Detailed Description
The present invention will be described in detail below with reference to the accompanying drawings and specific embodiments.
An embodiment of the utility model provides a semiconductor polishing piece cleaning equipment, as shown in figure 1, include: the silicon wafer cleaning device comprises a separation unit for separating a polished silicon wafer from a first wafer basket 14 for bearing the silicon wafer, a plurality of cleaning units 20 which are arranged in series and are used for cleaning the silicon wafer, a drying unit 30 for drying the cleaned silicon wafer, and a combination unit for loading the cleaned and dried silicon wafer into a second wafer basket 44. Among them, in the separation unit 10, the cleaning unit 20, the drying unit 30, and the integrating unit 40, independent manipulators are provided to move the first wafer basket 14 or the silicon wafer, respectively. In this embodiment, the separation unit 10 is adopted to separate the polished silicon wafer from the first wafer basket 14 containing the polished wafer, then the silicon wafer is separately cleaned and dried step by step in the cleaning unit 20 and the drying unit 30 in sequence, and finally the cleaned and dried silicon wafer is loaded into the second wafer basket 44 in the combination unit 40, so that the situation that the first wafer basket 14 bearing the polished wafer contains polishing liquid, particle pollutants or metal pollutants which flow out of the polished wafer in the cleaning process is avoided, the situation that the polishing liquid or pollutants are re-adhered to the cleaned silicon wafer when the first wafer basket 14 is cleaned together with the silicon wafer is prevented, the technical problem that the silicon wafer is secondarily polluted by the residual liquid medicine or pollutants in the first wafer basket 14 is solved, and the effect of thoroughly cleaning the silicon wafer is achieved. Meanwhile, in the whole cleaning process, a plurality of manipulators are used for independently operating the wafer basket or the silicon wafer for each process in the separation unit 10, the cleaning unit 20, the drying unit 30 and the combination unit 40, so that the situation that the silicon wafer is cleaned due to the fact that the manipulators are corroded by liquid medicine and cross contamination is caused can be prevented, the grafting rate of each cleaning device can be improved, the cleaning quality of the silicon wafer is further guaranteed, and the cleaning efficiency is improved.
Specifically, as shown in fig. 2, the separating unit 10 includes an upper loading slot 11 for loading the polished silicon wafer into a first wafer basket 14 for carrying the silicon wafer, a separating slot 12 for separating the silicon wafer from the first wafer basket 14, and a first robot 13 for operating the first wafer basket 14 to move the first wafer basket 14 together with the silicon wafer, and the first robot 13 may be a robot of any structure as long as it can cooperate with the first wafer basket 14, without being particularly limited thereto. Wherein, the upper loading groove 11 and the separating groove 12 are independent water grooves with open upper end surfaces and are arranged side by side, and preferably, the upper loading groove 11 and the separating groove 12 have the same size, thereby being convenient for arrangement and processing. The separation tank 12 is provided close to the cleaning unit 20, the upper loading tank 11 is fixedly provided on the side of the separation tank 12 remote from the cleaning unit 20, the first robot 13 is suspended on a guide rail (not shown) disposed directly above the upper loading tank 11 and the separation tank 12 and perpendicular to the longitudinal direction of the separation tank 12, and the first robot 13 moves along the guide rail and transfers the first wafer basket 14 and the silicon wafers together from the upper loading tank 11 to the separation tank 12. The water in the upper loading tank 11 and the separation tank 12 is pure water, the height of the pure water is higher than the height of the first wafer basket 14 and the silicon wafer, and the upper loading tank 11 and the separation tank 12 can be used for not only loading the silicon wafer into the first wafer basket 14 and separating the silicon wafer from the first wafer basket 14, but also used as a pre-cleaning tank for cleaning large particles on the polished silicon wafer.
Further, the purpose of the upper loading groove 11 is to place a group of silicon wafers into a first wafer basket 14 which is fixedly placed, positioning devices are arranged at the bottoms of the upper loading groove 11 and the separation groove 12, each positioning device comprises positioning blocks 15 which are symmetrically arranged, and the positioning blocks 15 are arranged in parallel in the width direction of the upper loading groove 11 and the separation groove 12 and are parallel to the length direction of the groove body. The width of the positioning block 15 is adjustable, when the positioning block 15 needs to be matched with an empty first sheet basket 14, the positioning block 15 firstly opens outwards along the width direction of the groove body, the first mechanical hand 13 grabs the empty first sheet basket 14 and enables the empty first sheet basket 14 to be placed between the positioning blocks 15, the first mechanical hand 13 is separated from the first sheet basket 14, the positioning block 15 synchronously approaches the first sheet basket 14 and clamps the first sheet basket 14, and therefore the first sheet basket 14 is fixed in the uploading groove 11; and then other wafer inserting manipulators (not shown) are used for placing the polished silicon wafers into the empty first wafer basket 14 one by one, so that the silicon wafer uploading work is completed. Then, the first wafer basket 14 filled with the silicon wafers is grabbed by the first manipulator 13 and is to be transported to the separation tank 12, the positioning block 15 is loosened, and the first wafer basket 14 and the silicon wafers are moved together with the first manipulator 13 from the uploading tank 11 to the separation tank 12; the first basket 14 filled with silicon wafers is placed between the positioning blocks 15 in the separation tank 12, and the first robot 13 is released and lifted up to move to just above the upper loading tank 11 to wait for the retrieval of the next empty first basket 14.
