CN86102788A - The fireworks composition of safe blue pyrotechnics - Google Patents
The fireworks composition of safe blue pyrotechnics Download PDFInfo
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- CN86102788A CN86102788A CN 86102788 CN86102788A CN86102788A CN 86102788 A CN86102788 A CN 86102788A CN 86102788 CN86102788 CN 86102788 CN 86102788 A CN86102788 A CN 86102788A CN 86102788 A CN86102788 A CN 86102788A
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- CN
- China
- Prior art keywords
- pyrotechnics
- fireworks
- fireworks composition
- blue
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 31
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims abstract description 11
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims abstract description 11
- 239000010949 copper Substances 0.000 claims description 14
- 229920003987 resole Polymers 0.000 claims description 6
- 239000004801 Chlorinated PVC Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000011324 bead Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 7
- 239000005864 Sulphur Substances 0.000 abstract description 7
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- -1 copper ion compound Chemical class 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 229910001431 copper ion Inorganic materials 0.000 abstract description 2
- 239000003446 ligand Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 description 7
- 238000009423 ventilation Methods 0.000 description 6
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 5
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 4
- 239000003814 drug Substances 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- PDZKZMQQDCHTNF-UHFFFAOYSA-M copper(1+);thiocyanate Chemical compound [Cu+].[S-]C#N PDZKZMQQDCHTNF-UHFFFAOYSA-M 0.000 description 2
- 229960003280 cupric chloride Drugs 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- XQJMXPAEFMWDOZ-UHFFFAOYSA-N 3exo-benzoyloxy-tropane Natural products CN1C(C2)CCC1CC2OC(=O)C1=CC=CC=C1 XQJMXPAEFMWDOZ-UHFFFAOYSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 101100175487 Glycine max CG-1 gene Proteins 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- QQXLDOJGLXJCSE-UHFFFAOYSA-N N-methylnortropinone Natural products C1C(=O)CC2CCC1N2C QQXLDOJGLXJCSE-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- QIZDQFOVGFDBKW-DHBOJHSNSA-N Pseudotropine Natural products OC1C[C@@H]2[N+](C)[C@H](C1)CC2 QIZDQFOVGFDBKW-DHBOJHSNSA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 241000030614 Urania Species 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000035572 chemosensitivity Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- CYHOMWAPJJPNMW-JIGDXULJSA-N tropine Chemical compound C1[C@@H](O)C[C@H]2CC[C@@H]1N2C CYHOMWAPJJPNMW-JIGDXULJSA-N 0.000 description 1
- FCTBKIHDJGHPPO-UHFFFAOYSA-N uranium dioxide Inorganic materials O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Abstract
The present invention relates to the fireworks composition of colored pyrotechnics.It adopts organism is the copper ion compound of ligand, and chlorinated benzene dioctyl phthalate copper is oxygenant as the luminous agent of blue firework with potassium perchlorate, adds toner, and save the high sulphur of susceptibility in fireworks composition.Bright-colored with the blue firework that safe blue pyrotechnics fireworks composition of the present invention is made, moisture absorption is little, the safety performance height, and the manufacture craft of look pearl is simple, and cost is lower, is applicable to make various firework products.
Description
The present invention relates to the fireworks composition of colored pyrotechnics.
Fireworks are the amusement articles in a kind of red-letter day that generally use in the world, use its color and the sound happy effect that causes people.But the blue streak of pyrotechnics is pyrotechnics circle still fails one of technical problem that thoroughly solves.In the fireworks composition prescription of existing blue look pyrotechnics, often use ammoniumper chlorate, sulphur and ventilation breather (CuCO
3Cu(OH)
2) wait material, as the fireworks composition prescription of ventilation breather blue streak pyrotechnics commonly used be:
Ammoniumper chlorate 30%
Potassium perchlorate 38%
Ventilation breather 12%
Sulphur 5%
Shellac 11%
Dextrin 4%
Because the big moisture absorption of ammoniumper chlorate and the high shortcoming of chemosensitivity of sulphur make the chemical stability of above-mentioned prescription very low in this prescription, easily cause spontaneous combustion, self-destruction; The pyrotechnics product of making is the moisture absorption in a short time, loses blue coloured light coloured silk thereby cause when setting off.
