CN202205847U - Lead acid battery grid - Google Patents

Lead acid battery grid Download PDF

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Publication number
CN202205847U
CN202205847U CN2010206196304U CN201020619630U CN202205847U CN 202205847 U CN202205847 U CN 202205847U CN 2010206196304 U CN2010206196304 U CN 2010206196304U CN 201020619630 U CN201020619630 U CN 201020619630U CN 202205847 U CN202205847 U CN 202205847U
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China
Prior art keywords
acid battery
lead
grid
titanium
lead acid
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Expired - Fee Related
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CN2010206196304U
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Chinese (zh)
Inventor
张�浩
程杰
曹高萍
杨裕生
徐斌
张文峰
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63971 Troops of PLA
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63971 Troops of PLA
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Priority to CN2010206196304U priority Critical patent/CN202205847U/en
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Publication of CN202205847U publication Critical patent/CN202205847U/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Cell Electrode Carriers And Collectors (AREA)

Abstract

The utility model relates to a grid structure of a lead acid battery, which comprises a titanium or titanium alloy positive pole current collector and a titanium or titanium alloy negative pole current collector. A hole channel communicating the front end and the rear end of a battery lead plate is arranged on the titanium or titanium alloy current collector. The shape of the hole channel is a circle, a polygon or any other shapes. The current collector can be used for a lamination or rolling type lead acid battery. The current collector enables the lead acid battery to have good pulse responding performance, can improve power density and cycling service life of the lead acid battery, and is expected to be applied to the lead acid battery in the field of electrical automobiles, electrical tools, pulse transmission, war industry and the like.

