CS195379B1 - Process for preparing polyolefinic waxes conaining oxygen - Google Patents
Process for preparing polyolefinic waxes conaining oxygen Download PDFInfo
- Publication number
- CS195379B1 CS195379B1 CS623773A CS623773A CS195379B1 CS 195379 B1 CS195379 B1 CS 195379B1 CS 623773 A CS623773 A CS 623773A CS 623773 A CS623773 A CS 623773A CS 195379 B1 CS195379 B1 CS 195379B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- oxidation
- oxygen
- weight
- melt
- polyolefin
- Prior art date
Links
- 239000001993 wax Substances 0.000 title claims abstract description 43
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 15
- 239000001301 oxygen Substances 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 36
- 230000003647 oxidation Effects 0.000 claims abstract description 35
- 229920000098 polyolefin Polymers 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 21
- 150000003839 salts Chemical class 0.000 claims abstract description 16
- 239000002253 acid Substances 0.000 claims abstract description 12
- 239000000155 melt Substances 0.000 claims abstract description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 150000001735 carboxylic acids Chemical class 0.000 claims abstract description 5
- 150000002148 esters Chemical class 0.000 claims abstract description 4
- 125000005474 octanoate group Chemical group 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 3
- 239000007789 gas Substances 0.000 claims abstract description 3
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910001385 heavy metal Inorganic materials 0.000 claims description 7
- 230000000737 periodic effect Effects 0.000 claims description 6
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 4
- SZINCDDYCOIOJQ-UHFFFAOYSA-L manganese(2+);octadecanoate Chemical compound [Mn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O SZINCDDYCOIOJQ-UHFFFAOYSA-L 0.000 claims description 3
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- -1 polyethylene Polymers 0.000 abstract description 19
- 239000004698 Polyethylene Substances 0.000 abstract description 14
- 229920000573 polyethylene Polymers 0.000 abstract description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 8
- 239000005977 Ethylene Substances 0.000 abstract description 8
- 239000004743 Polypropylene Substances 0.000 abstract description 4
- 229920001155 polypropylene Polymers 0.000 abstract description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract description 3
- 230000001590 oxidative effect Effects 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 229920001577 copolymer Polymers 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- QMTFKWDCWOTPGJ-KVVVOXFISA-N (z)-octadec-9-enoic acid;tin Chemical compound [Sn].CCCCCCCC\C=C/CCCCCCCC(O)=O QMTFKWDCWOTPGJ-KVVVOXFISA-N 0.000 abstract 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 abstract 1
- AMFIJXSMYBKJQV-UHFFFAOYSA-L cobalt(2+);octadecanoate Chemical class [Co+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AMFIJXSMYBKJQV-UHFFFAOYSA-L 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 10
- 230000035515 penetration Effects 0.000 description 7
- 230000035484 reaction time Effects 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- 241000556720 Manga Species 0.000 description 1
- 229920000057 Mannan Polymers 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UKRVECBFDMVBPU-UHFFFAOYSA-N ethyl 3-oxoheptanoate Chemical compound CCCCC(=O)CC(=O)OCC UKRVECBFDMVBPU-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- VQPKAMAVKYTPLB-UHFFFAOYSA-N lead;octanoic acid Chemical compound [Pb].CCCCCCCC(O)=O VQPKAMAVKYTPLB-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- CYCFYXLDTSNTGP-UHFFFAOYSA-L octadecanoate;tin(2+) Chemical compound [Sn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CYCFYXLDTSNTGP-UHFFFAOYSA-L 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 210000001562 sternum Anatomy 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/06—Oxidation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Lubricants (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD16554872A DD102712A1 (enrdf_load_stackoverflow) | 1972-09-08 | 1972-09-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS195379B1 true CS195379B1 (en) | 1980-01-31 |
