylierten Wollwachsalkohole,
• • der veretherten Fettsäurepropoxylate R-COO-(-CH₂-CH(CH₃)-O-)_n-R',
• • der veresterten Fettsäurepropoxylate der allgemeinen Formel R-COO-(-CH₂-CH(CH₃)-O-)_n-C(O)-R',
• • der Fettsäurepropoxylate der allgemeinen Formel R-COO-(-CH₂-CH(CH₃)-O-)_n-H,
• • der Polypropylenglycolglycerinfettsäureester
• • der propoxylierten Sorbitanester
• • der Cholesterinpropoxylate
• • der propoxylierten Triglyceride
• • der Alkylethercarbonsäuren der allgemeinen Formel R-O-(-CH₂-CH(CH₃)O-)_n-CH₂-COOH
• • der Alkylethersulfate bzw. die diesen Sulfaten zugrundeliegenden Säuren der allgemeinen Formel R-O-(-CH₂-CH(CH₃)-O-)_n-SO₃-H
• • der Fettalkoholethoxylate/propoxylate der allgemeinen Formel R-O-X_n-Y_m-H,
• • der Polypropylenglycolether der allgemeinen Formel R-O-X_n-Y_m-R',
• • der veretherten Fettsäurepropoxylate der allgemeinen Formel R-COO-X_n-Y_m-R',
• • der Fettsäureethoxylate/propoxylate der allgemeinen Formel R-COO-X_n-Y_m-H,.

Preparations present as emulsions according to the present invention comprise one or more emulsifiers. For example, O / W emulsifiers can be advantageously selected from the group of polyethoxylated or polypropoxylated or polyethoxylated and polypropoxylated products, eg. B .:

• • the fatty alcohol ethoxylates
• The ethoxylated wool wax alcohols,
• The polyethylene glycol ether of the general formula RO - (- CH ₂ -CH ₂ -O-) _n R ',
• The fatty acid ethoxylates of the general formula R-COO - (- CH ₂ -CH ₂ -O-) _n -H,
• The etherified fatty acid ethoxylates of the general formula R-COO - (- CH ₂ -CH ₂ -O-) _n -R ',
• • the esterified fatty acid ethoxylates of the general formula R-COO - (- CH ₂ -CH ₂ -O-) _n -C (O) -R ',
• • the polyethylene glycol glycerin fatty acid ester
• • the ethoxylated sorbitan ester
• • the cholesterol ethoxylates
• • the ethoxylated triglycerides
• The alkyl ether carboxylic acids of the general formula RO - (- CH ₂ -CH ₂ -O-) _n -CH ₂ -COOH nd n represent a number from 5 to 30,
• The polyoxyethylene sorbitol fatty acid ester,
• The alkyl ether sulfates of the general formula RO - (- CH ₂ -CH ₂ -O-) _n -SO ₃ -H
• The fatty alcohol propoxylates of the general formula RO - (- CH ₂ -CH (CH ₃ ) -O-) _n -H,
• The polypropylene glycol ether of the general formula RO - (- CH ₂ -CH (CH ₃ ) -O-) _n -R ',
• The propoxylated wool wax alcohols,
• • the etherified fatty acid propoxylates R-COO - (- CH ₂ -CH (CH ₃ ) -O-) _n -R ',
• The esterified fatty acid propoxylates of the general formula R-COO - (- CH ₂ -CH (CH ₃ ) -O-) _n -C (O) -R ',
• The fatty acid propoxylates of the general formula R-COO - (- CH ₂ -CH (CH ₃ ) -O-) _n -H,
• • the polypropylene glycol glycerin fatty acid ester
• • the propoxylated sorbitan ester
• • cholesterol propoxylates
• • the propoxylated triglycerides
• • the alkyl ether carboxylic acids of the general formula RO - (- CH ₂ -CH (CH ₃ ) O-) _n -CH ₂ -COOH
• The alkyl ether sulfates or the acids based on these sulfates of the general formula RO - (- CH ₂ -CH (CH ₃ ) -O-) _n -SO ₃ -H
• The fatty alcohol ethoxylates / propoxylates of the general formula ROX _n -Y _m -H,
• The polypropylene glycol ether of the general formula ROX _n -Y _m -R ',
• • etherified fatty acid propoxylates of the general formula R-COO-X -Y _m -R _'n,
• • the fatty acid ethoxylates / propoxylates of the general formula R-COO-X _n -Y _m -H ,.