In the fireworks composition of the existing blue look pyrotechnics prescription, also have and adopt cupric chloride to be used as luminous agent, as U.S. Pat 3951705, but must add sulphur and potassium perchlorate in this prescription, set off Shi Caineng and send blue streak, its prescription is:
Potassium perchlorate 6～10%
Magnesium powder 11～18%
Anhydrous cupric chloride 10～20%
Nitrate of baryta 35～45%
Hexachlorobenzene 12～18%
Sulphur 5～10%
Because the spontaneous combustion of this prescription, self-destruction may be very big.Also have and adopt cuprous thiocyanate or urania green as the luminous agent of blue look pyrotechnics, as russian patent SU 394345 (referring to " firework theory ", (U.S.) JHMelaiu work, East China Institute of Engineering three is Room 308,118 pages, December nineteen eighty-two version), its prescription is:
Ammoniumper chlorate 69～74%
Crow lattice tropine 12～16%
Cuprous thiocyanate 10～19%
Pyroxyline lacquer 1～4%
Not only the moisture absorption owing to ammoniumper chlorate is big in this prescription, and can strong dicyanogen or the arsenide of toxigenicity when setting off by the pyrotechnics of this prescription making.
The objective of the invention is to seek a kind of blue look bright in luster, the fireworks composition of the blue look pyrotechnics that security is high again.Because the luminous agent of pyrotechnics nearly all was to adopt inorganic materials, so moisture absorption problem fails to solve in earnest always in the past.It is the copper ion compound of ligand that the present invention adopts organism, and promptly chlorinated benzene dioctyl phthalate copper (abbreviating CPA-Cu as) is used as the luminous agent of blue look pyrotechnics fireworks composition.Because CPA-Cu is nontoxic, chemical stability is high, therefore with CPA-Cu as long And of the storage period of the firework product of blue look luminous agent and can in the prescription of blue look pyrotechnics fireworks composition, save the high sulphur composition of susceptibility, not only can greatly strengthen the security of pyrotechnics, and make pyrotechnics when setting off, alleviate the smell of the nose of choking, make the firework display effect of pyrotechnics more remarkable.
The fireworks composition of the blue look pyrotechnics of safety of the present invention has adopted CPA-Cu as luminous agent, and the potassium perchlorate higher with chemical stability, that the mechanical sensitivity degree is lower adds the vividness that toner strengthens its color as oxygenant ， And in medicament.The fireworks composition of the blue look pyrotechnics of safety of the present invention mainly by: CPA-Cu, potassium perchlorate, polyvinyl chloride (or chlorinated polyvinyl chloride), resol etc. are formed.Its concrete prescription can be:
Potassium perchlorate 60～80%
Polyvinyl chloride 5～10%
Copper powder 0.5～1%
Resol 3～7%
Diatomite 2～3%
CPA-Cu 10～20%
Perhaps its prescription is:
Potassium perchlorate 60～80%
Chlorinated polyvinyl chloride 5～10%
Copper powder 0.5～1%
Resol 3～7%
Diatomite 2～3%
CPA-Cu 10～20%
By above-mentioned be the fireworks composition formula rate of the blue look pyrotechnics of safety of raw material with CPA-Cu, various raw material thorough mixing are evenly crossed 120 order hole sizers in the back, Pen spills and contains the look bead that 95% ethanol bonds and makes pyrotechnics then, or mixes and relevant medicament.This fireworks composition is applicable to various firework products such as making " magic bullet ", " ground firework spraying tube ", " telling pearl ", " display shell ".Other manufacture crafts as for pyrotechnics are made identical with general pyrotechnics.
The physical and chemical performance that now with CPA-Cu is the blue look pyrotechnics of the safety fireworks composition of raw material is listed in down.
1. decomposition temperature
Blue look luminous agent kind decomposition temperature
CPA-Cu 247.15～299.36℃
200 ℃ of ventilation breathers
Instrument: DSC-2C Differential Scanning
Calorimeter
PeRKin Elmev
2. friction sensitivity
Fireworks kind rate of explosion
The blue look pyrotechnics fireworks composition 0 of safety
Ventilation breather pyrotechnics fireworks composition 100
(1) instrument: MGY-1 type friction pendulum tester Xi'an Physical and Chemical Inst. makes 96 ° of pendulum bars, gauge pressure 50kg, dose 30mg.
(2) with 25 long run test statistics.
3. impact sensitivity
Fireworks kind rate of explosion
The blue look pyrotechnics fireworks composition 0 of safety
Ventilation breather pyrotechnics fireworks composition 100
(1) instrument: the CGY-1 type instrument Xi'an Physical and Chemical Inst. of dropping hammer makes
The heavy 5kg of hammer, height 30Cm, dose 30mg
(2) with 25 long run test statistics.
