CN1934322A - 具有改进热稳定性和改进耐火性的绝热复合材料 - Google Patents
具有改进热稳定性和改进耐火性的绝热复合材料 Download PDFInfo
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Abstract
本发明涉及一种绝热复合材料，其包含具有绝热芯材的两个金属板，其中在绝热芯材和至少一个金属板之间设置有具有膨胀物质的防火层。本发明进一步涉及所述材料的生产方法及其在制造储存或冷藏仓库中的用途。
Description
本发明涉及一种绝热复合材料，其包含具有绝热芯材的两个金属板，其中在绝热芯材和至少一个金属板之间引入有防火层，本发明还涉及所述材料的生产方法及其在制造储存建筑物或冷藏建筑物中的用途。
由绝热芯材和双侧粘合剂结合的钢板或铝板构成的夹层板在建筑应用中用作构造单元或覆盖层。它们的耐热性在火灾发生时通常不够充分。例如在火灾发生时，热塑性泡沫仅仅由于暴露于热中而熔化并损害夹层板的机械稳定性。
WO 02/064672因此建议使用具有由酚醛树脂和分散的聚苯乙烯泡沫珠粒组成的连续相的聚合物泡沫作为芯材。
GB-A 2362586公开了一种用于改进聚苯乙烯泡沫板阻燃性的方法，其中用含有基于磷或氯化合物的阻燃剂的液体酚醛树脂涂布预发泡的聚苯乙烯泡沫珠粒，然后使之熔合以产生所述板。然而，这些阻燃的聚苯乙烯泡沫板在暴露于较高温度中较长时间时可能通过熔化而损失掉。
DE-A 196 39 842公开了由聚苯乙烯泡沫板构成的防火复合材料体系，该泡沫板的表面提供有被膨胀组合物饱和的型材或栅格或网格。优选将型材、栅格或网格引入泡沫板之间的连接点。
EP-A 0 942 107公开了基本上由PU泡沫构成且产生阻燃性的浸渍泡沫，将该泡沫层压为两个自粘合的薄膜，在这两个自粘合薄膜之间包含膨胀材料，并公开了其作为防火阻挡物的用途。
因此本发明的目的是消除上述缺点，并发明一种具有改进耐热性和改进耐火性能的绝热复合材料及其生产方法。
由此发明了本文开头所述的绝热复合材料。绝热复合材料的金属板通常由厚度为1-10毫米的钢板或铝板构成。
绝热芯材可以由模塑聚苯乙烯泡沫、挤出的聚苯乙烯泡沫板(XPS)、聚氨酯泡沫、PIR泡沫或石纤维构成。绝热芯材优选由模塑聚苯乙烯泡沫板构成，该泡沫板可通过将由可发泡的聚苯乙烯(EPS)组成的预发泡聚苯乙烯泡沫珠粒烧结而得到，这是因为该芯材具有低密度以及可加工性和长期的绝热性能。优选密度为10-50克/升和厚度为50-250毫米的模塑聚苯乙烯泡沫板。
施加在模制品上的防火层可以是层压材料、板、薄膜、分散体或溶液的形式。防火层的厚度取决于使用的材料且通常为0.1-50毫米，优选1-10毫米。合适材料的实例是：由耐热三聚氰胺树脂泡沫(例如Basotect)构成的泡沫薄膜或由胶凝的碱金属硅酸盐溶液(例如Palusol)构成的防火层压材料。绝热芯材优选涂有膨胀组合物。该涂层可以通过喷雾、浸渍、辊涂或展涂而施加到绝热芯材的一个或多个表面上。涂层材料本身阻燃。结果是使位于其下面的热敏性芯材不受高温和跳火的影响，并保持其结构完整性。
膨胀组合物是在暴露于较高温度，通常高于80℃至100℃时发泡且在此过程中形成绝热耐热泡沫的材料，其中所述绝热和耐热泡沫保护位于其下面的绝热芯材使其不暴露于火和热中。
存在于绝热复合材料中的膨胀组合物优选为碱金属硅酸盐，特别是含水硅酸钠、可膨胀石墨或可膨胀云母。
本发明绝热复合材料可以通过将两个金属板和绝热芯材结合而生产，其中将防火层引入到绝热芯材和至少一个金属板之间，优选引入到绝热芯材分别与两个金属板之间。用于生产绝热复合材料的市售机器可用于此目的。
在一种优选方法中，将膨胀组合物用于涂覆绝热芯材的至少一个表面，然后将该芯材粘合到金属板上。还可以将膨胀组合物与粘合剂混合并将该材料一起施加到绝热芯材或金属板上，或者使用对金属板具有充分粘合性的膨胀组合物。
使用的粘合剂可以含有基于聚氨酯树脂或环氧树脂的单组分或双组分粘合剂。然而，还可以使用基于分散体的粘合剂，例如丙烯酸酯分散体(Acronal)。
在一个实施方案中，粘合剂形成全部或部分防火层。为此，将添加剂如可膨胀石墨、含水硅酸钠、锌硼酸盐、三聚氰胺化合物、金属氢氧化物，或金属盐水合物或其混合物与粘合剂混合。基于粘合剂，添加剂的比例通常为2-98重量％，优选40-90重量％。为了改进例如在展涂或喷雾过程中的加工性能，或者促进干燥，或者改进粘合效果，也可以将其它的常规填料与粘合剂混合。
