CN1969626A - Thiazine mixed pesticide - Google Patents
Thiazine mixed pesticide Download PDFInfo
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- CN1969626A CN1969626A CN 200510061610 CN200510061610A CN1969626A CN 1969626 A CN1969626 A CN 1969626A CN 200510061610 CN200510061610 CN 200510061610 CN 200510061610 A CN200510061610 A CN 200510061610A CN 1969626 A CN1969626 A CN 1969626A
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Abstract
The invention relates to composite insecticide in the form of missible oil, or wet powder, or suspending agent, or microemulsion, which comprises thiazine ketone 2-70 wt%, chlorpyrifos 5-70%, wetting agent 1-40%, dispersing agent 0.3-25%, spreader 0.1-15%, stabilizing agent 0.1-30%, synergistic agent 0.5-40%, penetrating agent 0.1-20%, pH modifier 0.01-5% and packing material 5-90 wt%.
Description
Technical field
The invention belongs to the agricultural chemical insecticide technical field, relate in particular to thiazine mixed pesticide.
Background technology
The insecticide Buprofezin, (Bruprofezin), commodity are by name excellently readily takes the opportunity to, and claims buprofezin again, chemical name: 2-tertiary butyl imino group-3-isopropyl-5-3,4,5,6-tetrahydrochysene-2H-1,3,5-thiadiazine-4-ketone is the chitin inhibitor of the nitrogenous hexa-member heterocycle of sulfur-bearing.With common insecticides a great difference is arranged, the mechanism of action also has very big-difference, and low toxicity is extremely light to skin and eye irritation effect.It is a kind of selective insecticide that insect growth is grown that suppresses.Strong to the insect action of contace poison, stomach poison function is also arranged, it is synthetic to suppress insect chitin, disturbs metabolism.Tea tree smaller green leaf hopper, plant hopper, vegetables aleyrodid, oranges and tangerines arrowhead scales and the scale insect of main control Semiptera is active high.Comprehensive effect is good.To pest natural enemy and insect pollinator safety, environmentally friendly, thereby can improve the benefit evil ratio in field, but this type of insect growth regulator, IGR action activity spectrum is narrower, quick-acting is poor, time of application harshness etc. very, thereby can't replace common insecticides fully at present.
Poison cicada (chlorpyrifos) with poison, have another name called: Le Siben (Lorsban), chlorine arsenic sulphur phosphorus.Be the organic phosphates insecticidal/acaricidal agent, insecticidal spectrum is wide, have tag, stomach toxicity and fumigation action, insecticidal activity is higher relatively.But the organic phosphorous insecticide acute toxicity causes residue of pesticide in the food to the harm of human health easily, and after using for many years, insect is easy to generate pesticide resistance, strengthens using dosage, and quickens frequency of utilization and new varieties are replaced, and causes vicious circle.
Above-mentioned agricultural chemicals still can not satisfy efficiently, low toxicity, low-residual, safety, economic development trend with the sustainable development protection environment and the ecological balance.
Summary of the invention
The purpose of this invention is to provide a kind ofly have that drug effect improves, quick-acting improves, lasting effect is long, insecticidal activity is high, consumption is few, use is more convenient, hypotoxicity and environmental pollution close friend's thiazine mixed pesticide
The technical solution adopted for the present invention to solve the technical problems is:
A kind of thiazine mixed pesticide, it is characterized in that described compounded pesticides is a wetting powder, what contain by weight 2～70% Buprofezin and 5～70% poisons cicada, wetting agent 1%～40% with poison, dispersant 0.3～25%, spreader-sticker 0.1～15%, stabilizing agent 0.1～30%, synergist 0.5～40%, penetrating agent 0.1～20%, PH conditioning agent 0.01～5%, filler 5～90%, each component sum is 100%.
The wetting powder of preparing above-mentioned thiazine mixed pesticide is composed of the following components by weight percentage:
Buprofezin 10～30% is poisoned cicada 20～50% with poison, wetting agent 2%～15%, dispersant 1～5%, spreader-sticker 1～5%, stabilizing agent 0.3～5%, synergist 2～5%, penetrating agent 1～5%, PH conditioning agent 0.1～0.5%, filler 15～70%, each component sum is 100%.
Described wetting agent is lignosulfonates, alkylbenzenesulfonate, draw back powder, multi-sorbitol ester; Described dispersant is naphthalene sulfonate, alkylsulfonate, polyoxy ethyl sulfonate, diisopropyl phosphate; Described spreader-sticker is cocinic acid potassium, enuatrol, triethanolamine oleate, withered, the polyvinyl alcohol of tea; Described stabilizing agent is a Magnesiumaluminumsilicate; Described synergist is naphthyl propine ether, Butacide, synergy phosphorus, Octacide 264, eight chlorine dipropyl ethers, CPR dust, sulfoxide, alkyl carbonate, chlorination fat, formaldehyde, soya-bean oil; Described penetrating agent is the butadiene dilute acid di-sec-octyl sodium sulfonate of Laurocapram, JFC series, fatty sulfenic acid sodium class; Described pH value conditioning agent is sodium hydroxide, ammonium hydroxide, acetic acid, citric acid; Described filler is ammonium salt, kaolin, clay, talcum, diatomite, imvite, silica, quartz, atlapulgite, calcite, marble, dolomite, cocoa husk, corncob.