Particularly according to the invention The polyethoxylated or polypropoxylated used are advantageous or polyethoxylated and polypropoxylated O / W emulsifiers selected from the group of substances with HLB values from 11 to 18, especially advantageous with HLB values of 14.5 to 15.5, provided the O / W emulsifiers saturated Radicals R and R 'have. Do the O / W emulsifiers have unsaturated Radicals R and / or R ', or are Isoalkylderivate, so the preferred HLB value such emulsifiers are also lower or higher.

It is advantageous to choose the fatty alcohol ethoxylates from the group of ethoxylated stearyl alcohols, cetyl alcohols, cetylstearyl alcohols (cetearyl alcohols). Particularly preferred are:
Polyethylene glycol (13) stearyl ether (steareth-13), polyethylene glycol (14) stearyl ether (steareth-14), polyethylene glycol (15) stearyl ether (steareth-15), polyethylene glycol (16) stearyl ether (steareth-16), polyethylene glycol (17) stearyl ether ( Steareth-17), polyethylene glycol (18) stearyl ether (steareth-18), polyethylene glycol (19) stearyl ether (steareth-19), polyethylene glycol (20) stearyl ether (steareth-20),
Polyethylene glycol (12) isostearyl ether (isosteareth-12), polyethylene glycol (13) isostearyl ether (isosteareth-13), polyethylene glycol (14) isostearyl ether (isosteareth-14), polyethylene glycol (15) isostearyl ether (isosteareth-15), polyethylene glycol (16) isostearyl ether ( Iso-steareth-16), polyethylene glycol (17) isostearyl ether (isosteareth-17), polyethylene glycol (18) isostearyl ether (isosteareth-18), polyethylene glycol (19) isostearyl ether (isosteareth-19), polyethylene glycol (20) isostearyl ether (isosteareth-20),
Polyethylene glycol (13) Cetyl ether (Ceteth-13), Polyethylene glycol (14) Cetyl ether (Ceteth-14), Polyethylene glycol (15) Cetyl ether (Ceteth-15), Polyethylene glycol (16) Cetyl ether (Ceteth-16), Polyethylene glycol (17) Cetyl ether ( Ceteth-17), polyethylene glycol (18) cetyl ether (ceteth-18), polyethylene glycol (19) cetyl ether (ceteth-19), polyethylene glycol (20) cetyl ether (ceteth-20),
Polyethylene glycol (13) isocetyl ether (isoceteth-13), polyethylene glycol (14) isocetyl ether (isoceteth-14), polyethylene glycol (15) isocetyl ether (isoceteth-15), polyethylene glycol (16) isocetyl ether (isoceteth-16), polyethylene glycol (17) isocetyl ether ( Isoceteth-17), polyethylene glycol (18) isocetyl ether (isoceteth-18), polyethylene glycol (19) isocetyl ether (isoceteth-19), polyethylene glycol (20) isocetyl ether (isoceteth-20),
Polyethylene glycol (12) oleyl ether (oleth-12), polyethylene glycol (13) oleyl ether (oleth-13), polyethylene glycol (14) oleyl ether (oleth-14), polyethylene glycol (15) oleyl ether (oleth-15), polyethylene glycol (12) lauryl ether ( Laureth-12), polyethylene glycol (12) isolauryl ether (Isolaureth-12).

Polyethylene glycol (13) cetyl stearyl ether (ceteareth-13), polyethylene glycol (14) cetyl stearyl ether (ceteareth-14), polyethylene glycol (15) cetyl stearyl ether (ceteareth-15), polyethylene glycol (16) cetyl stearyl ether (ceteareth-16), polyethylene glycol (17) cetyl stearyl ether ( Ceteareth-17), polyethylene glycol (18) cetyl stearyl ether (ceteareth-18), polyethylene glycol (19) cetyl stearyl ether (ceteareth-19), polyethylene glycol (20) cetyl stearyl ether (Ceteareth-20),

It is also advantageous to choose the fatty acid ethoxylates from the following group:
Polyethylene glycol (20) stearate, polyethylene glycol (21) stearate, polyethylene glycol (22) stearate, polyethylene glycol (23) stearate, polyethylene glycol (24) stearate, polyethylene glycol (25) stearate, polyethylene glycol (12) isostearate, polyethylene glycol (13) isostearate, polyethylene glycol ( 14) isostearate, polyethylene glycol (15) isostearate, polyethylene glycol (16) isostearate, polyethylene glycol (17) isostearate, polyethylene glycol (18) isostearate, polyethylene glycol (19) isostearate, polyethylene glycol (20) isostearate, polyethylene glycol (21) isostearate, polyethylene glycol (22) isostearate, polyethylene glycol (23) isostearate, polyethylene glycol (24) isostearate, polyethylene glycol (25) isostearate,
Polyethylene glycol (12) oleate, polyethylene glycol (13) oleate, polyethylene glycol (14) oleate, polyethylene glycol (15) oleate, polyethylene glycol (16) oleate, polyethylene glycol (17) oleate, polyethylene glycol (18) oleate, polyethylene glycol (19) oleate, polyethylene glycol ( 20) oleate.

