CS258139B2 - Fungicide and method of its efficient substance production - Google Patents
Fungicide and method of its efficient substance production Download PDFInfo
- Publication number
- CS258139B2 CS258139B2 CS86709A CS70986A CS258139B2 CS 258139 B2 CS258139 B2 CS 258139B2 CS 86709 A CS86709 A CS 86709A CS 70986 A CS70986 A CS 70986A CS 258139 B2 CS258139 B2 CS 258139B2
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- Czechoslovakia
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- formula
- carbon atoms
- compound
- active ingredient
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- 238000000034 method Methods 0.000 title claims abstract description 9
- 230000000855 fungicidal effect Effects 0.000 title claims description 27
- 239000000417 fungicide Substances 0.000 title abstract description 5
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000000126 substance Substances 0.000 title description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 15
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 12
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- ZBNZAJFNDPPMDT-UHFFFAOYSA-N 1h-imidazole-5-carboxamide Chemical compound NC(=O)C1=CNC=N1 ZBNZAJFNDPPMDT-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims description 45
- 239000004480 active ingredient Substances 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 29
- 125000004432 carbon atom Chemical group C* 0.000 claims description 24
- -1 4-chloro-2-trifluoromethylphenyl Chemical group 0.000 claims description 22
- 125000004201 2,4-dichlorophenyl group Chemical group [H]C1=C([H])C(*)=C(Cl)C([H])=C1Cl 0.000 claims description 10
- 125000005843 halogen group Chemical group 0.000 claims description 10
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 6
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- 239000013543 active substance Substances 0.000 claims description 5
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- 125000004215 2,4-difluorophenyl group Chemical group [H]C1=C([H])C(*)=C(F)C([H])=C1F 0.000 claims description 2
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- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- YCFRSUCLXTZSBB-UHFFFAOYSA-N butan-2-yl n-(2,4-dichlorophenyl)-3-propan-2-ylimidazole-4-carboximidate Chemical compound C=1N=CN(C(C)C)C=1C(OC(C)CC)=NC1=CC=C(Cl)C=C1Cl YCFRSUCLXTZSBB-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical class [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- WORJEOGGNQDSOE-UHFFFAOYSA-N chloroform;methanol Chemical compound OC.ClC(Cl)Cl WORJEOGGNQDSOE-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012230 colorless oil Substances 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 101150047356 dec-1 gene Proteins 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000003113 dilution method Methods 0.000 description 1
- BDUPRNVPXOHWIL-UHFFFAOYSA-N dimethyl sulfite Chemical compound COS(=O)OC BDUPRNVPXOHWIL-UHFFFAOYSA-N 0.000 description 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N dimethylformamide Substances CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- UREBWPXBXRYXRJ-UHFFFAOYSA-N ethyl acetate;methanol Chemical compound OC.CCOC(C)=O UREBWPXBXRYXRJ-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000003818 flash chromatography Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 235000012243 magnesium silicates Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- VQCCUXJPUBGCTP-UHFFFAOYSA-N n-(2,4-dichlorophenyl)-3-propan-2-ylimidazole-4-carboxamide Chemical compound CC(C)N1C=NC=C1C(=O)NC1=CC=C(Cl)C=C1Cl VQCCUXJPUBGCTP-UHFFFAOYSA-N 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 230000001338 necrotic effect Effects 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- IPNPIHIZVLFAFP-UHFFFAOYSA-N phosphorus tribromide Chemical compound BrP(Br)Br IPNPIHIZVLFAFP-UHFFFAOYSA-N 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical compound CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000002426 superphosphate Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 230000019432 tissue death Effects 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/90—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Cultivation Of Plants (AREA)
- Compounds Of Unknown Constitution (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB858502398A GB8502398D0 (en) | 1985-01-31 | 1985-01-31 | Imidazole derivatives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS70986A2 CS70986A2 (en) | 1987-12-17 |
| CS258139B2 true CS258139B2 (en) | 1988-07-15 |
Family
ID=10573706