After the first wafer basket 14 loaded with silicon wafers is placed in the separation tank 12, the positioning block 15 in the separation tank 12 clamps and fixedly places the first wafer basket 14 on the tank bottom to prevent the first wafer basket 14 from moving in the separation tank 12. The bottom in the separation tank 12 is provided with a movable separation top frame 16, the separation top frame 16 is located between the positioning blocks 15 and arranged parallel to the positioning blocks 15, the upper end face of the separation top frame 16 is provided with a top plate 17, a top column 18 is arranged below the top plate 17, the top column 18 is fixedly connected with the top plate 17, the top column 18 can drive the top plate 17 to move in an up-and-down telescopic mode along the vertical direction, and the top plate 17 is located under the center of the first piece basket 14 and can penetrate through the bottom of the first piece basket 14 and enable a silicon wafer to be clamped and fixed on the upper end face of the top plate. In the process of cleaning the polished silicon wafer, the first wafer basket 14 bearing the silicon wafer can affect the cleaning effect of the silicon wafer, so that the secondary pollution of the first wafer basket 14 to the silicon wafer is avoided for ensuring the cleaning effect of the silicon wafer, and the silicon wafer is required to be separated from the first wafer basket 14 to be cleaned independently. During separation, the first wafer basket 14 is fixed, the top column 18 pushes the top plate 17 to move upwards, the top plate 17 jacks up the silicon wafers and drives the silicon wafers to move upwards together, and therefore the silicon wafers are separated from the first wafer basket 14. After the silicon wafer is separated from the first wafer basket 14, the first wafer basket 14 remains at the bottom of the separation tank 12, and the second robot 23 provided in the cleaning unit 20 for the next process grasps the silicon wafer and moves the silicon wafer from the separation tank 12 to the cleaning unit 20 for cleaning. After the silicon wafer is removed, the top column 18 drives the top plate 17 to retract to the initial position, the positioning block 15 in the separation tank 12 releases the first wafer basket 14, and the first mechanical arm 13 takes the first wafer basket 14 and puts the first wafer basket into the uploading tank 11 to prepare for uploading of the next group of silicon wafers.
As shown in fig. 1, the cleaning unit 20 includes a primary cleaning and a secondary cleaning, wherein the primary cleaning includes a first liquid tank 21 and a first cleaning tank 22 in sequence, and the first liquid tank 21 is disposed near the separation tank 12; the secondary cleaning sequentially comprises a second liquid tank 29 and a second washing tank 210, and the second liquid tank 29 is arranged close to the first washing tank 22. The cleaning unit 20 further comprises a second manipulator 23 and a third manipulator 211, wherein the second manipulator 23 is used for moving the silicon wafer out of the separation tank 12 in the separation unit 10 and sequentially moving the silicon wafer into the first liquid tank 21 and the first washing tank 22 for cleaning; the third manipulator 211 moves the silicon wafers out of the first washing tank 22 and sequentially moves the silicon wafers into the second liquid tank 29 and the second washing tank 210 for cleaning, the second manipulator 23 and the third manipulator 211 have the same structure and are used for clamping a group of silicon wafers, and any conventional clamping device capable of clamping a group of silicon wafers can be selected for the structures of the second manipulator 23 and the third manipulator 211, which is not important in the present disclosure and omitted here.
Specifically, as shown in fig. 3, in one cleaning, the silicon wafer is firstly oxidized and corroded by the chemical liquid in the first liquid tank 21, and then the oxidized and corroded surface layer is cleaned in the first washing tank 22, so as to completely remove the particle pollutants on the surface. The first liquid tank 21 is filled with a liquid containing NH4OH、H2O2And H20 mixed liquid, NH4OH:H2O2:H2The volume ratio of O is 1:1:5-1:2:7, and in order to ensure the removal effect of the particle pollutants on the surface of the silicon wafer, a constant cleaning temperature needs to be maintained, and in the embodiment, the cleaning temperature is 65-80 degrees. NH (NH)4OH、H2O2And H2The mixed liquid medicine of 0 can oxidize and micro-etch the surface of the polished silicon wafer, so that particle pollutants attached to the surface are removed along with the oxide layer, and meanwhile, slight organic pollutants and partial metal pollutants can be removed. A temperature tester (not shown) is arranged in the first washing tank 22 to monitor the temperature of the liquid medicine in the first washing tank, and a heater 28 is arranged at the bottom of the first washing tank 22 to ensure that the temperature of the liquid medicine in the first washing tank is constant. When the temperature tester monitors that the temperature in the first washing tank 22 is lower than 65 degrees, the temperature tester transmits the measured data to the temperature controller, and the temperature controller can control the heater 28 to heat; if the temperature is higher than 80 degrees, alarming is carried out, and the temperature controller controls the heater 28 to stop heating; and the liquid medicine has the best effect of removing particle pollutants on the surface of the silicon wafer in the temperature range.
