CS248253B1 - Method of organo-siliceous nitrodye stuffs production - Google Patents
Method of organo-siliceous nitrodye stuffs production Download PDFInfo
- Publication number
- CS248253B1 CS248253B1 CS791668A CS166879A CS248253B1 CS 248253 B1 CS248253 B1 CS 248253B1 CS 791668 A CS791668 A CS 791668A CS 166879 A CS166879 A CS 166879A CS 248253 B1 CS248253 B1 CS 248253B1
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- Czechoslovakia
- Prior art keywords
- natural
- general formula
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- hjih
- production
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- 238000000034 method Methods 0.000 title claims 5
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 239000001005 nitro dye Substances 0.000 title 1
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- -1 siloxanes Chemical class 0.000 claims 3
- 239000000835 fiber Substances 0.000 claims 2
- VBEGHXKAFSLLGE-UHFFFAOYSA-N n-phenylnitramide Chemical compound [O-][N+](=O)NC1=CC=CC=C1 VBEGHXKAFSLLGE-UHFFFAOYSA-N 0.000 claims 2
- 239000000985 reactive dye Substances 0.000 claims 2
- 150000004756 silanes Chemical class 0.000 claims 2
- 239000012209 synthetic fiber Substances 0.000 claims 2
- 229920002994 synthetic fiber Polymers 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 238000004040 coloring Methods 0.000 claims 1
- 239000006103 coloring component Substances 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 125000003700 epoxy group Chemical group 0.000 claims 1
- 229910010272 inorganic material Inorganic materials 0.000 claims 1
- 239000011147 inorganic material Substances 0.000 claims 1
- 125000000962 organic group Chemical group 0.000 claims 1
- 229920000620 organic polymer Polymers 0.000 claims 1
- 125000005375 organosiloxane group Chemical group 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 125000003107 substituted aryl group Chemical group 0.000 claims 1
- 101100384273 Dictyostelium discoideum clua gene Proteins 0.000 description 2
- 235000017399 Caesalpinia tinctoria Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 101100366940 Mus musculus Stom gene Proteins 0.000 description 1
- 241001454372 Onoba Species 0.000 description 1
- 241000388430 Tara Species 0.000 description 1
- 230000029305 taxis Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/008—Dyes containing a substituent, which contains a silicium atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Silicon Polymers (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Description
1
HasBanue Η3θ6ρετβΗΗΗ ,KpeMHHňcoflep»anuie HHTpOKpacHTenu OSjíaCTb ΠΡΗΜβΗβΗΜΗ Η3θ6ρβΤβΗΗΗ Η3θ6ρβτβΗΗβ KačaeTca KpeMHHňcoflepxaiipix HHTpoKpacHTeneň ftnn KpauieHna nonn-MepHblX OpraHHHeCKHX COeflHHeHHH H OCOSeHHO flJIH KpameHHH CHJlHKOHOBblX προ-ρ,ξκτοΒ, a Taxxe HeopraHHHecKHX MaTepManoB u peaxTHBHbix xpacHT&neň fínn chh-ΤβΤΗΊβΟΟΗΧ HJIH HaTypajlbHbIX BOJ1OKOH paCTHTeJlbHOrO HJIH «ΗΒΟΤΗΟΓΟ npOHCXO«fle~hhh. KpacHTejiH MoryT 6biTb BCTpoeHbí b nojiHMepHyio Mojiexyjiy hjih HaHeeeHbí coot-ΒβΤΟΤΒβΗΗΟ Ha BOJlOKHa 6β3 flOnOJIHHTeJIbHOrO 4>HKCHpOBaHHH.
XapaKTepHCTHKa H3BecTHbix τβχΗΗΗβοκκχ pemeHnň
Bonxyp (flHecepTaiíHH, 1970, TexHHnecxHft ΥΗΗΒβροΗΤβτ IfyopHx) h XamriMOTo(XxaraKH 33cínu, 80 (1960), 1399-1404) onncbieaioT nojiyneHne a3oxpacHT&neň HaOCHOBe TpHMeTHJICHJIHJiaHHJIHHOB peaKpHeň 3THX COeflHHéHHň KpeMHHH C flHa3OTHpO-BaHHbíMH apoMaraqecKHMH aMHHaMH. KpacHTejiH Ha 3Toít ocHoee He MoryT yflepxw-BaTbcn Ha oxpaiDHBaeMbix cy6cTpaTax no npHHHHe HeaxTHBHbix μθτηπβημχ rpynny aTOMa κρβΜΗΗΗ h noŠTOMy He nojiymuiH ηηκβκογο npoMbmuieHHoro sHaneHHH.