The preparation method of above-mentioned wetting powder is:
Proportionally take by weighing an amount of Buprofezin, poison the former medicine of cicada with poison and mix with the preliminary filler of pulverizing, pulverize 20～30min through Raymond machine, fully mix 10～30min with components such as certain amount of dispersant, wetting agents in batch mixer again, blowing gets final product after airslide disintegrating mill is pulverized.
The missible oil of preparation thiazine mixed pesticide is composed of the following components by weight percentage:
Buprofezin 5～60% is poisoned cicada 5～60% with poison, emulsifier 1%～40%, cosolvent 0.1～25%, stabilizing agent 0.1～30%, synergist 0.5～40%, organic solvent 5～70%, penetrating agent 0.1～25%, defoamer 0.0001～5%, PH conditioning agent 0.01～5%, each component sum is 100%.
The batching of preparing above-mentioned thiazine mixed pesticide missible oil is comparatively preferably: Buprofezin 5～30%, poison cicada 0.2～2% with poison, emulsifier 5%～15%, cosolvent 1～18%, stabilizing agent 1～6%, synergist 2～15%, organic solvent 10～40%, penetrating agent 0.2～20%, defoamer 0.1～2%, PH conditioning agent 0.01～2%, each component sum is 100%.
Described emulsifier is nonionic and ionic emulsifying agent; As fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene fatty acid, alkylaryl polyglycol ether, alkylsulfonate, arylsulphonate, fatty acid polyglycol ethylene glycol, dodecyl benzene sulfonate, alkylphenol polyoxyethylene phosphate, polyoxyethylene groups phenol formaldehyde condensate etc.;
Described cosolvent is isoamyl alcohol, phenol, ethyl acetate, dimethyl sulfoxide (DMSO);
Described stabilizing agent is epoxides vegetable oil such as epoxidized soybean oil, epoxidized linseed;
Described synergist is naphthyl propine ether, Butacide, synergy phosphorus, Octacide 264, eight chlorine dipropyl ethers, CPR dust, sulfoxide, alkyl carbonate, chlorination fat, formaldehyde, soya-bean oil;
Described organic solvent is dimethylbenzene, toluene, chlorobenzene, cyclohexane, methyl alcohol, ethanol, acetone, dimethylformamide, pyrrolidones, cyclohexanone, butanols, amylalcohol, ethers, ester class, laruyl alcohol, carrene, petroleum distillate etc.;
Described penetrating agent is the butadiene dilute acid di-sec-octyl sodium sulfonate of Laurocapram, JFC series, fatty sulfenic acid sodium class;
Defoamer is silicone based, as Si18, S-29, FZ-880, SAF, X-202 etc.;
The pH value conditioning agent is: sodium hydroxide, ammonium hydroxide, acetic acid, lemon etc.
The preparation method of above-mentioned thiazine mixed pesticide missible oil is:
According to aforementioned proportion take by weighing Buprofezin, poison cicada with poison, agricultural chemicals used additives and solvent etc. put into reactor.Add certain amount of solvent and defoamer earlier and stir 10～30min, add components such as stabilizing agent, synergist again, continue to stir 10～30min, the solvent with effective dose drops in the still again, and the back blowing that stirs gets final product.
The suspending agent of preparation thiazine mixed pesticide is composed of the following components by weight percentage:
Buprofezin 5～60% is poisoned cicada 5～70% with poison, wetting agent 1%～40%, dispersant 0.3～20%, spreader-sticker 0.1～15%, stabilizing agent 0.1～30%, synergist 0.5～25%, penetrating agent 0.1～10%, thickener 0.1～25%, antifreezing agent 0.05～12%, defoamer 0.01～5%, PH conditioning agent 0.01～5%, water 10～75%, each component sum is 100%.
The batching of above-mentioned thiazine mixed pesticide suspending agent is comparatively preferably: Buprofezin 5～30%, poison cicada 10～45% with poison, wetting agent 2%～15%, dispersant 1～15%, spreader-sticker 1～5%, stabilizing agent 1～7%, synergist 1～16%, penetrating agent 1～8%, thickener 2～20%, antifreezing agent 0.3～10%, defoamer 0.1～3%, PH conditioning agent 0.01～1%, water 10～60%, each component sum is 100%.