A liquid level sensor and a supply pipe 27 are also arranged in the first washing tank 21, the liquid level sensor is arranged to ensure the liquid level of the liquid medicine to be constant, and if the liquid level sensor monitors that the liquid level reaches a lower limit position, the liquid level sensor monitors that the liquid level reaches the lower limit positionH in supply pipe 272Starting to supplement liquid by an O liquid supplementing pipe; when the liquid surface reaches the upper limit position, the liquid supply is stopped. In order to ensure the stability of the concentration of the chemical in the first wash tank 21, an automatic concentration tester, which is a common instrument in the art, is provided in the first wash tank 21. If NH4OH or H2O2Is lower than the set value, NH4OH liquid supply pipe or H2O2And (4) starting to replenish the liquid by the liquid replenishing pipe, replenishing 10-20mL each time, measuring the concentration of the liquid medicine once after replenishing, continuing to replenish the liquid if the concentration of the liquid medicine is still lower than a set value, and circulating the steps until the set concentration value is reached.
In order to improve the cleaning effect, a shaking device and an ultrasonic device are also arranged in the first liquid tank 21 and are started synchronously.
Specifically, as shown in fig. 3, the shaking device includes a U-shaped bracket 24 and a shaking arm 25 disposed below the bracket 24, the silicon wafer is placed in the bracket 24, the shaking arm 25 can reciprocate up and down under the action of external force, the shaking arm 25 can shake and clean the silicon wafer by driving the bracket 24 to reciprocate up and down, and the shaking arrangement can avoid the difference in cleaning the same batch of particle pollutants, that is, the consistency in removing the particle pollutants of the same batch of silicon wafers is improved, the effect of cleaning the particles and organic pollutants on the surface of the silicon wafer is improved, and the cleaning efficiency is improved.
The ultrasonic device comprises an ultrasonic device 26 arranged on one side wall surface of the first liquid tank 21, the height of the ultrasonic device 26 is consistent with the height of the silicon wafer and is arranged in the direction vertical to the wall thickness of the silicon wafer, and the ultrasonic device 26 can generate ultrasonic waves parallel to the surface of the silicon wafer so as to enable NH in the liquid medicine4OH and H2O2The particles are soaked on the surface of the silicon wafer, then the mixed solution is gradually diffused into the interface, and finally NH is carried out4OH and H2O2The particles are completely infiltrated and become free NH in suspension4OH and H2O2The particles can more effectively remove particle pollutants on the surface of the silicon wafer. After the silicon wafer enters the first liquid tank 21, the ultrasonic device 26 starts to work, the ultrasonic frequency can be 20-50kHz or 1MHz, and the ultrasonic time is 1-5min。
In the working process of the first liquid tank 21, the temperature of the liquid medicine is constantly kept at 65-80 degrees by a temperature tester and a heater 28 arranged in the first liquid tank 21; then the volume ratio of the mixed liquid medicine is controlled to NH under the combined action of the liquid level sensor, the concentration tester and the liquid medicine supply pipe 274OH: H2O2:H2O is between 1:1:5 and 1:2: 7; after the silicon wafer is placed in the first liquid tank 21, the ultrasonic device 26 and the shaking arm 25 synchronously start to work, the ultrasonic device 26 performs microwave vibration on the silicon wafer in an ultrasonic mode, meanwhile, the shaking arm 25 performs shaking cleaning on the silicon wafer through the bracket 24, after 1-5min of cleaning, the ultrasonic device 26 and the shaking arm 25 synchronously stop working, and the second manipulator 23 moves the silicon wafer from the first liquid tank 21 to the first washing tank 22.
As shown in FIG. 4, the first washing tank 22 is mainly used for removing particle impurities and residual NH on the surface of the silicon wafer4OH and H2O2The surface of the silicon wafer is cleaned by the mixed chemical solution of (3). Wash tank 22 is including the water drainage tank 212 that is located the top and communicate and be located the aqua storage tank 213 of water drainage tank 212 below with water drainage tank 212, be equipped with two shower 214 that upper portion symmetry set up and two shower 214 that the lower part symmetry set up in water drainage tank 212, shower 214 group of upper portion and lower part is located water drainage tank 212 cell body both sides respectively, shower 214 perpendicular to silicon disk thickness direction sets up, four groups of shower 214 all spray rivers towards silicon disk central axis position, form intercrossing's spraying effect to the silicon disk, spray the washing fast with the all-round to the silicon disk.
In the working process of the working procedure, after the water drainage tank 212 is filled with water, the second mechanical arm 23 takes out the silicon wafer from the first liquid tank 21 and puts the silicon wafer into the bracket 24 in the first washing tank 22 for fixed placement, the second mechanical arm 23 is moved away, the control valve between the water drainage tank 212 and the water storage tank 213 is opened, water flow quickly enters the water storage tank 213 from the water drainage tank 212 within 5-10s, the upper spray pipe 214 group and the lower spray pipe 214 group work simultaneously, and the silicon wafer is sprayed in an intersecting manner. After the spraying is finished, the water discharge tank 212 is filled with water, and the third robot 211 moves the silicon wafer from the first washing tank 22 to the second washing tank 29 for secondary washing.