KpacHTejiH, xoTopbie coflepwar tphc- (TpHMeTHncHjiOKCH)-CHJinnajiKHJiaMHHOBoň pa-AHKan, npHBefleHbí b onncaHHHX Η3θθρετβΗΗϋ κ nareHTaM ClUA 3 888 891, 3 963744 h 3 981 859. Πρκ stom penb Ηββτ b ochobhom o χηηοη-,ηηαηγο-,τηοηηαηγο-,φΤΗΠΟΙξΗΗΗΗΗ— H aSOKpáCHTeJIHX. HcXOflH H3 ΤΟΓΟ, HTO flJIHnojiyweHHH tphc-(tph-MeTHJicHnoKCH)-CHnHJiajxHJiaMHHa TpefiyeTCH npoBOflHTb floporne peaKu.nn h bmxoa9Toro cnnara οηθηβ Man, KpacHTéJiH Ha hx OCHOBe T3K«e no npHMHHe HeaKTHBHoc-th cHnOKCHrpynn Hamen πρΗΜβΗβΗΗβ τοηπκο b orpaHHUeHHOM oSteMe «πη xpameHHHonpeneneHH^ix nonHCHnoxcaHOB.
KpeMHHňcoflepwamHe KpacHTejiH, κοτορωβ ywe oSjíanaioT rHflponH3yeMoň, cnocofi-CTByioiueň yflepxHBaHHio rpynnoň οπηοβημ, HanpnMep, b onncaHHHx H3o6peTeHHň κnaTeHTaM ClUA 2 925 313, 2 927. 839, 2 931 693, 2 934 459, 2 955 898, 2 955 899 h 2 963 338. Πρκ stomnna nonyneHHH aaoKpacHTeneň 6μπη Hcnonb3OBaHbi 248253 2 apnjiaMHHo- hjih aMHHoapHJiajiKHJiajiKOKCHCKnaHbí b. kanecTBe KpeMHuňcoflepxatuHxHCXOflHbIX ΚΟΜΠΟΗΘΗΤΟΒ. 3TH KpaCHTejIH ΠΟΚ33ΜΒ3ΙΟΤ XOpOniyiO CTOňKOCTb Ha creKno-BOJioRHe, Ha HaTypajibHbix BOJiOKHax, HanpHMep, Ha inepcTH, Ha mejixe h Ha xjion-HaTOÓyMaXHOM BOJIOKHe, H Ha CHHTeTHHéCKHX BOJiOKHax. Hx HenOCTaTKOM ΛΒΗΗβΤ-ch Taxíce cjiokHoe h noporoe nojiyneHHe ncxo,n(Horo KpeMHHňconepMamero aMHHocoe-flHHeHHH.
