CN209199953U - A kind of passivation solar battery of type metal electrode - Google Patents

A kind of passivation solar battery of type metal electrode Download PDF

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Publication number
CN209199953U
CN209199953U CN201822233558.0U CN201822233558U CN209199953U CN 209199953 U CN209199953 U CN 209199953U CN 201822233558 U CN201822233558 U CN 201822233558U CN 209199953 U CN209199953 U CN 209199953U
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metal electrode
region
type
polysilicon
solar battery
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林建伟
包杰
吴伟梁
刘志锋
陈嘉
吴兴华
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Taizhou Zhonglai Optoelectronics Technology Co Ltd
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Taizhou Zhonglai Optoelectronics Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/546Polycrystalline silicon PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Abstract

The utility model relates to a kind of passivation solar battery of type metal electrode, including N-type crystalline silicon matrix, the back surface of the N-type crystalline silicon matrix successively penetrates film, n+ metal electrode including n+ doped polysilicon layer, back passivated reflection reducing from inside to outside;The N-type crystalline silicon matrix is formed with DOPOS doped polycrystalline silicon magnetic tape trailer layer close to the side of the n+ doped polysilicon layer.Extend the magnetic tape trailer of Metal contact regions doped polysilicon layer, increases the depth that foreign atom is spread in crystalline silicon, reduce the compound of Metal contact regions;It keeps the doped polysilicon layer magnetic tape trailer of nonmetallic contact area shallower, reduces the compound of nonmetallic contact area;The n+ doped polysilicon layer of simple process, first area and second area can be completed by once doping, and the technical process being related to industrialization is suitble to large-scale production;Metal can be significantly reduced and contact compound and ohmic loss, improve the open-circuit voltage and transfer efficiency of battery.

