CN202107700U - Separate two-phase anaerobic fermentation device - Google Patents
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Abstract
Description
技术领域 technical field
本实用新型涉及一种分离式两相厌氧发酵发酵装置,属于农村生态环境保护与农村可再生清洁能源利用领域。The utility model relates to a separated two-phase anaerobic fermentation fermentation device, which belongs to the fields of rural ecological environment protection and rural renewable clean energy utilization.
背景技术 Background technique
近年来,随着我国经济快速发展、城市化进程加快,环境问题已越来越受到人们的重视。据2005年住建部对全国部分农村的调查,我国农村每年产生的生活污水达80多亿吨、96%的农村没有污水处理及收集系统,生活污水随意排放,严重危害了饮用水、生态环境安全和居民身体健康。此外,大量农作物秸秆未被利用,随意遗弃或焚烧,造成严重的环境污染及火灾等事故。In recent years, with the rapid development of my country's economy and the acceleration of urbanization, environmental issues have been paid more and more attention by people. According to a survey conducted by the Ministry of Housing and Urban-Rural Development on some rural areas across the country in 2005, more than 8 billion tons of domestic sewage are produced in rural areas of our country every year, and 96% of rural areas have no sewage treatment and collection systems, and domestic sewage is discharged randomly, which seriously endangers drinking water and ecological environment safety. and the health of the residents. In addition, a large number of crop stalks are not used, abandoned or burned at will, causing serious environmental pollution and fire accidents.
将稻秸、生活污水作为沼气原料进行混合厌氧发酵,一方面可解决农村环境污染问题,另一方面也可产生了清洁能源沼气,满足了环境保护和可持续发展的双重需要。Using rice straw and domestic sewage as biogas raw materials for mixed anaerobic fermentation can solve the problem of rural environmental pollution on the one hand, and on the other hand can also produce clean energy biogas, which meets the dual needs of environmental protection and sustainable development.
公开号为CN1769220的专利,提出了用厨余物、秸秆、畜禽粪便和活性污泥为原料的沼气生产技术,该专利特征是采用两个平行的高固形物沼气反应器,以城市生活污水处理厂厌氧消化污泥作为种泥,在反应器中将原料厨余物、秸秆、畜禽粪便、活性污泥和种泥混合,厨余物、秸秆、畜禽粪便和活性污泥的质量配比为1∶1∶1∶1,种泥用量为原料量的25%,北方地区采取中温33-37℃厌氧发酵,南方地区采取中高温33-55℃厌氧发酵,pH值维持在7.0,湿度控制在90%-100%,物料在反应器中的停留时间为40-45天;每2天进出料一次。The patent with the publication number CN1769220 proposes a biogas production technology using kitchen waste, straw, livestock and poultry manure and activated sludge as raw materials. The anaerobic digestion sludge of the treatment plant is used as the seed sludge, and the raw food waste, straw, livestock and poultry manure, activated sludge and seed sludge are mixed in the reactor, and the quality of the food waste, straw, livestock and poultry manure and activated sludge The ratio is 1:1:1:1, the amount of seed mud is 25% of the raw material, the northern region adopts anaerobic fermentation at medium temperature 33-37°C, and the southern region adopts medium-high temperature anaerobic fermentation at 33-55°C, and the pH value is maintained at 7.0, the humidity is controlled at 90%-100%, the residence time of the material in the reactor is 40-45 days; the material is fed in and out every 2 days.
公开号为CN101020912的专利,提出一种将甲烷菌回流与粉碎的秸秆原料混合发酵生产沼气的方法,其特征在于,它是采用将发酵沼气的原料农作物秸秆粉碎成秸秆粉末、秸秆颗粒、秸秆丝,再入沼气发酵罐,沼气发酵罐底部出料管排出的含甲烷菌渣料,根据实际测定的所含甲烷菌数量,按含甲烷菌渣料与新投入秸秆原料的体积比为0.5~8.0∶1.0的比例混合后输入到沼气发酵罐进行连续发酵生产沼气。The patent with the publication number CN101020912 proposes a method for producing biogas by mixing and fermenting methane bacteria backflow and crushed straw raw materials. , and then into the biogas fermentation tank, the methane-containing bacteria slag discharged from the discharge pipe at the bottom of the biogas fermentation tank, according to the actual measured number of methanogens, the volume ratio of the methane-containing bacteria slag to the newly input straw material is 0.5 to 8.0 : 1.0 ratio mixed and input to biogas fermentation tank for continuous fermentation to produce biogas.
