CS197191A3 - Process of simultaneous production of methane and carbon monoxide from a treated gas composed mainly of methane, carbon monoxide and hydrogen and apparatus for making same - Google Patents

Process of simultaneous production of methane and carbon monoxide from a treated gas composed mainly of methane, carbon monoxide and hydrogen and apparatus for making same Download PDF

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Publication number
CS197191A3
CS197191A3 CS911971A CS197191A CS197191A3 CS 197191 A3 CS197191 A3 CS 197191A3 CS 911971 A CS911971 A CS 911971A CS 197191 A CS197191 A CS 197191A CS 197191 A3 CS197191 A3 CS 197191A3
Authority
CS
Czechoslovakia
Prior art keywords
methane
column
carbon monoxide
hydrogen
liquid
Prior art date
Application number
CS911971A
Other languages
Czech (cs)
English (en)
Inventor
Jean Ing Billy
Original Assignee
Air Liquide
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide filed Critical Air Liquide
Publication of CS197191A3 publication Critical patent/CS197191A3/cs

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0261Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/506Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification at low temperatures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0223H2/CO mixtures, i.e. synthesis gas; Water gas or shifted synthesis gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0252Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/046Purification by cryogenic separation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/047Composition of the impurity the impurity being carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/048Composition of the impurity the impurity being an organic compound
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/70Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/74Refluxing the column with at least a part of the partially condensed overhead gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/02Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F25J2205/04Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/30Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00Processes characterised by the type or other details of the product stream
    • F25J2215/60Methane
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/02Internal refrigeration with liquid vaporising loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/12External refrigeration with liquid vaporising loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/24Quasi-closed internal or closed external carbon monoxide refrigeration cycle
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S62/00Refrigeration
    • Y10S62/92Carbon monoxide

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Gas Separation By Absorption (AREA)
  • Hydrogen, Water And Hydrids (AREA)
CS911971A 1990-07-04 1991-06-27 Process of simultaneous production of methane and carbon monoxide from a treated gas composed mainly of methane, carbon monoxide and hydrogen and apparatus for making same CS197191A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9008464A FR2664263B1 (fr) 1990-07-04 1990-07-04 Procede et installation de production simultanee de methane et monoxyde de carbone.

Publications (1)

Publication Number Publication Date
CS197191A3 true CS197191A3 (en) 1992-02-19

Family

ID=9398338

Family Applications (1)

Application Number Title Priority Date Filing Date
CS911971A CS197191A3 (en) 1990-07-04 1991-06-27 Process of simultaneous production of methane and carbon monoxide from a treated gas composed mainly of methane, carbon monoxide and hydrogen and apparatus for making same

Country Status (10)

Country Link
US (1) US5133793A (pt)
EP (1) EP0465366B1 (pt)
JP (1) JP3169634B2 (pt)
AT (1) ATE101258T1 (pt)
CA (1) CA2045763C (pt)
CS (1) CS197191A3 (pt)
DE (1) DE69101126T2 (pt)
ES (1) ES2048571T3 (pt)
FR (1) FR2664263B1 (pt)
PT (1) PT98200B (pt)

