DE10059453B4 - Method for producing an evacuated insulating element - Google Patents

Method for producing an evacuated insulating element Download PDF

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Publication number
DE10059453B4
DE10059453B4 DE10059453A DE10059453A DE10059453B4 DE 10059453 B4 DE10059453 B4 DE 10059453B4 DE 10059453 A DE10059453 A DE 10059453A DE 10059453 A DE10059453 A DE 10059453A DE 10059453 B4 DE10059453 B4 DE 10059453B4
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DE
Germany
Prior art keywords
core
evacuated
support member
adhesive
insulating element
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE10059453A
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German (de)
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DE10059453A1 (en
Inventor
Hans Bommer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PUREN SCHAUMSTOFF GmbH
PUREN-SCHAUMSTOFF GmbH
Original Assignee
PUREN SCHAUMSTOFF GmbH
PUREN-SCHAUMSTOFF GmbH
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Priority to DE10059453A priority Critical patent/DE10059453B4/en
Publication of DE10059453A1 publication Critical patent/DE10059453A1/en
Application granted granted Critical
Publication of DE10059453B4 publication Critical patent/DE10059453B4/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • GPHYSICS
    • G10MUSICAL INSTRUMENTS; ACOUSTICS
    • G10KSOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
    • G10K11/00Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/16Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/162Selection of materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/14Manufacture of cellular products
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78Heat insulating elements
    • E04B1/80Heat insulating elements slab-shaped
    • E04B1/803Heat insulating elements slab-shaped with vacuum spaces included in the slab
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/06Arrangements using an air layer or vacuum
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/06Arrangements using an air layer or vacuum
    • F16L59/065Arrangements using an air layer or vacuum using vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/727General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being porous, e.g. foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/04Condition, form or state of moulded material or of the material to be shaped cellular or porous
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/04Condition, form or state of moulded material or of the material to be shaped cellular or porous
    • B29K2105/045Condition, form or state of moulded material or of the material to be shaped cellular or porous with open cells
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0012Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular thermal properties
    • B29K2995/0015Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0065Permeability to gases
    • B29K2995/0067Permeability to gases non-permeable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0025Foam properties rigid
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/24Structural elements or technologies for improving thermal insulation
    • Y02A30/242Slab shaped vacuum insulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00Architectural or constructional elements improving the thermal performance of buildings
    • Y02B80/10Insulation, e.g. vacuum or aerogel insulation

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Acoustics & Sound (AREA)
  • Architecture (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Multimedia (AREA)
  • Electromagnetism (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Refrigerator Housings (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Thermal Insulation (AREA)

Abstract

Verfahren zur Herstellung eines evakuierten Dämmelements, bestehend aus einem Kern- bzw. Stützteil vorzugsweise aus offenzelligem Hartschaumstoff und einer dieses Teil luftdicht umschließenden Folie, deren Inneres evakuiert wird, dadurch gekennzeichnet, dass die Folie mit dem Kern- bzw. Stützteil mittels eines Klebers kraftschlüssig verbunden wird.A method for producing an evacuated Dämmelements, consisting of a core or support member preferably made of open-cell foam and a part of this airtight enclosing foil whose interior is evacuated, characterized in that the film with the core or support member by means of an adhesive positively connected becomes.

Description

Die Erfindung betrifft ein Verfahren nach dem Oberbegriff des Anspruchs 1.The The invention relates to a method according to the preamble of the claim 1.

