CN104585217A - Synergistic compound composition containing two active components - Google Patents
Synergistic compound composition containing two active components Download PDFInfo
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Abstract
The invention relates to a synergistic compound composition containing two active components, belonging to the field of pesticides. The composition comprises an active component A and an active component B, wherein the component A is pyriminostrobin, the component B is one selected from the group consisting of nicotine type or insect growth regulator type insecticidal and acaricidal agents, and a weight ratio of the component A to the component B is 1:99 to 99:1. The structure of pyriminostrobin is described in the specification. The composition provided by the invention has obvious synergistic effect and can be used for prevention and treatment of a plurality of insects and mites.
Description
Technical field
The invention belongs to pesticide field, relate to a kind of synergistic complex composition containing two kinds of active components.
Background technology
In the real process of agricultural production, using chemical agent is one of the most effective means of control plant pest, but is insect, the drug-fast generation of evil mite by the problem that chemical control insect the most easily produces.Use single pest control with insecticide, miticide continuously high dose simultaneously for a long time, easily cause the series of problems such as the remaining of medicament, environmental pollution.Composite or the mixture of rational pest control with insecticide, miticide has and expands desinsection, kills mite spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce and remain, delay insect, evil mite drug resistance and the positive feature such as drug-fast generation and development, the composite or mixture of Insecticidal and acaricidal agent is one of the effective method the most solved the problem.Develop new product insecticide price constantly rises, and by contrast, exploitation is efficient with research, low toxicity, low-residual composite and mixture has small investment, the lead time is short and be subject to domestic and international attention, numerous and confused increasing develops dynamics.
Nicotinic insecticide mainly acts on the acetylcholinergic receptor of insect.Owing to having unique mechanism of action, with conventional pesticide without cross resistance, there is absorption in efficient, wide spectrum and good root, tag and stomach poison function, and environmentally safe, be substitute one of the medicament with agricultural chemicals such as high poison, the organic phosphates of high residue, carbamates and organochlorine classes.Imidacloprid applies nicotinic insecticide comparatively early.For a long time, control plant hopper, aphid, aleyrodid etc. are widely used in.But over 2005, various pests is own creates higher pesticide resistance to Imidacloprid.And the medicaments such as Acetamiprid, Diacloden, thiacloprid, Nitenpyram, MTI-446 and clothianidin are the anabasine insecticides outstanding to insect preventive effect.
Insect growth regulator, IGR is a class specificity insecticide, does not directly kill insect in use, but hinders or interference insect normal development period in insect ontogeny, makes the individual viability reduction of insect, death.This insecticides comprises juvenile hormone, anti-JH, moulting hormone and chitin synthesis inhibitor, anti-feedant etc.Common pesticide species has diflubenzuron, d ichlorbenzuron, flufenoxuron, worm hydrazides etc.
Chinese invention patent CN101906075A discloses the purposes of a kind of E-type phenyl acrylates compounds containing substituted anilino pyrimidine group and Control pests thereof, evil mite, wherein phonetic mite amine (Universal Chinese character name: phonetic mite amine, English common name: pyriminostrobin) can be used for preventing and treating various pests, evil mite, especially to mite class, there is outstanding control efficiency, be subject to the extensive attention of industry.This structural formula of compound is as follows:
Different cultivars composition carries out composite, may produce the technique effect that some is unexpected, is also one of control resistant insect, the effective ways doing harm to mite.But, have no the report of phonetic mite amine and nicotinoids or insect growth regulator, IGR insecticides complex composition so far.
Summary of the invention
The object of the present invention is to provide a kind of synergistic complex composition containing two kinds of active components.
The technical solution used in the present invention is for achieving the above object:
Contain a synergistic complex composition for two kinds of active components, containing A, B two kinds of active components, component A is selected from phonetic mite amine, and B component is selected from the Insecticidal and acaricidal agent of nicotinoids or insect growth regulator, IGR class; The ratio of weight and number of component A, B two kinds of active components is 1:99 to 99:1; Wherein, phonetic mite amine structure formula is as follows:
Described nicotinic insecticide is selected from Acetamiprid (acetamiprid), Diacloden (thiamethoxam), clothianidin (clothianidin), thiacloprid (thiacloprid), Imidacloprid (imidacloprid), Nitenpyram (nitenpyram), MTI-446 (dinotefuran), imidaclothiz (imidaclothiz), sulfone worm pyridine (sulfoxaflor) or piperazine worm pyridine (paichongding);
Described insect growth regulator, IGR class desinsection, miticide is selected from pymetrozine (pymetrozine), flonicamid (flonicamid), Buprofezin (buprofezin), cyromazine (cyromazine), hydroprene (hydroprene), kinoprene (kinoprene), methoprene (methoprene), Nylar (pyriproxyfen), lufenuron (lufenuron), HEXAFLUMURON (hexaflumuron), diflubenzuron (diflubenzuron), fluazuron (fluazuron), pyridalyl (pyridalyl), bistrifluron (bistrifluron), chlorfluazuron (chlorfluazuron), CGA 183893 (dicyclanil), flucycloxuron (flucycloxuron), flufenoxuron (flufenoxuron), fluorine uride (novaluron), noviflumuron (noviflumuron), penfluron (penfluron), fluorobenzene urea (teflubenzuron), triflumuron (triflumuron), d ichlorbenzuron (chlorbenzuron), ring worm hydrazides (chromafenozide), chlorine worm hydrazides (halofenozide), methoxyfenozide (methoxyfenozide), worm hydrazides (tebufenozide), furan tebufenozide (fufenozide), diafenthiuron (diafenthiuron), deinsectization grand (chloromethiuron), fluorine mite piperazine (diflovidazin) or sulcofuron-sodium.