Described wetting agent is lignosulfonates, alkylbenzenesulfonate, draw back powder, multi-sorbitol ester; Dispersant is naphthalene sulfonate, alkylsulfonate, polyoxy ethyl sulfonate, two different basic propyl sulfonic acid salt; Described spreader-sticker is cocinic acid potassium, enuatrol, triethanolamine oleate, withered, the polyvinyl alcohol of tea; Described stabilizing agent is a Magnesiumaluminumsilicate; Described synergist is naphthyl propine ether, Butacide, synergy phosphorus, Octacide 264, eight chlorine dipropyl ethers, CPR dust, sulfoxide, alkyl carbonate, chlorination fat, formaldehyde, soya-bean oil; Described penetrating agent is the butadiene dilute acid di-sec-octyl sodium sulfonate of Laurocapram, JFC series, fatty sulfenic acid sodium class; Thickener is alkanolamide and derivative thereof, polyethyleneglycol derivative, fatty alcohol polyoxyethylene ether sulfate, gum Arabic, arm protein, xanthan gum, cellulose family, PAA, POLYPROPYLENE GLYCOL, polyvinylpyrrolidone, Sodium Polyacrylate, bentonite etc.; Described antifreezing agent is ethylene glycol, propane diols, glycerine, glycerine ether diglycol, methyl trimethylene diglycol etc.; Described defoamer is silicone based, as Si18, S-29, FZ-880, SAF, X-202 etc.; Described pH value conditioning agent is sodium hydroxide, ammonium hydroxide, acetic acid, citric acid etc.;
The preparation method of above-mentioned thiazine mixed pesticide suspending agent is:
Take by weighing Buprofezin, poison the cicada raw material with poison and mix according to aforementioned proportion with the preliminary filler of pulverizing, pulverize or comminution by gas stream through Raymond machine, crushed material is pulverized in ball mill with each component processes such as the preliminary dispersant of pulverizing of a certain amount of warp, wetting agents again, the general requirement of material fineness reaches 200 orders, material enter again one or through the series connection two sand mills in pulverize, sand milling final products particle diameter generally requires less than 3 μ m.
Above-mentioned buprofezin pesticide, when the microemulsion or the aqueous emulsion that are thiazine mixed pesticide, composed of the following components by weight percentage:
Buprofezin 5～60%, poison cicada 5～60% with poison, emulsifier 1%～45%, cosolvent 0.2～25%, stabilizing agent 0.1～30%, synergist 0.5～35%, organic solvent 5～60%, penetrating agent 0.1～25%, defoamer 0.05～5%, water 1～70%, PH conditioning agent 0.01～5%, each component sum is 100%.
Above-mentioned thiazine mixed pesticide microemulsion or aqueous emulsion, batching comparatively preferably: Buprofezin 5～30%, poison cicada 15～50% with poison, emulsifier 5%～15%, cosolvent 1～18%, stabilizing agent 1～6%, synergist 2～15%, organic solvent 10～70%, penetrating agent 0.2～20%, defoamer 0.1～2%, water 5～60%, PH conditioning agent 0.01～2%, each component sum is 100%.
Above-mentioned emulsifier is nonionic and ionic emulsifying agent; As fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene fatty acid, alkylaryl polyglycol ether, alkylsulfonate, arylsulphonate, fatty acid polyglycol ethylene glycol, dodecyl benzene sulfonate, alkylphenol polyoxyethylene phosphate, polyoxyethylene groups phenol formaldehyde condensate etc.; Cosolvent is isoamyl alcohol, phenol, ethyl acetate, dimethyl sulfoxide (DMSO); Described stabilizing agent is epoxides vegetable oil such as epoxidized soybean oil, epoxidized linseed; Described synergist is naphthyl propine ether, Butacide, synergy phosphorus, Octacide 264, eight chlorine dipropyl ethers, CPR dust, sulfoxide, alkyl carbonate, chlorination fat, formaldehyde, soya-bean oil; Organic solvent is dimethylbenzene, toluene, chlorobenzene, cyclohexane, methyl alcohol, ethanol, acetone, dimethylformamide, pyrrolidones, cyclohexanone, butanols, amylalcohol, ethers, ester class, laruyl alcohol, carrene, petroleum distillate etc.; Described penetrating agent is the butadiene dilute acid di-sec-octyl sodium sulfonate of Laurocapram, JFC series, fatty sulfenic acid sodium class; Described defoamer is silicone based, as Si18, S-29, FZ-880, SAF, X-202 etc.; Described pH value conditioning agent is sodium hydroxide, ammonium hydroxide, acetic acid, lemon etc.;
The preparation method of above-mentioned thiazine mixed pesticide microemulsion or aqueous emulsion is:
With the Buprofezin of aforementioned proportion, poison cicada with poison, agricultural chemicals is put into reactor with cosolvent and solvent etc., add certain amount of solvent and defoamer earlier and stir 10～30min, add components such as stabilizing agent, synergist again, continue to stir 10～30min, water with effective dose drops in the still again, and the back blowing that stirs gets final product.