公开号为CN10159167的专利,提出了一种纯秸秆无堆沤投料沼气发酵方法,该方法是:按常规发酵工艺启动,用菌种优选沼渣对秸秆接种、投料,按水料比9∶1加水,待加入的水料占沼气池总发酵容积10%时停止入料,等待产气;正常产气后,把铡碎的或青储的秸秆按多点进料方式投料,每天只由一个进料口投料,第二天换下一个进料口投料,以此逐天逐口循环投料;沼气池内顶部安装有多个喷头,池底设置泥渣泵,通过输液管道由泥渣泵将沼气池下部的沼液输至喷头,对进入沼气池内浮在沼液上部的发酵原料进行喷淋,使原料酸化中和;每天按当天的进料量,由沼气池下部排出一定量的已发酵完毕的废沼渣。The patent with the publication number CN10159167 proposes a biogas fermentation method for pure straw without composting and retting. The method is as follows: start the fermentation process according to the conventional method, inoculate and feed the straw with the preferred biogas residue of the strain, and feed the straw according to the water-to-material ratio of 9:1. Add water, stop feeding when the added water accounts for 10% of the total fermentation volume of the biogas digester, and wait for gas production; after normal gas production, feed the crushed or silage straw according to the multi-point feeding method, and only one feeder per day Feed at the feed port, and replace the feed with the next feed port on the next day, so as to circulate the feed day by day; there are multiple nozzles installed on the top of the biogas tank, and a sludge pump is installed at the bottom of the pool, and the biogas is pumped by the sludge pump through the infusion pipeline. The biogas slurry in the lower part of the pond is sent to the nozzle, and the fermentation raw materials that enter the biogas tank and float on the upper part of the biogas slurry are sprayed to acidify and neutralize the raw materials. of waste residue.
以上这些专利提出的工艺均为单相厌氧发酵工艺,即水解酸化以及产甲烷在同一个反应器中进行。针对农村有机废弃物种类多、来源复杂以及基于厌氧发酵的生物学过程,20世纪70年代初美国戈什(Ghosh)和波兰特(Pohland)开发的厌氧生物处理新工艺。该发酵系统使水解酸化和产甲烷两个反应阶段分别在两个反应系统进行,创造了2个不同的生物和营养环境条件,如温度和pH值等,各自形成产酸发酵微生物和产甲烷发酵微生物的最佳生态条件,以达到优化每个阶段工艺参数的目的。Ghosh(1995)以城市固废有机物为底物,发现在两相消化过程中,其沼气产率及挥发性固体的转化率均较单相法有所提高,Zhang等在1999年进行了两相厌氧发酵处理稻草的试验研究,该工艺将固态发酵和液态发酵进行合理的分割和联结,使得反应的稳定性和反应器的容积利用率提高,同时也提高了厌氧生物降解的效率。Lehtom ki(2008)采用两相发酵和单相发酵工艺处理青贮草,单相发酵及两相发酵的产酸阶段在滴滤床反应器内完成,产甲烷阶段在UASB反应器内完成。试验结果表明,采用两相发酵工艺时甲烷产率达到理论甲烷产率的66%,而单相发酵只有20%。刘广青(2006、2007)等以厨余和杂草废弃物混合物为发酵底物进行了单相和两相厌氧发酵试验,结果表明,与批式消化比较,该两相系统污染负荷高,产气稳定,周期短,是处理该类型有机废弃物的有效方法。张兴庆(2009)等采用两相法工艺研究了城镇有机垃圾水解试验,表明采用沼液回流方式可以获得较高的有机碳溶出率,De LaRubia(2010)以向日葵籽压渣残留物为底物研究发现在水力滞留时间为10天,有机负荷为6gVS·L-1·d-1条件下,其水解率可达到86%,Seung Gu Shin(2010)运用分子生物学的方法研究了两相反应器中优势微生物菌群,发现在水解相优势微生物会随有机负荷有所变化,但在产甲烷相,则优势种群结构稳定,进一步证明了两相法可以起到优化两类功能微生物生态条件的作用。两相发酵既可以分别在2个独立的反应器中进行,也可以在一个反应器内的2个反应区中完成,农业部规划院开发出一体化两相厌氧消化技术(公开号CN201581074U),即在同一消化器中实现“固相滤池产酸和液相全混产甲烷”的两相分区,保证了产酸菌和产甲烷菌在各自的反应区内的适宜生长环境。与单相发酵工艺相比,两相厌氧消化技术至少可达到以下两个目的,一是可以提高产甲烷相反应器中产甲烷菌的活性;二是可以提高整个处理系统的稳定性和处理效果。The processes proposed in the above patents are all single-phase anaerobic fermentation processes, that is, hydrolysis acidification and methane production are carried out in the same reactor. A new anaerobic biological treatment process was developed by Ghosh and Pohland in the United States in the early 1970s for the various types of organic waste in rural areas, complex sources, and biological processes based on anaerobic fermentation. The fermentation system enables the two reaction stages of hydrolysis acidification and methanogenic reaction to be carried out in two reaction systems respectively, creating two different biological and nutritional environmental conditions, such as temperature and pH value, to form acidogenic fermentation microorganisms and methanogenic fermentation respectively. The best ecological conditions for microorganisms, in order to achieve the purpose of optimizing the process parameters of each stage. Ghosh (1995) used urban solid waste organic matter as a substrate and found that in the two-phase digestion process, the biogas yield and the conversion rate of volatile solids were increased compared with the single-phase method. Zhang et al. carried out two-phase digestion in 1999. Experimental research on anaerobic fermentation treatment of rice straw. This process reasonably divides and connects solid-state fermentation and liquid-state fermentation, which improves the stability of the reaction and the volume utilization of the reactor, and also improves the efficiency of anaerobic biodegradation. Lehtom ki (2008) used two-phase fermentation and single-phase fermentation to treat silage grass. The acid production stage of