CO6781471A2 - Producto de combustible multietapas de circuito sencillo - Google Patents

Producto de combustible multietapas de circuito sencillo

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Publication number
CO6781471A2
CO6781471A2 CO13121018A CO13121018A CO6781471A2 CO 6781471 A2 CO6781471 A2 CO 6781471A2 CO 13121018 A CO13121018 A CO 13121018A CO 13121018 A CO13121018 A CO 13121018A CO 6781471 A2 CO6781471 A2 CO 6781471A2
Authority
CO
Colombia
Prior art keywords
stage
stream
gas
synthesis gas
fuel
Prior art date
Application number
CO13121018A
Other languages
English (en)
Inventor
Howard L Fang
Moshe Ben-Reuven
Richard E Boyle
Robert M Koros
Original Assignee
Primus Green Energy Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Primus Green Energy Inc filed Critical Primus Green Energy Inc
Publication of CO6781471A2 publication Critical patent/CO6781471A2/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0405—Apparatus
    • C07C1/041—Reactors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
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    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
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    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
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    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
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    • C10L3/08—Production of synthetic natural gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • C10G2300/304—Pour point, cloud point, cold flow properties
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    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Los combustibles sintéticos son producidos de gas de síntesis en un sistema reactor de cuatro etapas con un circuito de reciclaje sencillo proporcionando el requisito de la capacidad térmica para moderarla liberación alta de calor de las reacciones, y para proporcionar los reactivos y entornos de reacción para la operación eficiente del proceso. La primera etapa convierte una porción de gas de síntesis a metanol, la segunda etapa convierte el metanolaéter dimetílico, la tercera etapa convierte el metanol y éter dimetílico a combustible y la cuarta etapa convierte el componente de punto de fusión alto, dureno, y otros componentes aromáticos de volatilidad baja tal comotri- y tetra-metilbencenos hacia parafinas ramificadas de alto octano. El catalizador de cuatro etapas usado para hidrotratamiento es resistente a envenenamiento por CO. Las reacciones i producen agua como un producto secundario que es transportadora través de un separador de alta presión después de la cuarta etapa. Las corrientes del separador son una corriente de combustible líquido, una corriente de aguay una corriente de gas que contiene gases de hidrocarburos ligeros y el gas de síntesis no reaccionado. La parte más grande de esta corriente de gas se recicla a la entrada de la primera etapa y se mezcla con la corriente fresca de gas de síntesis. Alternativamente, la corriente fresca de gas sintético se mezcla con el producto de la segunda etapa. La parte más pequeña de la corriente de gas del separador se envía a recuperación de hidrocarburos y al gas combustible usado para proporcionar precalentamiento devanas corrientes. El combustible líquido se envía para mezclar en los productos combustibles, tal como gasolina, combustible para aviones, o diésel, y la corriente de agua puede ser enviada, por ejemplo, a la planta productora de gas de síntesis para generación de vapor.
CO13121018A 2010-11-09 2013-05-16 Producto de combustible multietapas de circuito sencillo CO6781471A2 (es)

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Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2013269955B2 (en) * 2012-05-29 2017-12-07 Haldor Topsoe A/S Process and catalyst for upgrading gasoline
US8569554B1 (en) * 2012-07-12 2013-10-29 Primus Green Energy Inc Fuel composition
RU2544241C1 (ru) * 2014-01-22 2015-03-20 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения ароматических углеводородов из природного газа и установка для его осуществления
CN103849421B (zh) * 2014-03-06 2015-09-09 山西潞安矿业(集团)有限责任公司 合成气制汽油一体化工艺及反应器
US9670416B2 (en) 2014-12-10 2017-06-06 Primus Green Energy Inc. Configuration in single-loop synfuel generation
WO2016105928A1 (en) * 2014-12-22 2016-06-30 Exxonmobil Research And Engineering Company Conversion of organic oxygenates to hydrocarbons
CN115851302A (zh) * 2015-06-12 2023-03-28 绿色物质有限公司 用于通过转化为烃类燃料来减少在醇燃料生产中资源消耗的系统和方法
CN105038838A (zh) * 2015-07-24 2015-11-11 麦森能源科技有限公司 甲醇制汽油的反应系统及甲醇制汽油的方法
WO2017027491A1 (en) * 2015-08-10 2017-02-16 Primus Green Energy Inc. Multi-stage reactor and system for making methanol in a once-through process and methods therefor
CN108138063B (zh) * 2015-10-26 2020-08-11 国际壳牌研究有限公司 包含甲烷和示踪剂的流体和制造其的方法以及其用途
US10450512B2 (en) * 2016-02-10 2019-10-22 Primus Green Energy Inc. Single-loop octane enrichment
JP2020500258A (ja) * 2016-08-29 2020-01-09 ダイオキサイド マテリアルズ，インコーポレイティド 再生可能燃料および化学品を製造するための装置および方法
US11603340B2 (en) * 2019-09-17 2023-03-14 ExxonMobil Technology and Engineering Company Methods for methanol-to-gasoline conversion with post-processing of heavy gasoline hydrocarbons
US12049597B2 (en) 2019-11-15 2024-07-30 Alliance For Sustainable Energy, Llc High octane synthetic fuels
KR20220148517A (ko) 2021-04-29 2022-11-07 현대자동차주식회사 디메틸에테르의 가솔린화 반응용 촉매, 이의 제조 방법, 및 이를 이용한 가솔린의 제조 방법
US20240336713A1 (en) * 2023-04-06 2024-10-10 Battelle Memorial Institute Co-oligomerization method embodiments for producing jet-range olefins suitable for making jet fuel