Complex preparation has been an important directions of formulations of pesticide development in recent years, have advantages such as synergy, expanding prevention spectrum, the use toxicity that reduces medicament, delaying drug resistance, saving labour and reduction agricultural cost, the present invention makes the stabilizer type product that can directly be applied to field crops according to the Buprofezin and the mechanism of action of poisoning cicada with poison with the proportioning of rational effective ingredient and the selection of auxiliary agent with the reasonable process method.
Prove through indoor virulence test and field plot trial, thiazine mixed pesticide of the present invention and single pharmacy variety, and the thiazine mixed pesticide that provides in the prior art to compare the synergy of coccid drug effect obvious, quick-acting improves, lasting effect is long, insecticidal activity is high.Alternative in the past as methidathion, the contour malicious agricultural chemicals of flolimat, and consumption reduces, toxicity is low, environmentally friendly.For example use embodiment 5 produce the effect following (%) of all kinds of coccids of control citrus compared with 40% first methidathion missible oil of 40% Buprofezin+poison with poison cicada missible oil:
The brown round a red-spotted lizard ceroplastes rubens of the long white a red-spotted lizard of title extension rate arrowhead scales
40% Buprofezin+poison with poison cicada missible oil 1,200 95 89 92 90
40% Buprofezin+poison with poison cicada missible oil 1,000 98 95 96 95
40% Buprofezin+poison with poison cicada missible oil 600 100 100 100 100
40% first methidathion missible oil 800 100 85 92 90
By above-mentioned experimental data as can be known 40% Buprofezin missible oil of the present invention adopt the effect of 800～1200 times all kinds of coccids of control to be better than 40% first methidathion missible oil.And the cost that uses is 1/3 of 40% first methidathion missible oil, and Buprofezin missible oil provided by the invention is littler, safe in utilization than the 40% first methidathion missible oil environmental pollution of poisoning.
Embodiment
Below in conjunction with embodiment the present invention is further described.
Embodiment 1:40% Buprofezin with poison cicada wetting powder (weight) with poison
The component weight percentage
Buprofezin 10%
Poison cicada 30% with poison
Wetting agent 5%
Dispersant 3%
Spreader-sticker 2%
Stabilizing agent 2%
Synergist 2%
Penetrating agent 3%
PH conditioning agent 0.5%
Filler 42.7%
Each component sum is 100%.
Wetting agent is selected lignosulfonates; Dispersant is an alkylsulfonate; Spreader-sticker is a cocinic acid potassium; Stabilizing agent is a Magnesiumaluminumsilicate; Synergist is a naphthyl propine ether; Penetrating agent is a Laurocapram; The pH value conditioning agent is the sodium hydroxide citric acid; Filler is a kaolin.
Proportionally take by weighing Buprofezin, poison the former medicine of cicada with poison and mix with the preliminary filler of pulverizing, pulverize 20～30min through Raymond machine, fully mix 30min with the dispersant alkylsulfonate of said ratio, wetting agent lignosulfonates etc. in batch mixer again, blowing can obtain 40% buprofezin compound wetting powder after airslide disintegrating mill is pulverized.
Embodiment 2:30 Buprofezin+poison with poison cicada compounded cream (weight)
The component weight percentage
Buprofezin 7%
Poison cicada 23% with poison
Emulsifier 8%
Cosolvent 3%
Stabilizing agent 3%
Synergist 2%
Organic solvent 52%
Penetrating agent 1%
Defoamer 0.5%
PH conditioning agent 0.5%
Each component sum is 100%.
Emulsifier is an alkylphenol polyoxyethylene; Cosolvent is an ethyl acetate; Stabilizing agent is an epoxidized linseed; Synergist is a naphthyl propine ether; Organic solvent is an ethanol; Penetrating agent is a butadiene dilute acid di-sec-octyl sodium sulfonate; Defoamer is S-29; The pH value conditioning agent is an acetic acid.
According to aforementioned proportion take by weighing Buprofezin, poison cicada with poison, cosolvent ethyl acetate, agricultural chemicals used additives etc. add reactor, add ethanol and defoamer S-29 earlier and stir 10～30min, add stabilizing agent epoxidized linseed, synergist naphthyl propine ether, penetrating agent butadiene dilute acid di-sec-octyl sodium sulfonate etc. again, continue to stir 10～30min, regulate pH value, solvent with effective dose drops in the still again, and the back blowing that stirs gets final product.
Embodiment 3:50% buprofezin compound suspending agent (weight)
The component weight percentage
Buprofezin 10%
Poison cicada 40% with poison
Wetting agent 8%
Dispersant 5%
Spreader-sticker 3%
Stabilizing agent 2%
Synergist 2%
Penetrating agent 1%
Thickener 2%
Antifreezing agent 0.5%
Defoamer 0.5%
PH value conditioning agent 0.5%
Water 25.5%
Each component sum is 100%.