single-phase fermentation and two-phase fermentation was completed in the trickling filter bed reactor, and the methanogenic stage was completed in the UASB reactor. The test results show that the methane yield reaches 66% of the theoretical methane yield when the two-phase fermentation process is adopted, while the single-phase fermentation only has 20%. Liu Guangqing (2006, 2007) conducted single-phase and two-phase anaerobic fermentation experiments using a mixture of kitchen waste and weed waste as the fermentation substrate. The results showed that, compared with batch digestion, the two-phase system had a higher pollution load and yield The gas is stable and the cycle is short, which is an effective way to deal with this type of organic waste. Zhang Xingqing (2009) used the two-phase method to study the hydrolysis test of urban organic waste, showing that the biogas slurry reflux method can obtain a higher organic carbon dissolution rate, and De LaRubia (2010) studied the residue of sunflower seed pressing residue as the substrate It was found that under the conditions of hydraulic retention time of 10 days and organic load of 6gVS L -1 d -1 , the hydrolysis rate can reach 86%. Seung Gu Shin (2010) studied the two-phase reactor by using the method of molecular biology In the dominant microbial flora, it is found that the dominant microorganisms in the hydrolysis phase will change with the organic load, but in the methanogenic phase, the dominant population structure is stable, which further proves that the two-phase method can optimize the ecological conditions of two types of functional microorganisms. . Two-phase fermentation can be carried out in two independent reactors, or in two reaction zones in one reactor. The Planning Institute of the Ministry of Agriculture has developed an integrated two-phase anaerobic digestion technology (public number CN201581074U) , that is to realize the two-phase partition of "acid production by solid-phase filter and full-mixed methane production by liquid phase" in the same digester, which ensures the suitable growth environment for acid-producing bacteria and methanogenic bacteria in their respective reaction zones. Compared with the single-phase fermentation process, the two-phase anaerobic digestion technology can achieve at least the following two purposes, one is to increase the activity of methanogenic bacteria in the methanogenic phase reactor; the other is to improve the stability and treatment effect of the entire treatment system .
然而,以上所提及的研究成果以及专利技术在涉及秸秆作为原料时,均提出需要进行堆腐或粉碎等预处理,且进出料困难,操作要求高,且秸秆粉碎成本高、劳动工况环境恶劣,加之劳动力成本高,从而导致现有的技术难以在农村推广使用;另外,朱瑾等人(2011)对秸秆两相与单相发酵比较试验研究发现,若两相工艺中相分离不佳,其由于产甲烷相中产甲烷菌不断进入水解酸化池中,导致最终水解酸化相产沼气的比例占总产沼气量的79.52%,而往往水解酸化相都为敞开式,势必会导致大量的甲烷、二氧化碳等温室气体的排放,这样与沼气工程的低碳及循环技术理念背道而驰;再次,现有沼气工程中均会产生大量的沼液,若得不到妥善使用而任意排放,势必会造成二次污染或加重后续净化处理的负担,而目前所拥有的技术及专利均未有效解决这些实际问题。However, when the above-mentioned research results and patented technologies involve straw as a raw material, it is proposed that pretreatment such as composting or crushing is required, and it is difficult to feed and discharge materials, and the operation requirements are high, and the cost of straw crushing is high, and the working conditions and environment In addition, Zhu Jin et al. (2011) compared two-phase and single-phase fermentation of straw and found that if the phase separation in the two-phase process is not good , because the methanogenic bacteria in the methanogenic phase continuously enter the hydrolysis and acidification tank, the proportion of biogas produced in the final hydrolysis and acidification phase accounts for 79.52% of the total biogas production, and the hydrolysis and acidification phase is often open, which will inevitably lead to a large amount of methane , carbon dioxide and other greenhouse gases, which runs counter to the concept of low-carbon and recycling technology of biogas projects; thirdly, existing biogas projects will produce a large amount of biogas slurry, if it is not properly used and discharged randomly, it will inevitably cause secondary pollution. secondary pollution or aggravate the burden of subsequent purification treatment, and the current technologies and patents have not effectively solved these practical problems.