The secondary cleaning mainly uses HCL and H2O2The mixed liquid medicine removes metal pollutants on the surface of the silicon wafer. Specifically, the secondary cleaning sequentially comprises a second liquid tank 29 and a second washing tank 210, the structures of the second liquid tank 29 and the second washing tank 210 are respectively the same as those of the first liquid tank 21 and the first washing tank 22, and the drawings are omitted and will not be described in detail.
The second liquid tank 29 is filled with HCL and H2O2And H2Mixed liquid of O, HCL, H2O2:H2The volume ratio of O is 1:1:6-1:2:8, the cleaning temperature is constant at 65-80 degrees, and HCL and H are in the temperature2O2The mixed liquid medicine can dissolve alkali metal ions and hydroxides of aluminum, iron and magnesium, in addition, chloride ions in hydrochloric acid and residual metal ions are subjected to a complex reaction to form a complex compound which is easy to dissolve in an aqueous solution, and metal pollutants can be removed from the bottom layer of the silicon wafer. In order to ensure the removal effect of particles on the surface of the silicon wafer, it is necessary to maintain a constant temperature and a constant concentration of the chemical solution as in the first liquid tank 21 while shaking and ultrasonically cleaning the silicon wafer.
The working process of the second liquid tank 29 is the same as that of the first liquid tank 21, and specifically comprises the following steps: the temperature of the liquid medicine is kept constant at 65-80 degrees by a temperature tester and a heater 28 arranged in a second liquid tank 29; the volume ratio of the mixed liquid medicine is controlled to be HCL: H under the combined action of the liquid level sensor, the concentration tester and the liquid medicine supply pipe 272O2:H2O is between 1:1:6 and 1:2: 8; after the silicon wafer is placed in the second liquid tank 29, the ultrasonic device 26 and the shaking arm 25 start to work synchronously, the ultrasonic device 26 performs microwave vibration on the silicon wafer in an ultrasonic mode, meanwhile, the shaking arm 25 performs shaking cleaning on the silicon wafer through the bracket 24, after 1-5min of cleaning, the ultrasonic device 26 and the shaking arm 25 stop working synchronously, and the third manipulator 211 moves the silicon wafer from the second liquid tank 29 to the second washing tank 210.
The second washing tank 210 is mainly used for removing particle impurities and residual HCL and H on the surface of the silicon wafer2O2The mixed chemical solution of (4) cleans the surface of the wafer. Working of the second washing tank 210The process is the same as the first washing tank 22, and specifically comprises the following steps: after the water discharge tank 212 is filled with water, the third mechanical arm 211 takes the silicon wafer out of the second liquid tank 29 and places the silicon wafer on the bracket 24 in the second washing tank 210, the third mechanical arm 211 is moved away, the control valve between the water discharge tank 212 and the water storage tank 213 is opened, water flow rapidly enters the water storage tank 213 from the water discharge tank 212 within 5-10s, the upper spray pipe 214 group and the lower spray pipe 214 group work simultaneously, and the silicon wafer is sprayed in an intersecting mode. After the spraying is finished, the drain tank 212 is filled with water, and the fourth robot 42 provided in the drying unit 30 moves the silicon wafer from the second washing tank 210 into the drying unit 29 to be dried and cleaned.
The drying unit 30 includes a slow-pulling tank 31 and a drying tank 32 in this order, the slow-pulling tank 31 is disposed near the second washing tank 210, and the drying tank 32 is disposed near the combining tank 41 in the combining unit 40. The integrated unit 40 and the drying unit 30 share the fourth manipulator 42, that is, the fourth manipulator 42 moves the silicon wafer out of the second washing tank 210 and sequentially moves the silicon wafer into the slow lifting tank 31 and the drying tank 32; then, the fourth robot 42 moves the dried silicon wafer from the drying tank 32 to the integrating tank 41, and loads the cleaned silicon wafer into the second wafer basket 43. The fourth robot 42 is the same as the second robot 23 and the third robot 211 in order to clamp a set of silicon wafers, and therefore, the configuration is the same and is omitted.
The purpose of the slow lifting groove 31 is to slowly lift the silicon wafer by the fourth manipulator 42, so that the water film on the surface of the silicon wafer naturally flows down, and the formation of watermarks on the surface of the silicon wafer after being dried is avoided. After the slow-lift tank 31 is cleaned, the fourth robot 42 moves the silicon wafer into the drying tank 32.
The drying tank 32 is provided to thoroughly dry the silicon wafer after the silicon wafer is subjected to the slow-pulling tank 31, and the whole drying process is performed in a high-purity nitrogen atmosphere. After the silicon wafer is placed in the drying groove 32, high-purity nitrogen sweeps the silicon wafer through a sweeping opening to take away moisture on the surface of the silicon wafer, a hot exhaust opening exhausts the gas, and after sweeping is carried out for 10-60min, a heating wire starts to heat and keeps the temperature at 40-70 ℃ for 1-5 min.