Description

A kind of passivation solar battery of type metal electrode
Technical field
The utility model relates to technical field of solar batteries, and in particular to a kind of passivation solar energy of type metal electrode Battery.
Background technique
Currently, most common method for metallising is that silk-screen printing adds sintering in crystal-silicon solar cell industrialization, using silk Wire mark brush adds sintering that can make metal piercing tunnel oxide and doped polysilicon layer, directly contacts with silicon substrate, leads to metal area Compound surge under domain, causes biggish recombination losses.Particularly with the slurry using silver-colored aluminium paste, metal piercing oxide layer and mix The phenomenon that miscellaneous polysilicon layer, can be more serious.
In crystal-silicon solar cell, metal and semiconductor contact regions it is serious compound, become and restrict crystalline silicon too An important factor for positive battery efficiency develops.In current commercialized crystal-silicon solar cell, front surface generally uses shallow junction Gao Fang Resistance design, for p-type battery, front surface is the emitter structure of phosphorus doping, the metal contact zone after silk-screen printing, sintering Dark saturation current density (the J in domain0,metal) it is 800~1000fA/cm2;For N-shaped battery, front surface has the hair of identical sheet resistance Emitter-base bandgap grading is after silk-screen printing, sintering, the dark saturation current density (J of Metal contact regions0,metal) it is 1000~2000fA/ cm2.Demand with market to high-efficiency battery and high power component sharply increases, and reduces answering for metal and semiconductor contact regions Conjunction is particularly important.
Application No. is the Chinese utility model patents of CN201721045632.5 to disclose what kind of back pastes were directly burnt Back passivation solar battery, including silicon nitride anti-reflecting film, phosphorus-diffused layer, the P-type silicon matrix, passivation being successively laid with from top to bottom Layer and the non-burn-through type aluminium paste layer in the back side, it further includes silicon oxynitride film that passivation layer, which includes silicon oxide film and silicon nitride film, the nitridation Silicon antireflective coating is equipped with several positive silver electrodes for having burnt silicon nitride anti-reflecting film, and overleaf passivation layer is equipped with back electricity Pole, back electrode are connect with P-type silicon matrix, pulp layer and P-type silicon substrate contact, overleaf on passivation layer, print one layer of non-burn-through Type aluminium paste layer.It is subsequent easily to increase PERL structure technology, front in production process using the design of the utility model The superposition of SE structure technology, back side boron diffusion technique or above-mentioned technology, scalability are strong.
Above-mentioned patent is burnt layer using silver paste and is contacted through silicon oxide film and silicon nitride film with silicon substrate, but does not consider To the serious compound of metal and semiconductor contact regions, the problem of the serious efficiency for affecting crystal-silicon solar cell.
Utility model content
The purpose of this utility model is that in view of the deficiencies of the prior art, provide a kind of significant decrease metal contact it is compound and Ohmic loss improves the passivation solar battery of the open-circuit voltage of battery and the type metal electrode of transfer efficiency, this is practical new The technical solution that type is taken are as follows:
A kind of passivation solar battery of type metal electrode, including N-type crystalline silicon matrix, the N-type crystalline silicon matrix Back surface from inside to outside successively include n+ doped polysilicon layer, back passivated reflection reducing penetrate film, n+ metal electrode;
The N-type crystalline silicon matrix is formed with DOPOS doped polycrystalline silicon magnetic tape trailer layer close to the side of the n+ doped polysilicon layer.
Wherein, the DOPOS doped polycrystalline silicon magnetic tape trailer layer includes the first band tail region domain being arranged alternately and the second magnetic tape trailer region, institute The thickness that first band tail area thickness is greater than second magnetic tape trailer region is stated, the n+ metal electrode corresponds to the first band tail region Domain setting.
Wherein, the n+ doped polysilicon layer includes the first polysilicon region and the second polysilicon region, more than described first The thickness of polysilicon regions is less than the thickness of second polysilicon region;First polysilicon region corresponds to first magnetic tape trailer Area, second polysilicon region correspond to second magnetic tape trailer region.