The comparatively preferred technical scheme of the present invention is:
In described desinsection, miticide composition, component A is selected from phonetic mite amine, B component is selected from Acetamiprid (acetamiprid), Diacloden (thiamethoxam), clothianidin (clothianidin), Nitenpyram (nitenpyram), pymetrozine (pymetrozine), Buprofezin (buprofezin), cyromazine (cyromazine), Nylar (pyriproxyfen), lufenuron (lufenuron), HEXAFLUMURON (hexaflumuron), diflubenzuron (diflubenzuron), pyridalyl (pyridalyl), flucycloxuron (flucycloxuron), flufenoxuron (flufenoxuron), penfluron (penfluron), d ichlorbenzuron (chlorbenzuron), worm hydrazides (tebufenozide), diafenthiuron (diafenthiuron), fluorine mite piperazine (diflovidazin) etc.,
The ratio of weight and number of A, B two kinds of active components is 1:20 to 20:1.
The present invention further preferred technical scheme is:
In described desinsection, miticide composition, component A is selected from phonetic mite amine; B component is selected from Acetamiprid (acetamiprid), Diacloden (thiamethoxam), clothianidin (clothianidin);
The ratio of weight and number of A, B two kinds of active components is 1:10 to 10:1.
Or the present invention further preferred technical scheme is:
In described desinsection, miticide composition, component A is selected from phonetic mite amine; B component is selected from pymetrozine (pymetrozine);
The ratio of weight and number of A, B two kinds of active components is 1:4 to 2:1.
Or the present invention further preferred technical scheme is:
In described desinsection, miticide composition, component A is selected from phonetic mite amine; B component is selected from Buprofezin (buprofezin);
The ratio of weight and number of A, B two kinds of active components is 1:5 to 3:1.
Or the present invention further preferred technical scheme is:
In described desinsection, miticide composition, component A is selected from phonetic mite amine; B component is selected from lufenuron (lufenuron), HEXAFLUMURON (hexaflumuron), diflubenzuron (diflubenzuron);
The ratio of weight and number of A, B two kinds of active components is 1:10 to 10:1.
Or the present invention further preferred technical scheme is:
In described desinsection, miticide composition, component A is selected from phonetic mite amine; B component is selected from diafenthiuron (diafenthiuron);
The ratio of weight and number of A, B two kinds of active components is 3:1 to 5:1.
Desinsection of the present invention, miticide composition have obvious synergistic effect for preventing and treating the insect on fruit tree, vegetables, ornamental plants, tea, cotton, cereal crop, harmful mite or urban health insect.Indoor biological determination of activity result shows, and phonetic mite amine and nicotinoids or insect growth regulator, IGR class Insecticidal and acaricidal agent mixture can be improved preventive effect, reduces dosage, expansion insecticidal spectrum.Such as, when phonetic mite amine and Acetamiprid, Diacloden, clothianidin, pymetrozine, Buprofezin, lufenuron, diafenthiuron etc. carry out mixture in the proportion of 1:10 to 10:1, the activity to Tetranychus cinnabarinus can greatly be improved; When phonetic mite amine and Acetamiprid, Diacloden carry out mixture in the proportion of 1:1 to 1:10, to the control of black peach aphid, there is synergistic effect; When phonetic mite amine and Diacloden in the proper ratio mixture time, to the control of brown plant-hopper, there is synergistic effect; When phonetic mite amine and lufenuron, HEXAFLUMURON, diflubenzuron etc. carry out mixture in the proportion of 1:10 to 10:1, good synergistic effect is shown to mythimna separata; Therefore, another technical scheme of the present invention is the purposes of two kinds of active component compositions of the present invention for the preparation of Insecticidal and acaricidal agent medicine.
In desinsection of the present invention, miticide composition, the cumulative amount (by weight, lower same) of active component, between 0.5% ~ 95%, is preferably between 1% ~ 85%.According to different preparation types, active component cumulative amount scope is different.Usually, in liquid preparation, the cumulative amount of active component is between l% ~ 70%, is preferably 5% ~ 50%; In solid pharmaceutical preparation, the cumulative amount of active component is between 5% ~ 85%, is preferably 10% ~ 80%;
At least containing a kind of surfactant in desinsection of the present invention, miticide composition, the dispersion of active component in water when being beneficial to use.The cumulative amount of surfactant is between 5% ~ 30%, and surplus is solid or liquid diluent.Surfactant selected by desinsection of the present invention, miticide composition is known in those skilled in the art, as: one or more in dispersant, wetting agent, binding agent, defoamer, stabilizing agent or emulsifier.According to different dosage form, in preparation, antifreeze known in those skilled in the art, thickener, disintegrant etc. can also be contained.
Desinsection of the present invention, miticide composition can by user before use through diluting or directly using.Its preparation can be prepared by common processing method known in those skilled in the art, after mixing with liquid flux or solid carrier by active substance, then add surfactant as one or more in dispersant, wetting agent, binding agent, defoamer, stabilizing agent etc.
Desinsection of the present invention, miticide composition, can be processed into acceptable any formulation on agricultural chemicals on demand, wherein excellent formulation of comparatively selecting is: missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent.
Desinsection of the present invention, miticide composition, comprise following constituent content when making missible oil: active component A l ~ 50%, active component B l ~ 50%, emulsifier 2 ~ 20%, synergist 0 ~ 20%, cosolvent 0 ~ 20%, solvent complement to 100%.Active component A and B added after dissolving completely in solvent, add cosolvent if desired, then add the oily liquids becoming transparent and homogeneous after emulsifier, synergist etc. stir, be i.e. the missible oil product of the obtained present composition.
Desinsection of the present invention, miticide composition, comprise following constituent content when making suspending agent: active component A l ~ 50%, active component B l% ~ 50%, dispersant 2 ~ 10%, wetting agent 2 ~ 10%, defoamer 0.1 ~ 1%, thickener 0.1 ~ 2%, binding agent 0.1 ~ 2%, antifreeze 0.1 ~ 8%, water add to 100%.Dispersant, wetting agent, defoamer, thickener, binding agent, antifreeze, water in above-mentioned formulation material are mixed through high speed shear, add active component A and B, in ball mill, ball milling 2 ~ 3 hours, makes diameter of particle all at below 5um, the suspending agent product of the obtained present composition.
