CN103875699B - Composition containing pyrethroid pesticide and applications thereof - Google Patents
Composition containing pyrethroid pesticide and applications thereof Download PDFInfo
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- CN103875699B CN103875699B CN201210559125.9A CN201210559125A CN103875699B CN 103875699 B CN103875699 B CN 103875699B CN 201210559125 A CN201210559125 A CN 201210559125A CN 103875699 B CN103875699 B CN 103875699B
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Abstract
The invention belongs to the field of pesticides, and discloses a composition for killing inspects and mites. The composition comprises two active components, namely an active component A and an active component B; the active component A is pyriminostrobin, the active component B is pyrethroid pesticide, and the weight ratio of the active component A to the active component B is 1:99 to 99:1. The composition has a prominent synergetic effect, and is used to control multiple kinds of harmful insects and mites.
Description
Technical field
The invention belongs to pesticide field, relate to a kind of synergistic complex composition containing two kinds of active components, be specifically related to a kind of composition containing pyrethroid insecticides and application thereof.
Background technology
In the real process of agricultural production, using chemical agent is one of the most effective means of control plant pest, but is insect, the drug-fast generation of evil mite by the problem that chemical control insect the most easily produces.Use single pest control with insecticide, miticide continuously high dose simultaneously for a long time, easily cause the series of problems such as the remaining of medicament, environmental pollution.Composite or the mixture of rational pest control with insecticide, miticide has and expands desinsection, kills mite spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce and remain, delay insect, evil mite drug resistance and the positive feature such as drug-fast generation and development, the composite or mixture of Insecticidal and acaricidal agent is one of the effective method the most solved the problem.
Pyrethroid insecticides take natural products as the pesticide species that lead compound is succeeded in developing.That to have bioactive natural products pyrethrin be lead compound, the insecticides for health and crop protection carrying out that further synthesis optimizing obtains, existing tens kinds of this insecticides at present.Pyrethrin from chrysanthemum Tanacetum cinerariifolium or its extract, at present still for preventing and treating public health insect.Pyrethrin has six components (pyrethrin I, pyrethrin II, cinerin I, cinerin II, jasmolin I, jasmolin II), and wherein pyrethrin I has contact toxicity, and pyrethrin II knocks down activity.Pyrethroid insecticides is efficient, the broad spectrum pesticide that a class can prevent and treat various pests, and it has strong action of contace poison to insect, and quick-acting is good, and power of knocking down is fast.Pyrethroid insecticides is to the virulence of insect than other common insecticide height 1-2 order of magnitude, and its mechanism of action upsets the normal physiological of insect nerve, make it by excited, spasm is dead to benumbing.The insect of pyrethroid insecticides to aspects such as agricultural, gardening, warehouse, herding, health all has good control efficiency, but to mite class weak effect.
Chinese invention patent CN101906075A discloses the purposes of a kind of E-type phenyl acrylates compounds containing substituted anilino pyrimidine group and Control pests thereof, evil mite, wherein compound 9(Universal Chinese character name: phonetic mite amine, English common name: pyriminostrobin) can be used for preventing and treating various pests, evil mite, especially to mite class, there is outstanding control efficiency, be subject to the extensive attention of industry.This structural formula of compound is as follows:
Different cultivars composition carries out composite, may produce the technique effect that some is unexpected, is also one of control resistant insect, the effective ways doing harm to mite.But, have no the report of phonetic mite amine and pyrethroid insecticides complex composition so far.
Summary of the invention
The object of the invention is to develop a kind of the binary desinsection, the miticide composition that contain phonetic mite amine and pyrethroid insecticides, to improve preventive effect, reduce dosage, expand insecticidal spectrum.Result of study shows, by phonetic mite amine and pyrethroid insecticides, the composite binary composition obtained under suitable ratio has good synergistic effect, thus completes the present invention.