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DE4210637A1 (de) * 1992-03-31 1993-10-07 Linde Ag Verfahren zur Gewinnung von hochreinem Wasserstoff und hochreinem Kohlenmonoxid
FR2718428B1 (fr) * 1994-04-11 1997-10-10 Air Liquide Procédé et installation de production de monoxyde de carbone.
FR2718725B1 (fr) * 1994-04-13 1996-05-24 Air Liquide Procédé et installation de séparation d'un mélange gazeux.
DE4433114A1 (de) * 1994-09-16 1996-03-21 Linde Ag Verfahren zum Gewinnen einer Kohlenmonoxid-Reinfraktion
GB9715983D0 (en) * 1997-07-29 1997-10-01 Air Prod & Chem Process and apparatus for seperating a gaseous mixture
FR2772896B1 (fr) * 1997-12-22 2000-01-28 Inst Francais Du Petrole Procede de liquefaction d'un gaz notamment un gaz naturel ou air comportant une purge a moyenne pression et son application
GB9807797D0 (en) * 1998-04-09 1998-06-10 Air Prod & Chem Separation of carbon monoxide from gaseous mixtures containing carbon monoxide and hydrogen
GB9918420D0 (en) 1999-08-04 1999-10-06 Air Prod & Chem Process and apparatus for separating mixtures of hydrogen and carbon monoxide
US6192706B1 (en) 1999-10-05 2001-02-27 Praxair Technology, Inc. Cryogenic system for producing carbon monoxide
US6266976B1 (en) 2000-06-26 2001-07-31 Air Products And Chemicals, Inc. Cryogenic H2 and carbon monoxide production with an impure carbon monoxide expander
US6726747B2 (en) * 2001-03-21 2004-04-27 American Air Liquide Methods and apparatuses for treatment of syngas and related gases
US6578377B1 (en) * 2002-03-11 2003-06-17 Air Products And Chemicals, Inc. Recovery of hydrogen and carbon monoxide from mixtures including methane and hydrocarbons heavier than methane
DE102007013325A1 (de) * 2007-03-20 2008-09-25 Linde Ag Verfahren und Vorrichtung zur Gewinnung von Gasprodukten und flüssigem Methan aus Synthesegas
FR2915791B1 (fr) * 2007-05-04 2009-08-21 Air Liquide Procede et appareil de separation d'un melange d'hydrogene, de methane et de monoxyde de carbonne par distillation cryogenique
FR2916523B1 (fr) * 2007-05-21 2014-12-12 Air Liquide Capacite de stockage, appareil et procede de production de monoxyde de carbone et/ou d'hydrogene par separation cryogenique integrant une telle capacite.
US8640495B2 (en) 2009-03-03 2014-02-04 Ait Products and Chemicals, Inc. Separation of carbon monoxide from gaseous mixtures containing carbon monoxide
US20100251765A1 (en) 2009-04-01 2010-10-07 Air Products And Chemicals, Inc. Cryogenic Separation of Synthesis Gas
FR2953004B1 (fr) * 2009-11-24 2013-12-20 Air Liquide Procede de separation cryogenique d'un melange d'azote et de monoxyde de carbone
US8845790B2 (en) * 2011-01-06 2014-09-30 Alstom Technology Ltd Method and system for removal of gaseous contaminants
US9376584B2 (en) 2013-09-20 2016-06-28 Xerox Corporation Coating for aqueous inkjet transfer
US9273218B2 (en) 2013-09-20 2016-03-01 Xerox Corporation Coating for aqueous inkjet transfer
FR3011320A1 (fr) * 2013-10-02 2015-04-03 Air Liquide Procede et appareil de separation par distillation cryogenique d'un melange compose d'hydrogene, de monoxyde de carbone et de methane
US10436505B2 (en) * 2014-02-17 2019-10-08 Black & Veatch Holding Company LNG recovery from syngas using a mixed refrigerant
FR3018599B1 (fr) 2014-03-17 2019-06-28 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procede et appareil de separation cryogenique d’un gaz de synthese contenant du monoxyde de carbone, du methane et de l’hydrogene
US10443930B2 (en) 2014-06-30 2019-10-15 Black & Veatch Holding Company Process and system for removing nitrogen from LNG
US9604471B2 (en) 2015-07-06 2017-03-28 Xerox Corporation System and method for operating an aqueous inkjet printer to coat media prior to printing images on the media with the aqueous inkjet printer
US9688079B2 (en) 2015-07-06 2017-06-27 Xerox Corporation System and method for image receiving surface treatment in an indirect inkjet printer
FR3052159B1 (fr) 2016-06-06 2018-05-18 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procede et installation pour la production combinee d'un melange d'hydrogene et d'azote ainsi que de monoxyde de carbone par distillation et lavage cryogeniques
SG11202008918SA (en) 2018-03-21 2020-10-29 Air Liquide Method and appliance for separating a synthesis gas by cryogenic distillation
FR3100057A1 (fr) * 2019-08-20 2021-02-26 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Procede et appareil de production de monoxyde de carbone par condensation partielle

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Also Published As

Publication number Publication date
FR2664263A1 (fr) 1992-01-10
ES2048571T3 (es) 1994-03-16
PT98200B (pt) 1998-12-31
CA2045763C (fr) 2000-05-30
EP0465366B1 (fr) 1994-02-02
CA2045763A1 (fr) 1992-01-05
US5133793A (en) 1992-07-28
FR2664263B1 (fr) 1992-09-18
DE69101126T2 (de) 1994-05-11
ATE101258T1 (de) 1994-02-15
JPH05346287A (ja) 1993-12-27
EP0465366A1 (fr) 1992-01-08
JP3169634B2 (ja) 2001-05-28
DE69101126D1 (de) 1994-03-17
PT98200A (pt) 1992-05-29

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