When ethoxylated alkyl ether carboxylic acid or its salt may advantageously be the sodium laureth-11-carboxylate be used.

When Alkyl ether sulfate can be advantageously used sodium laureth 1-4 sulfate become.

When Ethoxylated cholesterol derivative may advantageously be polyethylene glycol (30) cholesteryl ether be used. Also, polyethylene glycol (25) sojasterol has become proven.

When ethoxylated triglycerides can Advantageously, the Polyethylene Glycol (60) Evening Primrose Glycerides is used become (Evening Primrose = evening primrose)

Farther is advantageous, the Polyethylenglycolglycerinfettsäureester from the group polyethylene glycol (20) glyceryl laurate, polyethylene glycol (21) glyceryl laurate, Polyethylene glycol (22) glyceryl laurate, polyethylene glycol (23) glyceryl laurate, Polyethylene glycol (6) glyceryl caprate / caprinate, polyethylene glycol (20) glyceryl oleate, Polyethylene glycol (20) glyceryl isostearate, polyethylene glycol (18) glyceryl oleate / cocoate to choose.

It is also cheap the sorbitan esters from the group polyethylene glycol (20) sorbitan monolaurate, polyethylene glycol (20) sorbitan monostearate, Polyethylene glycol (20) sorbitan monoisostearate, polyethylene glycol (20) sorbitan monopalmitate, Polyethylene glycol (20) to choose sorbitan monooleate.

Especially preferred O / W emulsifiers are glyceryl stearate citrate, polyglyceryl-3-methyl glucose distearate, Cetearyl glucosides, PEG-40 stearate, PEG-100 stearate, stearic acid, ceteareth-20 and steareth-21.

When advantageous W / O emulsifiers can be used: fatty alcohols having 8 to 30 carbon atoms, Monoglycerol ester saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, especially 12-18 C atoms, diglycerol esters saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, especially 12-18 C atoms, monoglycerol ether saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 8 to 24, especially 12-18 C atoms, diglycerol ether saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 8 to 24, especially 12-18 C atoms, propylene glycol esters saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, especially 12-18 C atoms and saturated sorbitan esters and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, especially 12-18 C-atoms.

Especially advantageous W / O emulsifiers are glyceryl monostearate, glyceryl monoisostearate, Glyceryl monomyristate, glyceryl monooleate, diglyceryl monostearate, Diglyceryl monoisostearate, propylene glycol monostearate, propylene glycol monoisostearate, Propylene glycol monocaprylate, propylene glycol monolaurate, sorbitan monoisostearate, Sorbitan monolaurate, sorbitan monocaprylate, sorbitan monoisooleate, Sucrose distearate, cetyl alcohol, stearyl alcohol, arachidyl alcohol, Behenyl alcohol, isobehenyl alcohol, selachyl alcohol, chimyl alcohol, Polyethylene glycol (2) stearyl ether (steareth-2), glyceryl monolaurate, Glyceryl monocaprinate, glyceryl monocaprylate.

Also can be advantageous the emulsions in the context of the present invention also hydrocolloids (also as thickener or gelling agent) containing the preparations can stabilize.

As advantageous according to the invention hydrocolloids agar-agar, carrageenan, tragacanth, gum ara bicum, alginates, xanthan gum, pectins, polyoses, guar flour, locust bean gum, starch, dextrins, cellulose ethers, hydroxyethyl and propyl cellulose derivatives, vinyl polymers, polycarboxylic acids, polyethers, polyimines, polyamides, polysilicic acids, clay minerals, zeolites, silicic acids ,

Further advantageous gelling agents are, for example, copolymers of C _10-30 -alkyl acrylates and one or more monomers of acrylic acid, methacrylic acid or their esters. The INCI name for such compounds is "Acrylates / C 10-30 Alkyl Acrylate Crosspolymer". Particularly advantageous are the Pemulen ^® types TR 1, TR 2 and TRZ from. Goodrich (Noveon).