Wetting agent is selected lignosulfonates; Dispersant is a naphthalene sulfonate; Spreader-sticker is a polyvinyl alcohol; Stabilizing agent is a Magnesiumaluminumsilicate; Synergist is an Octacide 264; Penetrating agent is a JFC series; Thickener is an alkanolamide; Antifreezing agent is a glycerine; Defoamer is SAF; The pH value conditioning agent is a citric acid;
The preparation method is: take by weighing Buprofezin, poison the cicada raw material with poison and mix with the preliminary filler of pulverizing according to aforementioned proportion, pulverize or comminution by gas stream through Raymond machine, crushed material is pulverized in ball mill with component processes such as the preliminary dispersant naphthalene sulfonate of pulverizing of a certain amount of warp, wetting agent lignosulfonates, polyvinyl alcohol, Magnesiumaluminumsilicate, Octacide 264, JFC, alkanolamides again, the general requirement of material fineness reaches 200 orders, material enter again one or through the series connection two sand mills in pulverize, sand milling final products particle diameter generally requires less than 3 μ m.
Embodiment 4:25% buprofezin compound microemulsion (weight)
The component weight percentage
Buprofezin 5%
Poison cicada 20% with poison
Emulsifier 10%
Cosolvent 5%
Stabilizing agent 3%
Synergist 5%
Organic solvent 8%
Penetrating agent 3%
Defoamer 0.5%
Water 40%
PH value conditioning agent 0.5%
Each component sum is 100%.
Emulsifier is a fatty alcohol-polyoxyethylene ether; Cosolvent is an ethyl acetate; Stabilizing agent is an epoxidized soybean oil; Synergist is a naphthyl propine ether; Organic solvent is a chlorobenzene; Penetrating agent is a Laurocapram; Defoamer is Si1; The pH value conditioning agent is a sodium hydroxide;
The preparation method: with the Buprofezin of aforementioned proportion, poison cicada with poison, agricultural chemicals is put into reactor with cosolvent and solvent etc., add certain amount of solvent and defoamer earlier and stir 10～30min, add adjuvant components such as epoxidized soybean oil, naphthyl propine ether again, continue to stir 10～30min, water with effective dose drops in the still again, and the back blowing that stirs gets final product.
Embodiment 5:40% Buprofezin missible oil (weight)
The component weight percentage
Buprofezin 29%
Poison cicada 11% with poison
Emulsifier 5%
Cosolvent 4%
Stabilizing agent 2%
Synergist 3%
Organic solvent 25%
Penetrating agent 18%
Defoamer 2%
PH value conditioning agent 1%
Each component sum is 100%.
Emulsifier is an alkylphenol polyoxyethylene; Cosolvent is a phenol; Stabilizing agent is epoxidized soybean oil, epoxidized linseed; Synergist is a Butacide; Organic solvent is a dimethylbenzene; Penetrating agent is a Laurocapram; Defoamer is Si18; The pH value conditioning agent is a sodium hydroxide.
The preparation method is with reference to embodiment 2.
Embodiment 6:10% Buprofezin with poison cicada wetting powder (weight) with poison
The component weight percentage
Buprofezin 5%
Poison cicada 5% with poison
Wetting agent 10%
Dispersant 4%
Spreader-sticker 5%
Stabilizing agent 4%
Synergist 3%
Penetrating agent 7%
PH conditioning agent 2%
Filler 55%
Each component sum is 100%.
Wetting agent is an alkylbenzenesulfonate; Dispersant is the polyoxy ethyl sulfonate; Spreader-sticker is a polyvinyl alcohol; Stabilizing agent is a Magnesiumaluminumsilicate; Synergist is an alkyl carbonate; Penetrating agent is a butadiene dilute acid di-sec-octyl sodium sulfonate; The pH value conditioning agent is an acetic acid; Filler is a diatomite.
Embodiment 7:30% buprofezin compound microemulsion (weight)
The component weight percentage
Buprofezin 25%
Poison cicada 5% with poison
Emulsifier 5%
Cosolvent 15%
Stabilizing agent 3%
Synergist 6%
Organic solvent 10%
Penetrating agent 2%
Defoamer 1%
Water 27%
PH value conditioning agent 1%
Each component sum is 100%.
Above-mentioned emulsifier is an arylsulphonate; Cosolvent is an ethyl acetate; Stabilizing agent is the epoxides vegetable oil; Synergist is an alkyl carbonate; Organic solvent is a laruyl alcohol; Penetrating agent is a Laurocapram; Defoamer is silicone based FZ-880; The pH value conditioning agent is a sodium hydroxide;
Embodiment 8:10% buprofezin compound microemulsion (weight)
The component weight percentage
Buprofezin 5%
Poison cicada 5% with poison
Emulsifier 5%
Cosolvent 10%
Stabilizing agent 6%
Synergist 15%
Organic solvent 23.2%
Penetrating agent 0.2%
Defoamer 0.1%
Water 20%
PH value conditioning agent 0.5%
Each component sum is 100%.