Desinsection of the present invention, miticide composition, comprise following constituent content when making water dispersible granules: active component A l ~ 60%, active component B l ~ 60%, dispersant 3 ~ 12%, wetting agent l ~ 8%, disintegrant l ~ 10%, binding agent l ~ 8%, solid packing complement to 100%.Active component A is obtained together with B, dispersant, wetting agent, disintegrant, solid carrier etc. the particle diameter needed through air-flow crushing, then add other auxiliary agents such as binding agent, obtain granulation materials.Item is quantitatively sent in fluidized bed granulating dryer through granulating and after drying, obtaining the water dispersible granules product of the present composition.
Desinsection of the present invention, miticide composition, comprise following constituent content when making aqueous emulsion: active component A l ~ 40%, active component B l ~ 40%, solvent 0 ~ 30%, emulsifier l ~ 15%, antifreeze 0 ~ 10%, thickener 0.1 ~ 2%, defoamer 0.0l ~ 2%, water complement to 100%.Active component A and B, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase; Water, antifreeze, thickener, defoamer are mixed, becomes homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added oil phase, the aqueous emulsion product of the obtained present composition.
Desinsection of the present invention, miticide composition, comprise following constituent content when making microemulsion: active component A l ~ 40%, active component B l ~ 40%, solvent 0 ~ 30%, emulsifier 3 ~ 20%, cosolvent 0 ~ 20%, antifreeze 0 ~ 10%, water complements to 100%.Active component A and B are dissolved in the homogenizer that solvent and cosolvent are housed; Emulsifier, antifreeze, water are joined after in the homogenizer that above-mentioned solution is housed and gives strong mixing and homogenize, finally obtains the microemulsion product of the transparent present composition of clear appearance.
Desinsection of the present invention, miticide composition, comprise following constituent content when making soluble liquid: active component A l ~ 50%, active component B l ~ 50%, emulsifier 1 ~ 20%, synergist 1 ~ 10%, organic solvent complement to 100%.Active component A and B, organic solvent, emulsifier, synergist etc. are mixed, becomes transparent and homogeneous liquid, be i.e. the soluble liquid product of the obtained present composition.
Desinsection of the present invention, miticide composition, comprise following constituent content when making wetting powder: active component A l ~ 60%, active component B l ~ 60%, dispersant 2 ~ 10%, wetting agent 2 ~ 10%, solid packing complement to 100%.Active component A and B, dispersant, wetting agent, filler are mixed, mixes in a mixer, mix again after airslide disintegrating mill is pulverized, namely can be made into wetting powder product of the present invention.
Desinsection of the present invention, miticide composition, comprise following constituent content when making oil-suspending agent: active component A l ~ 50%, active component B l ~ 50%, emulsifier 1 ~ 20%, cosolvent 1 ~ 20%, dispersant 0 ~ 0.3%, wetting agent 0.2 ~ 1%, solvent complement to 100%.Active component A and B, emulsifier, dispersant, solvent, cosolvent are added sand milling in sand mill, until particle diameter is qualified, i.e. the oil-suspending agent product of the obtained present composition.
Described dispersant is selected from, but be not limited to: alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic acid polyethenoxy ether, polyoxyethylene carboxylate, one or more in fatty acid glyceride APEO.
Described wetting agent is selected from but is not limited to: lauryl sodium sulfate, neopelex, calcium dodecyl benzene sulfonate, Nekal BX, washing powder, agriculture breast 2000# series, wetting and penetrating agent F, wetting agent T, spaonin powder, tea are withered, one or more in silkworm excrement, sldium lauryl sulfate, alkylnaphthalene sulfonate, alkylphenol ethoxylate, polyoxyethylene tri-styryl phosphenylic acid salt, soapberry powder.
Described binding agent is selected from but is not limited to: one or more in gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, polyvinyl alcohol.
Described defoamer is selected from but is not limited to: C
8 ~ 10aliphatic alcohols, C
10 ~ 20one or more in saturated fat acids (as capric acid) and acid amides, silicone oil, silicone compound, polyoxyethylene glycerol ether.
Described emulsifier is selected from, but be not limited to: agriculture breast 500#(alkyl benzene calcium sulfonate), 0P series phosphate (thermally coupled distillation columns), 600# phosphate (phenyl phenol polyoxyethanyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400#(benzyl dimethyl phenol polyoxyethyl ether), agriculture breast 600#(phenyl phenol polyoxyethyl ether), Nongru-700 #(alkylphenol-formaldehyde resin polyoxyethyl ether), agriculture breast 36#(phenethyl fluosite polyoxyethyl ether), agriculture breast 1600#(phenethyl phenol polyoxyethanyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, 0P series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), agriculture breast 33#(alkylaryl polyoxyethylene polyoxypropylene ether), agriculture breast 34#(alkylaryl polyoxyethylene poly-oxygen propylene aether), emulsifier T-60, Span series (sorbitan monostearate), TWEEN Series (sorbitan fatty acid ester APEO), AEO series (fatty alcohol-polyoxyethylene ether), naphthalene sulfonic acids methyl condensation product, calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, aliphatic acid polyethenoxy base ester, one or more in polyoxyethylene aliphatic alcohol ether.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol, diethylene glycol (DEG), triethylene glycol.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, glucose, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described solvent is selected from: one or more or more than one in toluene, dimethylbenzene, methyl alcohol, ethanol, acetone, ether, cyclohexanone, n-butanol, isopropyl alcohol, vegetable oil, dimethyl formamide, dimethyl sulfoxide (DMSO), acetonitrile, polyethylene glycol, sec-butyl acetate, methyl oleate, pyrrolidones, solvent N-chain alkyl pyrrolidones, biodiesel, diesel oil, turpentine oil, solvent naphtha, water are with mixed solvents of arbitrary proportion composition.
Described solid carrier is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Described synergist is selected from: any one in organic silicon pesticide synergist, organic silicon pesticide bleeding agent spreading agent, agricultural organic silicon pesticide synergist, azone.
