CN201545788U - Furnace transmutation polished glaze brick - Google Patents

Furnace transmutation polished glaze brick Download PDF

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Publication number
CN201545788U
CN201545788U CN2009201790365U CN200920179036U CN201545788U CN 201545788 U CN201545788 U CN 201545788U CN 2009201790365 U CN2009201790365 U CN 2009201790365U CN 200920179036 U CN200920179036 U CN 200920179036U CN 201545788 U CN201545788 U CN 201545788U
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glaze
layer
frit
brick
transmutation
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CN2009201790365U
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陈满坚
唐纳德·温·黑格比
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Abstract

The utility model discloses a polished glaze brick which comprises a brick adobe, a clinkerclue layer which is sintered on the upper surface of the brick adobe, and a furnace transmutation glaze layer which is formed by furnace transmutation reaction between the clinkerclue layer and glaze materials. The surface of the clinkerclue layer of a ceramic brick manufactured by the utility model reacts with glaze materials of a decorative glaze layer, the form of shapes and colors of patterns not only depends on polished materials printed on patterns, but also is influenced by post-reacting results of the surface of the clinkerclue layer and the glaze materials. The boundary between different color pieces is fuzzy, the transition is natural, and the polished glaze brick has mature, noble and luxuriant sense of beauty.

Description

A kind of Fambe glaze-polished brick
Technical field
The utility model relates to a kind of ceramic, relates in particular to throw the glazed brick product technical field.
Background technology
The application scenario of ceramic is very wide, is example with the ceramic tile only, just can be widely used in wall, ground, can be used for the large-area laying in household or office space, also can be used for the decorative wall of small area, or decoration painting.Different application scenarios needs the product of different-style.
Publication number is CN1197043A, denomination of invention discloses the making method of a kind of noctilucence screen printing glaze and printed luminous ornamental brick thereof for the Chinese invention patent application of " making method of noctilucence screen printing glaze and printed luminous ornamental brick thereof ", it has adopted three firing process of the roasting burning of the biscuiting of porcelain base, glaze firing and luminous glaze, the product brightness height that makes, time of persistence is long, can in the dark send colorama after irradiation.
Publication number is CN1281778A, denomination of invention discloses a kind of production method of crystal accumulated relief brick for the Chinese invention patent application of " a kind of production method of crystal accumulated relief brick ", this method is utilized the fusion of frit milkiness frit when high-temperature fusion and is flowing in the formation of product embossed portion branch and contains the decorative pattern combination that is similar to the brilliant flower of crystalline glaze, the product embossment of producing partly has unique brilliant naturally flower, and stereoscopic sensation is strong.
Publication number is CN100387545C, denomination of invention discloses a kind of manufacture method of wrapping up the stone imitation pattern glazed ceramic brick of painted art based on frit for the Chinese invention patent of " wrapping up the manufacture method of the stone imitation pattern glazed ceramic brick of painted art based on frit ", be through spraying with the color glaze slip, showering or get rid of mode such as spill is applied to the glass frit surface, then through super-dry, form the integument that necessarily has thickness on the frit surface, it is long-pending to ceramic adobe according to pre-designed scheme shop then will to wrap up painted frit, restock applies the viscosity aqueous slurry, the frit granular layer is adhesively fixed on the ceramic adobe, drying again, burn till, technologies such as rubbing down form the pattern with lithotome appearance effect.
For another example, publication number is CN1644559, denomination of invention discloses the manufacture craft that a kind of metallizing is thrown glazed brick for the Chinese invention patent of " a kind of metallizing is thrown glaze ceramic and manufacture craft thereof ", be characterized in: the stamp cream that earlier glaze is modulated into is printed on the brick embryo by the web plate of scribing into pattern, printing transparent frit powder on pattern again, once-firing carries out polished finish then then.Prepared product pattern is clear, boundary is clearly demarcated between pattern, stereoscopic sensation is strong.In making processes, chemical reaction does not take place in frit powder and glaze.Frit powder can make product more be rich in stereoscopic sensation, but itself does not constitute the integral part of pattern, just plays the pattern that glaze is printed to and is fixed on effect on the brick embryo.In order clearly to appear pattern and color, frit powder must adopt transparent frit powder.Can successfully produce the ceramic that color and luster is good, stereoscopic sensation is strong, pattern line is clear and distinctive according to foregoing invention, satisfy the market requirement of certain aspect.
But the demand in market is diversified, thereby the producer need constantly research and develop and innovate and could satisfy even create the diversified market requirement.
Summary of the invention