Ein derartiges Herstellungsverfahren ist vielfach bekannt, beispielsweise aus WO 99/61503 A1 . Das Kern- bzw. Stützteil dieses bekannten Dämmelementes besteht hier aus pulverförmigem oder festem Stützmaterial und ist mit einer Vakuumfolie umhüllt. Geht das Vakuum bzw. der Unterdruck durch Verletzung der Folie oder aus sonstigen Gründen verloren, so liegt oder flattert die Folie lose auf dem Stützteil. Abgesehen von einer drastischen Verschlechterung der Dämmleistung durch den Verlust des Vakuums verliert dabei das Dämmelement auch meist die stützende oder konstruktive Eigenschaft. Auch beim Einbringen des Dämmelements in einen weiteren Sandwichaufbau würde beim Verlust des Vakuums der innige Verbund des Sandwichaufbaus verloren gehen und die Gefahr bestehen, dass das Dämmelement ausbaucht oder auseinander fällt. Die durch bekannte Verfahren hergestellten evakuierten Dämmelemente sind daher nur sehr begrenzt anwendbar, nämlich als reines Einlegeteil in ein Gehäuse, wie beispielsweise das Gehäuse eines Kühlschranks.Such a manufacturing method is widely known, for example WO 99/61503 A1 , The core or support part of this known insulating element consists here of powdered or solid support material and is coated with a vacuum film. If the vacuum or the negative pressure is lost due to damage to the film or for other reasons, the film lies or flutters loosely on the support part. Apart from a drastic deterioration of the insulation performance due to the loss of the vacuum, the insulating element also loses most of the supporting or constructive property. Even when introducing the Dämmelements in a further sandwich structure would be lost to the loss of the vacuum, the intimate bond of the sandwich structure and there is a risk that the insulating element bulges or falls apart. The evacuated insulation elements produced by known methods are therefore very limited applicability, namely as a pure insert in a housing, such as the housing of a refrigerator.

Als weiterer Stand der Technik wird die DE 198 33 566 A1 genannt.As a further prior art, the DE 198 33 566 A1 called.

Der Erfindung liegt daher die Aufgabe zu Grunde, ein Herstellungsverfahren für ein derartiges evakuiertes Dämmelement zu schaffen, das auch bei Verlust des Vakuums seine Stützeigenschaft weitgehend aufrechterhält und daher sehr vielseitig als konstruktives Element einsetzbar ist.Of the The invention is therefore based on the object, a manufacturing method for a such evacuated insulation element to create, even with loss of the vacuum its support property largely maintained and therefore very versatile as a constructive element can be used.

Diese Aufgabe wird erfindungsgemäß durch die Merkmale des Anspruchs 1 gelöst. Durch die kraftschlüssige Verklebung des vorzugsweise aus Hartschaum bestehenden Stützteiles mit der dieses umschließenden Folie wird sichergestellt, dass die konstruktive Festigkeit des Dämmelements auch bei Verlust des Vakuums weitgehend erhalten bleibt.These The object is achieved by the Characteristics of claim 1 solved. By the non-positive Bonding of the preferably made of rigid foam support member with this surrounding Foil ensures that the structural strength of the insulating element is largely retained even if the vacuum is lost.

Die Unteransprüche sind auf vorteilhafte Ausgestaltungen des erfindungsgemäßen Verfahrens gerichtet. Die Ansprüche 2 und 3 betreffen die Anwendung und Form des Klebers, während die Ansprüche 4 und 5 auf die Ausbildung des Dämmelements als plattenförmiges Element, als sogenanntes Paneel, und insbesondere dessen Verklebung mit weiteren Materialien zu einem Sandwich-Aufbau, gerichtet sind. Die Ansprüche 6 bis 8 befassen sich mit der Wahl bevorzugter Materialien und die Größe des anzuwendenden Unterdrucks bei der Vakuumausbildung.The under claims are on advantageous embodiments of the method according to the invention directed. The requirements 2 and 3 relate to the application and form of the adhesive, while the claims 4 and 5 on the formation of the Dämmelements as a plate-shaped Element, as a so-called panel, and in particular its bonding with other materials to a sandwich structure, are addressed. The claims 6 to 8 are concerned with the choice of preferred materials and the size of the applicable Vacuum at the vacuum training.

Claims (8)