Also Carbopols are advantageous gelling agents for such preparations. Carbopols are polymers of acrylic acid, especially acrylate-alkyl acrylate copolymers. Advantageous Carbopols are for example the types 980, 981, 984 1342, 1382, 2984 and 5984. Also the ETD types 2001, 2020, 2050 and Carbopol Ultrez 10, PVM / MA Decadiene Crosspolymer (trade name Stabileze 06), polyglyceryl methacrylate and polyacrylamide, ammonium dimethyltauramide / vinylformamide copolymer, copolymer / crosspolymer comprising acryloyldimethyltaurate, polyacryloyldimethyltauramide, polyvinylpyrrolidone and copolymer thereof.

in der R ein Wasserstoff oder eine Methylgruppe darstellen kann.Hydrocolloids which are preferred according to the invention are magnesium and / or aluminum silicates and, for example, methylcelluloses, which are referred to as the methyl ethers of cellulose. They are characterized by the following structural formula

in which R can represent a hydrogen or a methyl group.

Especially advantageous in the context of the present invention are in general also referred to as methylcelluloses cellulose mixed ethers, which in addition to a dominating content of methyl additionally 2-hydroxyethyl, 2-hydroxypropyl or 2-hydroxybutyl groups. Especially preferred are (hydroxypropyl) methylcelluloses, for example the under the trade name Methocel E4M at the Dow Chemical Comp. available.

In order to improve the water resistance of cosmetic and dermatological sunscreen preparations, it may be advantageous to incorporate film formers into the cosmetic or dermatological preparations. According to the prior art, this z. As polyurethanes (eg. As the Avalure ^® grades from Goodrich), dimethicone copolyol polyacrylates (Surface Silsoft ^® from Witco Organo Silicones Group), PVP / VA (VA = vinyl acetate) copolymer (Luviscol VA 64 Powder from BASF), C _20-40 carboxylic acid with polyethylene (Performacid 350 from New Phase Technologies) and film formers from the group of polymers based on polyvinylpyrrolidone (PVP):

Especially Copolymers of polyvinylpyrrolidone are preferably used, for example, the PVP hexadecene copolymer and the PVP eicosene copolymer, which under the trade names Antaron V216 and Antaron V220 available from GAF Chemicals Cooperation, as well as the Tricontayl PVP and the like more.

adversely is however for Such preparations containing film formers in an effective (i.e. H. the water resistance increasing) contain concentration that they the application on the skin a sticky and greasy impression leave.

In addition to the influence of the basis is the binding ability of the UV filter in or on the skin Of great importance for the water resistance of the formulation. It is understood that oil-soluble UV filters are better bound to the (lipophilic) surface of the skin or are more difficult to wash off this than water-soluble UV filters.

The cosmetic preparations according to the invention can contain cosmetic excipients, such as those commonly used in such preparations be used, for. Preservatives, preservatives, Complexing agents, bactericides, perfumes, substances for increasing of foaming, Dyes, pigments that are a coloring Have effect, thickener, moisturizing and / or moisturizing Substances, fillers, the skin feeling improve, fats, oils, Waxes or other usual Constituents of a cosmetic formulation such as alcohols, polyols, Polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.

advantageous Preservatives according to the present invention are, for example Iodopropyl butyl carbamates (for example those sold under the trade names Glycacil-L, Glycacil-S available from Lonza and / or Dekaben LMB by Jan Dekker), parabens (i.e., p-hydroxybenzoic acid alkyl esters, such as methyl, ethyl, propyl and / or butylparaben), phenoxyethanol, Ethanol, benzoic acid and more. Usually comprises the preservation system according to the invention also advantageously also preservation aids, such as for example, octoxyglycerol, glycine soy etc.

advantageous Complexing agents in the sense of the present invention are, for example EDTA, [S, S] -ethylenediamine disuccinate (EDDS), which is for example available under the trade name Octaquest from the company Octel, Pentasodium ethylenediamine tetramethylene phosphonate, which z. B. available under the trade name Dequest 2046 from the company Monsanto and / or iminodisuccinic acid, which u. a. from Bayer AG under the trade name Iminodisuccinat VP OC 370 (about 30% solution) and Baypure CX 100 available is.

Especially advantageous preparations are also obtained if, as additional or agents used antioxidants. Included in the invention the preparations advantageously one or more antioxidants. As cheap, but yet optional antioxidants can all be used for cosmetic Applications suitable or common Antioxidants are used.