The purpose of this utility model is to fill up the part blank of prior art, provides a kind of pattern and color to have nature and mixes color gradient exquisiteness, the throwing glazed brick that gradation sense is strong.
In order to achieve the above object, the utility model has adopted following technical scheme: a kind of throwing glazed brick is characterized in that: comprise brick embryo, the frit layer of thermal sintering above the brick embryo and carry out transmutation by frit layer and glaze and react the transmutation glaze layer that forms.
The ceramic tile that the utility model is made, the frit layer surface takes place to send out with the glaze of decorating the glaze layer under the high temperature of kiln should, the glaze of printing is not only depended in the shape of pattern and the formation of color, also be subjected to frit layer surface and glaze take place to send out should after the result and influence.The influence of being reacted, the obscurity boundary between the different color blocks, transition nature has maturation, noble quality, magnificent aesthetic feeling.The ceramic tile good decorating effect of made can be used as arranging of rule, also can design according to large-scale ground/wall, and lay out the subject scenes with strong visual effect.The utlity model has vast market prospect and good economic and social benefit.
Description of drawings
Fig. 1 is the finished product structure iron of embodiment 1.
Fig. 2 is the finished product structure iron of embodiment 2.
Fig. 3 is the finished product structure iron of embodiment 3.
Fig. 4 is the finished product structure iron of embodiment 4.
Fig. 5 is the finished product structure iron of embodiment 5.
Fig. 6 is the finished product structure iron of embodiment 6.
Fig. 7 is the finished product structure iron of embodiment 7.
Embodiment
Embodiment 1
As shown in Figure 1, bottom is a brick embryo 1, be covered on the brick embryo for frit layer 2, uppermost be transmutation glaze layer 3 through polishing.
Produce according to following processing step successively:
(1) surface treatment is carried out in adobe 1;
(2) modulate frit powder, according to the web plate that has made the frit powder that modulates is printed on the brick face and forms pattern, carry out then burning till the first time;
Frit powder can adopt transparent frit powder, also can adopt opaque frit powder, and its color is selected according to the needs of design.The powder fineness of frit powder is 80~200 orders, and major ingredient is made of Boroalumino silicate glasses, and in this example, its major ingredient is expressed as follows with glaze formula:
The order number of frit paving silk screen is 40~60 orders, and the frit layer gauge control is at 0.3~5.0mm.
The temperature of burning till is 850~1050 ℃, and firing time is 60~90 minutes.Burn till the pattern that frit powder is formed and be fixed on brick embryo surface formation frit layer 2.
(3) according to the web plate that made at the deployed glaze of above-mentioned frit layer 2 surface printings, the firing range that requires glaze carries out burning till the second time in the fusion range of frit powder then;
The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.In kiln, frit powder at high temperature can melt, and with glaze generation high-temperature chemical reaction, forms transmutation glaze layer 3.The condition that takes place about transmutation reaction, " ceramic technology " that can compile in collaboration with referring to Huanan (South China) Polytechnic College, Nanjing Chemical Engineering College, building of wuhan material technology institute.Because the kind of glaze and different positions are printed the difference of thickness, so also there is difference in its degree of carrying out with the reaction on frit top layer, thereby the aberration of formation color gradient makes a kind of natural mixed effect of formation between the different colours.
(4) surface finish;
The reacted surface of semi-finished of glaze in the above-mentioned steps and frit top layer is carried out polished finish.Because the reaction of frit and glaze is along with the depth of living in position is different, the degree that reaction is carried out is also different, so also difference of the depth of color.The dark and shallow of polished finish also can exert an influence to the color of product surface.According to designing requirement, set the shade that the suitable polished finish degree of depth just can be controlled finished surface.
Through further finally obtaining finished product behind the pick.Finished bricks surface smoothing, color transition nature has noble quality, magnificent style.
Embodiment 2
As shown in Figure 2, bottom is a brick embryo 1, be covered on the brick embryo for frit layer 2, uppermost be transmutation glaze layer 3 through polishing, the depression of frit layer is interior to be another glaze layer 4.
Produce according to the following steps,
(1) surface treatment is carried out in adobe 1;
(2) modulate frit powder, according to the web plate that has made the frit powder that modulates is printed on the brick face and forms pattern, the sunk part in pattern is then left a blank, and carries out then burning till the first time, forms the frit layer 2 that has depression 22 and frit 21; The degree of depth of depression is mainly determined by the thickness of frit layer;
The prescription of frit powder can be identical with example 1 also can be different.The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.Burn till the pattern that frit powder is formed and be fixed on brick embryo surface formation frit layer 2.
(3) according to the web plate that made at the deployed glaze of above-mentioned frit layer surface printing, then leave a blank for the position of depression, carry out then burning till second time, form the transmutation glaze layer 3 of formation after glaze and the frit layer reaction;