Embodiment 9:40% buprofezin compound microemulsion (weight)
The component weight percentage
Buprofezin 30%
Poison cicada 10% with poison
Emulsifier 15%
Cosolvent 12.2%
Stabilizing agent 2.1%
Synergist 1.5%
Organic solvent 5%
Penetrating agent 0.2%
Defoamer 5%
Water 17%
PH value conditioning agent 2%
Each component sum is 100%.
Embodiment 10:60% buprofezin compound suspending agent (weight)
The component weight percentage
Buprofezin 30%
Poison cicada 30% with poison
Wetting agent 2%
Dispersant 1.3%
Spreader-sticker 2.1%
Stabilizing agent 3.1%
Synergist 1.5%
Penetrating agent 1.1%
Thickener 2.1%
Antifreezing agent 1.3%
Defoamer 1.5%
PH value conditioning agent 0.5%
Water 23.5%
Each component sum is 100%.
Embodiment 11:45% Buprofezin with poison cicada wetting powder (weight) with poison
The component weight percentage
Buprofezin 10%
Poison cicada 35% with poison
Wetting agent 2%
Dispersant 2.3%
Spreader-sticker 2.1%
Stabilizing agent 3.3%
Synergist 2%
Penetrating agent 2.2%
PH conditioning agent 1.1%
Filler 40%
Each component sum is 100%.
Embodiment 12:30% Buprofezin missible oil (weight)
The component weight percentage
Buprofezin 15%
Poison cicada 15% with poison
Emulsifier 2%
Cosolvent 2.1%
Stabilizing agent 6.1%
Synergist 2.5%
Organic solvent 39%
Penetrating agent 15.2%
Defoamer 2.1%
PH value conditioning agent 1%
Each component sum is 100%.
Claims (12)
1, a kind of thiazine mixed pesticide, contain Buprofezin and poison cicada with poison, and insecticides adjuvant is mixed and forms missible oil, or wetting powder, or missible oil, or suspending agent, or microemulsion, it is characterized in that described compounded pesticides is a wetting powder, what contain by weight 2～70% Buprofezin and 5～70% poisons cicada, wetting agent 1%～40% with poison, dispersant 0.3～25%, spreader-sticker 0.1～15%, stabilizing agent 0.1～30%, synergist 0.5～40%, penetrating agent 0.1～20%, PH conditioning agent 0.01～5%, filler 5～90%, each component sum is 100%.
2, thiazine mixed pesticide as claimed in claim 1, it is composed of the following components by weight percentage to it is characterized in that preparing wetting powder:
Buprofezin 10～30% is poisoned cicada 20～50% with poison, wetting agent 2%～15%, dispersant 1～5%, spreader-sticker 1～5%, stabilizing agent 0.3～5%, synergist 2～5%, penetrating agent 1～5%, PH conditioning agent 0.1～0.5%, filler 15～70%, each component sum is 100%.
3, fipronil mixed pesticide as claimed in claim 1 or 2 is characterized in that: described wetting agent is lignosulfonates, alkylbenzenesulfonate, draw back a kind of in powder, the multi-sorbitol ester or more than one mixing; Described dispersant is a kind of in naphthalene sulfonate, alkylsulfonate, polyoxy ethyl sulfonate, the diisopropyl phosphate or more than one mixing; Described spreader-sticker is that cocinic acid potassium, enuatrol, triethanolamine oleate, tea are withered, a kind of in the polyvinyl alcohol or more than one mixing; Described stabilizing agent is a Magnesiumaluminumsilicate; Described synergist is a kind of in naphthyl propine ether, Butacide, synergy phosphorus, Octacide 264, eight chlorine dipropyl ethers, CPR dust, sulfoxide, alkyl carbonate, chlorination fat, formaldehyde, the soya-bean oil or more than one mixing; Described penetrating agent is a kind of in Laurocapram, JFC series, the fatty sulfenic acid sodium class or more than one mixing; Described pH value conditioning agent is sodium hydroxide or ammonium hydroxide or acetic acid or citric acid; Described filler is a kind of in ammonium salt, kaolin, clay, talcum, diatomite, imvite, silica, quartz, atlapulgite, calcite, marble, dolomite, cocoa husk, the corncob or more than one mixing.
4, thiazine mixed pesticide as claimed in claim 1, it is characterized in that being mixed is missible oil, composed of the following components by weight percentage:
Buprofezin 5～60% is poisoned cicada 5～60% with poison, emulsifier 1%～40%, cosolvent 0.1～25%, stabilizing agent 0.1～30%, synergist 0.5～40%, organic solvent 5～70%, penetrating agent 0.1～25%, defoamer 0.0001～5%, PH conditioning agent 0.01～5%, each component sum is 100%.