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS86709A CS258139B2 (en) | 1985-01-31 | 1986-01-31 | Fungicide and method of its efficient substance production |
Country Status (19)
| Country | Link |
|---|---|
| EP (1) | EP0191514B1 (de) |
| JP (1) | JPH0662585B2 (de) |
| CN (1) | CN1010946B (de) |
| AT (1) | ATE62233T1 (de) |
| AU (1) | AU582621B2 (de) |
| BR (1) | BR8600337A (de) |
| CA (1) | CA1274524A (de) |
| CS (1) | CS258139B2 (de) |
| DE (1) | DE3678460D1 (de) |
| DK (1) | DK165636C (de) |
| ES (1) | ES8800167A1 (de) |
| GB (1) | GB8502398D0 (de) |
| GR (1) | GR860246B (de) |
| HU (1) | HU196290B (de) |
| IE (1) | IE58812B1 (de) |
| NZ (1) | NZ214969A (de) |
| SU (1) | SU1568881A3 (de) |
| TR (1) | TR22327A (de) |
| ZA (1) | ZA86430B (de) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8617083D0 (en) * | 1986-07-14 | 1986-08-20 | Shell Int Research | Imidazole derivatives |
| GB8617791D0 (en) * | 1986-07-21 | 1986-08-28 | Shell Int Research | Fungicides |
| GB8622900D0 (en) * | 1986-09-23 | 1986-10-29 | Shell Int Research | Fungicidal compositions |
| GB8631020D0 (en) * | 1986-12-30 | 1987-02-04 | Janssen Pharmaceutica Nv | 1-methyl-1h-imidazole-5-carboxylic acid derivatives |
| GB8631091D0 (en) * | 1986-12-31 | 1987-02-04 | Janssen Pharmaceutica Nv | 1-cyclyl/polycyclyl substituted-1h-imidazone-5-carboxylic acids |
| GB8726109D0 (en) * | 1987-11-06 | 1987-12-09 | Shell Int Research | Imidazole oxime derivatives |
| US4931448A (en) * | 1987-11-17 | 1990-06-05 | Ici Americas Inc. | Thiomidate insecticides |
| EP1178036A1 (de) | 2000-08-04 | 2002-02-06 | Aventis Cropscience S.A. | Fungizide Phenylimidate-Derivate |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL44350A0 (en) * | 1973-04-05 | 1974-06-30 | Sparamedica Ag | New imidazole derivatives,their manufacture and pharmaceutical compositions containing them |
| DE2732531A1 (de) * | 1977-07-19 | 1979-02-01 | Hoechst Ag | Imidazolcarbonsaeuren und deren derivate |
| DE3217094A1 (de) * | 1982-05-07 | 1983-11-10 | Hoechst Ag, 6230 Frankfurt | 1-substituierte imidazol-5-carbonsaeurederivate, ihre herstellung sowie ihre verwendung als biozide |
| GB8617083D0 (en) * | 1986-07-14 | 1986-08-20 | Shell Int Research | Imidazole derivatives |
| GB8617791D0 (en) * | 1986-07-21 | 1986-08-28 | Shell Int Research | Fungicides |
-
1985
- 1985-01-31 GB GB858502398A patent/GB8502398D0/en active Pending
-
1986
- 1986-01-20 AT AT86200092T patent/ATE62233T1/de not_active IP Right Cessation
- 1986-01-20 EP EP86200092A patent/EP0191514B1/de not_active Expired - Lifetime
- 1986-01-20 AU AU52477/86A patent/AU582621B2/en not_active Ceased
- 1986-01-20 DE DE8686200092T patent/DE3678460D1/de not_active Expired - Lifetime
- 1986-01-21 ZA ZA86430A patent/ZA86430B/xx unknown
- 1986-01-22 CA CA000500049A patent/CA1274524A/en not_active Expired - Fee Related
- 1986-01-28 GR GR860246A patent/GR860246B/el unknown
- 1986-01-29 NZ NZ214969A patent/NZ214969A/xx unknown
- 1986-01-29 BR BR8600337A patent/BR8600337A/pt not_active IP Right Cessation
- 1986-01-30 SU SU864022865A patent/SU1568881A3/ru active
- 1986-01-30 CN CN86101080A patent/CN1010946B/zh not_active Expired
- 1986-01-30 HU HU86440A patent/HU196290B/hu not_active IP Right Cessation
- 1986-01-30 IE IE26586A patent/IE58812B1/en not_active IP Right Cessation
- 1986-01-30 ES ES551421A patent/ES8800167A1/es not_active Expired
- 1986-01-30 TR TR4631/86A patent/TR22327A/xx unknown
- 1986-01-30 DK DK047886A patent/DK165636C/da not_active IP Right Cessation
- 1986-01-31 JP JP61018295A patent/JPH0662585B2/ja not_active Expired - Lifetime
- 1986-01-31 CS CS86709A patent/CS258139B2/cs unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE3678460D1 (de) | 1991-05-08 |
| ZA86430B (en) | 1986-08-27 |
| DK47886D0 (da) | 1986-01-30 |
| JPH0662585B2 (ja) | 1994-08-17 |
| CA1274524A (en) | 1990-09-25 |
| EP0191514A1 (de) | 1986-08-20 |
| JPS61180772A (ja) | 1986-08-13 |
| ES8800167A1 (es) | 1987-11-01 |
| BR8600337A (pt) | 1986-10-14 |
| DK47886A (da) | 1987-08-01 |
| AU5247786A (en) | 1986-08-07 |
| TR22327A (tr) | 1987-02-12 |
| AU582621B2 (en) | 1989-04-06 |
| ATE62233T1 (de) | 1991-04-15 |
| DK165636B (da) | 1992-12-28 |
| GB8502398D0 (en) | 1985-03-06 |
| GR860246B (en) | 1986-05-29 |
| CN86101080A (zh) | 1986-10-22 |
| ES551421A0 (es) | 1987-11-01 |
| SU1568881A3 (ru) | 1990-05-30 |
| IE58812B1 (en) | 1993-11-17 |
| HUT40553A (en) | 1987-01-28 |
| CN1010946B (zh) | 1990-12-26 |
| DK165636C (da) | 1993-06-01 |
| HU196290B (en) | 1988-11-28 |
| IE860265L (en) | 1986-07-31 |
| EP0191514B1 (de) | 1991-04-03 |
| CS70986A2 (en) | 1987-12-17 |
| NZ214969A (en) | 1989-01-06 |
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