The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.
(4) print another kind of glaze according to the web plate that has made at the formed sunk surface of above-mentioned steps, burn till for the third time then, form glaze layer 4;
The temperature of burning till is 750~950 ℃, and firing time is 60~90 minutes.This temperature of burning till is lower slightly than the temperature of last time burning till.
According to the needs of design, can also carry out once more direct colour print and burning till once more, to obtain the decorative effect of expection.
(5) surface finish;
Surface of semi-finished after burning till is carried out polished finish.According to designing requirement, thereby the shade of the degree of depth control finished surface of control polishing is to reach the effect of design.
Obtain product as shown in Figure 2.
Embodiment 3
As shown in Figure 3, bottom is a brick embryo 1, be covered on the brick embryo for frit layer 2, uppermost be transmutation glaze layer 3 through polishing, the depression of frit layer is interior to be metal plating 5.
Produce according to the following steps,
(1) surface treatment is carried out in the adobe among Fig. 31;
(2) modulate frit powder, according to the web plate that has made the frit powder that modulates is printed on the brick face and forms pattern, the sunk part in pattern is then left a blank, and carries out then burning till the first time, forms the frit layer 2 that has depression 22 and frit 21;
The prescription of frit powder can be identical or different with example 1 or example 2.The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.Burn till the pattern that frit powder is formed and be fixed on brick embryo surface formation frit layer 2.
(3) according to the web plate that made at the deployed glaze of above-mentioned frit layer surface printing, then leave a blank for the position of depression, carry out then burning till second time, form the transmutation glaze layer 3 of formation after glaze and the frit layer reaction;
The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.
(4) adopt the multi-arc ion coating method to plate metal level 5,, make metal plating cover the half-finished ceramic tile surface of monoblock (comprising that depression partly) as titanium, titanium silver etc. on half-finished whole surface.
(5) surface finish, promptly the transmutation glaze of surface of semi-finished part and top coating thereof are carried out polished finish, the grasp of the polishing degree of depth is will be with transmutation glaze laminar surface coating jettisoning, make and expose transmutation glaze layer after the polishing and control the depth of color well to reach designing requirement, the effect after sunk part then keeps plating.
Obtain product as shown in Figure 3.
Embodiment 4
As shown in Figure 4, bottom is a brick embryo 1, be covered on the brick embryo for frit layer 2, uppermost be transmutation glaze layer 3 through polishing, is glaze layer 4 and covering metal plating 5 thereon in the depression of frit layer.
Produce according to the following steps,
(1) surface treatment is carried out in the adobe among Fig. 41;
(2) modulate frit powder, according to the web plate that has made the frit powder that modulates is printed on the brick face and forms pattern, the sunk part in pattern is then left a blank, and carries out then burning till the first time, forms the frit layer 2 that has depression 22 and frit 21; The degree of depth of depression is mainly determined by the thickness of frit layer;
The prescription of frit powder can be identical or different with precedent.The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.Burn till the pattern that frit powder is formed and be fixed on brick embryo surface formation frit layer 2.
(3) according to the web plate that made at the deployed glaze of above-mentioned frit layer surface printing, then leave a blank for the position of depression, carry out then burning till second time, form the transmutation glaze layer 3 of formation after glaze and the frit layer reaction;
The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.
(4) print another kind of glaze according to the web plate that has made at the formed sunk surface of above-mentioned steps, burn till for the third time then, form glaze layer 4;
The temperature of burning till is 750~950 ℃, and firing time is 60~90 minutes.This temperature of burning till is lower slightly than the temperature of last time burning till.
(5) adopt the multi-arc ion coating method to plate metal level,, make metal plating 5 cover the half-finished ceramic tile surface of monoblock (comprising that depression partly) as titanium, titanium silver etc. on half-finished surface;
(6) surface finish, promptly the transmutation glaze layer of surface of semi-finished part and top coating thereof are carried out polished finish, the grasp of the polishing degree of depth is the overlay coating jettisoning will be made to expose transmutation glaze layer after the polishing and control the depth of color well to reach designing requirement, effect after sunk part then keeps plating obtains product as shown in Figure 4.
Embodiment 5
As shown in Figure 5, bottom is a brick embryo 1, be covered on the brick embryo for frit layer 2, uppermost be transmutation glaze layer 3 through polishing, the sunk part of frit layer is keeping adobe 1 original color.
Produce according to the following steps,
(1) surface treatment is carried out in the adobe among Fig. 51;
(2) modulate frit powder, according to the web plate that has made the frit powder that modulates is printed on the brick face and forms pattern, the sunk part in pattern is then left a blank, and carries out then burning till the first time, forms the frit layer 2 that has depression 22 and frit 21;
