CN1201811A - Novel architectural decorative coating and production method thereof - Google Patents
Novel architectural decorative coating and production method thereof Download PDFInfo
- Publication number
- CN1201811A CN1201811A CN 97108096 CN97108096A CN1201811A CN 1201811 A CN1201811 A CN 1201811A CN 97108096 CN97108096 CN 97108096 CN 97108096 A CN97108096 A CN 97108096A CN 1201811 A CN1201811 A CN 1201811A
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- CN
- China
- Prior art keywords
- coating
- mica titanium
- hydrochloric acid
- type coating
- imitative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000000576 coating method Methods 0.000 title claims abstract description 33
- 239000011248 coating agent Substances 0.000 title claims description 32
- 238000004519 manufacturing process Methods 0.000 title claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 39
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 37
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 17
- 239000010936 titanium Substances 0.000 claims abstract description 17
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 13
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003973 paint Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 36
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 36
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 16
- 239000010445 mica Substances 0.000 claims description 15
- 229910052618 mica group Inorganic materials 0.000 claims description 15
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 12
- 239000004202 carbamide Substances 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 12
- 229920002401 polyacrylamide Polymers 0.000 claims description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- -1 polyethylene Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 claims 2
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 claims 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 2
- 239000006228 supernatant Substances 0.000 claims 2
- 239000004615 ingredient Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000005034 decoration Methods 0.000 abstract description 3
- 231100000614 poison Toxicity 0.000 abstract description 2
- 230000007096 poisonous effect Effects 0.000 abstract description 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 3
- 241000700159 Rattus Species 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- LLPOLZWFYMWNKH-CMKMFDCUSA-N hydrocodone Chemical compound C([C@H]1[C@H](N(CC[C@@]112)C)C3)CC(=O)[C@@H]1OC1=C2C3=CC=C1OC LLPOLZWFYMWNKH-CMKMFDCUSA-N 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 241001191009 Gymnomyza Species 0.000 description 1
- 231100000215 acute (single dose) toxicity testing Toxicity 0.000 description 1
- 238000011047 acute toxicity test Methods 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A new-type decorative paint for building is prepared through sequentially adding hydrochloric acid and caustic soda to the aqueous solution containing polyvinyl alcohol as main component, stirring, adding ethanediol and mica-titanium nacreous pigment, and stirring. If other different raw material combinations are added into the mixed liquid, various colorful 'simulated' coatings can be formed. It not only overcomes the defect of poisonous paint, but also has the advantages of better flame retardance, water resistance, washing resistance and the like, thus being an ideal paint for indoor decoration.
Description
The present invention relates to a kind of inner wall of building decorative paint and production method thereof.
Along with the improving constantly of people's living standard and aesthetic consciousness, interior decoration are modish day by day.Oil-in-water-type multicolour pattern interior wall plastic-blasting was once once becoming fashion, but because this product contains a large amount of poisonous carcinogenic substances, the people is known from experience generation harm in various degree, constitute serious threat certainly will for people's living environment, thus make the wind gruel for the moment the body of wall plastic-blasting people that had health care consciousness day by day be subjected to unfrequented even keep someone at a respectful distance.
The purpose of this invention is to provide a kind of nontoxic decorative paint and production method thereof.
The object of the present invention is achieved like this: add in the reactor with a certain proportion of polyethylene alcohol and water earlier, under 90-95 ℃ of stirring, make it to dissolve the back and add hydrochloric acid, make pH value between 1.5-2, slowly add formaldehyde reaction about 20 minutes, it is 7-8 that adding caustic soda, urea are adjusted pH value, add again when dissolving polyacrylamide solution is well mixed thoroughly to 50 ℃ and add ethylene glycol, propylene glycol and dispersion agent, anti-settling agent, defoamer again, be composite base-material (tackiness agent) after the filtration.
Then can form imitative silk type coating (piece thread) if in above-mentioned base-material, add mica titanium nacreous material (filler).
If in imitative silk type coating, add a certain proportion of BC-01 benzene emulsion again to even, adopt different construction gimmicks, then can form imitative colorful type coating (putting broken shape).
If same BC-01 benzene emulsion and the appropriate amount of titanium (filler) of adding in above-mentioned imitative silk coating in conjunction with adopting professional mould printing machine, then can form imitative wallpaper pattern type coating.
If in above-mentioned imitative silk type coating, add BC-01 benzene emulsion and an amount of fine hair powder to even, adopt special-purpose spray gun, but then shape or imitative matte type coating.
In actual production process, the weight percent of each composition is:
Polyvinyl alcohol 4-10% water 50-72%
Hydrochloric acid 0.7-0.85% formaldehyde 2-3% (40% SILVER REAGENT)
Caustic soda 0.15-0.2% urea 1-1.2%
Polyacrylamide 0.15-1% ethylene glycol 0.5-1%
Propylene glycol 0.35-0.4% mica titanium nacreous material 0.4-10%
Dispersion agent, anti-settling agent, defoamer 0.3-0.4%
BC-01 benzene emulsion 0-28% titanium dioxide 0-9%
Fine hair powder 0-15%
Compare with former oil-in-water-type coating of multi-colour pattern, characteristics of the present invention are:
1. improved the base-material selection, make the main component trend Water-borne modification of coating, reduce the use kind and the usage quantity of organic solvent as far as possible, impel product finally to reach nontoxic substantially or nonirritant (detects through the acute toxicity test on March 27th, 96 of Loudi area health and epidemic prevention station and to show, to test rat skin nonirritant, do not find rats death) yet.