KpeMHHňcoflepxaHHe HHTpoKpacHTejiH no chx πορ b jinrepaType He 6mjih onHcaHbi.ΙΙβΛΒ_Η3°6ρβΤθΗΗΗ
Uejibio H3o6peTeHHH ηβπηθτολ nojiyneHHe no chx nop HeH3BecTHbix KpacHT&neňnpOCTbIM CIIOCO6OM, H3 JierKOnOCTynHOrO CbipbH H C XOpOmHMH BWXOnaMH. KpaCHntHěΚΟΜΠΟΗβΗΤΜ nOJEKHbl 6bITb Π0 BO3MOJKHOCTH CBH3»HbI C nOJIHMepHblMH CTpyKTypaMHrOMeonOJIHpHHMH CBH3HMH. flajiee, KpaCHTejIH ňOJDKHbl ΠΟ CBOeň CTOňKOCTH K CHJIH-KOHaM OTBenaTb CaMblM BblCOKHM Η Cneip^HHeCKHM TpeĎOBaHHHM Η ηθ·ΠΓΟΒβΗΗΟ OKpa-niHBaTb nojiHMepHbie MaTepHajibi h ocoóeHHO CHJIHKOHOBbie nponyKTbi. H3JIO«eHHe cymHOCTH Η3θ6ρβΤβΗΗΗ
Bbuio HaňneHO, hto KpeMHHňconepacaiHHe HHTpoKpacHTejiH obiqeň ýopMyjibi
Xb - Si*- Z - 1CH - 2CH2 - NH - Ár(NO2)a
Ri-b Óh
Cnoeo6HbI ηθ·ΠΓΟΒ6ΗΗΟ OKpafflHBaTb nojiHMepHbie H OCOĎeHHO CHJIHKOHOBbie MaTepHa-Jlbl, ynOBJíeTBOpHH npH 3ΤΟΜ T3KHM npenbHBJIHeMblM Κ CHJIHKOHaM CnenH<}>HHeCKHMTpeČOBaHHHM KaK, HanpHMep, TepMOCTaĎHJIbHOCTb. B o6meň (JiopMyjie HHneKCbi o6o3HanaK)T: . X = onHHaKOBbie hjih pa3JiHHHbie rHnponH3yeMhie rpynnw hjih CHJioKcaHOBbie pa-nHKajiw, Z = nsyxBajieHTHbiň ajiKHJibHbiň panuKaji c 2—10 aTOMaMH yrnepona, κοτορωήμοκθτ 3aKaHHHBáTbCH aTOMaMH KHcnopona, a TaKjKě conepxaTb nHKJiHnecKHe3BeHbH, ηρΗΗβΜ 1C T3K 3ΚΘ K3K H 2C ΜΟΙψΤ o6pa3OBbIBaTb HaCTH KOJIbnanHKJioajiKHJia, R - onHOBajieHTHbiň opraHHnecKHň panHKaji,
Ar = 3aMemeHHbiíí hjih He3aMemeHHbiň apoMaTHxecKHň panHKan, a h b = nejibie HHCJia οτ I no 3.
IlpenJiaraeMbiň cnocoS nojiyneHHH hobmx KpeMHHňconepxamHX HHTpoKpacHTeneňoweHb προετ h peajiH3ýeTCH peaxnHeň cwiaHOB hjih CHJiOKcaHOB oĎmeft φορΜγηΜί X, - Si - Z - - 2CH„
Rs-b θ c HHTpoaHHJiHHaMH o6m;eň φορΜνηΗίH2N - ΑΓ(Ν02)α 3HaneHHH ΗΗηθκεοΒ X, Z, R, Ar, a h b yace npHBeneHbí Bbnne. Πο 3τοή peaKnHHΒΠΟΚΟΗφνΗΚηΗΟΗΘΙΙΒΗωε CHJiaHbl HJIH CHJIOKCaHbl CMemHBaiOTCH C HHTpOaHHJIHHaMH HHarpeBaioTCH no ,κηπθηηη. HcxonHbie KOJinnecTBa BbiSnpaioTCH TaK, htoĎm b peaK-nHOHHOH CMeCH 3nOKCH- H aMHHOrpynnbl HaXOnHHHCb B CTeXHOMeTpHHeCKOM cootho-hi6hhh. PeaKnHH προτεκεετ KOJiHnecTBeHHo h 6es aaTpynneHHň. IIocKOJibKy cnnaHHJIH CHJIOKCaH TpynHO o6pa3yiOT COBMeCTHbie paCTBOPbl C HHTpoaHHJIHHOM, MOJKHOnpoBonuTb peaKHHio b pacTBopHTeJiHX TaKHX KaK, HanpHMep, MeTaHoji, 3TaHOJi,apeTOH, nHMeTHjnfcopMaMHn, cnoacHbie anKHJibHbie 3φκρΜ KapĎOHJBbix khcjiot, 6eH3OJihjih TOJiyoji.ZJobaBKa KaTajiH3aTopoB He HBJíneTCH HeoĎxonHMOň,TaK ksk npHpeaK- 248253 3 UHH, COrnaCHO Η3θ6ρβΤβΗΗΙ0, <£)yHKl|HOHajIbHbie rpynnbl