Especially For the purposes of the present invention, water-soluble antioxidants may be advantageous are used, such as vitamins.

preferred Antioxidants are also vitamin C and its derivatives, vitamin E and its derivatives as well as vitamin A and its derivatives.

The Amount of antioxidants (one or more compounds) in the Preparations is preferably from 0.001 to 30% by weight, particularly preferably from 0.05 to 20 Wt .-%, in particular 0.1 to 10 wt .-%, based on the total weight the preparation.

Provided Vitamin E and / or derivatives thereof are the antioxidant (s), is advantageous, their respective concentrations from the field from 0.001 to 10% by weight, based on the total weight of the formulation, to choose.

Provided Vitamin A or vitamin A derivatives or carotenes or their derivatives the one or more antioxidants are advantageous, their respective Concentrations from the range of 0.001 to 10 wt .-%, based on the total weight of the formulation to choose.

Further active ingredients to be used in the context of the present invention are those which have a positive effect on the condition of the skin, in particular active ingredients for positively influencing the aging skin, which reduce the development of wrinkles or even existing wrinkles. Particularly advantageous are biochinones, in particular ubiquinone (Q10) and ubiquinol, folic acid and its derivatives (in particular tetrahydrofolic acid and dihydrofolic acid), niacin and its derivatives (especially niacinamide), creatine and creatinine, carnitine, biotin, isoflavone and its derivatives, lipoic acid, ginkgo Extracts, hops and hops malt extracts. Also agents that promote the restructuring of connective tissue, such as natural and / or synthetic isoflavonoids and isoflavonoid-containing plant extracts - such. As soy and clover extracts - can be used very well in the formulations of the invention. It also shows that the formulations are particularly suitable, active ingredients to support the skin functions in dry skin (such as vitamin C, biotin, carnitine, propionic acid, green tea extracts, jojoba oil, urea and mineral salts (such as NaCl, marine minerals) as well as osmolytes (such as inositol, taurine, betaine, quaternary ammonium compounds). Similarly, the incorporation of drugs to alleviate or positively affect irritative skin conditions, whether sensitive skin in general or noxa-irritated skin (UV light, chemicals), has been found to be beneficial. Here are agents such as sericosides, various extracts of licorice, licochalcone, especially licochalcone A, dexpanthenol, inhibitors of prostaglandin metabolism, in particular cyclooxygenase and leukotriene metabolism, in particular the 5-lipoxygenase, but also the 5-lipoxevase inhibitor protein, FLAP. In particular, creatine and creatinine are suitable active ingredients to create and / or renew an (energy) depot and to activate the repair of various cellular structures, in particular the DNA. The incorporation of modulators of pigmentation also proved to be advantageous. Here are agents that reduce the pigmentation of the skin and thus lead to a cosmetically desired lightening of the skin and / or reduce the occurrence of age spots and / or lighten existing age spots. Examples include tyrosine sulfate, dioic acid (8-hexadecene-1,16-dicarboxylic acid) and various extracts of licorice, arbutin, alpha-arbutin, deoxyarbutin, fruit acids, especially alpha-hydroxy acids (AHAs), Bearberry (Uvae ursi), Ursolic acid, ascorbic acid, pyridoxamine, niacinamide, formulations according to the invention, which z. B. known anti-wrinkle active ingredients such as flavone glycosides (especially α-glycosyl rutin), coenzyme Q10, vitamin C and / or derivatives, vitamin E and / or derivatives and the like, are particularly advantageous for the prophylaxis and treatment of cosmetic or dermatological skin lesions, as z. Skin aging (such as dryness, roughness, dryness wrinkles, itching, decreased refatting (eg, after washing), visible vascular dilation (telangiectasia, cuperosis), slackness and wrinkle and wrinkle formation, localized hypersensitivity). , Hypo and false pigmentation (eg, age spots), increased susceptibility to mechanical stress (eg, cracking), and the like). Furthermore, they are advantageously suitable against the appearance of dry or rough skin.

When Moisturizers are substances or mixtures of substances, which give cosmetic properties the property after application or distributing on the skin surface the moisture release of the Horn layer (also called transepidermal water loss (TEWL)) to reduce and / or to positively influence the hydration of the horny layer.

All in all normalizes the skin's barrier function, which becomes skin noticeable refreshes and invigorates, and the skin appears smoother. By the Deep-acting increase in moisture, swelling and dark circles Visibly reduced, the formation of skin's own lipids is stimulated and the natural ones anti-aging functions of the skin as well as the efficiency the skin overall are stimulated.

advantageous Moisturizers for the purposes of the present invention are, for example Glycerol, lactic acid and / or Lactates, in particular sodium lactate, butylene glycol, propylene glycol, Biosaccaride gum-1, glycine soy, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid, panthenol and urea.