5, thiazine mixed pesticide as claimed in claim 4, it is composed of the following components by weight percentage to it is characterized in that preparing missible oil:
Buprofezin 5～30% is poisoned cicada 0.2～2% with poison, emulsifier 5%～15%, cosolvent 1～18%, stabilizing agent 1～6%, synergist 2～15%, organic solvent 10～40%, penetrating agent 0.2～20%, defoamer 0.1～2%, PH conditioning agent 0.01～2%, each component sum is 100%.
6, as claim 4 or 5 described thiazine mixed pesticides, it is characterized in that
Described emulsifier is a kind of of nonionic and ionic emulsifying agent or more than one mixing;
Described cosolvent is a kind of of isoamyl alcohol, phenol, ethyl acetate, dimethyl sulfoxide (DMSO) or more than one mixing;
Described stabilizing agent is a kind of of epoxides vegetable oil such as epoxidized soybean oil, epoxidized linseed or more than one mixing;
Described synergist is a kind of of naphthyl propine ether, Butacide, synergy phosphorus, Octacide 264, eight chlorine dipropyl ethers, CPR dust, sulfoxide, alkyl carbonate, chlorination fat, formaldehyde, soya-bean oil or more than one mixing;
Described organic solvent is a kind of of dimethylbenzene, toluene, chlorobenzene, cyclohexane, methyl alcohol, ethanol, acetone, dimethylformamide, pyrrolidones, cyclohexanone, butanols, amylalcohol, ethers, ester class, laruyl alcohol, carrene, petroleum distillate or more than one mixing;
Described penetrating agent is a kind of of Laurocapram, JFC series, butadiene dilute acid di-sec-octyl sodium sulfonate or more than one mixing;
Defoamer is silicone based;
The pH value conditioning agent is sodium hydroxide or ammonium hydroxide or acetic acid or lemon.
7, thiazine mixed pesticide as claimed in claim 1, it is composed of the following components by weight percentage to it is characterized in that being mixed into suspending agent:
Buprofezin 5～60% is poisoned cicada 5～70% with poison, wetting agent 1%～40%, dispersant 0.3～20%, spreader-sticker 0.1～15%, stabilizing agent 0.1～30%, synergist 0.5～25%, penetrating agent 0.1～10%, thickener 0.1～25%, antifreezing agent 0.05～12%, defoamer 0.01～5%, PH conditioning agent 0.01～5%, water 10～75%, each component sum is 100%.
8, thiazine mixed pesticide as claimed in claim 7, it is composed of the following components by weight percentage to it is characterized in that preparing suspending agent:
Buprofezin 5～30% is poisoned cicada 10～45% with poison, wetting agent 2%～15%, dispersant 1～15%, spreader-sticker 1～5%, stabilizing agent 1～7%, synergist 1～16%, penetrating agent 1～8%, thickener 2～20%, antifreezing agent 0.3～10%, defoamer 0.1～3%, PH conditioning agent 0.01～1%, water 10～60%, each component sum is 100%.
9, as claim 7 or 8 described thiazine mixed pesticides, it is characterized in that described wetting agent be lignosulfonates, alkylbenzenesulfonate, draw back powder, multi-sorbitol ester is a kind of or more than one mixing; Dispersant is naphthalene sulfonate, alkylsulfonate, polyoxy ethyl sulfonate, two different basic propyl sulfonic acid salt are a kind of or more than one mixing; Described spreader-sticker is cocinic acid potassium, enuatrol, triethanolamine oleate, tea is withered, polyvinyl alcohol is a kind of or more than one mixing; Described stabilizing agent is a Magnesiumaluminumsilicate; Described synergist is naphthyl propine ether, Butacide, synergy phosphorus, Octacide 264, eight chlorine dipropyl ethers, CPR dust, sulfoxide, alkyl carbonate, chlorination fat, formaldehyde, soya-bean oil is a kind of or more than one mixing; Described penetrating agent is Laurocapram, JFC series, butadiene dilute acid di-sec-octyl sodium sulfonate; Thickener is alkanolamide and derivative, polyethyleneglycol derivative, fatty alcohol polyoxyethylene ether sulfate, gum Arabic, arm protein, xanthan gum, cellulose family, PAA, POLYPROPYLENE GLYCOL, polyvinylpyrrolidone, Sodium Polyacrylate, bentonite is a kind of or more than one mixing; Described antifreezing agent is ethylene glycol, propane diols, glycerine, glycerine ether diglycol, methyl trimethylene diglycol is a kind of or more than one mixing; Described defoamer is silicone based; Described pH value conditioning agent is sodium hydroxide, ammonium hydroxide or acetic acid or citric acid.
10, thiazine mixed pesticide as claimed in claim 1, it is composed of the following components by weight percentage to it is characterized in that preparing microemulsion or aqueous emulsion:
Buprofezin 5～60%, poison cicada 5～60% with poison, emulsifier 1%～45%, cosolvent 0.2～25%, stabilizing agent 0.1～30%, synergist 0.5～35%, organic solvent 5～60%, penetrating agent 0.1～25%, defoamer 0.05～5%, water 1～70%, PH conditioning agent 0.01～5%, each component sum is 100%.