Wherein, the doping concentration of first polysilicon region is greater than the doping concentration of second polysilicon region.
Wherein, first polysilicon region with a thickness of 50~300nm, square resistance is 10~60 Ω/sq;
Second polysilicon region with a thickness of 150~400nm, square resistance is 30~200 Ω/sq.
It wherein, further include tunnel oxide between the back surface of the N-type crystalline silicon matrix and the n+ doped polysilicon layer Layer.
Wherein, the tunnel oxide with a thickness of 0.5~2.5nm.
Wherein, the front surface of the N-type crystalline silicon matrix successively includes that p+ adulterates emitter layer, preceding passivation subtracts from inside to outside Reflective film and p+ metal electrode.
Wherein, the n+ metal electrode and p+ metal electrode are " H " type grid line, main grid spaced set 4~12, wide 100~800 μm of degree, is highly 10~40 μm;Secondary grid spaced set 90~120, width are 20~60 μm, highly for 10~ 40μm。
The technological merit of the utility model is mainly reflected in:
The polysilicon layer of doping with height alternating structural is set, in Metal contact regions and nonmetallic contact area The polysilicon membrane with different levels of doping, different-thickness is formed, the window of metallization process is greatly expanded.This is practical new The technological merit that type embodies are as follows: 1) extend the magnetic tape trailer of Metal contact regions doped polysilicon layer, increase foreign atom in crystalline silicon The depth of middle diffusion reduces the compound of Metal contact regions;2) doped polysilicon layer of Metal contact regions is heavy doping, can be with The contact resistance of metal and semiconductor is significantly reduced, ohmic loss is reduced;3) DOPOS doped polycrystalline silicon of nonmetallic contact area is kept Layer magnetic tape trailer is shallower, reduces the compound of nonmetallic contact area;4) simple process, the first polysilicon region and the second polysilicon region N+ doped polysilicon layer by once doping can be completed, be suitble to large-scale production.In terms of comprehensive, the utility model can be shown Writing, which reduces metal, contacts compound and ohmic loss, improves the open-circuit voltage and transfer efficiency of battery, and the technology of use is applicable in In scale of mass production.
Detailed description of the invention
Fig. 1 is the structure chart of the passivation solar battery of the type metal electrode of the utility model embodiment.
Fig. 2 is that the passivation solar battery n+ doped polysilicon layer of the type metal electrode of the utility model embodiment measures Doping curve graph.
In figure, N-type crystalline silicon matrix 1, p+ doping emitter layer 2, tunnel oxide 3, n+ doped polysilicon layer 5, first Polysilicon region 51, the second polysilicon region 52, DOPOS doped polycrystalline silicon magnetic tape trailer layer 6, the second magnetic tape trailer region 61, first band tail region domain 62, back passivated reflection reducing penetrates film 7, and preceding passivated reflection reducing penetrates film 8, n+ metal electrode 9, p+ metal electrode 10;
The doping concentration N1 of first polysilicon region, the doping concentration N2 of the second polysilicon region, the first polysilicon region Thickness D1, the thickness D2 of the second polysilicon region, the thickness D11, the thickness D22 in the second magnetic tape trailer region in first band tail region domain.
Specific embodiment
The utility model is described in detail below in conjunction with embodiment and attached drawing, it should be pointed out that described Embodiment be intended merely to facilitate the understanding to the utility model, and do not play any restriction effect to it.
A kind of passivation solar battery of type metal electrode of the present embodiment, including N-type crystalline silicon matrix 1, N-type crystal The back surface of silicon substrate 1 successively penetrates film 7, n+ metal electrode 9 including n+ doped polysilicon layer 5, back passivated reflection reducing from inside to outside;
N-type crystalline silicon matrix 1 is formed with DOPOS doped polycrystalline silicon magnetic tape trailer layer 6 close to the side of n+ doped polysilicon layer 5.
The depth that the magnetic tape trailer of polysilicon doping, i.e. foreign atom are spread in crystalline silicon contacts compound size to metal It plays a decisive role.Result of study shows that magnetic tape trailer is thicker, and metal contact is compound lower;When magnetic tape trailer very little, metal contact Region is complex as 400-1000fA/cm2, when magnetic tape trailer is 0.3 μm, the compound of Metal contact regions is reduced to~200fA/cm2。 In this way, increasing the magnetic tape trailer thickness of polysilicon layer, increase the depth that foreign atom is spread in crystalline silicon, reduces Metal contact regions It is compound, improve the Generation Rate of solar battery.