y aTOMa ΧρβΜΗΗΗ COXpaHH-IOTCH, BO3MOXHO ΤβΚΧβ ΗβΠΟΗΒ3ΟΒβΗΗβ CHHHKOHOBbtX HaCTHHHbrX KOHfleHCaTOB BxauecTBe hcxoahmx coe^HHenHň, Beflynmx b cboio onepeflb κ nponyxTaM, κοτορωβp,&ne& HcnojibsyioTCH xax οττβΗΟΜΗωβ nacTbi. HHTpoKpacnTenH, cornacHo Η3ο6ρβτβΗΗΐο,. BCTpoeHHbie b cujihkohobyio MojiexyjiynocpeflCTBOM roMeonojiapHoň cbh3h, πρηγο^ημ κροΜβ OKpamHBaHHH nojiHCHJioxcaHOBH opraHHwecKMx nojtMMepoB u rhh oxpajaHBaHHH chuhxohobmx. HanojiHHTeneň, npH-ueM rHp,pojiH3yeMbie rpynnbl y aTOMa χρβΜΗΗΗ o6pasyioT c oxpamHBaeMbiMH MaTěpna-naMH roMeononnpHwe CBH3H, KOTopwe npeflnojrcaraioT oco6eHHo Bbicoxyio ycToňw-BocTb KpameHHx xax, HanpHMep, MHrpauHOHHyro h CBěToycToiViHBocTb, flanee, HHTpoxpacHTejiH, cornacHo Η3θ6ρβτβΗΗκ>, πρηγο^ηη b xanecTse peaxTHBHbixKpacHTejieň nna τβχκχ HaTypajibHbix h CHHTeTHHecxHx bojioxoh xax mepcTb, menx;xjionox, pereHepupoBaHHbie BojioxHa, nojinaMHflHbie, ποπΗ3φΗρΗωβ BOJioxHa h t»a. ,Tax xax HMeionpiecB b Monexyjie xpacHTejia peaxyHOHHbie rpynnbi oSpasyioT c cy6-CŤpaTOM rOMeonOJIHpHýlO CBB3b. IIpHMepbi ocymecTBJíeHHH Η3θ6ρβτβΗΗΗ ΠρΗΜβρ 1 27.6 secoBoň nacTH 4-HHTpóaHHHHHa pacTBopmoT npHHarpeBaHHH b 300 BecoBbixtiacTHX 3TaH0Jia h CMemHBaioT c 51,8 secoBoň, nacTH 3-rjiHHHfloxcHnponHJiTpHMeTOX“CMJiaHa. CMecb χηππτητ 4 Mac. c oSnaTHbíM xojioflWibHHXoM h aaTeM οτγοηηιοτpacTBopHTejib, πβη stom nonyqaeTCH χβπτο-xpacHbiň xpacHTenb. 1 r nonyyeHHoro TaxnM o6pa3OM xpacHTejia CMeniHBaroT c 50 r nacTU, cocTojnueňH3 100 BecoBbix nacTeň c(-w-nojiHnHMeTHnCHnoxcaHnHo.na h 50 BecoBbix HacreňaMop$Hoň flByoxncH xpeMHHB. Ilocne xopomero nepeMemnBaHHH nacTbi c 2 r cmHBaio-meň xhakocth, cocTOHmeft H3 80 Bečoebiň HacTeů TeTpaaToxcHcnuiaHa h 20 Beco-Bbix nacTeň flH6yTHJiflHjiaypaTa onoBa, wepe3 48 nac. BbwepxHBaHHH πρκ κοΜΗβτ-Hoň TeMnepaType nojiynaeTCH oKpameHHbiň b xenTbiň ιχΒβτ CHJiHKOHOBbift xayuvx,KOTOpbiň He τβρπβτ CBoeň oxpacxH h nepea 10 nac. HaroeBaHHH npH 180°C. ΠρΗΜβρ 2 ' 36,6 BecoBoň MacTH 2,4-nHHHTpoaHHjiHHa floÓaBjíHioT nocTeneHHo x 56 BecoBbíMUaCTHM 3-rjIHUHflOXCHnpnnHJlTpH3TOKCHCHnaHa, HarpeTOrO flO 150°C. Πο OKOHÚaHHMfloGaBjíeHHH peaxůHOHHyx) CMecb BbinepxHBajOT eme 5 nac. iidh 200ο0 h oxnaxflaioT,npH3tom nonyMaeTCH xopHHHeBbrii xpacHTenb. · ΠρΗΓΟΤΟΒΠΛΙΟΤ 15%-Hblft : paCTBOP XpaCHTejIH B 3TaHOJie, B XOTOpblň COQTBeTCTBeH-ho Ha 5 mhh. norpy»ax>T xnonHaTo6yMa»Hoe, mepcTSHoe, manxoBoe, nonHaMHflHoe,nojiHtJiHpHoe BOJioxHa H CTexjioBOJioxHO. BbixpameHHbie