2, simplified production technique, saved investment of production equipment, the production unit of former oil-in-water-type coating of multi-colour pattern generally needs hundreds of thousands of at least, even unit up to a million, and this products production at most several ten thousand only needs facility investment can produce for several thousand yuan at least.
3, required raw and auxiliary material kind is few, is based on homemade again and transportation, all safe and reliable certainly.
4, production, trimming cost are low, are fit to mass consumption.About 10 yuan of production cost per kilograms, per kilogram can be constructed 40-60 square metre, and every construction cost per square meter only needs several maos.
Embodiment one:
Prepare raw material according to above-mentioned basic skills, the preparation finished product, the weight percent of each component is:
1799 polyvinyl alcohol (PVA), 10% water 72%
Hydrochloric acid (technical pure contains HCL36%) 0.85% formaldehyde 3%
Caustic soda (Gu) 0.15% urea (agricultural) 1.2%
Polyacrylamide (M＞3,000,000) 1% ethylene glycol (aqua) 1%
Propylene glycol (aqua) 0.4% mica titanium nacreous material 10%
Anti-settling agent, dispersion agent, defoamer 0.4%
Adopt the special-purpose spray gun of hydrocone type to be inverted spraying above mixed solution, then can on metope, form imitative silk type coating.
Embodiment two:
Base-material production method and embodiment one are basic identical, but raw material slightly increases, and each weight percentages of components is:
1799 polyvinyl alcohol, 9% water 72%
Hydrochloric acid (technical pure contains HCL36%) 0.7% formaldehyde (40% SILVER REAGENT) 2%
Caustic soda (Gu) 0.15% urea (agricultural) 1%
Polyacrylamide (M＞3,000,000) 0.5% ethylene glycol (aqua) 0.5%
Propylene glycol (aqua) 0.35%
Mica titanium nacreous material 8.5% (powdery)
Anti-settling agent, dispersion agent, defoamer 0.3% BC-01 benzene emulsion 5%
Adopt hydrocone type bucket spray gun to change PQ-2 type spray gun above-mentioned mixed solution, nozzle is inverted spraying, can be sprayed into imitative colorful type (putting broken shape type) coating on metope.
Embodiment three:
The base-material production method is identical, but raw material increases to some extent, and the weight percent of each component is:
1799 polyvinyl alcohol, 6% water 70%
Hydrochloric acid (technical pure contains HCL36%) 0.7% formaldehyde (40% SILVER REAGENT) 2%
Caustic soda (Gu) 0.15% urea (agricultural) 1%
Polyacrylamide (M＞3,000,000) 1% ethylene glycol (aqua) 1%
Propylene glycol (aqua) 0.35% mica titanium nacreous material 4.5%
Anti-settling agent, dispersion agent, defoamer 0.3%
BC-01 benzene emulsion 10% titanium dioxide 3% (coating level)
Above-mentioned mixed solution is adopted the roll printing of GYI type wall decoration machine, can form imitative wallpaper pattern type coating at metope.
Embodiment four:
The base-material production method is identical, but raw material slightly changes, and each weight percentages of components is:
1799 polyvinyl alcohol, 4% water 50%
Hydrochloric acid (technical pure contains HCL36%) 0.7% formaldehyde 2%
Caustic soda (Gu) 0.2% urea (agricultural) 1%
Polyacrylamide 1% ethylene glycol 1%
Propylene glycol 0.4% mica titanium nacreous material 0.4%
Anti-settling agent, dispersion agent, defoamer 0.3%
BC-01 benzene emulsion 19% fine hair powder 20%
Spraying method with above-mentioned mixed solution employing embodiment one or example two can form imitative matte type coating on metope.
Claims (9)
1, a kind of production method of building decorative coating, it is characterized in that adding in the reactor with a certain proportion of polyethylene alcohol and water earlier, make it to add hydrochloric acid after the dissolving under the 90-95 ℃ of stirring, make pH value between 1.5-2, slowly add formaldehyde reaction about 20 minutes, add caustic soda, it is 7-8 that urea is adjusted pH value, add again and add ethylene glycol when dissolving polyacrylamide solution is well mixed thoroughly to 50 ℃ again, propylene glycol and dispersion agent, anti-settling agent, defoamer, be composite base-material after the filtration, in this composite base-material, add mica titanium nacreous material and then can form imitative silk type coating.
2, the production method of decorative paint according to claim 1 is characterized in that in described composite base-material, adds mica titanium nacreous material, BC-01 benzene emulsion to even, then can form imitative colorful type coating.
3, the production method of decorative paint according to claim 1 is characterized in that in described composite base-material, adds mica titanium nacreous material, BC-01 phenylpropyl alcohol supernatant liquid and titanium dioxide, then can form imitative wallpaper pattern type coating.