Wherein, DOPOS doped polycrystalline silicon magnetic tape trailer layer 6 includes the first band tail region domain 62 and the second magnetic tape trailer region 61 being arranged alternately, the One magnetic tape trailer region, 62 thickness is greater than the thickness in the second magnetic tape trailer region 61, and the corresponding first band tail region domain 62 of n+ metal electrode 9 is arranged.
The increase of magnetic tape trailer depth can also increase accordingly the compound of passive area, need control strip in the optimization process of battery The depth of tail carrys out the recombination losses of budget metals contact area and nonmetallic contact area.It is mixed in this way, extending Metal contact regions The magnetic tape trailer of miscellaneous polysilicon layer increases the depth that foreign atom is spread in crystalline silicon, reduces the compound of Metal contact regions, improves The Generation Rate of solar battery keeps the doped polysilicon layer magnetic tape trailer of nonmetallic contact area shallower, reduces nonmetallic contact zone Domain it is compound, further increase the Generation Rate of solar battery.
Wherein, n+ doped polysilicon layer 5 includes the first polysilicon region 51 and the second polysilicon region 52, the first polysilicon Thickness of the thickness in region 51 less than the second polysilicon region 52;First polysilicon region 51 correspondence first band tail region 62, second Polysilicon region 52 corresponds to the second magnetic tape trailer region 61.
Wherein, the doping concentration of the first polysilicon region 51 is greater than the doping concentration of the second polysilicon region 52.In this way, N+ doped polysilicon layer and DOPOS doped polycrystalline silicon magnetic tape trailer layer, the first polysilicon region can be formed simultaneously when being doped to polysilicon layer It can be completed with the n+ doped polysilicon layer of the second polysilicon region by once doping, simple process is suitble to large-scale production.
Wherein, 5 growth pattern of n+ doped polysilicon layer be low-pressure chemical vapor deposition it is intrinsic be mixed with the more of microcrystal silicon phase Crystal silicon.The mode of doping is ion implanting phosphorus atoms, phosphorus diffusion, normal pressure chemical vapor phase deposition phosphorosilicate glass, foreign atom activation Later, the first polysilicon region 51 with a thickness of 50~300nm, resistance value is 10~60 Ω/sq;
Second polysilicon region 52 with a thickness of 150~500nm, resistance value is 30~200 Ω/sq.
It wherein, further include tunnel oxide 3 between the back surface of N-type crystalline silicon matrix 1 and n+ doped polysilicon layer 5.
Tunnel oxide passive metal contact structures are made of the polysilicon layer of one layer of ultra-thin tunnel oxide and doping, This structure applies to crystal-silicon solar cell, obtains 26.1% battery conversion efficiency.The contact of tunnel oxide passive metal Structure, which both can be used for n-Si substrate, can be used for p-Si substrate, can obtain in Metal contact regions lower than 10fA/cm2's J0Value, while contact performance is good, contact resistivity is lower than 10m Ω cm2
Wherein, tunnel oxide 3 with a thickness of 0.5~2.5nm;Material is silica or titanium dioxide, titanium dioxide The preparation method of silicon is thermal oxide, HNO3Oxidation, O3Oxidation, atomic layer deposition etc., the preparation method of titanium dioxide are atomic layer deposition Area method.
Wherein, the front surface of N-type crystalline silicon matrix 1 successively includes that p+ adulterates emitter layer 2, preceding passivated reflection reducing from inside to outside Penetrate film 8, p+ metal electrode 10.
Wherein, p+ adulterate emitter layer 2 using boron diffusion method preparation, the standby emitter sheet resistance value of diffusion be 60~ 200 Ω/sq, preferably sheet resistance value are 80~140 Ω/sq.
Wherein, n+ metal electrode 9 and p+ metal electrode 10 are " H " type grid line, main grid spaced set 4~12, wide 100~800 μm of degree, is highly 10~40 μm;Secondary grid spaced set 90~120, width are 20~60 μm, highly for 10~ 40μm。
Wherein, it is stack membrane that front surface passivated reflection reducing, which penetrates film, for the group both in aluminium oxide, silica, silicon nitride It closes;Back surface passivation antireflection film is monofilm or stack membrane, is the combination of silica, silicon nitride or both.
Finally it should be noted that above embodiments are only to illustrate the technical solution of the utility model, rather than to this reality With the limitation of novel protected range, although being explained in detail referring to preferred embodiment to the utility model, this field it is general Lead to it will be appreciated by the skilled person that can be with the technical solution of the present invention is modified or equivalently replaced, without departing from this The spirit and scope of utility model technical solution.