The oil phase of Preparations in the context of the present invention contains advantageous contain nonpolar, for example, those which are chosen from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, Vaseline (petrolatum), paraffin oil, squalane, Polyolefins, hydrogenated polyisobutenes and isohexadecane. Under Polydefins are the preferred substances for polyolefins.

It is particularly advantageous in the context of the present invention, if the content of polar oils with a polarity of less than 20 mN / m (interfacial tension against water) less than 5 wt .-% - based on the total weight the preparation - is chosen.

Advantageous can the oil phase also have a content of cyclic or linear silicone oils or Completely from such oils although it is preferred, except the silicone oil or silicone oils additional Content of other oil phase components to use.

werden auch als Polydimethylsiloxan bzw. Dimethicon (INCI) bezeichnet. Dimethicone gibt es in verschiedenen Kettenlängen bzw. mit verschiedenen Molekulargewichten.Silicone oils are synthetic compounds in which silicon atoms via oxygen atoms chain and / or net-like linked and the remaining valences of silicon by hydrocarbon radicals (usually methyl, more rarely ethyl, propyl, phenyl groups, etc.) are saturated , Systematically, the silicone oils are called polyorganosiloxanes. The methyl-substituted polyorganosiloxanes, which are the quantitatively most important compounds of this group and are characterized by the following structural formula

are also referred to as polydimethylsiloxane or dimethicone (INCI). Dimethicones are available in different chain lengths or with different molecular weights.

According to the invention advantageous is to use cyclomethicone (octamethylcyclotetrasiloxane) as a silicone oil. But also other silicone oils are advantageous for the purposes of the present invention to use for example, hexamethylcyclotrisiloxane, polydimethylsiloxane, poly (methylphenylsiloxane).

Especially advantageous polyorganosiloxanes in the context of the present invention are, for example, dimethylpolysiloxanes (poly (dimethylsiloxane)], which, for example, under the trade names Abil 10 bis 10,000 available from Th. Goldschmidt are. Also advantageous are phenylmethylpolysiloxanes (INCI: phenyl dimethicone, Phenyl trimethicone), cyclic silicones (octamethylcyclotetrasiloxane or decamethylcyclopentasiloxane), which according to INCI also called cyclomethicones amino-modified silicones (INCI: amodimethicone) and silicone waxes, e.g. B. polysiloxane-polyalkylene copolymers (INCI: stearyl dimethicone and cetyl dimethicone) and dialkoxydimethylpolysiloxanes (stearoxy Dimethicones and behenoxy stearyl dimethicones) which are considered to be different Abil wax types are available from Th. Goldschmidt. But other silicone oils are advantageous to use in the context of the present invention, for example Cetyl dimethicone, hexamethylcyclotrisiloxane, polydimethylsiloxane, Poly (methylphenylsiloxane).

The The following examples are intended to illustrate the present invention, without restricting it. The Numerical values in the examples mean percentages by weight on the total weight of the respective preparations.

When Pimpinella anis fruit extract was used in Bioxylift.

Claims (9)

Contains cosmetic preparation (a) one aqueous Fruit extract from anise (Pimpinella anis fruit extract), under which Trade name Bioxilift in the company SILAB, St. Viance, France, available (B) and one or more fillers. Preparation according to one of the preceding claims characterized characterized in that Total amount of filler in the finished cosmetic or dermatological preparations from the range of 0.05 - 20.0 Wt .-%, preferably 0.5 - 10.0 % By weight selected is based on the total weight of the preparations. Preparation according to one of the preceding claims characterized characterized in that the average diameter of the fillers in the range 1-500 microns, preferably in the range 10-100μm and completely particularly preferably in the range 20-70 microns. Preparation according to claim 1, characterized that in addition Glycerol is included. Preparation according to one of the preceding claims characterized in that it is an emulsion, preferably an O / W emulsion or an O / W hydrodispersion, represents. Preparation according to one of the preceding claims characterized characterized in that as coated titanium dioxide substances with a Particle diameter of 10-250 nm, preferably 10-100 nm, chosen become. Preparation according to one of the preceding claims characterized characterized in that it has a pH of 3 to 10, preferably from 4 to 8, has. Use of a preparation according to one of the preceding claims against wrinkles. Use of a preparation according to one of the preceding claims to increase skin elasticity.