Technical solution of the present invention is as follows:
Desinsection, a miticide composition containing pyrethroid insecticides, containing A, B two kinds of active components,
Component A is selected from phonetic mite amine, and structural formula is as follows:
B component is selected from pyrethroid insecticides, and described pyrethroid insecticides is selected from pyrethrin (pyrethrins), Biphenthrin (bifenthrin), cyfloxylate (cyfluthrin), betacyfluthrin (beta-cyfluthrin), essence gamma cyhalothrin (gamma-cyhalothrin), gamma cyhalothrin (lambda-cyhalothrin), cypermethrin (cypermethrin), Cyhalothrin (cyhalothrin), alpha-cypermethrin (alpha-cypermethrin), beta-cypermethrin (beta-cypermethrin), beta-cypermethrin (theta-cypermethrin), zeta-cypermethrin (zeta-cypermethrin), tefluthrin (tefluthrin), tetramethrin (tetramethrin), allethrin (allethrin), bioallethrin (bioallethrin), cis resmethrin (cismethrin), resmethrin (resmethrin), bioresmethrin (bioresmethrin), flucythrinate (flucythrinate), permethrin (permethrin), fenpropathrin (fenpropathrin), cycloprothrin (cycloprothrin), taufluvalinate (tau-fluvalinate), metofluthrin (metofluthrin), decis (deltamethrin), acrinathrin (acrinathrin), dimefluthrin (dimefluthrin), etrafluorine ethofenprox (tetramethylfluthrin), cyphenothrin (cyphenothrin), empenthrin (empenthrin), sumicidin (fenvalerate), esfenvalerate (esfenvalerate), Imiprothrin (imiprothrin), tralomethrin (tralomethrin), chlorine fluorine ether chrysanthemum ester (meperfluthrin), transfluthrin (transfluthrin), phenothrin (phenothrin), prallethrin (prallethrin), fenfluthrin (fenfluthrin), fenpirithrin (fenpyrithrin), trifluoro chrysanthemum ester (flufenprox), flumethrin (flumethrin), kadethrin (kadethrine), terallethrin (terallethrin), brofluthrinate (brofluthrinate), ether chrysanthemum ester (ethofenprox), halfenprox (halfenprox), silafluofene (silafluofen), propyl benzene hydrocarbon chrysanthemum ester (protrifute), sulfime ether (sulfoxime), biopermethrin (biopermethrin), esdepallethrine, barthrin, bifenthrin, bioethanomethrin, brofenvalerate, bromethrin, butethrin, chlorempenthrin, cyclethrin, dimethrin, furamethrin, furethrin, japothrins, methothrin, pentmethrin, transpermethrin, profluthrin, proparthrin, pyresmethrin, tralocythrin, valerate, etofenprox, protrifenbute or thiofluoximate,
The ratio of weight and number of A, B two kinds of active components is 1:99 to 99:1.
The comparatively preferred technical scheme of the present invention is:
In described desinsection, miticide composition, component A is selected from phonetic mite amine; B component is selected from gamma cyhalothrin (B1), cypermethrin (B2), beta-cypermethrin (B3), permethrin (B4), cyfloxylate (B5), betacyfluthrin (B6), sumicidin (B7) or Biphenthrin (B8);
The ratio of weight and number of A, B two kinds of active components is 1:20 to 20:1.
The present invention further preferred technical scheme is:
In described desinsection, miticide composition, component A is selected from phonetic mite amine; B component is selected from gamma cyhalothrin (B1);
The ratio of weight and number of A, B two kinds of active components is 1:20 to 8:1.
Or the present invention further preferred technical scheme is:
In described desinsection, miticide composition, component A is selected from phonetic mite amine; B component is selected from cypermethrin (B2), beta-cypermethrin (B3), betacyfluthrin (B6) or sumicidin (B7);
The ratio of weight and number of A, B two kinds of active components is 1:20 to 1:1.
Or the present invention further preferred technical scheme is:
In described desinsection, miticide composition, component A is selected from phonetic mite amine; B component is selected from permethrin (B4);
The ratio of weight and number of A, B two kinds of active components is 1:10 to 1:1.
Or the present invention further preferred technical scheme is:
In described desinsection, miticide composition, component A is selected from phonetic mite amine; B component is selected from cyfloxylate (B5);
The ratio of weight and number of A, B two kinds of active components is 1:10 to 5:1.
Desinsection of the present invention, miticide composition have obvious synergistic effect for preventing and treating the insect on fruit tree, vegetables, ornamental plants, tea, cotton, cereal crop, harmful mite or urban health insect.Indoor biological determination of activity result shows, and phonetic mite amine and chrysanthemum ester insecticide mixture can be improved preventive effect, reduces dosage, expands insecticidal spectrum.Such as, when phonetic mite amine and gamma cyhalothrin (B1) carry out mixture in the proportion of 1:2 to 8:1, the activity to Tetranychus cinnabarinus can greatly be improved; When phonetic mite amine and gamma cyhalothrin (B1), cypermethrin (B2), beta-cypermethrin (B3) or sumicidin (B7) etc. carry out mixture in the proportion of 1:20 to 1:1, good synergistic effect is shown to brown plant-hopper or Groton bug; When phonetic mite amine and cyfloxylate (B5) carry out mixture in the proportion of 1:10 to 5:1, obvious to the synergistic effect of corn borer; When phonetic mite amine and permethrin (B4) or betacyfluthrin (B6) in the proper ratio mixture time, to the control of mythimna separata, there is synergistic effect.Therefore, another technical scheme of the present invention is the purposes of two kinds of active component compositions of the present invention for the preparation of Insecticidal and acaricidal agent medicine.
In desinsection of the present invention, miticide composition, the cumulative amount (by weight, lower same) of active component, between 0.5% ~ 95%, is preferably between 1% ~ 85%.According to different preparation types, active component cumulative amount scope is different.Usually, in liquid preparation, the cumulative amount of active component is between l% ~ 70%, is preferably 5% ~ 50%; In solid pharmaceutical preparation, the cumulative amount of active component is between 5% ~ 85%, is preferably 10% ~ 80%;
At least containing a kind of surfactant in desinsection of the present invention, miticide composition, the dispersion of active component in water when being beneficial to use.The cumulative amount of surfactant is between 5% ~ 30%, and surplus is solid or liquid diluent.Surfactant selected by desinsection of the present invention, miticide composition is known in those skilled in the art, as: one or more in dispersant, wetting agent, binding agent, defoamer, stabilizing agent or emulsifier.According to different dosage form, in preparation, antifreeze known in those skilled in the art, thickener, disintegrant etc. can also be contained.
