CN102505822A - Ceramic tile with gold-plated surface and manufacturing method thereof - Google Patents

Ceramic tile with gold-plated surface and manufacturing method thereof Download PDF

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Publication number
CN102505822A
CN102505822A CN2011103057366A CN201110305736A CN102505822A CN 102505822 A CN102505822 A CN 102505822A CN 2011103057366 A CN2011103057366 A CN 2011103057366A CN 201110305736 A CN201110305736 A CN 201110305736A CN 102505822 A CN102505822 A CN 102505822A
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China
Prior art keywords
gold
ceramic tile
cream
plated
manufacturing
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CN2011103057366A
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CN102505822B (en
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李小平
蒋平平
阎崔蓉
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Seagull Champion Co Ltd
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XINYI CERAMIC (CHINA) CO Ltd
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Abstract

The invention discloses a ceramic tile with a gold-plated surface. The ceramic tile consists of a blank body, an enamel layer and a surface plating layer, and is characterized in that the surface plating layer is a gold plating layer. The invention simultaneously discloses a manufacturing method of the ceramic tile with the gold-plated surface, wherein the manufacturing method comprises the following steps of: manufacturing a blank brick body, manufacturing molten gold, plating gold on the ceramic tile and the like. The ceramic tile with the gold-plated surface, which is manufactured by the manufacturing method disclosed by the invention, has the characteristics of excellent oxidation resistance, sudden cold and hot alternation resistance, wear resistance and the like, can be used for greatly enriching the effects and decorative effects of products and better showing luxurious, rich and honor effects in use.