BonoxHa npoMbiBajoT aaTeM3TaHOJioM h BOfloň. Πο TaxoMy cnocoCy nonynaiOTCH oxpameHHbie b xejiTbiň μββτBonoxHa, OTjiHqaromHeca Bbicoxoň CBeTocToftxocTbJo. ΠρΗΜβρ -3 24.6 BecoBoň nacTH ^-3,4-3noxcHiíHXJiorexcHn3THJiTpHMeToxcHCHJiaHa CMemHBaioTc 18,4 BecoBoň wacTbio 2,4-flHHHTpoaHHJiHHa h HarpeeatOT 2 nac. npH 180°C.BaxyyMHoň pasroHxoň oTflejnnoT 4,8 r He Bomeftmero b peaxtpMo /í-3,4-3iioxch-HHXJiorexcHJiaTHnTpHMeToxcHCHJiaHa. Οβτβτοχ npoMbieaioT STaHonóM η οτΦηπβτροβμ-BaioT, npH 3TOM nonynaeTCH 3κβΛτο-χορΗΊΗβΒωίί nopomox. 1 r 3ΤΟΓΟ HHTpoxpacHTejiH CMemHBaioT c 100 r 70%—Horo 1 TonyojibHoroi pacTBopaΠρΟβΤρβΗβΤΒβΗΗΟΓΟ ClUHTOň ΜβΤΗΠφβρΗΠβΗΗΗΧΟΗΟΒΟΑ CMOJIbl. PaCTBOp CHJIHXOHOBOň 248253 4 cmojim npocymHBaioT b φορΜβ npH 80°C h 3aTeM OTBepxyjaioT oxojío 3 nac. npw250 ^C. B pe3yjibTaTe nojiyuaeTca npo3paHHaH oTJiHBxa cnnuKOHosoň cmohm acenTo- ro μΒβτβ 4>opMyjia_H3o6peTeHHH_ l.CnocoO nojiyneiíiin hobhx KpeMHHňcoflepacamHX HHTpoxpacHTejieft ρ,ηχ oKpawuBaHtíftopraHiwecKHX nojiHMepoB hjih opraHocHJioxcaHOB, a Taxxe peaxTHBHbix xpacHTejieiiflJIH HáTypanbHbIX H CHHTeTHUeCKHX OpraHHHeCKHX BOJIOXOH HJIH flJIH HeopraHHMee-khx MaTepHanoB, o6meň φορΜγπΜ:
rp,e oKpamiBaiomnň κοΜποπβΗτ CBB3aH c θτομομ 'kpeMHHa γομθοποιιηρημμη cbh3hmhh HHflexcbi o6o3Ha»iaioT: X = OflHHaKOBbie hjih pa3JiHHHbie rHApojiH3yeMbie rpynnbi hjih ctuioxcaHOBbiň pa-. flHxan, Z = ajiKHJieHOBbiň paflHxan c 2-10 aTOMaMH yraepofla, xoTopbiň MoaceT οβρω-BaTbCH aTOMaMH KHCJiopofla, a Tarae coflepmaTb nHXJiHnecxHe 3BeHba, h1C Tax ace xax h MoryT o6pa3OBbiBaTb nacTH UHXJioajixHJibHoro xojibna, R = oflHogaaeHTHbiň opraHHnecxuft paflHxan,
Ar = aaMemeHHbiň hjih He3aMemeHHbift "φβΗΗπ" - paflHxaji,a, b = yejibie nncjia οτ 1 jjo 3, OTJiHHaK>mHňcH τβΜ, hto CHJiaHbí hjiH «HJioxcaHbí o6qeň φορί^ιίω: h HHTpaHHJiHHbí o6meň ^opMyjibi: H2N - Ar(N02)q BCTynaioT B peaxituro npH TeMnepaType ot 100 flo 200°C H npH CTexHOMeTpHnecxoMcooTHomeHHH anoxcH- h aMHHorpynn ηητρβηηπηηβ. 2, Cnoco6 no nyHXTy 1, oTnnuamntftíicB těm, hto peaxijHa προτβχββτ b pacTBope. 3. Ciioco6 no nyHXTaM 1 - 4 oTJiiraaiomHftcH τθμ, hto peaxnnH npoTexaeT b npH-cyrcTBHH HaTypanbHbix hjih cHHTeTHnecxHx bojioxoh h o6pa3yiomHecB peaxTHBHbiexpacjíTejiH cpa3y ace coenHHaroTca c bojioxhom. 5.Cnoco6 np nyHXTaM 1 - 4 OTJiHHaromHftca τβΜ, ητο naTypajibHbie hjih ΟΗΗτβτΗηβε-xne BOJioxHa, nponHTaHHbie cooTBeTCTByion[HMH cHnaHaMH hjih CHJioxcaHaMH, pearH-pyiOT C HHTpOaHHJIHHaMH.