The prescription of frit powder can be identical or different with precedent.The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.Burn till the pattern that frit powder is formed and be fixed on brick embryo surface formation frit layer 2.
(3) according to the web plate that made at the deployed glaze of above-mentioned frit layer surface printing, then leave a blank for the position of depression, carry out then burning till second time, form the transmutation glaze layer 3 of formation after glaze and the frit layer reaction;
The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.
(4) surface finish, promptly the transmutation glaze to the surface of semi-finished part carries out polished finish, obtains product as shown in Figure 5, and wherein at sunk part, owing to do not covered by glaze layer or frit powder, what therefore display is the adobe 1 original color that has.
Embodiment 6
As shown in Figure 6, bottom is a brick embryo 1, be covered on the brick embryo for frit layer 2, uppermost be transmutation glaze layer 3 through polishing, is glaze layer 4 and covering clear frit thin layer 6 thereon in the depression of frit layer.
Produce according to the following steps,
(1) surface treatment is carried out in the adobe among Fig. 61;
(2) modulate frit powder, according to the web plate that has made the frit powder that modulates is printed on the brick face and forms pattern, the sunk part in pattern is then left a blank, and carries out then burning till the first time, forms the frit layer 2 that has depression 22 and frit 21;
The prescription of frit powder can be identical or different with precedent.The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.Burn till the pattern that frit powder is formed and be fixed on brick embryo surface formation frit layer 2.
(3) according to the web plate that made at the deployed glaze of above-mentioned frit layer surface printing, then leave a blank for the position of depression, carry out then burning till second time, form the transmutation glaze layer 3 of formation after glaze and the frit layer reaction;
The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.
(4) decorate glaze according to the web plate that has made at the formed sunk surface printing of above-mentioned steps another kind, and on this glaze layer 4, cover a clear frit thin layer 6, burn till for the third time then; The transmutation reaction does not take place in clear frit layer in the depression and glaze layer, and the color that manifests in the depression is the color that glaze layer 4 is had, and therefore the frit powder of selecting for use is the clear frit powder;
The temperature of burning till is 750~950 ℃, and firing time is 60~90 minutes.This temperature of burning till is lower slightly than the temperature of last time burning till.
(5) as required, whether decision plates metal level on half-finished surface again, as titanium, titanium silver etc.
(6) surface finish, promptly transmutation glaze and the top coating thereof to the surface of semi-finished part carries out polished finish, the grasp of the polishing degree of depth is the overlay coating jettisoning will be made to expose transmutation glaze layer after the polishing and control the depth of color well to reach designing requirement, effect after sunk part then keeps plating obtains product as shown in Figure 6.
Embodiment 7
As shown in Figure 7, bottom is a brick embryo 1, be covered on the brick embryo for frit layer 2, uppermost be transmutation glaze layer 3 through polishing, is frit thin layer 7 and covering transmutation glaze layer 8 thereon in the depression of frit layer.
Produce according to the following steps,
(1) surface treatment is carried out in the adobe among Fig. 71;
(2) modulate frit powder, according to the web plate that has made the frit powder that modulates is printed on the brick face and forms pattern, the sunk part in pattern is then left a blank, and carries out then burning till the first time, forms the frit layer 2 that has depression 22 and frit 21;
The prescription of frit powder can be identical or different with precedent.The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.Burn till the pattern that frit powder is formed and be fixed on brick embryo surface formation frit layer 2.
(3) according to the web plate that made at the deployed glaze of above-mentioned frit layer surface printing, then leave a blank for the position of depression, carry out then burning till second time, form the transmutation glaze layer 3 of formation after glaze and the frit layer reaction;
The temperature of burning till is 950~1050 ℃, and firing time is 60~90 minutes.
(4) cover frit thin layer 7 according to the web plate that has made at the formed sunk surface of above-mentioned steps, and on this frit thin layer 7, cover another decoration glaze layer, burn till for the third time then, form the transmutation glaze layer 8 in the depression 22;
Selected frit powder can be identical or different with the selected frit powder of master pattern frit layer 2 in the depression, can select clear frit powder or opaque frit powder for use.
The temperature of burning till is 750~950 ℃, and firing time is 60~90 minutes.This temperature of burning till is lower slightly than the temperature of last time burning till.
(5) as required, whether decision plates metal level on half-finished surface again, as titanium, titanium silver etc.
(6) surface finish, promptly the transmutation glaze layer to the surface of semi-finished part carries out polished finish, and sunk part then keeps unpolished effect, obtains product as shown in Figure 7.