4. water absorbability
Condition: the fireworks composition of the blue look pyrotechnics of safety places 25～30 ℃, the environment of relative humidity 90%.
Time: placed 22 days
Medicament moisture absorption gain in weight: 1.55%
5. chemical stability
The blue look fireworks of safety that the fireworks composition of the blue look pyrotechnics of safety is made are being seted off after 1 year in the empty placement of indoor dew under the common weather condition, and the colourity of its blue coloured light is still constant.
This shows that it is bright-colored to use blue look pyrotechnics that the fireworks composition of the blue look pyrotechnics of safety of the present invention makes, moisture absorption is little, and the manufacture craft of safety performance Gao ， And and look pearl is simple, and cost is lower.But, use the look pearl diameter that reagent combination of the present invention produces generally will be in 1.0～1.5 meters scopes at ， And more than 3 millimeters and its best spraying decoration height.
Claims (5)
1, the fireworks composition of the blue look pyrotechnics of a kind of safety is characterized in that fireworks composition mainly is made up of potassium perchlorate, CPA-Cu, polyvinyl chloride (or chlorinated polyvinyl chloride), resol.
2, fireworks composition according to claim 1 is characterized in that proportioning is:
Potassium perchlorate 60～80%
Polyvinyl chloride 5～10%
Copper powder 0.5～1%
Resol 3～7%
Diatomite 2～3%
CPA-Cu 10～20%
3, fireworks composition according to claim 1 is characterized in that proportioning is:
Potassium perchlorate 60～80%
Chlorinated polyvinyl chloride 5～10%
Copper powder 0.5～1%
Resol 3～7%
Diatomite 2～3%
CPA-Cu 10～20%
4, according to claim 2 and 3 described fireworks compositions, it is characterized in that ratio in prescription, even various raw material thorough mixing, through 120 mesh sieves, Pen spills 95% ethanol and bonds and cause the look bead then.
5,, it is characterized in that being applicable to firework products such as making " magic bullet ", " ground firework spraying tube ", " telling pearl ", " display shell " according to the described fireworks composition of claim 1 to 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN86102788A CN86102788B (en) | 1986-04-16 | 1986-04-16 | Colour firing agent for safe blue fireworks |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN86102788A CN86102788B (en) | 1986-04-16 | 1986-04-16 | Colour firing agent for safe blue fireworks |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN86102788A true CN86102788A (en) | 1987-10-28 |
| CN86102788B CN86102788B (en) | 1988-04-06 |
Family
ID=4801844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN86102788A Expired CN86102788B (en) | 1986-04-16 | 1986-04-16 | Colour firing agent for safe blue fireworks |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN86102788B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105330497A (en) * | 2015-11-19 | 2016-02-17 | 湖南环宇烟花鞭炮有限公司 | Colorful firework and preparation method thereof |
| CN110498724A (en) * | 2019-06-22 | 2019-11-26 | 中国人民解放军69080部队 | Reduce smoke composition, the preparation method and application of initial reaction temperature |
| CN110498723A (en) * | 2019-06-22 | 2019-11-26 | 中国人民解放军69080部队 | Ammonium dihydrogen phosphate new application, the smoke agent and preparation method for adding it |
-
1986
- 1986-04-16 CN CN86102788A patent/CN86102788B/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105330497A (en) * | 2015-11-19 | 2016-02-17 | 湖南环宇烟花鞭炮有限公司 | Colorful firework and preparation method thereof |
| CN110498724A (en) * | 2019-06-22 | 2019-11-26 | 中国人民解放军69080部队 | Reduce smoke composition, the preparation method and application of initial reaction temperature |
| CN110498723A (en) * | 2019-06-22 | 2019-11-26 | 中国人民解放军69080部队 | Ammonium dihydrogen phosphate new application, the smoke agent and preparation method for adding it |
| CN110498723B (en) * | 2019-06-22 | 2021-01-29 | 中国人民解放军69080部队 | New application of ammonium dihydrogen phosphate, smoke agent added with ammonium dihydrogen phosphate and preparation method of smoke agent |
| CN110498724B (en) * | 2019-06-22 | 2021-01-29 | 中国人民解放军69080部队 | Fuming composition capable of reducing initial reaction temperature, preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN86102788B (en) | 1988-04-06 |
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