AHHOTanHH
KpeMHHňcoflepacamHe HHTpoxpacHTejiH očqeň φopMyJϊhí
X, - Si - Z - 1CH - 2CHz - NH - Ar(N02)aR3.fc OH rojiHTCH, b flaHHOM cnynae Taxace b BH«e οττβΗΡΗΗΜΧ nacr, wia oxpamHBaHHHnojiHMGpHbix coejjHHeHHň opraHHHecxoro κπη HeopraHHuecxoro npoHCxoacfleHHH,ocofíeHHo fljia CHJiHXOHOBbix npoflyxTOB, a Taxace b xanecree peaxTHBHbix xpacHTe-neň ajih HaTypajibHbix h cHHTeTHnecxHx bojioxoh. 248253 5
Hx ocoOoe npeHMymecTBo aaitnioMaeTCH b bosmoxhocth BCTpaHBaHHH KpacainHxκοΜΠΟΗβΗτοβ b nojiHMepHyw MOJiexyjiy nocpeflCTBOM roMeononapHoft cbh3h.
Hx nonyueKHe nerxo peanH3ye*rcH peaKuweft CHnanoB ηπη CHJioKcaHoe o6meft φορ-wyjibi *CH -x2CH2
Xc - Sí - ZR3-b C HHTpoaHHrtHHaMH o6meň ýopMyjibiH2N - Ar(NO2)a r«e X 03HaqaeT OgHHaKOBbie hjih pa3JiHHHbie rHflpojiHsyeMhie paflHKajibi hjih chjiokc$-HOBýro rpynny h Z-ajiKHJieHOByio rpynny hjih coflepxamyio uHKJiHuecKHe sseHbH aji-XMJieHOByio rpynny.
IlpH3HaHO Η3θ6ρβτβΗΗβΜ no peayjibTaTaM 3xcnepTH3bi, ocymecTBjíeHHoťi BeflOMCTBOMno aejiaM Η3οδρβτβΗΗΰ η naTeHTOB PflP. 248353
Claims (4)
1. Způsob výroby nových organokřemičitých nitrobarviv probarvení organických polymerů nebo organosiloxanů a téžreaktivnífeh barviv pro přírodní i syntetická organickávlákna nebo pro anorganické materiály obecného vzorceXfc - Si - Z - 1CH - 2CH2 - NH - Ar/N02/a Si^ OH kde barvicí složka je vázána na atom křemíku homeopolárnímivazbami, přičemž znamená X stejné nebo různé hydrolyzovatelné skupiny nebo siloxa-novou skupinu, - Z alkylenovou skupinu s 2 až 10 atomy uhlíku, která může být přerušena atomy kyslíku a může být obsažena v cyklu1 2 v a C a C mohou tvořit části cykloalkylového řetězce, R jednovalentní organickou skupinu, Ar popřípadě substituovanou arylovou skupinu,a, b celé číslo 1 až 3 vyznačený tím, že silany nebo siloxany obecného vzorce XH - Si - Z - 1CH - 2CHo b I \/ 2t R, v 0 3-b kde X, Z, R,b mají shora uvedený význam a nitroanilinyobecného vzorce H2N - Ar/N02/a , kde R, Ar, a mají shora uvedený význam, se nechají reagovatpři teplotě 100 až 200 °C a při stechiometrickém poměruepoxidových skupin a aminoskupin nitroanilinu. 248 253
2. Způsob podle bodu 1, vyznačující se tím, že se reak-ce provádí v rozpouštědle.
3· Způsob podle bodů 1 až 2, vyznačený tím, že reakceprobíhá v přítomnosti přírodních nebo syntetických vlá-ken a vznikající reaktivní barviva se ihned slučují svláknem.