Description

A kind of ceramic tile and manufacturing approach thereof of surface plating gold
Technical field
The invention belongs to building material field, particularly relate to a kind of ceramic tile and manufacturing approach thereof of surface plating gold.
Background technology
Along with the enhancing of china's overall national strength, the people's living standard improves constantly, and people have had higher requirement to the life class of oneself.Ceramic tile is as one of essential ornament materials of building trade, and is closely bound up with people's life especially.People pay attention to the lifting of class especially when decorating oneself tame.When gold all is rich and honour, luxurious representative, very popular, and gold is incorporated to ceramic tile, has attracted customer's eyeball especially.Also really be not coated with the ceramic tile of gold in the existing product.
Summary of the invention
The object of the invention is to provide to existing product the ceramic tile and the manufacturing approach thereof of the surface plating gold that a kind of surface has the sense of gold color and luster.
The present invention adopts following technical scheme for realizing above-mentioned purpose:
A kind of ceramic tile of surface plating gold, it is by base substrate, and glaze layer and overlay coating are formed, and it is characterized in that: said overlay coating is a gold coating.
The main composition of said base substrate, middle aluminum pyrophyllite: 10%~15%, high aluminum pyrophyllite: 20%~25%, diopside: 15%~20%, white clay soil: 15%~20%, the soil of realizing: 15%~20%, quartz sand: 3%~5%, high-al clay: 8%~10%.
The main composition of said glaze layer glaze, the zirconium white frit: 45%~50%, potassic feldspar: 15%~20%, dolomite: 5%~10%, kaolin: 20%~25%, ball clay: 10%~15%.
Said gold coating is that gold cream is plated to, and it is mainly formed, gold: 8%~15%, and chloroazotic acid: 30%~50%, thickener: 0.5%~2%, alcohol: 2%~5%, alkali: 30%~50%.
A kind of manufacturing approach of ceramic tile of surface plating gold comprises the following steps:
(1) plain adobe system is done:
By the prescription of each raw material, to put in the ball mill in proportion and grind, fineness of grind leaks into heavy rotten 24h in the mud pit with mud after reaching 5.5 ± 0.5g/100mg; Again with 580 ℃ of heated-air dryings of spray drying tower, form moisture content at 5.8 ± 0.3% powder particle, reenter the powder bucket and store heavy rotten 24h; Be transported to press through conveyer belt and carry out operations for forming; Be pressed into base substrate and after drying, carry out glazing, printing, reenter kiln and burn till, firing temperature is controlled at 1180 ± 10 ℃; Firing period is promptly processed plain brick at 65min;
(2) making of gold cream:
The true yellow gold is dissolved in the wang aqueous solution according to prescription; Through fully carrying out neutralization reaction with alkali again after the dissolving, neutralization reaction back is fully carried out rinsing with alcohol, filters after leaving standstill 8h; Add the viscosity number that thickener is adjusted to requirement behind the elimination impurity and get final product, viscosity number is controlled at about 800pas;
(3) ceramic tile is gold-plated:
Pattern is processed half tone; Gold cream is printed on ceramic tile surface with rubber squeegee; A kind of mode prints to gold cream on the transferable paper, and the marble paper that will be printed on gold cream again is plated to ceramic tile surface, and the ceramic tile that is coated with gold cream is burnt till, solidifies through 800 ℃ of low temperature; With the ceramic tile surface fusion, promptly become the gold-plated ceramic tile of the present invention.
The ceramic tile of the present invention's surface plating gold has good anti-oxidant, and anti-characteristic such as sometimes hot and sometimes cold, wear-resisting has been enriched effect, the decoration of product greatly, uses the effect that more can embody luxury, wealth and rank.
Description of drawings
Fig. 1 is a sketch map of the present invention;
1, idiosome; 2, glaze layer; 3, overlay coating.
The specific embodiment
The ceramic tile of a kind of surface plating gold as shown in Figure 1, it is by base substrate 1, and glaze layer 2 is formed with overlay coating 3, and said overlay coating is a gold coating.
The concrete manufacturing approach of the present invention is following:
1, the base substrate constitutive material is cooperated in following ratio: middle aluminum pyrophyllite: 10%~15%, high aluminum pyrophyllite: 20%~25%, diopside: 15%~20%, white clay soil: 15%~20%, the soil of realizing: 15%~20%, quartz sand: 3%~5%, high-al clay: 8%~10%.Put in the ball mill and grind, fineness of grind leaks into heavy rotten 24h in the mud pit with mud after reaching 5.5 ± 0.5g/100mg, again with 580 ℃ of heated-air dryings of spray drying tower; Form moisture content at 5.8 ± 0.3% powder particle, reenter the powder bucket and store heavy rotten 24h, be transported to press through conveyer belt and carry out operations for forming; Be pressed into base substrate and after drying, carry out glazing, printing, reenter kiln and burn till, firing temperature is controlled at 1180 ± 10 ℃; Firing period is promptly processed plain brick at 65min.
2, the constitutive material with gold cream cooperates in following ratio: gold: 8%~15%, and chloroazotic acid: 30%~50%, thickener: 0.5%~2%, alcohol: 2%~5%, alkali: 30%~50%.The true yellow gold is dissolved in the wang aqueous solution according to prescription; Through fully carrying out neutralization reaction with alkali again after the dissolving; Neutralization reaction fully back is carried out rinsing with alcohol, filters after leaving standstill 8h, adds the viscosity number that thickener is adjusted to requirement behind the elimination impurity and gets final product; Viscosity number is controlled at 800pas, makes gold cream.
3, glazing on base substrate is burnt till the back and is become biscuit.
4, prepared gold cream is plated in the top layer; Carry out as follows: pattern is processed half tone, gold cream is printed on ceramic tile surface with rubber squeegee, a kind of mode prints to gold cream on the transferable paper; The marble paper that will be printed on gold cream again is plated to ceramic tile surface; The ceramic tile that is coated with gold cream is burnt till, solidifies through 800 ℃ of low temperature,, promptly become the gold-plated ceramic tile of the present invention with the ceramic tile surface fusion.