Verfahren zur Herstellung eines evakuierten Dämmelements, bestehend aus einem Kern- bzw. Stützteil vorzugsweise aus offenzelligem Hartschaumstoff und einer dieses Teil luftdicht umschließenden Folie, deren Inneres evakuiert wird, dadurch gekennzeichnet, dass die Folie mit dem Kern- bzw. Stützteil mittels eines Klebers kraftschlüssig verbunden wird.A process for producing an evacuated Dämmelements, consisting of a core or support member preferably made of open-cell foam and a part of this airtight enclosing foil whose interior is evacuated, characterized in that the film with the core or support member by means of an adhesive positively connected becomes. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass der Kleber ein dauerfester Kleber ist, der entweder in pastöser Form oder in Form einer aktivierbaren Folie aufgebracht wird.Method according to claim 1, characterized in that that the adhesive is a durable adhesive, either in pasty form or applied in the form of an activatable film. Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass der Kleber vor dem Evakuieren aufgebracht wird.Method according to claim 1 or 2, characterized that the glue is applied before evacuation. Verfahren nach einem der vorangehenden Ansprüche, dadadurch gekennzeichnet, dass das Dämmelement als Paneel geformt wird.A method according to any one of the preceding claims, characterized characterized in that the insulating element is shaped as a panel. Verfahren nach Anspruch 4, dadurch gekennzeichnet, dass das Paneel mit weiteren Materialien zu einem Sandwichaufbau verklebt wird.Method according to claim 4, characterized in that that the panel with other materials to a sandwich construction is glued. Verfahren nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das Kern- oder Stützteil aus Polyurethan-Hartschaum oder einem mit Urethan modifiziertem Polyisocyanurat-Hartschaum besteht.Method according to one of the preceding claims, characterized characterized in that the core or supporting part made of rigid polyurethane foam or urethane-modified Polyisocyanurate hard foam exists. Verfahren nach Anspruch 6, dadurch gekennzeichnet, dass der Hartschaum eine Dichte von mehr als 40 kg/m3 besitzt.Method according to Claim 6, characterized that the hard foam has a density of more than 40 kg / m3. Verfahren nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass zum Evakuieren ein Druck von höchstens 10 bar angewendet wird.Method according to one of the preceding claims, characterized characterized in that for evacuating a pressure of at most 10 bar is applied.
DE10059453A 2000-11-30 2000-11-30 Method for producing an evacuated insulating element Expired - Fee Related DE10059453B4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE10059453A DE10059453B4 (en) 2000-11-30 2000-11-30 Method for producing an evacuated insulating element

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Application Number Priority Date Filing Date Title
DE10059453A DE10059453B4 (en) 2000-11-30 2000-11-30 Method for producing an evacuated insulating element

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DE10059453A1 DE10059453A1 (en) 2002-06-06
DE10059453B4 true DE10059453B4 (en) 2009-12-31

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10239371B3 (en) * 2002-08-28 2004-05-19 Puren-Schaumstoff Gmbh Insulation for a solar energy collector under a glass cover has a hard foam core with a metal foil lamination to withstand high temperatures without gassing
DE10333299B4 (en) * 2003-07-22 2006-02-16 Sto Ag thermal insulation system
DE102011050632A1 (en) 2011-05-25 2012-11-29 Gerd Niemöller Honeycomb element for insulation
CN115816812A (en) 2014-09-25 2023-03-21 巴斯夫欧洲公司 Method for producing composite element for vacuum insulation element

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19833566A1 (en) * 1997-07-29 1999-02-04 Univ Dresden Tech Gas-filled or evacuable thermal insulation body
DE69413231T2 (en) * 1993-07-14 1999-03-04 Imperial Chemical Industries Plc, London POLYURETHANE HARD FOAM
WO1999061503A1 (en) * 1998-05-22 1999-12-02 Huntsman Ici Chemicals Llc Evacuated insulation panels
DE19906774A1 (en) * 1999-02-17 2000-08-24 Gerhard Klaus Hering Heat insulation element comprises a honeycomb structure (1) which is under vacuum, and is surrounded on all sides with a cover (3) impermeable to gases
DE19915311A1 (en) * 1999-04-03 2000-10-05 Bayer Ag Vacuum insulating panel, especially for refrigerators, has a microporous core encased in a 7-layer plastic foil with a polyolefin sealing layer, a gas barrier, a polyolefin layer and a metallised polymer layer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69413231T2 (en) * 1993-07-14 1999-03-04 Imperial Chemical Industries Plc, London POLYURETHANE HARD FOAM
DE19833566A1 (en) * 1997-07-29 1999-02-04 Univ Dresden Tech Gas-filled or evacuable thermal insulation body
WO1999061503A1 (en) * 1998-05-22 1999-12-02 Huntsman Ici Chemicals Llc Evacuated insulation panels
DE19906774A1 (en) * 1999-02-17 2000-08-24 Gerhard Klaus Hering Heat insulation element comprises a honeycomb structure (1) which is under vacuum, and is surrounded on all sides with a cover (3) impermeable to gases
DE19915311A1 (en) * 1999-04-03 2000-10-05 Bayer Ag Vacuum insulating panel, especially for refrigerators, has a microporous core encased in a 7-layer plastic foil with a polyolefin sealing layer, a gas barrier, a polyolefin layer and a metallised polymer layer

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