实用新型内容 Utility model content
本实用新型的目的在于:现有农村有机废弃物厌氧发酵产沼气技术,均要求对物料进行粉碎或破碎或堆腐等预处理,且操作复杂、技术要求高,其次,既是采用水解酸化批次进料、产甲烷相半连续进料的两相发酵工艺,可以不需要对底物作特别的预处理,但要求对水解酸化反应器进行密闭,以收集部分沼气,从而增加了施工、进出料操作难度,且也增加了投资成本等一系列问题,提出一种分离式两相厌氧发酵装置。The purpose of this utility model is: the existing rural organic waste anaerobic fermentation biogas production technology requires pretreatment of materials such as crushing or crushing or composting, and the operation is complicated and the technical requirements are high. Secondly, both the hydrolysis and acidification batch The two-phase fermentation process with secondary feed and semi-continuous feed in the methanogenic phase does not require special pretreatment of the substrate, but requires the hydrolysis and acidification reactor to be sealed to collect part of the biogas, thus increasing the construction, entry and exit. Due to the difficulty of material operation and the increase of investment cost, a separate two-phase anaerobic fermentation device was proposed.
本实用新型的目的是这样实现的:一种分离式两相厌氧发酵发酵装置,其特征在于:包括水解酸化反应装置、厌氧发酵装置、沼气处理装置和沼液氧化装置,其中:The purpose of this utility model is achieved in the following way: a separate two-phase anaerobic fermentation fermentation device is characterized in that it includes a hydrolysis acidification reaction device, anaerobic fermentation device, biogas treatment device and biogas slurry oxidation device, wherein:
a)所述的水解酸化反应装置包括至少两个并联的水解酸化基本单元的水解酸化反应池和水解液收集池,每个基本单元均为敞口的物料堆积池,物料堆积池设有水解酸化液出口和氧化后沼液的回用入口,所述的水解酸化液出口位于物料堆积池的底部,并与水解液收集池沟通,所述的水解酸化液出口和氧化后沼液的回用入口均设有独立的控制阀;各基本单元的上部均配有独立的栅栏盖板,每个基本单元均配有独立的防雨棚;所述的氧化后沼液的回用入口高于或等于栅栏盖板的安装位置;a) The hydrolytic acidification reaction device includes at least two parallel hydrolytic acidification reaction tanks and hydrolyzed liquid collection tanks, each basic unit is an open material storage tank, and the material storage tank is equipped with hydrolytic acidification liquid outlet and the reuse inlet of the oxidized biogas slurry, the outlet of the hydrolysis and acidification solution is located at the bottom of the material accumulation tank, and communicates with the hydrolysis solution collection tank, the outlet of the hydrolysis and acidification solution and the reuse inlet of the oxidized biogas slurry Each is equipped with an independent control valve; the upper part of each basic unit is equipped with an independent fence cover, and each basic unit is equipped with an independent rainproof shed; the reuse inlet of the oxidized biogas slurry is higher than or equal to The installation location of the fence cover;
b)所述的厌氧发酵装置为密闭的厌氧消化反应器、厌氧消化反应器底部设有进料口、在厌氧消化反应器顶部设有沼气输出口,在厌氧消化反应器0.8~0.9的高度设有沼液溢流口,沼液溢流口配有过滤装置;水解液收集池通过进料泵与厌氧消化反应器的进料口沟通;b) The described anaerobic fermentation device is a closed anaerobic digestion reactor, the bottom of the anaerobic digestion reactor is provided with a feed inlet, and the top of the anaerobic digestion reactor is provided with a biogas output port. In the anaerobic digestion reactor 0.8 The height of ~0.9 is equipped with a biogas slurry overflow port, and the biogas slurry overflow port is equipped with a filter device; the hydrolyzate collection tank communicates with the feed port of the anaerobic digestion reactor through a feed pump;
c)所述的沼液氧化装置为沼液氧化池,沼液氧化池的一端为沼液进料口,另一端为被氧化沼液出料口,由沼液氧化池的沼液进料口到被氧化沼液出料口之间设有上下错位的折流遮挡板,折流遮挡板至少将沼液氧化池分割为三个氧化区,沼液氧化池配有增氧装置,增氧装置的出气口为微孔曝气头,所述的微孔曝气头分布于各氧化区的底部;所述的沼液进料口与厌氧消化反应器的沼液溢流口沟通,被氧化沼液出料口与水解酸化液的氧化后沼液的回用入口对接;c) The biogas slurry oxidation device is a biogas slurry oxidation pond, one end of the biogas slurry oxidation pond is a biogas slurry feed port, the other end is an oxidized biogas slurry discharge port, and the biogas slurry feed port of the biogas slurry oxidation pond Up and down misaligned baffle baffles are provided between the outlet of the oxidized biogas slurry, and the baffle baffles at least divide the biogas slurry oxidation tank into three oxidation zones. The gas outlet is a microporous aeration head, and the microporous aeration head is distributed at the bottom of each oxidation zone; the biogas slurry feed port communicates with the biogas slurry overflow port of the anaerobic digestion reactor, and is oxidized The biogas slurry outlet is connected with the reuse inlet of the oxidized biogas slurry of the hydrolysis acidification solution;
d)所述的水解酸化池、厌氧消化反应器、沼液氧化池的体积比为2~5∶1∶0.2~0.5。d) The volume ratio of the hydrolytic acidification tank, anaerobic digestion reactor and biogas slurry oxidation tank is 2-5:1:0.2-0.5.