Description

A kind of lead-acid battery grid
Technical field
Novel titanium or the titanium alloy collector that relates to a kind of lead-acid battery of present technique belongs to field of chemical engineering.Be expected to be applied to the lead-acid battery in fields such as electric motor car, electric tool, pulse emission and military project.
Background technology
The energy is the basis of human society survival and development, has represented the course of development in science and technology to the utilization of electric energy from the natural mineral reserve energy.Modern age; The last century quick development of human society particularly; Make the human resource consumption sharply increase; Causing with the oil is main being becoming tight traditional fossil energy day, and causes air pollution serious all the more, seek sustainable development approach, protect national resource and natural environment becomes the serious challenge of 21 century.Electric energy has become the energy of the indispensable a kind of cleaning of human society, and any other utilization of resources generally all must be used electric energy, and battery/capacitance technology is all used in the storage of electric energy, conversion, conveying.
Electric automobile (comprising pure electric vehicle and hybrid electric vehicle HEV) is pollution-free, use cost is low and be expected to the tuning network system paddy electricity at night, becomes the development trend of present research focus and future transportation instrument.Lead-acid battery application promise in clinical practice is arranged, but its specific energy shortcoming low, that cycle life is short has restricted its application in electric motor car at present because of characteristics such as its raw material resources are abundant, cheap, preparation, service procedure maturation and fail safe are good in electric motor car.
Lead accumulator is compared with lithium ion battery, and energy density is low, and its reason is that the lead or the lead alloy that are used for the battery lead plate collector are more thick and heavy.Titanium or titanium alloy with density is less are made the mass ratio that the afflux physical efficiency improves the battery lead plate active material, and then improve the battery specific energy.Yet it is loose that the lead base active material combines with titanium or titanium alloy sheet, phenomenon such as in the battery cyclic process, is prone to dry linting take place, come off, and causes battery life relatively poor.
Compare with common tabular or paper tinsel shape collector, cellular or draw in the net collector and have higher specific area, thereby can better must contact with active material.In addition, lead plaster has the characteristic of autoadhesion, and the cellular collector can make the lead plaster that is coated in the two sides be in contact with one another, thereby obtains better bond properties, makes battery obtain cycle life preferably.
Summary of the invention
The purpose of the utility model provides a kind of titanium or titanium alloy collector of carbonaceous lead-acid battery, and the duct of through electrode plate front and back is arranged on this collector, can improve the specific energy of lead-acid battery and recycle the life-span.
The technical scheme of the utility model is following: a kind of lead-acid battery grid, it is characterized in that this grid 1 is made up of collector electrode 2 and barrier 3, and collector electrode is connected conduct charges with external circuit, two barrier 3 clamping a slice collector electrodes 2.The thickness of grid 1 is at 0.5~8mm.Have collector electrode to connect duct 4 on the collector electrode 2, hole shape can be circle, ellipse, polygon, star or their combination, and the cross-sectional area in each duct is 0.25~100mm 2, pitch of holes is 1~20mm, thickness is 0.04~2mm.Have barrier to connect duct 5 on the barrier 3, hole shape can be circle, ellipse, polygon, star or their combination, and the cross-sectional area in each duct is 1~1000mm 2, pitch of holes is 1~20mm, thickness is 0.2~4mm.Collector electrode 2 is titanium, tantalum or their alloy with barrier 3, and it is shaped as paper tinsel, strip or netted, and the surface can have TiOx or TaOx to modify film.In addition, barrier 3 is polymethylpentene, polyethylene, polypropylene, polybutene, nylon, polystyrene, polyvinyl chloride, polyvinylidene chloride, rubber or silicon rubber, their composite material, or conductive plastics.
The collector advantage that the utility model provides is: make lead-acid battery have more high-energy-density, long-life advantage.Titanium or titanium alloy collector light weight make the shared mass ratio of battery lead plate active material improve, thereby obtain higher specific energy.Loose structure on the collector makes the lead plaster be coated in the two sides be in contact with one another, and bondingly closely suppressed the generation of dry linting, active material obscission, improved the life-span.
Description of drawings
Fig. 1 is a kind of sketch map of lead-acid battery grid
Fig. 2 is a kind of current collector structure sketch map of lead-acid battery grid
Fig. 3 is a kind of structural representation of grid of lead-acid battery grid
Fig. 4 is a kind of sketch map of lead-acid battery grid
Wherein: 1. grid, 2. collector electrode, 3. barrier, 4. collector electrode connects the duct, and 5. grid connects the duct.
Embodiment
Embodiment 1
As shown in Figure 2, six sides that stamp diameter 1.5mm, spacing 2mm on the titanium foil that 0.04mm is thick are uniformly distributed with the collector electrode 2 of circular hole 4 as lead-acid battery grid 1.This collector electrode 2 can be used as the collector electrode 2 of the grid 1 of lead-acid battery negative pole, when these collector electrode 2 surface treatments become Ti 40 7Can be used as the collector electrode 2 of the anodal grid 1 of lead-acid battery behind the skin covering of the surface.As shown in Figure 3, be injection molded into the hard polypropylene have 10mm * the 14mm square-grid connects the square sheet frame of duct 5, the wide 1mm * 1mm of rib, thickness 2mm, as the barrier 3 of lead-acid battery grid 1.With barrier 3 and the mode lamination of collector electrode 2 according to a collector electrode 2 of two barriers, 3 folders, heat seal is handled two barriers 3 and collector electrode 2 heat bondings is integral, the grid 1 of lead-acid battery, as shown in Figure 1.
Embodiment 2
As shown in Figure 4, impact positive and negative alternate square hole on the titanium foil that 1mm is thick, the part of going out the titanium foil plane is protruding in echelon.The barrier 3 of the trapezoidal bossing lead-acid battery grid 1 on titanium foil plane is gone out as the collector electrode 2 of lead-acid battery grid 1 in the titanium foil plane.Wherein impact the square hole that on the titanium foil and be of a size of 5mm * 7mm, spacing 4mm, the trapezoidal through hole that is parallel to the titanium foil plane that convexes to form is of a size of 7mm * 1.5mm, the gross thickness 6mm of lead-acid battery grid 1.This grid can become Ti with this grid surface treatment directly as the grid 1 of lead-acid battery negative pole 40 7Can be used as the anodal grid 1 of lead-acid battery behind the skin covering of the surface.
Embodiment 3
Laminated type lead-acid battery as shown in Figure 3, titanium matter collector 1 thick 0.3mm for drawing in the net the shape structure, draws in the net with the wide 5mm of titanium silk.This lead-acid battery specific energy reaches 50Wh/kg, 1000 capacity attenuations 25% of 80%DOD cycle charge-discharge.