Desinsection of the present invention, miticide composition, can be used for insect, evil mite, soil insect or the urban health insect on control fruit tree, vegetables, ornamental plants, tea, cotton, cereal crop etc. and have protective effect to plurality of plant diseases; Especially can be used for the sucking pest prevented and treated in various crop, as lepidoptera pest and urban health insects such as plant hopper, aleyrodid, aphid, thrips, leafhopper, blister mite, tetranychid and striped rice borer, corn borer, diamond-back moth, mythimna separata, leaf miner, cotton bollworm, cockroaches.
Especially, desinsection of the present invention, miticide composition, can be used for preventing and treating citrus red mite (crm) especially, citrus rust mite, the citrus beginning tetranychid, tetranychus viennensis, panonychus ulmi, carex fruit mite, Tetranychus urticae, yellow tea mite, pink tea rust mite, privet mite, tealeaves goitre mite, Tetranychus cinnabarinus, Mite, O.turkestanicumvar. tuberculata, Dunhuang tetranychid, penthaleus major, grain spider mite, jujube tick, to cause harm the Tetranychus of jujube tree, Eotetranychus evil mite, harmful mite on vegetable or flower, citrus leaf-miner, citrus scale insect, fruit tree leaf miner, fruit tree budworm, soybean pod borer, apple leaf miner, tea geometrid, tea caterpillar, tea lesser leafhopper, pear sucker, water rice hopper, Trialeurodes vaporariorum Westwood, Americal rice leaf miner, striped flea-beetle, striped rice borer, paddy stem borer, corn borer, lima bean pod borer, pathogenicity test, rice water weevil, cotton bollworm, pink bollworm, root-knot nematode, fruit aphid, soybean aphid, vegetable aphid, wheat aphid, cotten aphid, diamond-back moth, mythimna separata, cabbage caterpillar, oriental tobacco budworm, longicorn, mosquito, fly, blattaria, the insects such as termite, evil mite or urban health insect, therefore, technical scheme of the present invention also comprises desinsection of the present invention, miticide composition for the preparation of the purposes of agricultural insecticidal, miticide medicine.
Desinsection of the present invention, miticide composition, can effective dose impose on need control insect/evil mite and/or its habitat on.
The advantage that the present invention has: phonetic mite amine and nicotinoids or insect growth regulator, IGR class Insecticidal and acaricidal agent composite binary composition obtained under suitable ratio are had good synergistic effect by the present invention, and then raising preventive effect, reduce dosage, expand insecticidal spectrum.Specifically,
1, composite A, B two kinds of active components have the different mechanism of action, can delay insect, the drug-fast generation of evil mite.2, expand insecticidal spectrum, can be used for preventing and treating the various pests in the various crop such as fruit tree, vegetables, ornamental plants, tea, cotton, harmful mite; 3, reduce Pesticide use amount, reduce the residual quantity of agricultural chemicals on crop, enhance the friendly to environment.4, A, B two active components are composite in suitable proportion, improve the control efficiency to the insects such as Tetranychus cinnabarinus, brown plant-hopper, mythimna separata, black peach aphid, evil mite.
Embodiment
Following examples for describing the present invention in detail so that understand the present invention further.Active component A is selected from phonetic mite amine (preparing gained by the record in CN101906075A patent document, content 98%); Active component B and other raw materials are commercial goods.Be metered into after active component folding hundred in formulation Example, each component is measured by weight percentage.
Formulation Example
Embodiment 1:10% phonetic mite amine acetamiprid EC (1:1)
Phonetic mite amine 5%, Acetamiprid 5%, styrylphenol polyoxyethylene ether 8%, calcium dodecyl benzene sulfonate 12%, dimethylbenzene complement to 100%.Above raw material is prepared routinely the method for missible oil, after mixing, stirring and dissolving completely, i.e. obtained 10% phonetic mite amine acetamiprid EC.
Embodiment 2:25% phonetic mite amine Diacloden suspending agent (1:4)
Phonetic mite amine 5%, Diacloden 20%, sodium lignin sulfonate 2%, xanthans 0.2%, ethylene glycol 5%, Magnesiumaluminumsilicate 1%, neopelex 2%, silicone defoaming agent 0.2%, water complement to 100%.Above raw material is prepared routinely the method for suspending agent, after mixing, high speed shear dispersion, sand milling, i.e. obtained 25% phonetic mite amine Diacloden suspending agent.
Embodiment 3:70% phonetic mite amine pymetrozine water dispersing granule (3:2)
Phonetic mite amine 42%, pymetrozine 28%, alkylphenol polyoxyethylene formaldehyde condensation products sulphate 4%, lignosulfonates 5%, calcium dodecyl benzene sulfonate 3%, polyethylene glycol 5%, sodium bicarbonate 6%, white carbon complement to 100%.Above raw material is prepared routinely the method for water dispersible granules, through mixing, air-flow crushing, i.e. obtained 70% phonetic mite amine pymetrozine water dispersing granule.
Embodiment 4:9% phonetic mite amine lufenuron aqueous emulsion (1:5)
Phonetic mite amine 1.5%, lufenuron 7.5%, polyoxyethylene nonylphenol ether 10%, alkylaryl polyoxyethylene polyoxypropylene ether 3%, methyl alcohol 15%, water complement to 100%.Above raw material is prepared routinely the method for aqueous emulsion, through being fully uniformly mixed, i.e. obtained 9% phonetic mite amine lufenuron aqueous emulsion.
Embodiment 5:5% phonetic mite amine acetamiprid micro emulsion agent (4:1)
Phonetic mite amine 4%, Acetamiprid 1%, thermally coupled distillation columns 20%, neopelex 10%, toluene 12%, ethanol 8%, water complement to 100%.Above raw material is prepared routinely the method for microemulsion, dissolve completely and stir, be i.e. obtained 5% phonetic mite amine acetamiprid micro emulsion agent.