11, thiazine mixed pesticide as claimed in claim 10, it is composed of the following components by weight percentage to it is characterized in that preparing microemulsion or aqueous emulsion:
Buprofezin 5～30%, poison cicada 15～50% with poison, emulsifier 5%～15%, cosolvent 1～18%, stabilizing agent 1～6%, synergist 2～15%, organic solvent 10～70%, penetrating agent 0.2～20%, defoamer 0.1～2%, water 5～60%, PH conditioning agent 0.01～2%, each component sum is 100%.
12,, it is characterized in that emulsifier is a kind of or more than one mixing in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene fatty acid, alkylaryl polyglycol ether, alkylsulfonate, arylsulphonate, fatty acid polyglycol ethylene glycol, dodecyl benzene sulfonate, alkylphenol polyoxyethylene phosphate, the polyoxyethylene groups phenol formaldehyde condensate as claim 10 or 11 described thiazine mixed pesticides; Cosolvent is one or more the mixing in isoamyl alcohol, phenol, ethyl acetate, the dimethyl sulfoxide (DMSO); Described stabilizing agent is the epoxides vegetable oil; Described synergist is one or more mixing of naphthyl propine ether, Butacide, synergy phosphorus, Octacide 264, eight chlorine dipropyl ethers, CPR dust, sulfoxide, alkyl carbonate, chlorination fat, formaldehyde, soya-bean oil; Organic solvent is one or more mixing of dimethylbenzene, toluene, chlorobenzene, cyclohexane, methyl alcohol, ethanol, acetone, dimethylformamide, pyrrolidones, cyclohexanone, butanols, amylalcohol, ethers, ester class, laruyl alcohol, carrene, petroleum distillate; Described penetrating agent is one or more mixing in Laurocapram, JFC series, the fatty sulfenic acid sodium; Described defoamer is one or more the mixing of Si18, S-29, FZ-880, SAF, X-202; Described pH value conditioning agent is sodium hydroxide or ammonium hydroxide or acetic acid, lemon.
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| CN 200510061610 CN1969626A (en) | 2005-11-21 | 2005-11-21 | Thiazine mixed pesticide |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510061610 CN1969626A (en) | 2005-11-21 | 2005-11-21 | Thiazine mixed pesticide |
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| CN1969626A true CN1969626A (en) | 2007-05-30 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101933524A (en) * | 2010-09-16 | 2011-01-05 | 陕西恒田化工有限公司 | Water suspending agent pesticides containing dursban and buprofezin and preparation method thereof |
| CN101700034B (en) * | 2009-08-01 | 2013-02-13 | 深圳诺普信农化股份有限公司 | Pesticide composition |
| CN103749562A (en) * | 2013-12-30 | 2014-04-30 | 青岛崂乡茶制品有限公司 | Novel insecticide for tea trees |
| CN104137854A (en) * | 2014-07-24 | 2014-11-12 | 江苏神禾农业科技发展有限公司 | Insecticide composition for preventing and treating small brown rice planthopper and stem borer and application of insecticide composition |
| CN106259497A (en) * | 2016-08-15 | 2017-01-04 | 卞佳林 | A kind of Synergistic type method for producing insecticide |
| CN106962369A (en) * | 2017-03-03 | 2017-07-21 | 安徽金培因科技有限公司 | A kind of agricultural chemicals and preparation method based on Rice Cropping |
| CN108552228A (en) * | 2018-04-25 | 2018-09-21 | 芜湖扬展新材料科技服务有限公司 | A kind of rice compounded pesticides |
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2005
- 2005-11-21 CN CN 200510061610 patent/CN1969626A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101700034B (en) * | 2009-08-01 | 2013-02-13 | 深圳诺普信农化股份有限公司 | Pesticide composition |
| CN101933524A (en) * | 2010-09-16 | 2011-01-05 | 陕西恒田化工有限公司 | Water suspending agent pesticides containing dursban and buprofezin and preparation method thereof |
| CN103749562A (en) * | 2013-12-30 | 2014-04-30 | 青岛崂乡茶制品有限公司 | Novel insecticide for tea trees |
| CN104137854A (en) * | 2014-07-24 | 2014-11-12 | 江苏神禾农业科技发展有限公司 | Insecticide composition for preventing and treating small brown rice planthopper and stem borer and application of insecticide composition |
| CN106259497A (en) * | 2016-08-15 | 2017-01-04 | 卞佳林 | A kind of Synergistic type method for producing insecticide |
| CN106962369A (en) * | 2017-03-03 | 2017-07-21 | 安徽金培因科技有限公司 | A kind of agricultural chemicals and preparation method based on Rice Cropping |
| CN108552228A (en) * | 2018-04-25 | 2018-09-21 | 芜湖扬展新材料科技服务有限公司 | A kind of rice compounded pesticides |
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