4, the production method of decorative paint according to claim 1 is characterized in that in described composite base-material, adds mica titanium nacreous material, BC-01 phenylpropyl alcohol supernatant liquid and fine hair powder to even, then can form imitative matte type coating.
5, a kind of building decorative coating is characterized in that the weight percent of each composition is:
Polyvinyl alcohol 4-10% water 50-72%
Hydrochloric acid 0.7-0.85% formaldehyde 2-3% (40% SILVER REAGENT)
Caustic soda 0.15-0.2% urea 1-1.2%
Polyacrylamide 0.5-1% ethylene glycol 0.5-1%
Propylene glycol 0.35-0.4% mica titanium nacreous material 0.4-10%
Dispersion agent, anti-settling agent, defoamer 0.3-0.4%
BC-01 benzene emulsion 0-28%
Titanium dioxide 0-9% fine hair powder 0-15%
6, coating according to claim 5 is characterized in that the weight percent of each component is: 1799 polyvinyl alcohol (PVA), 10% water, 72% hydrochloric acid (technical pure contains HCL36%), 0.85% formaldehyde, 3% caustic soda (Gu) 0.15% urea (agricultural), 1.2% polyacrylamide (M＞3,000,000) 1% ethylene glycol (aqua), 1% propylene glycol (aqua), 0.4% mica titanium nacreous material, 10% anti-settling agent, dispersion agent, defoamer 0.4% is the best proportioning of imitative silk type coating.
7, coating according to claim 5 is characterized in that each percentages of ingredients is: 1799 polyvinyl alcohol 9% water, 72% hydrochloric acid (technical pure contains HCL36%), 0.7% formaldehyde (40% SILVER REAGENT), 2% caustic soda (Gu) 0.15% urea (agricultural), 1% polyacrylamide (M＞3,000,000) 0.5% ethylene glycol (aqua), 0.5% propylene glycol (aqua), 0.35% mica titanium nacreous material 8.5% (powdery) dispersion agent, anti-settling agent, defoamer 0.3% BC-01 benzene emulsion 5% is the best proportioning of imitative colorful type coating.
8, coating according to claim 5 is characterized in that the weight percent of each component is: 1799 polyvinyl alcohol 6% water, 70% hydrochloric acid (technical pure contains HCL36%), 0.7% formaldehyde (40% SILVER REAGENT), 2% caustic soda (Gu) 0.15% urea (agricultural 1% polyacrylamide (M＞3,000,000) 1% ethylene glycol (aqua) 1% propylene glycol (aqua) 0.35% mica titanium nacreous material 4.5% dispersion agent, anti-settling agent, defoamer 0.3%BC-01 benzene emulsion 10% titanium dioxide 3% (coating level) is the best proportioning of imitative wallpaper pattern type coating.
9, coating according to claim 5 is characterized in that the weight percent of each component is: 1799 polyvinyl alcohol 4% water, 50% hydrochloric acid (technical pure contains HCL36%), 0.7% formaldehyde, 2% caustic soda (Gu) 0.2% urea (agricultural), 1% polyacrylamide, 1% ethylene glycol, 1% propylene glycol, 0.4% mica titanium nacreous material, 0.4% dispersion agent, anti-settling agent, defoamer 0.3%BC-01 benzene emulsion 19% fine hair powder 20% is the best proportioning of imitative matte type coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97108096 CN1201811A (en) | 1997-06-07 | 1997-06-07 | Novel architectural decorative coating and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97108096 CN1201811A (en) | 1997-06-07 | 1997-06-07 | Novel architectural decorative coating and production method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1201811A true CN1201811A (en) | 1998-12-16 |
Family
ID=5170124
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 97108096 Pending CN1201811A (en) | 1997-06-07 | 1997-06-07 | Novel architectural decorative coating and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1201811A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761989A (en) * | 2015-04-08 | 2015-07-08 | 佛山市南海万磊建筑涂料有限公司 | Composite inorganic metal velvet coating and preparation method thereof |
| CN108129922A (en) * | 2017-12-24 | 2018-06-08 | 谢涛 | A kind of easy working water-soluble pearlescent coating |
| CN109321020A (en) * | 2018-10-18 | 2019-02-12 | 合肥永泰新型建材有限公司 | A kind of preparation method of cabinet waterproof midew resistant pain |
-
1997
- 1997-06-07 CN CN 97108096 patent/CN1201811A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761989A (en) * | 2015-04-08 | 2015-07-08 | 佛山市南海万磊建筑涂料有限公司 | Composite inorganic metal velvet coating and preparation method thereof |
| CN104761989B (en) * | 2015-04-08 | 2017-03-08 | 佛山市南海万磊建筑涂料有限公司 | A kind of composite inorganic metal velvet coating and preparation method thereof |
| CN108129922A (en) * | 2017-12-24 | 2018-06-08 | 谢涛 | A kind of easy working water-soluble pearlescent coating |
| CN109321020A (en) * | 2018-10-18 | 2019-02-12 | 合肥永泰新型建材有限公司 | A kind of preparation method of cabinet waterproof midew resistant pain |
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