As shown in fig. 5, the combining unit 40 includes a combining groove 41 and a fourth robot 42, wherein a positioning block 43 is symmetrically disposed at the bottom of the combining groove 41, and the positioning block 43 has the same structure and function as the positioning block 15, and will not be described in detail herein. The empty second sheet basket 44 is fixed in advance between the positioning blocks 43 at the bottom of the combining groove 41, and the second sheet basket 44 has the same structure as the first sheet basket 14 and is omitted here. Then the silicon wafer in the drying tank 32 is placed in the second wafer basket 44 by the fourth manipulator 42, and the combination operation of the cleaned silicon wafer and the second wafer basket 44 is completed.
Compared with the prior art, adopt the utility model provides a cleaning equipment, structural design is reasonable, the controllability is strong and degree of automation is high, break away from separately with a piece basket 14 that is equipped with this silicon disk the silicon disk after will being equipped with the polishing, carry out substep washing and stoving to the silicon disk again, it washs, the silicon disk after the stoving is packed into again in No. two piece baskets 44, avoid remaining liquid medicine or pollutant on a piece basket 14 in the cleaning process and cause secondary pollution to the silicon disk after the washing, guarantee silicon disk rinse thoroughly, furthest gets rid of remaining polishing solution on the silicon disk surface after the chemical mechanical polishing, particle pollutant and metal contaminant. Meanwhile, a plurality of manipulators are used for independently operating the silicon wafer in each process in the whole cleaning process, so that the situation that the cleaning effect of the silicon wafer is influenced due to the fact that the manipulators are corroded by liquid medicine and cross contamination is generated between the manipulator and the silicon wafer can be prevented, the grafting rate of cleaning equipment can be improved, the cleaning efficiency is improved, and the cleaning quality of the silicon wafer is further guaranteed.
Meanwhile, in the cleaning process of the liquid medicine, the temperature of the liquid medicine is kept constant within a constant range through a temperature tester and a heater which are arranged in the liquid medicine groove. And the volume ratio of the mixed liquid medicine is controlled between standard proportions through the combined action of the liquid level sensor, the concentration tester and the liquid medicine supply pipe. Meanwhile, the shaking device and the ultrasonic device are adopted for synchronous cleaning, the shaking device can further improve the consistency of removing particle pollutants of silicon wafers in the same batch, improve the cleaning effect on the particles and organic pollutants on the surfaces of the silicon wafers and improve the high efficiency; the ultrasonic device can enable chemical component particles in the liquid medicine to be soaked on the surface of the silicon wafer, then the mixed solution is gradually diffused into an interface, and finally the mixed solution is completely soaked and uniformly dispersed on the silicon wafer and becomes suspended free particles, so that particle pollutants on the surface of the silicon wafer can be more effectively removed.
In the pure water cleaning process, the silicon wafer is cleaned by adopting a rapid water drainage overflow method and a cross spray mode so as to remove particulate impurities and residual chemical liquid on the surface of the silicon wafer and clean the surface of the silicon wafer.
A method for cleaning a semiconductor polishing pad, using the cleaning apparatus as defined in any one of the above, comprising the steps of:
the first step is as follows: the silicon wafer is detached from the first wafer basket 14 in the separation unit 10.
Specifically, as shown in fig. 2, the separating unit 10 includes an upper loading tank 11 for loading the polished silicon wafer into a first wafer basket 14 for carrying the silicon wafer, a separating tank 12 for separating the silicon wafer from the first wafer basket 14, and a first robot 13 for operating the first wafer basket 14 to move the first wafer basket 14 together with the silicon wafer, the water in the upper loading tank 11 and the separating tank 12 is pure water, the height of the pure water is less than the height at which the first wafer basket 14 and the silicon wafer are placed, and the upper loading tank 11 and the separating tank 12 not only serve to load the silicon wafer into the first wafer basket 14 and separate the silicon wafer from the first wafer basket 14, but also serve as a pre-cleaning tank to clean large particles on the polished silicon wafer.
Furthermore, the upper loading groove 11 is arranged to place a group of silicon wafers into a first wafer basket 14 which is fixedly placed, in the process of loading, the symmetrically arranged positioning blocks 15 which are positioned at the bottom of the upper loading groove 11 are firstly outwards opened along the width direction of the groove body, the first mechanical hand 13 grabs the first vacant wafer basket 14 and enables the first vacant wafer basket 14 to be placed between the positioning blocks 15, the first mechanical hand 13 is separated from the first wafer basket 14, and the positioning blocks 15 synchronously approach the first wafer basket 14 and clamp the first wafer basket 14, so that the first wafer basket 14 is fixed in the upper loading groove 11; and then other insert manipulators are used for placing the polished silicon wafers into the empty first wafer basket 14 one by one, so that the silicon wafers are uploaded. Then, the first wafer basket 14 filled with the silicon wafers is grabbed by the first manipulator 13 and is to be transported to the separation tank 12, the positioning block 15 is loosened, and the first wafer basket 14 and the silicon wafers are moved together with the first manipulator 13 from the uploading tank 11 to the separation tank 12; the first basket 14 filled with silicon wafers is placed between the positioning blocks 15 in the separation tank 12, and the first robot 13 is released and lifted up to move to just above the upper loading tank 11 to wait for the retrieval of the next empty first basket 14.