在本实用新型中,厌氧消化反应器的进料口距反应器底部50cm,厌氧消化反应器中设有叶片搅拌器。In the utility model, the feeding port of the anaerobic digestion reactor is 50 cm away from the bottom of the reactor, and a blade stirrer is arranged in the anaerobic digestion reactor.
在本实用新型中,所述的沼液氧化池深度不超过1000mm;在沼液氧化装置中位于沼液进料口一端的氧化区为第一氧化区,至少一个微孔曝气头位于第一氧化区的底部。In the present utility model, the depth of the biogas slurry oxidation pond does not exceed 1000mm; in the biogas slurry oxidation device, the oxidation zone located at one end of the biogas slurry feed port is the first oxidation zone, and at least one microporous aeration head is located in the first bottom of the oxidation zone.
在本实用新型中,所述的水解酸化反应池由2~6个并联的水解酸化基本单元组成。In the utility model, the hydrolytic acidification reaction pool is composed of 2 to 6 parallel hydrolytic acidification basic units.
在本实用新型中,所述的水解酸化反应池的水解酸化液出口高于水解液收集池的收集池最大容纳量的设计液面,沼液氧化池的被氧化沼液出料口高于水解酸化池的氧化后沼液的回用入口。In the utility model, the outlet of the hydrolysis and acidification solution of the hydrolysis acidification reaction tank is higher than the design liquid level of the maximum capacity of the collection tank of the hydrolysis solution collection tank, and the outlet of the oxidized biogas slurry in the biogas slurry oxidation tank is higher than the hydrolysis solution outlet. The reuse inlet of the biogas slurry after oxidation in the acidification pond.
在本实用新型中,所述的水解液收集池置于地下。In the utility model, the hydrolyzate collection pool is placed underground.
在本实用新型中,所述的水解酸化液置于地下。In the utility model, the hydrolysis and acidification solution is placed underground.
在本实用新型中,所述的水解酸化反应池和沼液氧化池均设在地下或地上,沼液氧化池的被氧化沼液出料口与水解酸化液的氧化后沼液的回用入口之间均配有压力泵相互沟通。In the present utility model, the hydrolytic acidification reaction pond and the biogas slurry oxidation pond are both arranged underground or on the ground, and the oxidized biogas liquor outlet of the biogas liquor oxidation pond and the reuse inlet of the oxidized biogas liquor of the hydrolysis acidification liquid They are equipped with pressure pumps to communicate with each other.
在本实用新型中,所述的分离式两相厌氧发酵发酵装置还包括沼气处理装置,所述的沼气处理装置由沼气贮气罐、脱水塔、脱硫塔、沼气增压机组成,沼气贮气罐与厌氧消化反应器的沼气输出口连接,沼气贮气罐、脱水塔、脱硫塔依次串接后,由沼气增压机与沼气用户连接。In the utility model, the separated two-phase anaerobic fermentation device also includes a biogas treatment device, and the biogas treatment device is composed of a biogas storage tank, a dehydration tower, a desulfurization tower, and a biogas booster. The gas tank is connected to the biogas output port of the anaerobic digestion reactor, and after the biogas storage tank, dehydration tower, and desulfurization tower are connected in series, the biogas booster is connected to the biogas user.