在一个优选的实施方案中，防火层由基于硅酸钠的膨胀组合物形成。为此，使用水含量为约65重量％的市售水玻璃溶液，并且将该溶液与水含量为约18重量％的水玻璃粉末混合。可以借助水玻璃粉末的用量而根据需要调节混合物的胶凝时间。如果合适的话，可以将0-50重量％的无机填料如金属氢氧化物或金属硫酸盐水合物，或者至多10重量％的有机填料加入混合物中。可以直接将液体混合物施用或喷雾到芯材板材上。此处的涂层厚度可以为0.05-5毫米。
胶凝在室温下进行，然而也可以通过暴露于不超过80℃的较高温度下而促进胶凝。由此在芯材板材的所有面上都进行涂布，或者仅在随后用于粘合到金属板上的宽面上进行涂布。
还可以用水玻璃混合物涂布绝热芯材，并且在完全胶凝之前用金属片在两侧上压住该芯材。
同样，也可以在芯材没有被金属板覆盖的裸露的边角处提供涂料组合物，或者可以通过将由石纤维构成的绝热楔引入到板结构中而保护关键点如端部或连接点使其不暴露于热或跳火中。涂料的发泡还可以密封所产生的孔隙并由此阻止跳火进入到芯材中。
本发明的绝热复合材料优选适用于建筑行业进行正面覆盖，或者作为已知的“结构绝热板”用于制造储存建筑物或冷藏建筑物。
实施例：
本发明实施例1：
在泡沫密度为18克/升的由EPS构成的模塑聚苯乙烯泡沫板(600×1000×100毫米)的两侧提供厚度为2毫米的水玻璃混合物层，该水玻璃混合物由混有水玻璃粉末(水含量18重量％)的水玻璃溶液(水含量65重量％)组成。在该层胶凝和硬化之后，在所得板的两侧涂布厚度为50微米的PU粘合剂层，然后通过粘合施加厚度为1毫末的钢板。为了评价耐热性和阻燃性，在粘合剂硬化之后将所得的板水平固定，并暴露于来自下方的气体火焰(火焰温度大于500℃)中达30分钟。在测试的整个30分钟时间内，仅有小比例的EPS泡沫芯材熔化，并且该材料没有着火。由水玻璃组成的泡沫保护层显著抑制了对芯材的损害，并且保持了板的结构完整性。
对比试验
在泡沫密度为18克/升的由EPS构成的模塑聚苯乙烯泡沫板(600×1000×100毫米)的两侧提供厚度为50微米的PU粘合剂层，并且通过粘合施加厚度为1毫末的钢板。为了评价耐热性和阻燃性，在粘合剂硬化之后将所得的板水平固定，并暴露于来自下方的气体火焰(火焰温度大于500℃)中30达分钟。仅在5分钟后，EPS泡沫芯材熔化并着火，并且丧失了板的结构完整性。
Claims (9)
1.一种绝热复合材料，其包含具有绝热芯材的两个金属板，其中在绝热芯材和至少一个金属板之间引入有防火层。
2.根据权利要求1的绝热复合材料，其中防火层包含基于碱金属硅酸盐、可膨胀石墨或可膨胀云母的膨胀组合物。
3.根据权利要求2的绝热复合材料，其中膨胀组合物包含含水硅酸钠。
4.根据权利要求1-3中任何一项的绝热复合材料，其中金属板由钢或铝构成。
5.根据权利要求1-4中任何一项的绝热复合材料，其中绝热芯材由模塑聚苯乙烯泡沫、挤出的聚苯乙烯泡沫板、聚氨酯泡沫或石纤维构成。
6.一种通过结合两个金属板和绝热芯材而生产绝热复合材料的方法，该方法包括在绝热芯材和至少一个金属板之间引入防火层。
7.根据权利要求6的方法，其中在芯材的至少一个表面上涂覆膨胀组合物以形成防火层，然后将其粘合到金属板上。
8.根据权利要求6的方法，其中用包含膨胀组合物的粘合剂将芯材粘合到金属板上。
9.根据权利要求1-6中任何一项的绝热复合材料在制造储存建筑物或冷藏建筑物中的用途。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004016081.3 | 2004-03-30 | ||
| DE200410016081 DE102004016081A1 (de) | 2004-03-30 | 2004-03-30 | Wärmedämmverbund mit verbesserter Thermostabilität und verbessertem Brandverhalten |
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| Publication Number | Publication Date |
|---|---|
| CN1934322A true CN1934322A (zh) | 2007-03-21 |
Family
ID=34963319