Family
ID=5488134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS623773A CS195379B1 (en) | 1972-09-08 | 1973-09-07 | Process for preparing polyolefinic waxes conaining oxygen |
Country Status (9)
| Country | Link |
|---|---|
| BE (1) | BE804113A (enrdf_load_stackoverflow) |
| BG (2) | BG21095A1 (enrdf_load_stackoverflow) |
| CS (1) | CS195379B1 (enrdf_load_stackoverflow) |
| DD (1) | DD102712A1 (enrdf_load_stackoverflow) |
| DE (1) | DE2334868A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2198964B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1429012A (enrdf_load_stackoverflow) |
| HU (1) | HU166883B (enrdf_load_stackoverflow) |
| SU (1) | SU540875A1 (enrdf_load_stackoverflow) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4981605A (en) * | 1987-06-08 | 1991-01-01 | Mitsui Petrochemical Industries, Ltd. | Liquid modified ethylenic random copolymer and its uses |
| JPH02245069A (ja) * | 1989-03-17 | 1990-09-28 | Nippon Oil Co Ltd | 塗膜保護用水性組成物 |
-
1972
- 1972-09-08 DD DD16554872A patent/DD102712A1/xx unknown
-
1973
- 1973-05-21 FR FR7318357A patent/FR2198964B1/fr not_active Expired
- 1973-07-09 DE DE19732334868 patent/DE2334868A1/de active Pending
- 1973-08-09 HU HULE000718 patent/HU166883B/hu unknown
- 1973-08-24 GB GB4031873A patent/GB1429012A/en not_active Expired
- 1973-08-24 BG BG2725673A patent/BG21095A1/xx unknown
- 1973-08-24 BG BG2437573A patent/BG21936A1/xx unknown
- 1973-08-28 BE BE135019A patent/BE804113A/xx unknown
- 1973-09-07 SU SU1961014A patent/SU540875A1/ru active
- 1973-09-07 CS CS623773A patent/CS195379B1/cs unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HU166883B (enrdf_load_stackoverflow) | 1975-06-28 |
| DE2334868A1 (de) | 1974-03-14 |
| BG21936A1 (enrdf_load_stackoverflow) | 1976-11-25 |
| GB1429012A (en) | 1976-03-24 |
| DD102712A1 (enrdf_load_stackoverflow) | 1973-12-20 |
| SU540875A1 (ru) | 1976-12-30 |
| BG21095A1 (enrdf_load_stackoverflow) | 1976-03-20 |
| FR2198964A1 (enrdf_load_stackoverflow) | 1974-04-05 |
| FR2198964B1 (enrdf_load_stackoverflow) | 1976-03-05 |
| BE804113A (fr) | 1973-12-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3756999A (en) | Sprocess for the preparation of oxidation products of ethylene polymer | |
| US4060569A (en) | Hydrocarbon polymers | |
| US6211303B1 (en) | Process for the oxidation of polyethylene waxes | |
| DE1720566C3 (de) | Verfahren zur Herstellung von emulgierbaren Poly-α-olefinen | |
| JP5542803B2 (ja) | 溶媒をベースとするコーティングのためのシリコーンを含まない消泡剤 | |
| US3060163A (en) | Process for the oxidation of high molecular weight aliphatic waxes and product | |
| US2443735A (en) | Emulsion copolymerization of unsaturated alkyd resins | |
| US3577365A (en) | Novel blends of chlorinated carboxyl group containing polymers and ethylene-vinyl acetate copolymers | |
| US4239546A (en) | Hydrocarbon polymers to improve the hardness of waxes | |
| CA2156437C (en) | Ethylene-vinyl acetate emulsions with and improved balance of adhesive properties | |
| US3278513A (en) | Production of emulsifiable waxes | |
| US3547847A (en) | Aqueous emulsion copolymers of vinyl alkanoates,alkyl acrylates,drying oil and another unsaturated compound | |
| EP3470440B1 (en) | Oxidized polyethylene wax | |
| US2928816A (en) | Process for increasing the emulsifiability of a polyethylene/isopropanol telomer wax | |
| CS195379B1 (en) | Process for preparing polyolefinic waxes conaining oxygen | |
| EP0734399A1 (en) | Process for the maleation of polyethylene waxes | |
| KR20010024086A (ko) | 에틸렌과 비닐 카르복실레이트의 공중합 방법 | |
| US3519609A (en) | Method for making polyolefin waxes by thermal degradation of higher molecular weight polyolefins in the presence of organic acids and anhydrides | |
| US9315694B2 (en) | Vinyl acetate/vinyl 3,5,5-trimethylhexanoate copolymer binder resins | |
| US3258438A (en) | Addition polymer compositions and methods of producing them | |
| JPS6128685B2 (enrdf_load_stackoverflow) | ||
| CN104017137B (zh) | 一种涂料高效胶黏剂及其应用方法 | |
| JP2935517B2 (ja) | エチレンとアルケンカルボン酸またはアルケンカルボン酸誘導体またはその混合物とからの共重合体 | |
| EP0028384A1 (de) | Oxidationsprodukte von Äthylen-Copolymerisaten und deren Verwendung | |
| JP4234582B2 (ja) | α−オレフィンダイマー−無水カルボン酸共重合体及びその製造方法 |