Claims (5)

1. the ceramic tile of a surface plating gold, it is by base substrate, glaze layer and overlay coating composition, it is characterized in that: said overlay coating is a gold coating.
2. the ceramic tile of a kind of surface plating gold according to claim 1 is characterized in that: the main composition of said base substrate, middle aluminum pyrophyllite: 10%~15%; High aluminum pyrophyllite: 20%~25%; Diopside: 15%~20%, white clay soil: 15%~20%, the soil of realizing: 15%~20%; Quartz sand: 3%~5%, high-al clay: 8%~10%.
3. the ceramic tile of a kind of surface plating gold according to claim 1 is characterized in that: the main composition of said glaze layer glaze, zirconium white frit: 45%~50%; Potassic feldspar: 15%~20%; Dolomite: 5%~10%, kaolin: 20%~25%, ball clay: 10%~15%.
4. the ceramic tile of a kind of surface plating gold according to claim 1, it is characterized in that: said gold coating is that gold cream is plated to, and it is mainly formed; Gold: 8%~15%, chloroazotic acid: 30%~50%, thickener: 0.5%~2%; Alcohol: 2%~5%, alkali: 30%~50%.
5. the manufacturing approach of the ceramic tile of a surface plating gold comprises the following steps:
(1) plain adobe system is done:
By the prescription of each raw material, to put in the ball mill in proportion and grind, fineness of grind leaks into heavy rotten 24h in the mud pit with mud after reaching 5.5 ± 0.5g/100mg; Again with 580 ℃ of heated-air dryings of spray drying tower, form moisture content at 5.8 ± 0.3% powder particle, reenter the powder bucket and store heavy rotten 24h; Be transported to press through conveyer belt and carry out operations for forming; Be pressed into base substrate and after drying, carry out glazing, printing, reenter kiln and burn till, firing temperature is controlled at 1180 ± 10 ℃; Firing period is promptly processed plain brick at 65min;
(2) making of gold cream:
The true yellow gold is dissolved in the wang aqueous solution according to prescription; Through fully carrying out neutralization reaction with alkali again after the dissolving, neutralization reaction back is fully carried out rinsing with alcohol, filters after leaving standstill 8h; Add the viscosity number that thickener is adjusted to requirement behind the elimination impurity and get final product, viscosity number is controlled at about 800pas;
(3) ceramic tile is gold-plated:
Pattern is processed half tone; Gold cream is printed on ceramic tile surface with rubber squeegee; A kind of mode prints to gold cream on the transferable paper, and the marble paper that will be printed on gold cream again is plated to ceramic tile surface, and the ceramic tile that is coated with gold cream is burnt till, solidifies through 800 ℃ of low temperature; With the ceramic tile surface fusion, promptly become the gold-plated ceramic tile of the utility model.
CN2011103057366A 2011-10-11 2011-10-11 Ceramic tile with gold-plated surface and manufacturing method thereof Active CN102505822B (en)

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CN102505822B CN102505822B (en) 2013-12-11

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104150871A (en) * 2014-08-06 2014-11-19 苏州科德溯源仪器有限公司 Fullerene reinforced ceramic tile
CN104193292A (en) * 2014-08-06 2014-12-10 苏州科德溯源仪器有限公司 Carbon nano tube enhanced ceramic tile
CN104999821A (en) * 2015-07-10 2015-10-28 祥和彩瓷制造(上海)有限公司 Preparation method of high-temperature friction gold stained paper and high-temperature friction gold stained paper
CN111960672A (en) * 2020-07-08 2020-11-20 湖南省醴陵市特种电瓷电器有限公司 Glaze for 95 porcelain surface, 95 porcelain and manufacturing method
CN112405795A (en) * 2020-11-30 2021-02-26 王金听 Preparation method of Jun porcelain with metal patterns on surface