4» Způsob podle bodů 1 až 2, vyznačený tím, že přírodnínebo syntetická vlákna napuštěná příslušnými silany ne-bo siloxany reagují s nitroaniliny.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD78204587A DD145022A3 (de) | 1978-04-05 | 1978-04-05 | Verfahren zur herstellung von neue siliziumhaltigen nitrofarbstoffen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS248253B1 true CS248253B1 (en) | 1987-02-12 |
Family
ID=5512074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS791668A CS248253B1 (en) | 1978-04-05 | 1979-03-12 | Method of organo-siliceous nitrodye stuffs production |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4403099A (cs) |
| JP (1) | JPS54148022A (cs) |
| BE (1) | BE875230A (cs) |
| CS (1) | CS248253B1 (cs) |
| DD (1) | DD145022A3 (cs) |
| DE (1) | DE2908204A1 (cs) |
| FR (1) | FR2421934A1 (cs) |
| GB (1) | GB2018799B (cs) |
| SU (1) | SU1013454A1 (cs) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19710461A1 (de) | 1997-03-13 | 1998-09-17 | Wacker Chemie Gmbh | Farbstoffreste aufweisende Organopolysiloxane |
| US7354459B2 (en) | 2004-11-03 | 2008-04-08 | L'oreal S.A. | Use of organosilane compounds for dyeing keratin fibers |
| FR2877217B1 (fr) | 2004-11-03 | 2007-01-26 | Oreal | Utilisation de composes de type organosilane en teinture des fibres keratiniques |
| DE102006027533A1 (de) * | 2006-06-14 | 2007-12-20 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Farbige Organopolysiloxane |
| DE102006046465A1 (de) * | 2006-09-29 | 2008-04-03 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Farbige Organopolysiloxane |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2256246A (en) * | 1939-10-06 | 1941-09-16 | Master Metal Products Inc | Welding apparatus |
| US2985680A (en) * | 1959-08-03 | 1961-05-23 | Union Carbide Corp | Nitro and nitrito derivatives of organosilicon compounds |
| US2998406A (en) * | 1960-06-14 | 1961-08-29 | Union Carbide Corp | Aminoaralkyl silicon compounds and process for their production |
| US3131205A (en) * | 1962-03-09 | 1964-04-28 | Aerojet General Co | N-(silico-alkyl) polynitro-alkyl amines and their preparation |
| US4139403A (en) * | 1977-08-19 | 1979-02-13 | The United States Of America As Represented By The Secretary Of The Navy | Dinitroalkyl and fluorodinitroalkyl silicon compounds |
-
1978
- 1978-04-05 DD DD78204587A patent/DD145022A3/de not_active IP Right Cessation
-
1979
- 1979-03-02 DE DE19792908204 patent/DE2908204A1/de not_active Withdrawn
- 1979-03-07 SU SU797770487A patent/SU1013454A1/ru active
- 1979-03-12 CS CS791668A patent/CS248253B1/cs unknown
- 1979-03-23 GB GB7910303A patent/GB2018799B/en not_active Expired
- 1979-03-30 BE BE0/194332A patent/BE875230A/xx unknown
- 1979-04-04 FR FR7908520A patent/FR2421934A1/fr not_active Withdrawn
- 1979-04-05 JP JP4152579A patent/JPS54148022A/ja active Pending
-
1982
- 1982-02-26 US US06/352,830 patent/US4403099A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| SU1013454A1 (ru) | 1983-04-23 |
| FR2421934A1 (fr) | 1979-11-02 |
| JPS54148022A (en) | 1979-11-19 |
| US4403099A (en) | 1983-09-06 |
| GB2018799B (en) | 1982-07-07 |
| BE875230A (fr) | 1979-07-16 |
| DD145022A3 (de) | 1980-11-19 |
| GB2018799A (en) | 1979-10-24 |
| DE2908204A1 (de) | 1979-10-18 |
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