Desinsection of the present invention, miticide composition can by user before use through diluting or directly using.Its preparation can be prepared by common processing method known in those skilled in the art, after mixing with liquid flux or solid carrier by active substance, then add surfactant as one or more in dispersant, wetting agent, binding agent, defoamer, stabilizing agent etc.
Desinsection of the present invention, miticide composition, can be processed into acceptable any formulation on agricultural chemicals on demand, wherein excellent formulation of comparatively selecting is: missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent.
Desinsection of the present invention, miticide composition, comprise following constituent content when making missible oil: active component A l ~ 50%, active component B l ~ 50%, emulsifier 2 ~ 20%, synergist 0 ~ 20%, cosolvent 0 ~ 20%, solvent complement to 100%.Active component A and B added after dissolving completely in solvent, add cosolvent if desired, then add the oily liquids becoming transparent and homogeneous after emulsifier, synergist etc. stir, be i.e. the missible oil product of the obtained present composition.
Desinsection of the present invention, miticide composition, comprise following constituent content when making suspending agent: active component A l ~ 50%, active component B l% ~ 50%, dispersant 2 ~ 10%, wetting agent 2 ~ 10%, defoamer 0.1 ~ 1%, thickener 0.1 ~ 2%, binding agent 0.1 ~ 2%, antifreeze 0.1 ~ 8%, water add to 100%.Dispersant, wetting agent, defoamer, thickener, binding agent, antifreeze, water in above-mentioned formulation material are mixed through high speed shear, add active component A and B, in ball mill, ball milling 2 ~ 3 hours, makes diameter of particle all at below 5um, the suspending agent product of the obtained present composition.
Desinsection of the present invention, miticide composition, comprise following constituent content when making water dispersible granules: active component A l ~ 60%, active component B l ~ 60%, dispersant 3 ~ 12%, wetting agent l ~ 8%, disintegrant l ~ 10%, binding agent l ~ 8%, solid packing complement to 100%.Active component A is obtained together with B, dispersant, wetting agent, disintegrant, binding agent, solid carrier etc. the particle diameter needed through air-flow crushing, then add other auxiliary agents such as binding agent, obtain granulation materials.Item is quantitatively sent in fluidized bed granulating dryer through granulating and after drying, obtaining the water dispersible granules product of the present composition.
Desinsection of the present invention, miticide composition, comprise following constituent content when making aqueous emulsion: active component A l ~ 40%, active component B l ~ 40%, solvent 0 ~ 30%, emulsifier l ~ 15%, antifreeze 0 ~ 10%, thickener 0.1 ~ 2%, defoamer 0.0l ~ 2%, water complement to 100%.Active component A and B, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase; Water, antifreeze, thickener, defoamer are mixed, becomes homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added oil phase, the aqueous emulsion product of the obtained present composition.
Desinsection of the present invention, miticide composition, comprise following constituent content when making microemulsion: active component A l ~ 40%, active component B l ~ 40%, solvent 0 ~ 30%, emulsifier 3 ~ 20%, cosolvent 0 ~ 20%, antifreeze 0 ~ 10%, water complements to 100%.Active component A and B are dissolved in the homogenizer that solvent and cosolvent are housed; Emulsifier, antifreeze, water are joined after in the homogenizer that above-mentioned solution is housed and gives strong mixing and homogenize, finally obtains the microemulsion product of the transparent present composition of clear appearance.
Desinsection of the present invention, miticide composition, comprise following constituent content when making soluble liquid: active component A l ~ 50%, active component B l ~ 50%, emulsifier 1 ~ 20%, synergist 1 ~ 10%, organic solvent complement to 100%.Active component A and B, organic solvent, emulsifier, synergist etc. are mixed, becomes transparent and homogeneous liquid, be i.e. the soluble liquid product of the obtained present composition.
Desinsection of the present invention, miticide composition, comprise following constituent content when making wetting powder: active component A l ~ 60%, active component B l ~ 60%, dispersant 2 ~ 10%, wetting agent 2 ~ 10%, solid packing complement to 100%.Active component A and B, dispersant, wetting agent, filler are mixed, mixes in a mixer, mix again after airslide disintegrating mill is pulverized, namely can be made into wetting powder product of the present invention.
Desinsection of the present invention, miticide composition, comprise following constituent content when making oil-suspending agent: active component A l ~ 50%, active component B l ~ 50%, emulsifier 1 ~ 20%, cosolvent 1 ~ 20%, dispersant 0 ~ 0.3%, wetting agent 0.2 ~ 1%, solvent complement to 100%.Active component A and B, emulsifier, dispersant, solvent, cosolvent are added sand milling in sand mill, until particle diameter is qualified, i.e. the oil-suspending agent product of the obtained present composition.
Described dispersant is selected from, but be not limited to: alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic acid polyethenoxy ether, polyoxyethylene carboxylate, one or more in fatty acid glyceride APEO.
Described wetting agent is selected from but is not limited to: lauryl sodium sulfate, neopelex, Nekal BX, washing powder, agriculture breast 2000# series, wetting and penetrating agent F, wetting agent T, spaonin powder, tea are withered, one or more in silkworm excrement, sldium lauryl sulfate, alkylnaphthalene sulfonate, alkylphenol ethoxylate, polyoxyethylene tri-styryl phosphenylic acid salt, soapberry powder.