Embodiment 6:24% phonetic mite amine diafenthiuron soluble liquid (5:1)
Phonetic mite amine 20%, diafenthiuron 4%, calcium dodecyl benzene sulfonate 6%, styrylphenol polyoxyethylene ether 3%, dimethyl formamide complement to 100%.Above raw material is prepared routinely the method for soluble liquid, first active component is dissolved in a solvent, then add surfactant and other components, stir, be i.e. obtained 24% phonetic mite amine diafenthiuron soluble liquid.
Embodiment 7:36% phonetic mite amine wettable powder with buprofezin (1:5)
Phonetic mite amine 6%, Buprofezin 30%, calcium lignosulfonate 5%, alkylnaphthalene sulfonate formaldehyde condensation products 4%, white carbon 6%, attapulgite complement to 100%.Above raw material is prepared routinely the method for wetting powder, fully mix and be crushed to certain fineness, be i.e. obtained 36% phonetic mite amine wettable powder with buprofezin.
Embodiment 8:50% phonetic mite amine diflubenzuron wetting powder (2:3)
Phonetic mite amine 20%, diflubenzuron 30%, calcium lignosulfonate 4%, polyoxyethylene nonylphenol ether 3%, Nekal BX 2%, white carbon 3%, precipitated calcium carbonate complement to 100%.Above raw material is prepared routinely the method for wetting powder, fully mix and be crushed to certain fineness, be i.e. obtained 50% phonetic mite amine diflubenzuron wetting powder.
Embodiment 9:20% phonetic mite amine pymetrozine oil suspending agent (1:3)
Phonetic mite amine 5%, pymetrozine 15%, naphthalene sulfonic acids methyl condensation product 3%, Nongru-700 5%, BY-1105%, agriculture breast 22010.3%, white carbon 0.5%, isopropyl alcohol 6%, methyl oleate complement to 100%.Above raw material is prepared routinely the method for oil-suspending agent, by mixing after each component grinding, i.e. obtained 20% phonetic mite amine pymetrozine oil suspending agent.
Toxicity measures embodiment
Embodiment 10: phonetic mite amine and Acetamiprid mixture are tested the indoor joint toxicity measuring of Tetranychus cinnabarinus
For examination target: Tetranychus cinnabarinus [Tetranychus cinnabarinus(boisduval)] become mite, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt potted plant seedling spray-on process to measure active size Tetranychus cinnabarinus being become to mite.First becoming mite to receive Tetranychus cinnabarinus of the same size is on the Tolerance of Kidney Bean Seedlings blade of first pair of true leaf open and flat phase, after becoming mite stable, count radix; Then by the order even spraying of experimental scheme from low dosage to high dose, every strain 1.5mL, often processes and repeats for 3 times, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours " Invest, Then Investigate " mite numbers dead, alive.With abbott formulae discovery corrected mortality, carry out statistical analysis with DPS data processing software, obtain each the virulence regression equation formula, the LC that use with for examination single dose and variant proportioning
50value and 95% confidence limit, then use Sun Yunpei (Sun y-p) method to calculate the co-toxicity coefficient of each proportioning, evaluate mixed effect, result of the test is in table 1.
The co-toxicity coefficient (CTC value) of mixture is by following formulae discovery:
In formula: ATI-mixture actual measurement toxicity index; The LC of S-standard agent
50; The LC of M-mixture
50.
TTI=TIA×PA+TIB×PB
In formula: the theoretical toxicity index of TTI-mixture; TIA-A medicament toxicity index; The percentage composition of PA-A medicament in mixture; TIB-B medicament toxicity index; The percentage composition of PB-B medicament in mixture.
In formula: CTC-co-toxicity coefficient; ATI-mixture actual measurement toxicity index; The theoretical toxicity index of TTI-mixture.
The co-toxicity coefficient (CTC) of built agent: CTC >=100 show as synergistic effect; CTC≤100 show as antagonism.
The phonetic mite amine of table 1 and Acetamiprid mixture are to the indoor joint toxicity measuring result of Tetranychus cinnabarinus
Embodiment 11: phonetic mite amine and Acetamiprid mixture are tested black peach aphid synergism determination
For examination target: black peach aphid [Myzus persicae(Sulzer)] if become aphid, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: if adopt spray-on process to measure active size black peach aphid being become to aphid.First select, with the cabbage seedling blade of neat, consistent black peach aphid, often to open blade and carry worm amount about 20, then by the order even spraying of experimental scheme from low dosage to high dose, every sheet leaf 1.5mL, often processes repetition 3 times, separately establishes blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.48 hours dead, alive borer populations of " Invest, Then Investigate ".By the actual measurement lethality of each process of abbott formulae discovery.
Mixture effect assessment adopts Bliss method, and the independent joint action concept that Bliss proposes according to it is thought, theoretical lethality P during Mixture Use of Insecticides can calculate with following formula:
P=Pm+Pn（1-Pm）
Pm is the actual measurement lethality (%) of the first active component target when concentration is m; The actual measurement lethality (%) of Pn is the second active component working concentration when being n target.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, then judge that two kinds of active components are used in combination under setting concentration and has synergistic effect, otherwise be then antagonism, result of the test is in table 2.
The phonetic mite amine of table 2 and Acetamiprid mixture are to black peach aphid synergism determination result
Embodiment 12: phonetic mite amine and Diacloden mixture are tested the indoor joint toxicity measuring of Tetranychus cinnabarinus
For examination target: Tetranychus cinnabarinus [Tetranychus cinnabarinus(boisduval)] become mite, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt potted plant seedling spray-on process to measure active size Tetranychus cinnabarinus being become to mite.First becoming mite to receive Tetranychus cinnabarinus of the same size is on the Tolerance of Kidney Bean Seedlings blade of first pair of true leaf open and flat phase, after becoming mite stable, count radix; Then by the order even spraying of experimental scheme from low dosage to high dose, every strain 1.5mL, often processes and repeats for 3 times, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours " Invest, Then Investigate " mite numbers dead, alive.With abbott formulae discovery corrected mortality, carry out statistical analysis with DPS data processing software, obtain each the virulence regression equation formula, the LC that use with for examination single dose and variant proportioning
50value and 95% confidence limit, co-toxicity calculates and adopts Sun Yunpei (Sun y-p) method, with embodiment 10.Result of the test is in table 3.