本实用新型的优点在于:采用分离式两相厌氧发酵装置,将底物水解酸化与厌氧发酵产沼气两个过程分开,其中水解酸化过程在敞口池中完成,这样便于随时进出料,且可适应不同物理性状底物的处理需要;水解液进入厌氧消化反应器后,由于自身带入一定量的好氧菌可以快速消耗掉反应器中的氧气,从而不影响其厌氧环境;经过厌氧消化处理后的沼液经过滤处理后去除掉大量的杂质,以防止后续管道及沼液氧化池的堵塞;沼液进入氧化池后经过曝气充氧处理后使产甲烷菌因接触氧气而基本被杀灭,从而降低了因沼液回流至水解酸化池而导致甲烷外泄的风险。The utility model has the advantages of adopting a separate two-phase anaerobic fermentation device to separate the two processes of substrate hydrolysis and acidification and anaerobic fermentation to produce biogas, wherein the hydrolysis and acidification process is completed in an open pool, which is convenient for feeding and discharging materials at any time. And it can adapt to the processing needs of substrates with different physical properties; after the hydrolyzate enters the anaerobic digestion reactor, a certain amount of aerobic bacteria can be brought into it to quickly consume the oxygen in the reactor, thus not affecting its anaerobic environment; After anaerobic digestion, the biogas slurry is filtered to remove a large amount of impurities to prevent the blockage of subsequent pipelines and biogas slurry oxidation tanks; after the biogas slurry enters the oxidation tank, it is aerated and oxygenated to make methanogenic bacteria contact Oxygen is basically killed, thereby reducing the risk of methane leakage due to the return of biogas slurry to the hydrolysis acidification pond.
本实用新型的技术总体性能指标与同类技术比较的优势在于:水解酸化池呈敞口状,进出料操作简单,且随时可以进料,较好地适应了农村废弃物产生种类以及数量的不确定性,且水解酸化池不做封闭处理,减少了工程造价;第二,经厌氧消化后的沼液经过滤处理后去除掉大量的杂质,防止了对后续管道及沼液氧化池的堵塞;第三,沼液进入氧化池后经过曝气充氧处理后使产甲烷菌因接触氧气而基本被杀灭,从而降低了因沼液回流至水解酸化池而导致甲烷外泄的风险;第四,维护管理方便。Compared with similar technologies, the overall technical performance index of the utility model has the advantages that the hydrolytic acidification tank is open, the operation of feeding and discharging materials is simple, and the materials can be fed at any time, which is better adapted to the uncertainty of the types and quantities of rural wastes. The hydrolytic acidification tank is not closed, which reduces the project cost; second, the biogas slurry after anaerobic digestion is filtered to remove a large amount of impurities, preventing the blockage of subsequent pipelines and biogas slurry oxidation tank; Third, after the biogas slurry enters the oxidation pond, it is aerated and oxygenated, so that the methanogenic bacteria are basically killed due to exposure to oxygen, thereby reducing the risk of methane leakage caused by the return of the biogas slurry to the hydrolysis acidification pond; , easy maintenance and management.
附图说明 Description of drawings
图1是本实用新型的实施例的示意图;Fig. 1 is the schematic diagram of the embodiment of the utility model;
图2是沼液氧化池的结构示意图。Figure 2 is a schematic diagram of the structure of the biogas slurry oxidation pond.
图中:1、水解酸化反应池;2、固定螺栓;3、栅栏盖板;4、水解酸化液出口;5、水解液收集池;6、进料泵;7、厌氧消化反应器;8、进料口;9、沼液溢流口;10、电动机;11、叶片搅拌器;12、沼气输出口;13、过滤器;14、沼液氧化池;15、增氧装置;16、微孔曝气头;17、折流遮挡板;18、被氧化沼液出料口;19、沼液的回用入口;20、沼气贮气罐;21、脱水塔;22、脱硫塔;23、沼气增压机。In the figure: 1. Hydrolysis and acidification reaction tank; 2. Fixing bolts; 3. Fence cover; 4. Hydrolysis and acidification solution outlet; 5. Hydrolysis solution collection tank; 6. Feed pump; 7. Anaerobic digestion reactor; 8 , feed inlet; 9, biogas slurry overflow port; 10, motor; 11, blade agitator; 12, biogas output port; 13, filter; 14, biogas slurry oxidation pond; 15, aeration device; 16, micro Hole aeration head; 17. Baffle plate; 18. Oxidized biogas slurry outlet; 19. Biogas slurry reuse inlet; 20. Biogas storage tank; 21. Dehydration tower; 22. Desulfurization tower; 23. Biogas booster.
具体实施方式 Detailed ways
附图非限制性地公开了本实用新型实施例的具体结构,下面结合附图对本实施例作进一步描述。The accompanying drawings disclose the specific structure of the embodiment of the utility model without limitation, and the present embodiment will be further described below in conjunction with the accompanying drawings.