Described binding agent is selected from but is not limited to: one or more in gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, polyvinyl alcohol.
Described defoamer is selected from but is not limited to: C
8 ~ 10aliphatic alcohols, C
10 ~ 20one or more in saturated fat acids (as capric acid) and acid amides, silicone oil, silicone compound, polyoxyethylene glycerol ether.
Described emulsifier is selected from, but be not limited to: agriculture breast 500#(alkyl benzene calcium sulfonate), 0P series phosphate (thermally coupled distillation columns), 600# phosphate (phenyl phenol polyoxyethanyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400#(benzyl dimethyl phenol polyoxyethyl ether), agriculture breast 600#(phenyl phenol polyoxyethyl ether), Nongru-700 #(alkylphenol-formaldehyde resin polyoxyethyl ether), agriculture breast 36#(phenethyl fluosite polyoxyethyl ether), agriculture breast 1600#(phenethyl phenol polyoxyethanyl polypropylene-base ether), oxirane-propylene oxide block copolymer, 0P series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), agriculture breast 33#(alkylaryl polyoxyethylene polyoxypropylene ether), agriculture breast 34#(alkylaryl polyoxyethylene poly-oxygen propylene aether), emulsifier T-60, Span series (sorbitan monostearate), TWEEN Series (sorbitan fatty acid ester APEO), AEO series (fatty alcohol-polyoxyethylene ether), naphthalene sulfonic acids methyl condensation product, calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, aliphatic acid polyethenoxy base ester, one or more in polyoxyethylene aliphatic alcohol ether.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol, diethylene glycol (DEG), triethylene glycol.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, glucose, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described solvent is selected from: one or more or more than one in toluene, dimethylbenzene, methyl alcohol, ethanol, acetone, ether, cyclohexanone, n-butanol, isopropyl alcohol, vegetable oil, dimethyl formamide, dimethyl sulfoxide (DMSO), acetonitrile, polyethylene glycol, pyrrolidones, solvent N-chain alkyl pyrrolidones, biodiesel, diesel oil, turpentine oil, solvent naphtha, water are with mixed solvents of arbitrary proportion composition.
Described solid carrier is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Described synergist is selected from: any one in organic silicon pesticide synergist, organic silicon pesticide bleeding agent spreading agent, agricultural organic silicon pesticide synergist, azone.
Desinsection of the present invention, miticide composition, can be used for preventing and treating the insect on fruit tree, vegetables, ornamental plants, tea, cotton, cereal crop etc., harmful mite, soil insect or urban health insect; Especially can be used for the sucking pest prevented and treated in various crop, as lepidoptera pest and urban health insects such as plant hopper, aleyrodid, aphid, thrips, leafhopper, blister mite, tetranychid and striped rice borer, corn borer, diamond-back moth, leaf miner, cotton bollworm, cockroaches.
Especially, desinsection of the present invention, miticide composition, can be used for preventing and treating citrus red mite (crm) especially, citrus rust mite, the citrus beginning tetranychid, tetranychus viennensis, panonychus ulmi, carex fruit mite, Tetranychus urticae, yellow tea mite, pink tea rust mite, privet mite, tealeaves goitre mite, Tetranychus cinnabarinus, Mite, O.turkestanicumvar. tuberculata, Dunhuang tetranychid, penthaleus major, grain spider mite, jujube tick, to cause harm the Tetranychus of jujube tree, Eotetranychus evil mite, harmful mite on vegetable or flower, citrus rust mite, citrus scale insect, fruit tree leaf miner, fruit tree budworm, soybean pod borer, apple leaf miner, tea geometrid, tea caterpillar, tea lesser leafhopper, pear sucker, water rice hopper, Trialeurodes vaporariorum Westwood, Americal rice leaf miner, striped flea-beetle, striped rice borer, corn borer, lima bean pod borer, rice water weevil, cotton bollworm, pink bollworm, root-knot nematode, fruit aphid, soybean aphid, vegetable aphid, wheat aphid, cotten aphid, diamond-back moth, mythimna separata, cabbage caterpillar, oriental tobacco budworm, longicorn, mosquito, fly, blattaria, the insects such as termite, evil mite or urban health insect, therefore, technical scheme of the present invention also comprises desinsection of the present invention, miticide composition for the preparation of the purposes of agricultural insecticidal, miticide medicine.
Desinsection of the present invention, miticide composition, can effective dose impose on need control insect/evil mite and/or its habitat on.
Desinsection of the present invention, miticide composition have the following advantages: 1, expand insecticidal spectrum, can be used for preventing and treating the various pests in the various crop such as fruit tree, vegetables, ornamental plants, tea, cotton, harmful mite.2, reduce Pesticide use amount, reduce the residual quantity of agricultural chemicals on crop, enhance the friendly to environment.3, composite A, B two kinds of active components have the different mechanism of action, can delay insect, the drug-fast generation of evil mite.4, A, B two active components are composite in suitable proportion, improve the control efficiency to the insects such as Tetranychus cinnabarinus, brown plant-hopper, mythimna separata, corn borer, Groton bug, evil mite.