Claims (9)

1. a kind of passivation solar battery of type metal electrode, which is characterized in that including N-type crystalline silicon matrix, the N-type is brilliant The back surface of body silicon substrate successively penetrates film, n+ metal electrode including n+ doped polysilicon layer, back passivated reflection reducing from inside to outside;
The N-type crystalline silicon matrix is formed with DOPOS doped polycrystalline silicon magnetic tape trailer layer close to the side of the n+ doped polysilicon layer.
2. a kind of passivation solar battery of type metal electrode according to claim 1, which is characterized in that the doping Polysilicon magnetic tape trailer layer includes the first band tail region domain being arranged alternately and the second magnetic tape trailer region, and the first band tail area thickness is greater than The thickness in second magnetic tape trailer region, the n+ metal electrode correspond to the setting of first band tail region domain.
3. a kind of passivation solar battery of type metal electrode according to claim 2, which is characterized in that the n+ mixes Miscellaneous polysilicon layer includes the first polysilicon region and the second polysilicon region, and the thickness of first polysilicon region is less than described The thickness of second polysilicon region;First polysilicon region corresponds to the first band tail region, second polysilicon region Corresponding second magnetic tape trailer region.
4. a kind of passivation solar battery of type metal electrode according to claim 3, which is characterized in that described first The doping concentration of polysilicon region is greater than the doping concentration of second polysilicon region.
5. a kind of passivation solar battery of type metal electrode according to claim 4, which is characterized in that described first Polysilicon region with a thickness of 50~300nm, square resistance is 10~60 Ω/sq;
Second polysilicon region with a thickness of 150~400nm, square resistance is 30~200 Ω/sq.
6. a kind of passivation solar battery of type metal electrode according to claim 1, which is characterized in that the N-type It further include tunnel oxide between the back surface of crystal silicon substrate and the n+ doped polysilicon layer.
7. a kind of passivation solar battery of type metal electrode according to claim 6, which is characterized in that the tunnelling Oxide layer with a thickness of 0.5~2.5nm.
8. a kind of passivation solar battery of type metal electrode according to claim 1, which is characterized in that the N-type The front surface of crystal silicon substrate successively includes p+ doping emitter layer from inside to outside, preceding passivated reflection reducing penetrates film and p+ metal is electric Pole.
9. a kind of passivation solar battery of type metal electrode according to claim 8, which is characterized in that the n+ gold Belong to electrode and p+ metal electrode is " H " type grid line, main grid spaced set 4~12,100~800 μm of width, be highly 10 ~40 μm;Secondary grid spaced set 90~120, width are 20~60 μm, are highly 10~40 μm.
CN201822233558.0U 2018-12-28 2018-12-28 A kind of passivation solar battery of type metal electrode Active CN209199953U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114242803A (en) * 2022-02-25 2022-03-25 浙江晶科能源有限公司 Solar cell, preparation method thereof and photovoltaic module
CN114695591A (en) * 2020-12-25 2022-07-01 苏州阿特斯阳光电力科技有限公司 Silicon wafer, silicon wafer textured structure and preparation method thereof
CN114843349A (en) * 2020-10-30 2022-08-02 浙江晶科能源有限公司 Solar cell

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114843349A (en) * 2020-10-30 2022-08-02 浙江晶科能源有限公司 Solar cell
US11901467B2 (en) 2020-10-30 2024-02-13 Zhejiang Jinko Solar Co., Ltd. Solar cell
CN114695591A (en) * 2020-12-25 2022-07-01 苏州阿特斯阳光电力科技有限公司 Silicon wafer, silicon wafer textured structure and preparation method thereof
CN114695591B (en) * 2020-12-25 2024-03-12 苏州阿特斯阳光电力科技有限公司 Silicon wafer, silicon wafer textured structure and preparation method thereof
CN114242803A (en) * 2022-02-25 2022-03-25 浙江晶科能源有限公司 Solar cell, preparation method thereof and photovoltaic module
CN114242803B (en) * 2022-02-25 2022-08-12 浙江晶科能源有限公司 Solar cell, preparation method thereof and photovoltaic module

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Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant
IP01 Partial invalidation of patent right

Commission number: 5W129993

Conclusion of examination: Declare claims 1-2 and 6-9 of utility model number 201822233558.0 invalid, and continue to maintain the validity of the patent on the basis of claims 3-5

Decision date of declaring invalidation: 20230504

Decision number of declaring invalidation: 561199

Denomination of utility model: A passive solar cell with printed metal electrodes

Granted publication date: 20190802

Patentee: JOLYWOOD (TAIZHOU) SOLAR TECHNOLOGY Co.,Ltd.

IP01 Partial invalidation of patent right