由图1和图2可见,分离式两相厌氧发酵发酵装置包括水解酸化反应装置、厌氧发酵装置和沼液氧化装置,其中:It can be seen from Figure 1 and Figure 2 that the separated two-phase anaerobic fermentation fermentation device includes a hydrolysis acidification reaction device, anaerobic fermentation device and biogas slurry oxidation device, in which:
水解酸化反应装置包括2~6个并联的水解酸化基本单元的水解酸化反应池1和水解液收集池5,每个基本单元均为敞口的物料堆积池,物料堆积池设有水解酸化液出口4和氧化后沼液的回用入口19,所述的水解酸化液出口4位于物料堆积池的底部,并与水解液收集池5沟通,所述的水解酸化液出口4和氧化后沼液的回用入口19均设有独立的控制阀;各基本单元的上部均配有独立的栅栏盖板3,并通过固定螺栓2固定,每个基本单元均配有独立的防雨棚(图中未显示);所述的氧化后沼液的回用入口19高于或等于栅栏盖板3的安装位置。The hydrolysis acidification reaction device includes 2 to 6 parallel hydrolysis acidification basic units of hydrolysis
厌氧发酵装置为密闭的厌氧消化反应器7、厌氧消化反应器7底部设有进料口8、在厌氧消化反应器顶部设有沼气输出口12,在厌氧消化反应器0.8~0.9的高度设有沼液溢流口9,沼液溢流口9配有过滤装置13;水解液收集池5通过进料泵6与厌氧消化反应器7的进料口8沟通。The anaerobic fermentation device is a closed
沼液氧化装置为沼液氧化池14,沼液氧化池14的一端为沼液进料口,另一端为被氧化沼液出料口,由沼液氧化池的沼液进料口到被氧化沼液出料口18之间设有上下错位的折流遮挡板17,折流遮挡板17至少将沼液氧化池分割为三个氧化区,沼液氧化池配有增氧装置15,增氧装置15的出气口为微孔曝气头16,所述的微孔曝气头位于氧化区的底部;所述的沼液进料口与厌氧消化反应器的沼液溢流口9沟通,被氧化沼液出料口18与水解酸化液1的氧化后沼液的回用入口19对接。The biogas slurry oxidation device is a biogas
在本实施例中,厌氧消化反应器7的进料口8距反应器底部50cm,厌氧消化反应器7中设有叶片搅拌器11,叶片搅拌器11的驱动电机10位于厌氧消化反应器7顶部中央。在沼液氧化池14中位于沼液进料口一端的氧化区为第一氧化区,至少一个微孔曝气头16位于第一氧化区的底部,也可以根据实际情况在每个氧化区的底部多点布置。In this embodiment, the feed port 8 of the
在本实施例中,所述的水解酸化反应池1由3个并联的水解酸化基本单元组成,所述的折流遮挡板17将沼液氧化池分割为4个氧化区。In this embodiment, the hydrolytic
在本实施例中,所述的沼气处理装置由沼气贮气罐20、脱水塔21、脱硫塔22、沼气增压机23组成,沼气贮气罐20与厌氧消化反应器7的沼气输出口12连接,沼气贮气罐20、脱水塔21、脱硫塔22依次串接后,由沼气增压机23与沼气用户连接。In this embodiment, the biogas treatment device is composed of a
具体实施时,沼液氧化池14深度不超过1000mm,水解酸化池1、厌氧消化反应器7、沼液氧化池14的体积比为2~5∶1∶0.2~0.5。During specific implementation, the depth of the biogas
具体实施时,所述的水解酸化反应池1的水解酸化液出口4高于水解液收集池5的收集池最大容纳量的设计液面,沼液氧化池14的被氧化沼液出料口18高于水解酸化液池1的氧化后沼液的回用入口19,依靠水位差自流入水解酸化反应池1。在此前提下,水解液收集池5可以置于地下,或水解酸化液1和水解液收集池5都置于地下。During specific implementation, the hydrolytic
具体实施时,还可以将所述的水解酸化反应池1和沼液氧化池14都设在地下或地上,沼液氧化池14的被氧化沼液出料口18与水解酸化液1的氧化后沼液的回用入口19之间通过压力泵相互沟通。During specific implementation, the hydrolytic
本实用新型的运行过程是:首先准备好水解酸化池1所需的好氧活性污泥和厌氧发酵池7所需的厌氧活性污泥,其中好氧活性污泥采用污水处理厂好氧活性污泥与新鲜牛粪混合(质量比为5-10∶1),间隔曝气充氧两周后备用,而厌氧活性污泥则直接采集运行良好沼气工程的沼渣沼液即可,加入量以维持反应器7中浓度以5kgVS·m-3左右为宜(即每立方米混合液中含有5公斤左右的挥发性有机物),经过不断少量多次添加秸秆浸泡液使该厌氧活性污泥适应待处理原料特性,从而使污泥中形成消化性能良好的颗粒状污泥(即沉降性能良好的微生物菌团),此过程通常称为厌氧发酵过程的启动阶段或污泥驯化阶段,一般周期为15-45天。待上述准备工作完毕后开始向水解酸化池1的第一格中依次分层加入农村废弃物和好氧污泥,加入好氧活性污泥的量按照废弃物∶污泥(干物质比)为1∶0.2-0.5(可依据农村废弃物的处理量而定),相间1~2天向第2格按照相同的方法加入物料,再间隔1~2天,第3格按照相同的方法加入物料......依次继续向后续各格中添加物料,直至最后一格。