Embodiment
Following examples for describing the present invention in detail so that understand the present invention further.Active component A is selected from phonetic mite amine (self-control, content 98%); Active component B and other raw materials are commercial goods.Be metered into after active component folding hundred in formulation Example, each component is measured by weight percentage.
Formulation Example
Embodiment 1:2% phonetic mite amine efficient cyhalothrin emulsifiable concentrate (1:1)
Phonetic mite amine 1%, gamma cyhalothrin 1%, emulsifier T-60 3%, agriculture breast 2,201 3%, acetone 25%, ethyl acetate 10%, biodiesel complement to 100%.Above raw material is prepared routinely the method for missible oil, after mixing, stirring and dissolving completely, i.e. obtained 2% phonetic mite amine efficient cyhalothrin emulsifiable concentrate.
Embodiment 2:10% phonetic mite amine betacyfluthrin missible oil (2:3)
Phonetic mite amine 4%, betacyfluthrin 6%, agriculture breast 500#4%, agriculture breast 400#3%, agriculture breast 1601#5%, epoxychloropropane 1%, ethyl acetate 10%, acetone 10%, toluene complement to 100%.Above raw material is prepared routinely the method for missible oil, after mixing, stirring and dissolving completely, i.e. obtained 10% phonetic mite amine betacyfluthrin missible oil.
Embodiment 3:30% phonetic mite amine gamma cyhalothrin suspending agent (5:1)
Phonetic mite amine 25%, gamma cyhalothrin 5%, naphthalene sulfonic acids methyl condensation product 2%, xanthans 0.2%, aluminium-magnesium silicate 1%, ethylene glycol 5%, Sodium Benzoate 0.3%, silicone defoaming agent 0.5%, water complement to 100%.Above raw material is prepared routinely the method for suspending agent, through mixing, high speed shear dispersion, after sand milling, i.e. obtained 30% phonetic mite amine gamma cyhalothrin suspending agent.
Embodiment 4:25% phonetic mite amine cyfloxylate suspending agent (1:4)
Phonetic mite amine 5%, cyfloxylate 20%, naphthalene sulfonic acids methyl condensation product 2%, xanthans 0.2%, ethylene glycol 5%, benzoic acid 0.3%, methylcellulose 0.2%, silicone defoaming agent 0.2%, water complement to 100%.Above raw material is prepared routinely the method for suspending agent, after mixing, high speed shear dispersion, sand milling, i.e. obtained 25% phonetic mite amine cyfloxylate suspending agent.
Embodiment 5:15% phonetic mite amine cypermethrin suspending agent (1:2)
Phonetic mite amine 5%, cypermethrin 10%, naphthalene sulfonic acids methyl condensation product 2%, emulsifier T-602%, Nongru-700 3%, xanthans 0.1%, propane diols 5%, formaldehyde 0.5%, silicone defoaming agent 0.2%, water complement to 100%.Above raw material is prepared routinely the method for suspending agent, after mixing, high speed shear dispersion, sand milling, i.e. obtained 15% phonetic mite amine cypermethrin suspending agent.
Embodiment 6:50% phonetic mite amine gamma cyhalothrin water dispersible granules (3:2)
Phonetic mite amine 30%, gamma cyhalothrin 20%, naphthalene sulfonic acids methyl condensation product 4%, dextrin 0.8%, Nekal BX 1%, ammonium sulfate 5%, diatomite 5%, attapulgite complement to 100%.Above raw material is prepared routinely the method for water dispersible granules, through mixing, air-flow crushing, i.e. obtained 50% phonetic mite amine gamma cyhalothrin water dispersible granules.
Embodiment 7:80% phonetic mite amine sumicidin water dispersible granules (1:3)
Phonetic mite amine 20%, sumicidin 60%, naphthalene sulfonic acids methyl condensation product 3%, dispersing agent NNO 2%, Nekal BX 1%, soluble starch 3%, kaolin complement to 100%.Above raw material is prepared routinely the method for water dispersible granules, through mixing, air-flow crushing, i.e. obtained 80% phonetic mite amine sumicidin water dispersible granules.
Embodiment 8:7.5% phonetic mite amine gamma cyhalothrin aqueous emulsion (1:4)
Phonetic mite amine 1.5%, gamma cyhalothrin 6%, acetone 50%, sodium sorbate 3%, polyoxyethylene nonylphenol ether 10%, polyethylene glycol 7%, water complement to 100%.Above raw material is prepared routinely the method for aqueous emulsion, through being fully uniformly mixed, i.e. obtained 36% phonetic mite amine gamma cyhalothrin aqueous emulsion.
Embodiment 9:15% phonetic mite amine permethrin microemulsion (1:1)
Phonetic mite amine 7.5%, permethrin 7.5%, agriculture breast 600#8%, agriculture breast 500#6%, cyclohexanone 20%, 1-METHYLPYRROLIDONE 10%, toluene 5%, epoxychloropropane 1%, water complement to 100%.Above raw material is prepared routinely the method for microemulsion, dissolve completely and stir, be i.e. obtained 15% phonetic mite amine permethrin microemulsion.