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990011985A1 (en) * 1989-04-04 1990-10-18 Hatten Limited Surface treatment method for ceramic articles
CN2206291Y (en) * 1994-04-29 1995-08-30 金晖 Multicolour ceramic tile with titanium-plating chemical compound on surface
CN1219521A (en) * 1997-12-10 1999-06-16 董英助 Method for coating surface of ceramic tile with noble metal
CN1887606A (en) * 2006-07-18 2007-01-03 杨仕学 Production process of building decorating glazed tile with golden patterns
CN201545788U (en) * 2009-06-22 2010-08-11 陈满坚 Furnace transmutation polished glaze brick
CN201843292U (en) * 2010-08-16 2011-05-25 广东道氏标准制釉股份有限公司 Ceramic glazed brick with gold metal effect
CN102181834A (en) * 2011-03-08 2011-09-14 深圳市金华威进出口有限公司 Method for electroplating imitation gold on glaze of enamel product and enamel product
CN202299247U (en) * 2011-10-11 2012-07-04 信益陶瓷(中国)有限公司 Ceramic tile coated with gold

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990011985A1 (en) * 1989-04-04 1990-10-18 Hatten Limited Surface treatment method for ceramic articles
CN2206291Y (en) * 1994-04-29 1995-08-30 金晖 Multicolour ceramic tile with titanium-plating chemical compound on surface
CN1219521A (en) * 1997-12-10 1999-06-16 董英助 Method for coating surface of ceramic tile with noble metal
CN1887606A (en) * 2006-07-18 2007-01-03 杨仕学 Production process of building decorating glazed tile with golden patterns
CN201545788U (en) * 2009-06-22 2010-08-11 陈满坚 Furnace transmutation polished glaze brick
CN201843292U (en) * 2010-08-16 2011-05-25 广东道氏标准制釉股份有限公司 Ceramic glazed brick with gold metal effect
CN102181834A (en) * 2011-03-08 2011-09-14 深圳市金华威进出口有限公司 Method for electroplating imitation gold on glaze of enamel product and enamel product
CN202299247U (en) * 2011-10-11 2012-07-04 信益陶瓷(中国)有限公司 Ceramic tile coated with gold

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吴晓东: "《我国低温低质陶瓷原料的开发利用》", 《中国陶瓷》 *
徐熙武: "《北京东陶的陶瓷原料应用概况》", 《陶瓷》 *
李惠玲: "《高档卫生陶瓷色釉的研制》", 《佛山陶瓷》 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104150871A (en) * 2014-08-06 2014-11-19 苏州科德溯源仪器有限公司 Fullerene reinforced ceramic tile
CN104193292A (en) * 2014-08-06 2014-12-10 苏州科德溯源仪器有限公司 Carbon nano tube enhanced ceramic tile
CN104150871B (en) * 2014-08-06 2016-05-18 朱玉华 The Ceramic Tiles that a kind of fullerene strengthens
CN104193292B (en) * 2014-08-06 2016-07-06 佛山市金环球陶瓷有限公司 The Ceramic Tiles that a kind of CNT strengthens
CN104999821A (en) * 2015-07-10 2015-10-28 祥和彩瓷制造(上海)有限公司 Preparation method of high-temperature friction gold stained paper and high-temperature friction gold stained paper
CN111960672A (en) * 2020-07-08 2020-11-20 湖南省醴陵市特种电瓷电器有限公司 Glaze for 95 porcelain surface, 95 porcelain and manufacturing method
CN112405795A (en) * 2020-11-30 2021-02-26 王金听 Preparation method of Jun porcelain with metal patterns on surface

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TR01 Transfer of patent right

Effective date of registration: 20170629

Address after: 234000, No. three, No. 228, Jin Jiang Road, Suzhou Economic Development Zone, Anhui

Patentee after: Champion building materials (Anhui) Co., Ltd.

Address before: 215300, No. 8, Feng Feng Road, Yushan Town, Kunshan, Jiangsu, Suzhou

Patentee before: Xinyi Ceramic (China) Co., Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20200911

Address after: Building 7, No.8, Yuanfeng Road, Yushan Town, Kunshan City, Suzhou City, Jiangsu Province

Patentee after: Seagull champion Limited

Address before: 234000 Jin Jiang three road, Suzhou Economic Development Zone, Anhui 228

Patentee before: CHAMPION BUILDING MATERIAL (ANHUI) Co.,Ltd.

TR01 Transfer of patent right