After the first wafer basket 14 loaded with silicon wafers is placed in the separation tank 12, the positioning block 15 in the separation tank 12 clamps and fixedly places the first wafer basket 14 on the tank bottom to prevent the first wafer basket 14 from moving in the separation tank 12. The bottom in the separation tank 12 is provided with a movable separation top frame 16, the separation top frame 16 is located between the positioning blocks 15 and arranged parallel to the positioning blocks 15, the upper end face of the separation top frame 16 is provided with a top plate 17, a top column 18 is arranged below the top plate 17, the top column 18 is fixedly connected with the top plate 17, the top column 18 can drive the top plate 17 to move in an up-and-down telescopic mode along the vertical direction, and the top plate 17 is located under the center of the first piece basket 14 and can penetrate through the bottom of the first piece basket 14 and enable a silicon wafer to be clamped and fixed on the upper end face of the top plate. In the process of cleaning the polished silicon wafer, the first wafer basket 14 bearing the silicon wafer can affect the cleaning effect of the silicon wafer, so that the secondary pollution of the first wafer basket 14 to the silicon wafer is avoided for ensuring the cleaning effect of the silicon wafer, and the silicon wafer is required to be separated from the first wafer basket 14 to be cleaned independently. During separation, the first wafer basket 14 is fixed, the top column 18 pushes the top plate 17 to move upwards, the top plate 17 jacks up the silicon wafers and drives the silicon wafers to move upwards together, and therefore the silicon wafers are separated from the first wafer basket 14. After the silicon wafer is separated from the first wafer basket 14, the first wafer basket 14 remains at the bottom of the separation tank 12, and the second robot 23 provided in the cleaning unit 20 for the next process grasps the silicon wafer and moves the silicon wafer from the separation tank 12 to the cleaning unit 20 for cleaning. After the silicon wafer is removed, the top column 18 drives the top plate 17 to retract to the initial position, the positioning block 15 in the separation tank 12 releases the first wafer basket 14, and the first mechanical arm 13 takes the first wafer basket 14 and puts the first wafer basket into the uploading tank 11 to prepare for uploading of the next group of silicon wafers.
The second step is that: the separated silicon wafers are individually cleaned in the cleaning unit 20.
Specifically, the cleaning unit 20 comprises primary cleaning and secondary cleaning, wherein the primary cleaning sequentially comprises a first liquid tank 21 cleaning and a first washing tank 22 cleaning; the secondary cleaning sequentially comprises a second liquid tank 29 cleaning and a second washing tank 210 cleaning.
Specifically, as shown in fig. 3, in one cleaning, the silicon wafer is firstly oxidized and corroded by the chemical liquid in the first liquid tank 21, and then the oxidized and corroded surface layer is cleaned in the first washing tank 22, so as to completely remove the particle pollutants on the surface. The first liquid tank 21 is filled with a liquid containing NH4OH、H2O2And H20 mixed liquid, NH4OH:H2O2:H2The volume ratio of O is 1:1:5-1:2:7, and in order to ensure the removal effect of the particle pollutants on the surface of the silicon wafer, a constant cleaning temperature needs to be maintained, and in the embodiment, the cleaning temperature is 65-80 degrees. NH (NH)4OH、H2O2And H2The mixed liquid medicine of 0 can oxidize and micro-etch the surface of the polished silicon wafer, so that particle pollutants attached to the surface are removed along with the oxide layer, and meanwhile, slight organic pollutants and partial metal pollutants can be removed. A temperature tester (not shown) is arranged in the first washing tank 22 to monitor the temperature of the liquid medicine in the first washing tank, and a heater 28 is arranged at the bottom of the first washing tank 22 to ensure that the temperature of the liquid medicine in the first washing tank is constant. When the temperature tester monitors that the temperature in the first washing tank 22 is lower than 65 degrees, the temperature tester transmits the measured data to the temperature controller, and the temperature controller can control the heater 28 to heat; if the temperature is higher than 80 degrees, alarming is carried out, and the temperature controller controls the heater 28 to stop heating; and the liquid medicine has the best effect of removing particle pollutants on the surface of the silicon wafer in the temperature range.
A liquid level sensor and a supply pipe 27 are also arranged in the first washing tank 21, the liquid level sensor is arranged to ensure the liquid level of the liquid medicine to be constant, and H in the supply pipe 27 is detected when the liquid level sensor monitors that the liquid level reaches a lower limit position2Starting to supplement liquid by an O liquid supplementing pipe; when the liquid surface reaches the upper limit position, the liquid supply is stopped. In order to ensure the stability of the concentration of the chemical in the first wash tank 21, an automatic concentration tester, which is a common instrument in the art, is provided in the first wash tank 21. Such asFruit NH4OH or H2O2Is lower than the set value, NH4OH liquid supply pipe or H2O2And (4) starting to replenish the liquid by the liquid replenishing pipe, replenishing 10-20mL each time, measuring the concentration of the liquid medicine once after replenishing, continuing to replenish the liquid if the concentration of the liquid medicine is still lower than a set value, and circulating the steps until the set concentration value is reached.