Embodiment 10:5% phonetic mite amine gamma cyhalothrin microemulsion (4:1)
Phonetic mite amine 4%, gamma cyhalothrin 1%, agriculture breast 2201#6%, Nongru-700 #5%, agriculture breast 600#6%, cyclohexanone 10%, 1-METHYLPYRROLIDONE 5%, toluene 5%, epoxychloropropane 1%, water complement to 100%.Above raw material is prepared routinely the method for microemulsion, dissolve completely and stir, be i.e. obtained 5% phonetic mite amine gamma cyhalothrin microemulsion.
Embodiment 11:13% phonetic mite amine gamma cyhalothrin soluble liquid (1:12)
Phonetic mite amine 1%, gamma cyhalothrin 12%, phenethyl phenol polyethenoxy ether 5%, fatty alcohol-polyoxyethylene ether 10%, cyclohexanone 5%, dimethyl formamide complement to 100%.Above raw material is prepared routinely the method for soluble liquid, first active component is dissolved in a solvent, then add surfactant and other components, stir, be i.e. obtained 13% phonetic mite amine gamma cyhalothrin soluble liquid.
Embodiment 12:10% phonetic mite amine beta-cypermethrin soluble liquid (1:9)
Phonetic mite amine 1%, beta-cypermethrin 9%, phenethyl phenol polyethenoxy ether 5%, fatty alcohol-polyoxyethylene ether 10%, cyclohexanone 5%, dimethyl formamide complement to 100%.Above raw material is prepared routinely the method for soluble liquid, first active component is dissolved in a solvent, then add surfactant and other components, stir, be i.e. obtained 10% phonetic mite amine beta-cypermethrin soluble liquid.
Embodiment 13:28% phonetic mite amine gamma cyhalothrin soluble liquid (6:1)
Phonetic mite amine 24%, gamma cyhalothrin 4%, phenethyl phenol polyethenoxy ether 6%, fatty alcohol-polyoxyethylene ether 12%, isopropyl alcohol 5%, dimethyl formamide complement to 100%.Above raw material is prepared routinely the method for soluble liquid, first active component is dissolved in a solvent, then add surfactant and other components, stir, be i.e. obtained 28% phonetic mite amine gamma cyhalothrin soluble liquid.
Embodiment 14:12% phonetic mite amine sumicidin wetting powder (1:5)
Phonetic mite amine 2%, sumicidin 10%, calcium lignosulfonate 4%, alkylnaphthalene sulfonate formaldehyde condensation products 4%, Nekal BX 2%, white carbon 5%, attapulgite complement to 100%.Above raw material is prepared routinely the method for wetting powder, fully mix and be crushed to certain fineness, be i.e. obtained 12% phonetic mite amine sumicidin wetting powder.
Embodiment 15:50% phonetic mite amine gamma cyhalothrin wetting powder (2:3)
Phonetic mite amine 20%, gamma cyhalothrin 30%, calcium lignosulfonate 4%, naphthalene sulfonic acids methyl condensation product 3%, Nekal BX 2%, white carbon 3%, precipitated calcium carbonate complement to 100%.Above raw material is prepared routinely the method for wetting powder, fully mix and be crushed to certain fineness, be i.e. obtained 50% phonetic mite amine gamma cyhalothrin wetting powder.
Embodiment 16:15% phonetic mite amine gamma cyhalothrin oil-suspending agent (2:1)
Phonetic mite amine 10%, gamma cyhalothrin 5%, naphthalene sulfonic acids methyl condensation product 3%, emulsifier T-60 3%, BY-110 8%, white carbon 0.5%, propane diols 5%, epoxidized soybean oil 20%, methyl oleate complement to 100%.Above raw material is prepared routinely the method for oil-suspending agent, by mixing after each component grinding, i.e. obtained 15% phonetic mite amine gamma cyhalothrin oil-suspending agent.
Embodiment 17:20% phonetic mite amine permethrin oil-suspending agent (1:3)
Phonetic mite amine 5%, permethrin 15%, dispersing agent NNO 3%, BY-125 5%, agriculture breast 1,601 4%, phenethyl phenol polyethenoxy base ether phosphate 1%, bentonite 0.5%, glycerine 5%, triphenyl phosphate 3%, rapeseed oil complement to 100%.Above raw material is prepared routinely the method for oil-suspending agent, by mixing after each component grinding, i.e. obtained 20% phonetic mite amine permethrin oil-suspending agent.
Embodiment 18:9% phonetic mite amine gamma cyhalothrin oil-suspending agent (8:1)
Phonetic mite amine 8%, gamma cyhalothrin 1%, naphthalene sulfonic acids methyl condensation product 3%, agriculture breast 2,201 4%, Nongru-700 5%, BY-110 5%, white carbon 0.5%, propane diols 5%, epoxidized soybean oil 20%, methyl oleate complement to 100%.Above raw material is prepared routinely the method for oil-suspending agent, by mixing after each component grinding, i.e. obtained 9% phonetic mite amine gamma cyhalothrin oil-suspending agent.