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4076761A (en) 1973-08-09 1978-02-28 Mobil Oil Corporation Process for the manufacture of gasoline
US3894102A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Conversion of synthesis gas to gasoline
US4011275A (en) 1974-08-23 1977-03-08 Mobil Oil Corporation Conversion of modified synthesis gas to oxygenated organic chemicals
US3928483A (en) * 1974-09-23 1975-12-23 Mobil Oil Corp Production of gasoline hydrocarbons
US3931349A (en) 1974-09-23 1976-01-06 Mobil Oil Corporation Conversion of methanol to gasoline components
US4304951A (en) 1981-01-14 1981-12-08 Mobil Oil Corporation Hydrotreating of bottoms fractions resulting from conversion of methanol to gasoline in order to decrease durene and produce distillate
US4347397A (en) 1981-04-27 1982-08-31 Mobil Oil Corporation Treatment of effluent resulting from conversion of methanol to gasoline in order to decrease durene and produce distillate
US4387261A (en) 1982-04-09 1983-06-07 Mobil Oil Corporation Treatment of effluent resulting from conversion of methanol to gasoline in order to decrease durene and produce distillate
DK147705C (da) 1982-09-07 1985-05-13 Haldor Topsoe As Fremgangsmaade til fremstilling af carbonhydrider ud fra syntesegas
DK149529C (da) * 1983-05-11 1986-12-22 Haldor Topsoe As Fremgangsmaade til fremstilling af syntetiske carbonhydrider ud fra syntesegas
US4482772A (en) 1983-11-03 1984-11-13 Mobil Oil Corporation Multistage process for converting oxygenates to hydrocarbons
US4898717A (en) * 1984-01-04 1990-02-06 Mobil Oil Corp. Multistage process for converting oxygenates to distillate hydrocarbons with interstage ethene recovery
US4973784A (en) * 1988-10-06 1990-11-27 Mobil Oil Corp. Process for reducing the durene content of effluent resulting from the catalytic conversion of C1 -C4 oxygenates to gasoline
US5321183A (en) * 1992-03-12 1994-06-14 Mobil Oil Corp. Process for the regioselective conversion of aromatics to para-disubstituted benzenes
US6444712B1 (en) * 2000-09-28 2002-09-03 Exxonmobil Chemical Patents, Inc. Methanol, olefin, and hydrocarbon synthesis process
GB0320684D0 (en) * 2003-09-03 2003-10-01 Bp Chem Int Ltd Process
US7988848B2 (en) * 2005-04-15 2011-08-02 Exxonmobil Research And Engineering Company Activating hydroprocessing catalysts using carbon monoxide and use of catalysts for hydroprocessing
AU2006281556B2 (en) 2005-08-18 2010-07-29 Haldor Topsoe A/S Process for converting difficultly convertible oxygenates to gasoline
US9255227B2 (en) 2006-12-13 2016-02-09 Haldor Topsoe A/S Process for the synthesis of hydrocarbon constituents of gasoline
CN101519336B (zh) * 2008-02-29 2012-11-14 杭州林达化工技术工程有限公司 合成气制烃类的方法和设备
US7919660B2 (en) 2007-12-21 2011-04-05 Uop Llc Methods of converting methanol feedstock to olefins
EP2233460A1 (en) 2009-03-23 2010-09-29 Haldor Topsøe A/S Process for the preparation of hydrocarbons from oxygenates

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US20140199213A1 (en) 2014-07-17
EP2638128A4 (en) 2016-08-24
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BR112013011571A2 (pt) 2016-08-09
US9169166B2 (en) 2015-10-27
CN103270139A (zh) 2013-08-28
IL225986A0 (en) 2013-06-27
ZA201303045B (en) 2014-07-30
US20120116137A1 (en) 2012-05-10
AU2011326572B2 (en) 2016-02-25
EP2638128A2 (en) 2013-09-18
WO2012064844A3 (en) 2012-08-16
KR101899124B1 (ko) 2018-09-17
CA2816141A1 (en) 2012-05-18
AU2011326572A1 (en) 2013-05-23
CN103270139B (zh) 2015-11-25
WO2012064844A2 (en) 2012-05-18
AP2013006910A0 (en) 2013-06-30
MX2013005223A (es) 2013-09-26
NZ609789A (en) 2014-12-24
AP3697A (en) 2016-05-31
US8686206B2 (en) 2014-04-01
CA2816141C (en) 2018-12-11
RU2013124424A (ru) 2014-12-20

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