The phonetic mite amine of table 3 and Diacloden mixture are to the indoor joint toxicity measuring result of Tetranychus cinnabarinus
Embodiment 13: phonetic mite amine and Diacloden mixture are tested brown plant-hopper synergism determination
For examination target: brown plant-hopper [Nilaparvata lugens(Stal)] nymph, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt the active size of potted plant seedling spray-on process mensuration to rice brown planthopper nymph.First plant in culturing pot by rice seedling, by the order even spraying of experimental scheme from low dosage to high dose, every strain 2mL, is then connected on rice seedling by rice brown planthopper nymph of the same size, often processes 3 times and repeats, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours dead, alive borer populations of " Invest, Then Investigate ".By the actual measurement lethality of each process of abbott formulae discovery.
Mixture effect assessment adopts Bliss method, with embodiment 11.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, are then judging that two kinds of active components are used in combination under setting concentration and there is synergistic effect, otherwise be then antagonism.Result of the test is in table 4.
The phonetic mite amine of table 4 and Diacloden mixture are to rice fulgorid synergism determination result
Embodiment 14: phonetic mite amine and Diacloden mixture are tested black peach aphid synergism determination
For examination target: black peach aphid [Myzus persicae(Sulzer)] if become aphid, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: if adopt spray-on process to measure active size black peach aphid being become to aphid.First select, with the cabbage seedling blade of neat, consistent black peach aphid, often to open blade and carry worm amount about 20, then by the order even spraying of experimental scheme from low dosage to high dose, every sheet leaf 1.5mL, often processes repetition 3 times, separately establishes blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.48 hours dead, alive borer populations of " Invest, Then Investigate ".By the actual measurement lethality of each process of abbott formulae discovery.
Mixture effect assessment adopts Bliss method, with embodiment 11.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, are then judging that two kinds of active components are used in combination under setting concentration and there is synergistic effect, otherwise be then antagonism.Result of the test is in table 5.
The phonetic mite amine of table 5 and Diacloden mixture are to black peach aphid synergism determination result
Embodiment 15: phonetic mite amine and clothianidin mixture are tested the indoor joint toxicity measuring of Tetranychus cinnabarinus
For examination target: Tetranychus cinnabarinus [Tetranychus cinnabarinus(boisduval)] become mite, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt potted plant seedling spray-on process to measure active size Tetranychus cinnabarinus being become to mite.First becoming mite to receive Tetranychus cinnabarinus of the same size is on the Tolerance of Kidney Bean Seedlings blade of first pair of true leaf open and flat phase, after becoming mite stable, count radix; Then by the order even spraying of experimental scheme from low dosage to high dose, every strain 1.5mL, often processes and repeats for 3 times, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours " Invest, Then Investigate " mite numbers dead, alive.With abbott formulae discovery corrected mortality, carry out statistical analysis with DPS data processing software, obtain each the virulence regression equation formula, the LC that use with for examination single dose and variant proportioning
50value and 95% confidence limit, co-toxicity calculates and adopts Sun Yunpei (Sun y-p) method, with embodiment 10.Result of the test is in table 6.
The phonetic mite amine of table 6 and clothianidin mixture are to the indoor joint toxicity measuring result of Tetranychus cinnabarinus
Embodiment 16: phonetic mite amine and pymetrozine mixture are tested the indoor joint toxicity measuring of Tetranychus cinnabarinus
For examination target: Tetranychus cinnabarinus [Tetranychus cinnabarinus(boisduval)] become mite, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt potted plant seedling spray-on process to measure active size Tetranychus cinnabarinus being become to mite.First becoming mite to receive Tetranychus cinnabarinus of the same size is on the Tolerance of Kidney Bean Seedlings blade of first pair of true leaf open and flat phase, after becoming mite stable, count radix; Then by the order even spraying of experimental scheme from low dosage to high dose, every strain 1.5mL, often processes and repeats for 3 times, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours " Invest, Then Investigate " mite numbers dead, alive.With abbott formulae discovery corrected mortality, carry out statistical analysis with DPS data processing software, obtain each the virulence regression equation formula, the LC that use with for examination single dose and variant proportioning
50value and 95% confidence limit, co-toxicity calculates and adopts Sun Yunpei (Sun y-p) method, with embodiment 10.Result of the test is in table 7.
The phonetic mite amine of table 7 and pymetrozine mixture are to the indoor joint toxicity measuring result of Tetranychus cinnabarinus
Embodiment 17: phonetic mite amine and Buprofezin mixture are tested the indoor joint toxicity measuring of Tetranychus cinnabarinus
For examination target: Tetranychus cinnabarinus [Tetranychus cinnabarinus(boisduval)] become mite, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt potted plant seedling spray-on process to measure active size Tetranychus cinnabarinus being become to mite.First becoming mite to receive Tetranychus cinnabarinus of the same size is on the Tolerance of Kidney Bean Seedlings blade of first pair of true leaf open and flat phase, after becoming mite stable, count radix; Then by the order even spraying of experimental scheme from low dosage to high dose, every strain 1.5mL, often processes and repeats for 3 times,
Separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours " Invest, Then Investigate " mite numbers dead, alive.With abbott formulae discovery corrected mortality, carry out statistical analysis with DPS data processing software,
Obtain each the virulence regression equation formula, the LC that use with for examination single dose and variant proportioning
50value and 95% confidence limit, co-toxicity calculates and adopts Sun Yunpei (Sun y-p) method, with embodiment 10.Result of the test is in table 8.