Toxicity measures embodiment
Embodiment 19: phonetic mite amine and gamma cyhalothrin mixture are tested the indoor joint toxicity measuring of Tetranychus cinnabarinus
For examination target: Tetranychus cinnabarinus [Tetranychus cinnabarinus(boisduval)] become mite, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt potted plant seedling spray-on process to measure active size Tetranychus cinnabarinus being become to mite.First becoming mite to receive Tetranychus cinnabarinus of the same size is on the Tolerance of Kidney Bean Seedlings blade of first pair of true leaf open and flat phase, after becoming mite stable, count radix; Then by the order even spraying of experimental scheme from low dosage to high dose, every strain 1.5mL, often processes and repeats for 3 times, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours " Invest, Then Investigate " mite numbers dead, alive.With abbott formulae discovery corrected mortality, carry out statistical analysis with DPS data processing software, obtain each the virulence regression equation formula, the LC that use with for examination single dose and variant proportioning
50value and 95% confidence limit, then use Sun Yunpei (Suny-p) method to calculate the co-toxicity coefficient of each proportioning, evaluate mixed effect, result of the test is in table 1.
The co-toxicity coefficient (CTC value) of mixture is by following formulae discovery:
In formula: ATI-mixture actual measurement toxicity index; The LC of S-standard agent
50; The LC of M-mixture
50.
TTI=TIA×PA+TIB×PB
In formula: the theoretical toxicity index of TTI-mixture; TIA-A medicament toxicity index; The percentage composition of PA-A medicament in mixture; TIB-B medicament toxicity index; The percentage composition of PB-B medicament in mixture.
In formula: CTC-co-toxicity coefficient; ATI-mixture actual measurement toxicity index; The theoretical toxicity index of TTI-mixture.
The co-toxicity coefficient (CTC) of built agent: CTC >=100 show as synergistic effect; CTC≤100 show as antagonism.
Phonetic mite amine and gamma cyhalothrin mixture the results are shown in Table 1 to the indoor joint toxicity measuring of Tetranychus cinnabarinus.
Table 1
Embodiment 20: phonetic mite amine and gamma cyhalothrin, cypermethrin, beta-cypermethrin mixture are tested brown plant-hopper synergism determination
For examination target: brown plant-hopper [Nilaparvata lugens(Stal)] nymph, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt the active size of potted plant seedling spray-on process mensuration to rice brown planthopper nymph.First plant in culturing pot by rice seedling, by the order even spraying of experimental scheme from low dosage to high dose, every strain 2mL, is then connected on rice seedling by rice brown planthopper nymph of the same size, often processes 3 times and repeats, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours dead, alive borer populations of " Invest, Then Investigate ".By the actual measurement lethality of each process of abbott formulae discovery.
Mixture effect assessment adopts Bliss method, and the independent joint action concept that Bliss proposes according to it is thought, theoretical lethality P during Mixture Use of Insecticides can calculate with following formula:
P=Pm+Pn（1-Pm）
Pm is the actual measurement lethality (%) of the first active component target when concentration is m; The actual measurement lethality (%) of Pn is the second active component working concentration when being n target.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, are then judging that two kinds of active components are used in combination under setting concentration and there is synergistic effect, otherwise be then antagonism.
Phonetic mite amine and gamma cyhalothrin, cypermethrin, beta-cypermethrin mixture the results are shown in Table 2 to brown plant-hopper synergism determination.
Table 2
Embodiment 21: phonetic mite amine and permethrin, betacyfluthrin mixture are tested mythimna separata synergism determination
For examination target: mythimna separata (Mythimna seperata) 3 instar larvaes, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt the active size of infusion process mensuration to armyworm larvae.First blade in the middle part of the fresh corn of greenhouse culture is selected to be cut into 3cm segment, by the order of experimental scheme from low dosage to high dose, put into the liquid prepared and flood 10s, naturally drying in the shade, to be placed on the diameter being placed with filter paper be in the culture dish of 9cm, access neat health examination worm, often process 10, often process 3 times and repeat, separately establish blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours dead, alive borer populations of " Invest, Then Investigate ".By the actual measurement lethality of each process of abbott formulae discovery.
Mixture effect assessment adopts Bliss method, with embodiment 20.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, are then judging that two kinds of active components are used in combination under setting concentration and there is synergistic effect, otherwise be then antagonism.
Phonetic mite amine and permethrin, betacyfluthrin mixture the results are shown in Table 3 to mythimna separata synergism determination.
Table 3
Embodiment 22: phonetic mite amine and cyfloxylate mixture are tested corn borer synergism determination
For examination target: corn borer (Ostrinia furnacalis) 3 instar larvaes, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt the active size of medicine embrane method mensuration to corn borer larvae.First 24 well culture plates of selection standard cleaning, every hole adds 1mL artificial feed, after cooled and solidified, adds 0.05mL liquid with continuous sampler to each hole of culture plate, then puts shady and cool place nature and dries in the shade.Select in the examination worm access culture plate of neat and consistent, 1, every hole, often processes repetition 3 times, separately establishes blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.72 hours dead, alive borer populations of " Invest, Then Investigate ".By the actual measurement lethality of each process of abbott formulae discovery.
Mixture effect assessment adopts Bliss method, with embodiment 20.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, are then judging that two kinds of active components are used in combination under setting concentration and there is synergistic effect, otherwise be then antagonism.