Claims (7)

1. Fambe glaze-polished brick is characterized in that: comprise brick embryo, the frit layer of thermal sintering above the brick embryo and carry out transmutation by frit layer and glaze and react the transmutation glaze layer that forms.
2. throwing glazed brick according to claim 1 is characterized in that: described frit layer comprises the main body pattern that formed by the frit powder sintering and the depression between the main body pattern.
3. throwing glazed brick according to claim 2 is characterized in that: fill glaze in the described depression.
4. throwing glazed brick according to claim 2 is characterized in that: filler metal coating in the described depression.
5. throwing glazed brick according to claim 3 is characterized in that: be coated with metal plating on the glaze layer in the described depression.
6. throwing glazed brick according to claim 2 is characterized in that: have the glaze of filling in the described depression, and be coated with a clear frit layer on the glaze of described filling.
7. throwing glazed brick according to claim 2 is characterized in that: a frit thin layer is arranged in the described depression, reach one by this frit thin layer and the back transmutation glaze layer that forms of glaze transmutation reaction that is covered on the frit thin layer.
CN2009201790365U 2009-06-22 2009-09-16 Furnace transmutation polished glaze brick Expired - Fee Related CN201545788U (en)

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CN2009201790365U CN201545788U (en) 2009-06-22 2009-09-16 Furnace transmutation polished glaze brick

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102505822A (en) * 2011-10-11 2012-06-20 信益陶瓷(中国)有限公司 Ceramic tile with gold-plated surface and manufacturing method thereof
CN107216167A (en) * 2016-03-21 2017-09-29 何赋森 A kind of trailing of ceramic furnace transmutation glaze

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102505822A (en) * 2011-10-11 2012-06-20 信益陶瓷(中国)有限公司 Ceramic tile with gold-plated surface and manufacturing method thereof
CN102505822B (en) * 2011-10-11 2013-12-11 信益陶瓷(中国)有限公司 Ceramic tile with gold-plated surface and manufacturing method thereof
CN107216167A (en) * 2016-03-21 2017-09-29 何赋森 A kind of trailing of ceramic furnace transmutation glaze

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Granted publication date: 20100811

Termination date: 20170916