In order to improve the cleaning effect, a shaking device and an ultrasonic device are also arranged in the first liquid tank 21.
Specifically, as shown in fig. 3, the shaking device includes a U-shaped bracket 24 and a shaking arm 25 disposed below the bracket 24, the silicon wafer is placed in the bracket 24, the shaking arm 25 can reciprocate up and down under the action of external force, the shaking arm 25 can shake and clean the silicon wafer by driving the bracket 24 to reciprocate up and down, and the shaking arrangement can avoid the difference in cleaning the same batch of particle pollutants, that is, the consistency in removing the particle pollutants of the same batch of silicon wafers is improved, the effect of cleaning the particles and organic pollutants on the surface of the silicon wafer is improved, and the cleaning efficiency is improved.
The ultrasonic device comprises an ultrasonic device 26, the height of the ultrasonic device 26 is consistent with the height of the silicon wafer and is perpendicular to the wall thickness direction of the silicon wafer, and the ultrasonic device 26 can generate ultrasonic waves parallel to the surface of the silicon wafer so as to enable NH in the liquid medicine4OH and H2O2The particles are soaked on the surface of the silicon wafer, then the mixed solution is gradually diffused into the interface, and finally NH is carried out4OH and H2O2The particles are completely infiltrated and become free NH in suspension4OH and H2O2The particles can more effectively remove particle pollutants on the surface of the silicon wafer. After the silicon wafer enters the first liquid tank 21, the ultrasonic device 26 starts to work, the ultrasonic frequency can be 20-50kHz or 1MHz, and the ultrasonic time is 1-5 min.
In the working process of the first liquid tank 21, the temperature of the liquid medicine is constantly kept at 65-80 degrees by a temperature tester and a heater 28 arranged in the first liquid tank 21; then the volume ratio of the mixed liquid medicine is controlled to NH under the combined action of the liquid level sensor, the concentration tester and the liquid medicine supply pipe 274OH: H2O2:H2O is between 1:1:5 and 1:2: 7; after the silicon wafer is placed in the first liquid tank 21, the ultrasonic device 26 and the shaking arm 25 synchronously start to work, the ultrasonic device 26 performs microwave vibration on the silicon wafer in an ultrasonic mode, meanwhile, the shaking arm 25 performs shaking cleaning on the silicon wafer through the bracket 24, after 1-5min of cleaning, the ultrasonic device 26 and the shaking arm 25 synchronously stop working, and the second manipulator 23 moves the silicon wafer from the first liquid tank 21 to the first washing tank 22.
As shown in FIG. 4, the first washing tank 22 is mainly used for removing particle impurities and residual NH on the surface of the silicon wafer4OH and H2O2The surface of the silicon wafer is cleaned by the mixed chemical solution of (3). Wash tank 22 is including the water drainage tank 212 that is located the top and communicate and be located the aqua storage tank 213 of water drainage tank 212 below with water drainage tank 212, be equipped with two shower 214 that upper portion symmetry set up and two shower 214 that the lower part symmetry set up in water drainage tank 212, shower 214 group of upper portion and lower part is located water drainage tank 212 cell body both sides respectively, shower 214 perpendicular to silicon disk thickness direction sets up, four groups of shower 214 all spray rivers towards silicon disk central axis position, form intercrossing's spraying effect to the silicon disk, spray the washing fast with the all-round to the silicon disk.
In the working process of the working procedure, after the water drainage tank 212 is filled with water, the second mechanical arm 23 takes out the silicon wafer from the first liquid tank 21 and puts the silicon wafer into the bracket 24 in the first washing tank 22 for fixed placement, the second mechanical arm 23 is moved away, the control valve between the water drainage tank 212 and the water storage tank 213 is opened, water flow quickly enters the water storage tank 213 from the water drainage tank 212 within 5-10s, the upper spray pipe 214 group and the lower spray pipe 214 group work simultaneously, and the silicon wafer is sprayed in an intersecting manner. After the spraying is finished, the water discharge tank 212 is filled with water, and the third robot 211 moves the silicon wafer from the first washing tank 22 to the second washing tank 29 for secondary washing.
The secondary cleaning mainly uses HCL and H2O2The mixed liquid medicine removes metal pollutants on the surface of the silicon wafer. Specifically, the secondary cleaning sequentially comprises a second liquid tank 29 and a second washing tank 210, and the structures of the second liquid tank 29 and the second washing tank 210 are respectively connected with the first liquid tank 21 and the first washing tankThe grooves 22 have the same structure, and the drawings are omitted and will not be described in detail.
The second liquid tank 29 is filled with HCL and H2O2And H2Mixed liquid of O, HCL, H2O2:H2The volume ratio of O is 1:1:6-1:2:8, the cleaning temperature is constant at 65-80 degrees, and HCL and H are in the temperature2O2The mixed liquid medicine can dissolve alkali metal ions and hydroxides of aluminum, iron and magnesium, in addition, chloride ions in hydrochloric acid and residual metal ions are subjected to a complex reaction to form a complex compound which is easy to dissolve in an aqueous solution, and metal pollutants can be removed from the bottom layer of the silicon wafer. In order to ensure the removal effect of particles on the surface of the silicon wafer, it is necessary to maintain a constant temperature and a constant concentration of the chemical solution as in the first liquid tank 21 while shaking and ultrasonically cleaning the silicon wafer.