Phonetic mite amine and cyfloxylate mixture the results are shown in Table 4 to corn borer synergism determination.
Table 4
Embodiment 23: phonetic mite amine and sumicidin mixture are tested Groton bug synergism determination
For examination target: Groton bug (Blattella germanica) adult, the sensitive strain of indoor feeding.
Drug solution preparing: according to different tests needs, accurately take test sample respectively with electronic analytical balance, former medicine with acetone solution, then becomes the serial liquid of tool finite concentration gradient according to experimental scheme dose dilution with 0.1% Tween 80 water.
Test method: adopt the active size of medicine embrane method mensuration to Groton bug adult.First clean 250mL triangular flask is selected, by the order of experimental scheme from low dosage to high dose, the liquid of the variable concentrations by acetone diluted is joined in triangular flask, every bottle of 10mL, then rotating rapidly triangular flask makes liquid evenly open up on bottle wall, puts shady and cool place nature and dries in the shade.The examination worm selecting neat and consistent is linked in triangular flask, 10 every bottle, often processes repetition 3 times, separately establishes blank.
Be placed in observation ward by the examination material after process, the temperature of observation ward, humidity, illumination are adjustable as required.96 hours dead, alive borer populations of " Invest, Then Investigate ".By the actual measurement lethality of each process of abbott formulae discovery.
Mixture effect assessment adopts Bliss method, with embodiment 20.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, are then judging that two kinds of active components are used in combination under setting concentration and there is synergistic effect, otherwise be then antagonism.
Phonetic mite amine and sumicidin mixture the results are shown in Table 5 to Groton bug synergism determination.
Table 5
The explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.From above technical scheme, desinsection of the present invention, miticide composition have raising drug effect, expand insecticidal spectrum, reduce pesticide dosage, reduce the residual quantity of agricultural chemicals on crop, alleviate the pollution to environment, to person poultry safety, Environmental compatibility is good, and insect not easily develops immunity to drugs.The present composition can be applicable to the various pests of various crop, the control of evil mite, can be widely used in agriculture field.
Claims (9)
1. containing a composition for pyrethroid insecticides, containing A, B two kinds of active components,
Component A is selected from phonetic mite amine, and structural formula is as follows:
B component is selected from pyrethroid insecticides;
Described pyrethroid insecticides is selected from gamma cyhalothrin (B1), cypermethrin (B2), beta-cypermethrin (B3), permethrin (B4), cyfloxylate (B5), betacyfluthrin (B6) or sumicidin (B7);
The ratio of weight and number of A, B two kinds of active components is 1:20 to 20:1.
2. composition according to claim 1, is characterized in that:
Component A is selected from phonetic mite amine; B component is selected from gamma cyhalothrin (B1);
The ratio of weight and number of A, B two kinds of active components is 1:20 to 8:1.
3. composition according to claim 1, is characterized in that:
Component A is selected from phonetic mite amine; B component is selected from cypermethrin (B2), beta-cypermethrin (B3), betacyfluthrin (B6) or sumicidin (B7);
The ratio of weight and number of A, B two kinds of active components is 1:20 to 1:1.
4. composition according to claim 1, is characterized in that:
Component A is selected from phonetic mite amine; B component is selected from permethrin (B4);
The ratio of weight and number of A, B two kinds of active components is 1:10 to 1:1.
5. composition according to claim 1, is characterized in that:
Component A is selected from phonetic mite amine; B component is selected from cyfloxylate (B5);
The ratio of weight and number of A, B two kinds of active components is 1:10 to 5:1.
6. the composition according to any one of claim l ~ 5, is characterized in that: in composition, the accumulating weight content of active component is 0.5%-95%.
7. the composition according to any one of claim l ~ 5, is characterized in that: make missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent on demand;
8. the purposes of the composition according to claim l, is characterized in that: for preventing and treating the insect on fruit tree, vegetables, ornamental plants, tea, cotton, cereal crop, harmful mite or urban health insect.
9. the purposes of composition according to claim 1, is characterized in that: for the preparation of agricultural insecticidal, miticide medicine.
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| CN1911033A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. high efficiency cypermethrin and pyrimidifen and its application |
| CN101906075A (en) * | 2009-06-05 | 2010-12-08 | 中国中化股份有限公司 | E-type phenyl acrylic acid ester compound containing substituted anilino pyrimidine group and applications thereof |
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| CN1911032A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. pyrimidifen and high efficiency cyfluthrin, and its application |
| CN1911033A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. high efficiency cypermethrin and pyrimidifen and its application |
| CN101906075A (en) * | 2009-06-05 | 2010-12-08 | 中国中化股份有限公司 | E-type phenyl acrylic acid ester compound containing substituted anilino pyrimidine group and applications thereof |
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Effective date of registration: 20160202 Address after: 110021 Liaodong Road, Tiexi District, Liaoning, No. 8-1, No. Patentee after: SHENYANG SINOCHEM PESTICIDE CHEMICAL RESEARCH AND DEVELOPMENT CO., LTD. Address before: 100031 Beijing, Xicheng District, the door of the revitalization of the main street, No. 28 Patentee before: Sinochem Corporation Patentee before: Shenyang Research Institute of Chemical Industry |