The phonetic mite amine of table 8 and Buprofezin mixture are to the indoor joint toxicity measuring result of Tetranychus cinnabarinus
Embodiment 18: phonetic mite amine and lufenuron mixture are tested the indoor joint toxicity measuring of Tetranychus cinnabarinus
For examination target: Tetranychus cinnabarinus [Tetranychus cinnabarinus(boisduval)] become mite, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt potted plant seedling spray-on process to measure active size Tetranychus cinnabarinus being become to mite.First becoming mite to receive Tetranychus cinnabarinus of the same size is on the Tolerance of Kidney Bean Seedlings blade of first pair of true leaf open and flat phase, after becoming mite stable, count radix; Then by the order even spraying of experimental scheme from low dosage to high dose, every strain 1.5mL, often processes and repeats for 3 times, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours " Invest, Then Investigate " mite numbers dead, alive.With abbott formulae discovery corrected mortality, carry out statistical analysis with DPS data processing software, obtain each the virulence regression equation formula, the LC that use with for examination single dose and variant proportioning
50value and 95% confidence limit, co-toxicity calculates and adopts Sun Yunpei (Sun y-p) method, with embodiment 10.Result of the test is in table 9.
The phonetic mite amine of table 9 and lufenuron mixture are to the indoor joint toxicity measuring result of Tetranychus cinnabarinus
Embodiment 19: phonetic mite amine and lufenuron mixture are tested mythimna separata synergism determination
For examination target: mythimna separata (Mythimna seperata) 3 instar larvaes, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt the active size of infusion process mensuration to armyworm larvae.First blade in the middle part of the fresh corn of greenhouse culture is selected to be cut into 3cm segment, by the order of experimental scheme from low dosage to high dose, put into the liquid prepared and flood 10s, naturally drying in the shade, to be placed on the diameter being placed with filter paper be in the culture dish of 9cm, access neat health examination worm, often process 10, often process 3 times and repeat, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours dead, alive borer populations of " Invest, Then Investigate ".By the actual measurement lethality of each process of abbott formulae discovery.
Mixture effect assessment adopts Bliss method, with embodiment 11.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, then judge that two kinds of active components are used in combination under setting concentration and has synergistic effect, otherwise be then antagonism, result of the test is in table 10.
The phonetic mite amine of table 10 and lufenuron mixture are to mythimna separata synergism determination result
Embodiment 20: phonetic mite amine and HEXAFLUMURON, diflubenzuron mixture are tested mythimna separata synergism determination
For examination target: mythimna separata (Mythimna seperata) 3 instar larvaes, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt the active size of infusion process mensuration to armyworm larvae.First blade in the middle part of the fresh corn of greenhouse culture is selected to be cut into 3cm segment, by the order of experimental scheme from low dosage to high dose, put into the liquid prepared and flood 10s, naturally drying in the shade, to be placed on the diameter being placed with filter paper be in the culture dish of 9cm, access neat health examination worm, often process 10, often process 3 times and repeat, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours dead, alive borer populations of " Invest, Then Investigate ".By the actual measurement lethality of each process of abbott formulae discovery.
Mixture effect assessment adopts Bliss method, with embodiment 11.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, then judge that two kinds of active components are used in combination under setting concentration and has synergistic effect, otherwise be then antagonism, result of the test is in table 11.
The phonetic mite amine of table 11 and HEXAFLUMURON, diflubenzuron mixture are to mythimna separata synergism determination result
Embodiment 21: phonetic mite amine and diafenthiuron mixture are tested the indoor joint toxicity measuring of Tetranychus cinnabarinus
For examination target: Tetranychus cinnabarinus [Tetranychus cinnabarinus(boisduval)] become mite, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt potted plant seedling spray-on process to measure active size Tetranychus cinnabarinus being become to mite.First becoming mite to receive Tetranychus cinnabarinus of the same size is on the Tolerance of Kidney Bean Seedlings blade of first pair of true leaf open and flat phase, after becoming mite stable, count radix; Then by the order even spraying of experimental scheme from low dosage to high dose, every strain 1.5mL, often processes and repeats for 3 times, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours " Invest, Then Investigate " mite numbers dead, alive.With abbott formulae discovery corrected mortality, carry out statistical analysis with DPS data processing software, obtain each the virulence regression equation formula, the LC that use with for examination single dose and variant proportioning
50value and 95% confidence limit, co-toxicity calculates and adopts Sun Yunpei (Sun y-p) method, with embodiment 10.Result of the test is in table 12.
The phonetic mite amine of table 12 and diafenthiuron mixture are to the indoor joint toxicity measuring result of Tetranychus cinnabarinus
The explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.From above technical scheme, desinsection of the present invention, miticide composition have raising drug effect, expand insecticidal spectrum, reduce pesticide dosage, reduce the residual quantity of agricultural chemicals on crop, alleviate the pollution to environment, to person poultry safety, Environmental compatibility is good, and insect not easily develops immunity to drugs.The present composition can be applicable to the various pests of various crop, the control of evil mite, can be widely used in agriculture field.
Claims (10)
1. the synergistic complex composition containing two kinds of active components, is characterized in that: containing A, B two kinds of active components, component A is selected from phonetic mite amine, and B component is selected from the Insecticidal and acaricidal agent of nicotinoids or insect growth regulator, IGR class; The ratio of weight and number of component A, B two kinds of active components is 1:99 to 99:1; Wherein, phonetic mite amine structure formula is as follows:
2. the synergistic complex composition containing two kinds of active components according to claim 1, is characterized in that: described B component is nicotinic insecticide or insect growth regulator, IGR class Insecticidal and acaricidal agent;
Described nicotinic insecticide is selected from Acetamiprid, Diacloden, clothianidin, thiacloprid, Imidacloprid, Nitenpyram, MTI-446, imidaclothiz, the pyridine of sulfone worm or the pyridine of piperazine worm;
Described insect growth regulator, IGR class desinsection, miticide is selected from pymetrozine, flonicamid, Buprofezin, cyromazine, hydroprene, kinoprene, methoprene, Nylar, lufenuron, HEXAFLUMURON, diflubenzuron, fluazuron, pyridalyl, bistrifluron, chlorfluazuron, CGA 183893, flucycloxuron, flufenoxuron, fluorine uride, noviflumuron, penfluron, fluorobenzene urea, triflumuron, d ichlorbenzuron, ring worm hydrazides, chlorine worm hydrazides, methoxyfenozide, worm hydrazides, furan tebufenozide, diafenthiuron, deinsectization is grand, fluorine mite piperazine or sulcofuron-sodium.
