CS200190B2 - Method for processing fluorine containing waste sludges from polishing lead glass by acid to lead hydroxide carbonate - Google Patents
Method for processing fluorine containing waste sludges from polishing lead glass by acid to lead hydroxide carbonate Download PDFInfo
- Publication number
- CS200190B2 CS200190B2 CS764357A CS435776A CS200190B2 CS 200190 B2 CS200190 B2 CS 200190B2 CS 764357 A CS764357 A CS 764357A CS 435776 A CS435776 A CS 435776A CS 200190 B2 CS200190 B2 CS 200190B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- carbonate
- lead
- acid
- alkali metal
- filtered
- Prior art date
Links
- 239000002253 acid Substances 0.000 title claims abstract description 29
- 238000005498 polishing Methods 0.000 title claims abstract description 24
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims description 25
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims description 8
- 229910052731 fluorine Inorganic materials 0.000 title claims description 8
- 239000011737 fluorine Substances 0.000 title claims description 8
- 239000005355 lead glass Substances 0.000 title abstract description 16
- 239000002699 waste material Substances 0.000 title description 2
- 229910000004 White lead Inorganic materials 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- -1 alkali metal hexafluorosilicate Chemical class 0.000 claims abstract description 15
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims abstract description 11
- 150000008041 alkali metal carbonates Chemical class 0.000 claims abstract description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 8
- 229910001413 alkali metal ion Inorganic materials 0.000 claims abstract description 7
- 239000002244 precipitate Substances 0.000 claims abstract description 7
- 239000010802 sludge Substances 0.000 claims description 38
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 15
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 14
- 229910017604 nitric acid Inorganic materials 0.000 claims description 14
- 239000000047 product Substances 0.000 claims description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 8
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 claims description 7
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- 150000002222 fluorine compounds Chemical class 0.000 claims description 5
- 239000007790 solid phase Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 229910000464 lead oxide Inorganic materials 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- 238000005530 etching Methods 0.000 abstract description 5
- 238000001914 filtration Methods 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 description 10
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000011521 glass Substances 0.000 description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 5
- 229910000003 Lead carbonate Inorganic materials 0.000 description 5
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- 241001676573 Minium Species 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Inorganic materials [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910004883 Na2SiF6 Inorganic materials 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000001175 calcium sulphate Substances 0.000 description 2
- 235000011132 calcium sulphate Nutrition 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 150000004761 hexafluorosilicates Chemical class 0.000 description 2
- 229940046892 lead acetate Drugs 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- JTDPJYXDDYUJBS-UHFFFAOYSA-N quinoline-2-carbohydrazide Chemical compound C1=CC=CC2=NC(C(=O)NN)=CC=C21 JTDPJYXDDYUJBS-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010891 toxic waste Substances 0.000 description 2
- 229910020440 K2SiF6 Inorganic materials 0.000 description 1
- 229910020261 KBF4 Inorganic materials 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910020489 SiO3 Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 1
- 229910052924 anglesite Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- XMYLSWOTJKUSHE-UHFFFAOYSA-N cyanamide;lead Chemical compound [Pb].NC#N XMYLSWOTJKUSHE-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002611 lead compounds Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/08—Compounds containing halogen
- C01B33/10—Compounds containing silicon, fluorine, and other elements
- C01B33/103—Fluosilicic acid; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G21/00—Compounds of lead
- C01G21/14—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Surface Treatment Of Glass (AREA)
- Processing Of Solid Wastes (AREA)
- Treatment Of Sludge (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19752529545 DE2529545C2 (de) | 1975-07-02 | Verfahren zum Aufarbeiten des beim Säurepolieren von Bleiglas anfallenden, fluorhältigen Schlammes zu basischem Bleicarbonat |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS200190B2 true CS200190B2 (en) | 1980-08-29 |
Family
ID=5950514
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS764357A CS200190B2 (en) | 1975-07-02 | 1976-07-01 | Method for processing fluorine containing waste sludges from polishing lead glass by acid to lead hydroxide carbonate |
Country Status (10)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ301117B6 (cs) * | 2006-07-20 | 2009-11-11 | Výzkumný ústav anorganické chemie, a. s. | Zpusob zpracování leštírenských kalu z výroby olovnatých krištálových skel |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US641751A (en) * | 1896-05-21 | 1900-01-23 | Foreign Chemical And Electrolytic Syndicate Ltd | Process of producing basic lead carbonate. |
| FR341241A (fr) * | 1904-03-14 | 1904-08-02 | Walter Mills | Perfectionnements dans la préparation des sels de plomb |
| US2114600A (en) * | 1933-12-23 | 1938-04-19 | Kunstdunger Patent Verwertungs | Manufacture of dicalcium phosphate and alkali salts |
| GB1359460A (en) * | 1971-12-21 | 1974-07-10 | Imi Refiners Ltd | Preparation of aqueous inorganic solutions the assembly to be run deflated |
-
1976
- 1976-04-01 AT AT235376A patent/AT340879B/de active
- 1976-05-05 IT IT68098/76A patent/IT1062188B/it active
- 1976-05-12 FR FR7614228A patent/FR2316193A1/fr active Granted
- 1976-05-14 US US05/686,599 patent/US4041127A/en not_active Expired - Lifetime
- 1976-06-04 SE SE7606373A patent/SE405110B/xx not_active IP Right Cessation
- 1976-06-04 GB GB23229/76A patent/GB1513515A/en not_active Expired
- 1976-06-21 FI FI761798A patent/FI58476C/fi not_active IP Right Cessation
- 1976-07-01 CS CS764357A patent/CS200190B2/cs unknown
- 1976-07-02 JP JP51077976A patent/JPS5235798A/ja active Granted
- 1976-07-02 BE BE2055160A patent/BE843707A/xx not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ301117B6 (cs) * | 2006-07-20 | 2009-11-11 | Výzkumný ústav anorganické chemie, a. s. | Zpusob zpracování leštírenských kalu z výroby olovnatých krištálových skel |
Also Published As
| Publication number | Publication date |
|---|---|
| SE405110B (sv) | 1978-11-20 |
| ATA235376A (de) | 1977-05-15 |
| AT340879B (de) | 1978-01-10 |
| FR2316193A1 (fr) | 1977-01-28 |
| FI761798A7 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1977-01-03 |
| JPS5235798A (en) | 1977-03-18 |
| SE7606373L (sv) | 1977-01-03 |
| GB1513515A (en) | 1978-06-07 |
| IT1062188B (it) | 1983-07-28 |
| FI58476B (fi) | 1980-10-31 |
| BE843707A (fr) | 1976-11-03 |
| JPS5415879B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1979-06-18 |
| FI58476C (fi) | 1981-02-10 |
| DE2529545B1 (de) | 1976-04-29 |
| FR2316193B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1979-04-06 |
| US4041127A (en) | 1977-08-09 |
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