Claims (7)

1. a lead-acid battery grid is characterized in that this grid (1) is made up of collector electrode (2) and barrier (3), and collector electrode (2) is connected conduct charges with external circuit, two barriers (3) clamping a slice collector electrodes (2).
2. the grid of lead-acid battery according to claim 1, the thickness that it is characterized in that this grid (1) is at 0.5~8mm.
3. the grid of lead-acid battery according to claim 1 is characterized in that having on the collector electrode (2) collector electrode to connect duct (4), and hole shape can be circle, ellipse, polygon, star or their combination, and the cross-sectional area in each duct is 0.25~100mm 2, pitch of holes is 1~20mm, thickness is 0.04~2mm.
4. the grid of lead-acid battery according to claim 1 is characterized in that having on the barrier (3) barrier to connect duct (5), and hole shape can be circle, ellipse, polygon, star or their combination, and the cross-sectional area in each duct is 1~1000mm 2, pitch of holes is 1~20mm, thickness is 0.2~4mm.
5. the grid of lead-acid battery according to claim 1 is characterized in that collector electrode (2) is titanium, tantalum or their alloy, and it is shaped as paper tinsel, strip or netted, and the surface can have TiOx or TaOx to modify film.
6. the grid of lead-acid battery according to claim 1 is characterized in that barrier (3) is titanium, tantalum or their alloy, and the surface can have TiOx or TaOx to modify film.
7. the grid of lead-acid battery according to claim 1 is characterized in that barrier (3) is polymethylpentene, polyethylene, polypropylene, polybutene, nylon, polystyrene, polyvinyl chloride, polyvinylidene chloride, rubber or silicon rubber, or conductive plastics.
CN2010206196304U 2010-11-23 2010-11-23 Lead acid battery grid Expired - Fee Related CN202205847U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010206196304U CN202205847U (en) 2010-11-23 2010-11-23 Lead acid battery grid

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CN2010206196304U CN202205847U (en) 2010-11-23 2010-11-23 Lead acid battery grid

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CN202205847U true CN202205847U (en) 2012-04-25

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104785075A (en) * 2015-04-27 2015-07-22 南京九思高科技有限公司 Gas membrane separation device capable of eliminating static electricity and method
CN104868176A (en) * 2015-05-19 2015-08-26 李毛丁 3D lead-acid battery and production method thereof
CN104882616A (en) * 2015-05-19 2015-09-02 李毛丁 Lead-acid battery 3D current collector and production method thereof
CN105514442A (en) * 2015-12-15 2016-04-20 常熟市万隆电源技术研发有限公司 UPS storage battery grid not prone to deformation
CN109065891A (en) * 2018-07-26 2018-12-21 安徽迅启电源科技有限公司 A kind of accumulator for fork-lift truck pole plate and production method

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104785075A (en) * 2015-04-27 2015-07-22 南京九思高科技有限公司 Gas membrane separation device capable of eliminating static electricity and method
CN104785075B (en) * 2015-04-27 2018-12-28 南京九思高科技有限公司 A kind of gaseous jet simulation device and method for eliminating electrostatic
CN104868176A (en) * 2015-05-19 2015-08-26 李毛丁 3D lead-acid battery and production method thereof
CN104882616A (en) * 2015-05-19 2015-09-02 李毛丁 Lead-acid battery 3D current collector and production method thereof
CN104868176B (en) * 2015-05-19 2018-10-09 李毛丁 A kind of 3D lead-acid batteries and preparation method thereof
CN105514442A (en) * 2015-12-15 2016-04-20 常熟市万隆电源技术研发有限公司 UPS storage battery grid not prone to deformation
CN109065891A (en) * 2018-07-26 2018-12-21 安徽迅启电源科技有限公司 A kind of accumulator for fork-lift truck pole plate and production method
CN109065891B (en) * 2018-07-26 2021-03-19 安徽迅启电源科技有限公司 Storage battery polar plate for forklift and manufacturing method

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GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120425

Termination date: 20131123