3. the synergistic complex composition containing two kinds of active components according to claim 1, is characterized in that: component A is selected from phonetic mite amine; B component is selected from Acetamiprid, Diacloden, clothianidin, Nitenpyram, pymetrozine, Buprofezin, cyromazine, Nylar, lufenuron, HEXAFLUMURON, diflubenzuron, pyridalyl, flucycloxuron, chlorfluazuron, fluorine uride, triflumuron, flufenoxuron, penfluron, d ichlorbenzuron, worm hydrazides, diafenthiuron or fluorine mite piperazine;
The ratio of weight and number of component A, B two kinds of active components is 1:20 to 20:1.
4. the synergistic complex composition containing two kinds of active components according to claim 3, is characterized in that: described component A is selected from phonetic mite amine; B component is selected from Acetamiprid, Diacloden, clothianidin;
The ratio of weight and number of component A, B two kinds of active components is 1:10 to 10:1.
5. the synergistic complex composition containing two kinds of active components according to claim 3, is characterized in that:
Component A is selected from phonetic mite amine; B component is selected from pymetrozine;
The ratio of weight and number of component A, B two kinds of active components is 1:4 to 2:1.
6. the synergistic complex composition containing two kinds of active components according to claim 3, is characterized in that:
Component A is selected from phonetic mite amine; B component is selected from Buprofezin;
The ratio of weight and number of component A, B two kinds of active components is 1:5 to 3:1.
7. the synergistic complex composition containing two kinds of active components according to claim 3, is characterized in that:
Component A is selected from phonetic mite amine; B component is selected from lufenuron, HEXAFLUMURON, diflubenzuron;
The ratio of weight and number of component A, B two kinds of active components is 1:10 to 10:1.
8. the synergistic complex composition containing two kinds of active components according to claim 3, is characterized in that:
Component A is selected from phonetic mite amine; B component is selected from diafenthiuron;
The ratio of weight and number of component A, B two kinds of active components is 3:1 to 5:1.
9. the synergistic complex composition containing two kinds of active components according to claim 1-8 any one, is characterized in that:
Described composition can be made into missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent.
10. the application containing the synergistic complex composition of two kinds of active components according to claim 1, is characterized in that: described composition is for the preparation of the insect on control fruit tree, vegetables, ornamental plants, tea, cotton, cereal crop, evil mite or urban health insect and the Insecticidal and acaricidal agent medicine to plurality of plant diseases.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104920372A (en) * | 2015-05-08 | 2015-09-23 | 天峨县平昌生态农业有限公司 | Acaricidal composition comprising pyriminostrobin and chlorofluorocarbon cyantraniliprole |
| CN105994327A (en) * | 2016-05-31 | 2016-10-12 | 刘雨 | Composition for preventing and treating Chinese cabbage white spot disease and preparation method thereof |
| CN108684664A (en) * | 2018-05-15 | 2018-10-23 | 唐勇 | Mite killing auxiliary agent |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114631535B (en) * | 2020-12-15 | 2024-06-07 | 江苏扬农化工股份有限公司 | Composition and method for preventing and controlling breeding field fly larvae |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101087531A (en) * | 2004-12-24 | 2007-12-12 | 拜尔农作物科学股份公司 | Insecticides based on selected neonicotinoids and strobilurins |
| CN101642128A (en) * | 2009-08-01 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Pesticide composite with fenpyroximate |
| CN101906075A (en) * | 2009-06-05 | 2010-12-08 | 中国中化股份有限公司 | E-type phenyl acrylic acid ester compound containing substituted anilino pyrimidine group and applications thereof |
| CN103329914A (en) * | 2013-07-23 | 2013-10-02 | 陕西农心作物科技有限公司 | Acaricidal composition containing pyriminostrobin and bifenazate |
| CN103355314A (en) * | 2013-08-02 | 2013-10-23 | 陕西上格之路生物科学有限公司 | Acaricidal composition containing pyriminostrobin and etoxazole |
| CN103907623A (en) * | 2012-12-31 | 2014-07-09 | 陕西汤普森生物科技有限公司 | Efficient acaricidal composition containing pyriminostrobin |
-
2013
- 2013-10-31 CN CN201310531151.5A patent/CN104585217B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101087531A (en) * | 2004-12-24 | 2007-12-12 | 拜尔农作物科学股份公司 | Insecticides based on selected neonicotinoids and strobilurins |
| CN101906075A (en) * | 2009-06-05 | 2010-12-08 | 中国中化股份有限公司 | E-type phenyl acrylic acid ester compound containing substituted anilino pyrimidine group and applications thereof |
| CN101642128A (en) * | 2009-08-01 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Pesticide composite with fenpyroximate |
| CN103907623A (en) * | 2012-12-31 | 2014-07-09 | 陕西汤普森生物科技有限公司 | Efficient acaricidal composition containing pyriminostrobin |
| CN103329914A (en) * | 2013-07-23 | 2013-10-02 | 陕西农心作物科技有限公司 | Acaricidal composition containing pyriminostrobin and bifenazate |
| CN103355314A (en) * | 2013-08-02 | 2013-10-23 | 陕西上格之路生物科学有限公司 | Acaricidal composition containing pyriminostrobin and etoxazole |
Non-Patent Citations (1)
| Title |
|---|
| 嵇保中主编: "《林木化学保护学》", 31 August 2011 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104920372A (en) * | 2015-05-08 | 2015-09-23 | 天峨县平昌生态农业有限公司 | Acaricidal composition comprising pyriminostrobin and chlorofluorocarbon cyantraniliprole |
| CN105994327A (en) * | 2016-05-31 | 2016-10-12 | 刘雨 | Composition for preventing and treating Chinese cabbage white spot disease and preparation method thereof |
| CN108684664A (en) * | 2018-05-15 | 2018-10-23 | 唐勇 | Mite killing auxiliary agent |
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|---|---|
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