The working process of the second liquid tank 29 is the same as that of the first liquid tank 21, and specifically comprises the following steps: the temperature of the liquid medicine is kept constant at 65-80 degrees by a temperature tester and a heater 28 arranged in a second liquid tank 29; the volume ratio of the mixed liquid medicine is controlled to be HCL: H under the combined action of the liquid level sensor, the concentration tester and the liquid medicine supply pipe 272O2:H2O is between 1:1:6 and 1:2: 8; after the silicon wafer is placed in the second liquid tank 29, the ultrasonic device 26 and the shaking arm 25 start to work synchronously, the ultrasonic device 26 performs microwave vibration on the silicon wafer in an ultrasonic mode, meanwhile, the shaking arm 25 performs shaking cleaning on the silicon wafer through the bracket 24, after 1-5min of cleaning, the ultrasonic device 26 and the shaking arm 25 stop working synchronously, and the third manipulator 211 moves the silicon wafer from the second liquid tank 29 to the second washing tank 210.
The second washing tank 210 is mainly used for removing particle impurities and residual HCL and H on the surface of the silicon wafer2O2The mixed chemical solution of (4) cleans the surface of the wafer. The working process of the second washing tank 210 is the same as that of the first washing tank 22, and specifically comprises the following steps: after the water drainage tank 212 is filled with water, the third mechanical arm 211 takes the silicon wafer out of the second liquid tank 29 and places the silicon wafer on the bracket 24 in the second washing tank 210 fixedly, the third mechanical arm 211 is moved away, a control valve between the water drainage tank 212 and the water storage tank 213 is opened, and water flow rapidly enters the water storage tank from the water drainage tank 212 within 5-10sIn the water tank 213, the upper shower 214 group and the lower shower 214 group operate simultaneously to spray the silicon wafers in a cross manner. After the spraying is finished, the drain tank 212 is filled with water, and the fourth robot 42 provided in the drying unit 30 moves the silicon wafer from the second washing tank 210 into the drying unit 29 to be dried and cleaned.
The third step: the cleaned silicon wafer is subjected to a drying process in a drying unit 30.
Specifically, the drying unit 30 sequentially comprises a slow-pulling tank 31 and a drying tank 32, and the integrated unit 40 and the drying unit 30 share the fourth manipulator 42, that is, the fourth manipulator 42 moves the silicon wafer out of the second washing tank 210 and sequentially moves the silicon wafer into the slow-pulling tank 31 and the drying tank 32; then, the fourth robot 42 moves the dried silicon wafer from the drying tank 32 to the integrating tank 41, and loads the cleaned silicon wafer into the second wafer basket 43.
The purpose of the slow lifting groove 31 is to slowly lift the silicon wafer by the fourth manipulator 42, so that the water film on the surface of the silicon wafer naturally flows down, and the formation of watermarks on the surface of the silicon wafer after being dried is avoided. After the slow-lift tank 31 is cleaned, the fourth robot 42 moves the silicon wafer into the drying tank 32.
The drying tank 32 is provided to thoroughly dry the silicon wafer after the silicon wafer is subjected to the slow-pulling tank 31, and the whole drying process is performed in a high-purity nitrogen atmosphere. After the silicon wafer is placed in the drying groove 32, high-purity nitrogen sweeps the silicon wafer through a sweeping opening to take away moisture on the surface of the silicon wafer, a hot exhaust opening exhausts the gas, and after sweeping is carried out for 10-60min, a heating wire starts to heat and keeps the temperature at 40-70 ℃ for 1-5 min.
The fourth step: the cleaned silicon wafer is loaded into a second wafer basket 44 in the combination unit 40.
Specifically, as shown in fig. 5, the combining unit 40 includes a combining groove 41, and positioning blocks 43 are symmetrically disposed at the bottom of the combining groove 41, and the positioning blocks 43 have the same structure and function as the positioning blocks 15, and will not be described in detail herein. The empty second sheet basket 44 is fixed in advance between the positioning blocks 43 at the bottom of the combining groove 41, and the second sheet basket 44 has the same structure as the first sheet basket 14 and is omitted here. Then the silicon wafer in the drying tank 32 is placed in the wafer basket 44 by the fourth manipulator 42, and the combination operation of the cleaned silicon wafer and the second wafer basket 44 is completed.
The utility model provides a cleaning method reduces the secondary pollution that basket of flowers and manipulator caused to the washing of silicon disk furthest to can get rid of remaining liquid medicine and pollutant on the polishing back silicon disk surface completely, the cleaning performance is good and the cleaning efficiency is high.
The embodiments of the present invention have been described in detail, and the description is only for the preferred embodiments of the present invention, and should not be construed as limiting the scope of the present invention. All the equivalent changes and improvements made according to the application scope of the present invention should still fall within the patent coverage of the present invention.