然后加水淹没浸泡至少1-2天后,打开水解酸化池1中第一格的水解酸化出口4的阀门,使水解液汇入收集池5中,然后通过提升泵6将其从水解液进料口8泵入厌氧消化反应器7中,同时消化完毕后的沼液通过沼液溢流口9流出,进出料完毕后关闭水解液进料口8和沼液溢流口9,开启电动机10驱动的叶片搅拌机11,叶片的转速低于30转/分,以使反应器7中的物料充分混合,每天可开启电动机2-3次,每次不超过10分钟。打开水解酸化池1中第二格的水解液出水4的阀门,使水解液汇入收集池5中,然后通过提升泵6将其从水解液进料口8泵入厌氧消化反应器7中,同时开启沼液溢流口9的阀门,沼液经沼液溢流口9流出后,由过滤器13将悬浮物去除掉后流入沼液氧化池14中,首先经过增氧装置15(如曝气充氧机)和微孔曝气头16进行充氧后,使沼液中残留的产甲烷菌与氧气接触而被杀灭,并经迂回的折流遮挡板17作用,停迂回后达到净化目的后备用。而水解酸化池1中物料由于大量水解液被抽出导致水位下降,可打开水解酸化池1顶部的遮雨棚,水解酸化池1第一格中水解完毕的废料可以采用人工或机械清理出(经过沥水处理),加入一定量的农村废弃物,然后打开净化后沼液出口18与沼液的回用入口19之间的阀门,使消化完毕的沼液回用来弥补先前水解酸化池1第一格中水的需求,而此处沼液经过前期氧化处理后已基本无产甲烷菌,因此进入水解酸化池1第一格中基本不会产生甲烷,从而避免了甲烷泄露。可见,在整个工作过程中,水解酸化池1中只有一格处于清理和添加物料,一格处于提供水解酸化液,其他各格处于水解酸化反应的交替工作状态,各格的水解酸化液依序间隔相继进入厌氧消化反应器7,而含有厌氧菌的沼液经过沼液氧化池14处理后又引入水解酸化池1中刚刚添加物料的相应格。The operation process of the utility model is: first prepare the aerobic activated sludge required by the
从水解酸化池1中各格取出的水解酸化后的物料还可以继续用做有机肥或基质生产原料,而整个系统中也可以实现沼液零排放。The hydrolyzed and acidified materials taken out from each compartment of the hydrolyzed
从上述而实现循环利用的实施例仅以水解酸化池1和水解液汇入收集池5为地下式,而厌氧消化反应器7和沼液氧化池14均为地上式,工作过程中主要是靠液体重力自流,如果厌氧消化反应器7、沼液氧化池14和水解酸化池1以及水解液汇入收集池5受环境限制,工作中液体无法实现重力自流,则需增添压力泵强制液体遵守本实用新型的特定流向。The embodiment that realizes recycling from the above only takes the
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102260019A (en) * | 2011-05-25 | 2011-11-30 | 衢州市土肥与农村能源技术推广站 | Separated two-phase anaerobic fermentation device |
| CN105062869A (en) * | 2015-07-31 | 2015-11-18 | 符放中 | Zero-residue biogas fermentation apparatus and application and biogas production method thereof |
| CN106517714A (en) * | 2016-11-30 | 2017-03-22 | 四川宏基博业企业管理有限公司 | Efficient livestock excrement biogas manure pool |
| CN112342124A (en) * | 2020-12-28 | 2021-02-09 | 中国农业科学院农业环境与可持续发展研究所 | Dry-semi-dry-wet method collaborative biogas production device and operation method |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102260019A (en) * | 2011-05-25 | 2011-11-30 | 衢州市土肥与农村能源技术推广站 | Separated two-phase anaerobic fermentation device |
| CN105062869A (en) * | 2015-07-31 | 2015-11-18 | 符放中 | Zero-residue biogas fermentation apparatus and application and biogas production method thereof |
| CN106517714A (en) * | 2016-11-30 | 2017-03-22 | 四川宏基博业企业管理有限公司 | Efficient livestock excrement biogas manure pool |
| CN106517714B (en) * | 2016-11-30 | 2019-06-18 | 衢州佳苑牧业有限公司 | A kind of efficient feces of livestock and poultry biogas residue-biogas liquid pool |
| CN112342124A (en) * | 2020-12-28 | 2021-02-09 | 中国农业科学院农业环境与可持续发展研究所 | Dry-semi-dry-wet method collaborative biogas production device and operation method |
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