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005800091387A Pending CN1934322A (zh) | 2004-03-30 | 2005-03-26 | 具有改进热稳定性和改进耐火性的绝热复合材料 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20080038516A1 (zh) |
| EP (1) | EP1733102A1 (zh) |
| KR (1) | KR20070004916A (zh) |
| CN (1) | CN1934322A (zh) |
| AR (1) | AR050404A1 (zh) |
| AU (1) | AU2005229118A1 (zh) |
| BR (1) | BRPI0508977A (zh) |
| CA (1) | CA2562128A1 (zh) |
| DE (1) | DE102004016081A1 (zh) |
| MX (1) | MXPA06010475A (zh) |
| RU (1) | RU2006137945A (zh) |
| WO (1) | WO2005095728A1 (zh) |
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| CN102007256B (zh) * | 2008-02-08 | 2012-11-21 | 3M创新有限公司 | 具有粘合剂表面的多层膨胀型防火屏障 |
| CN104010701A (zh) * | 2011-10-25 | 2014-08-27 | B/E航空公司 | 热屏蔽的复合板 |
| CN101835827B (zh) * | 2007-05-30 | 2014-10-22 | 英尼奥斯诺瓦国际有限公司 | 阻燃聚苯乙烯 |
| CN107001736A (zh) * | 2014-12-03 | 2017-08-01 | J.M.休伯有限公司 | 金属复合芯组合板及其制造工艺 |
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| DE602004009786T2 (de) * | 2003-05-15 | 2008-08-28 | Huntsman International Llc, Salt Lake City | Klebstoffzusammensetzung auf basis von polyisocyanate zur verwendung in sandwichplatten |
| DE102007034543B4 (de) * | 2007-07-20 | 2018-11-22 | Fritz Egger Gmbh & Co. Og | Verfahren und Vorrichtung zur Herstellung einer Leichtbauplatte sowie Leichtbauplatte |
| EP2207672A1 (de) | 2007-11-06 | 2010-07-21 | Basf Se | Flammschutz- und klebeschicht |
| JP5587202B2 (ja) * | 2007-12-19 | 2014-09-10 | ビーエーエスエフ ソシエタス・ヨーロピア | 発泡可能な反応性樹脂を含む支持材の成形体 |
| CN102105283A (zh) * | 2008-07-24 | 2011-06-22 | 陶氏环球技术公司 | 用于制造成形泡沫复合材料制品的方法 |
| ES2320403B1 (es) * | 2008-10-22 | 2009-11-23 | Leopoldo Vicedo Uliarte | Almacen ignifugo para productos explosivos. |
| CN102471632B (zh) * | 2009-07-22 | 2014-12-03 | 巴斯夫欧洲公司 | 用作具有改善的火行为的灰泥和涂料的粘合剂的水性聚合物分散体 |
| KR101113577B1 (ko) * | 2009-10-01 | 2012-02-22 | 기아자동차주식회사 | 자동차용 고압 가스 연료탱크의 화재안전장치 |
| DE202009017484U1 (de) * | 2009-12-22 | 2010-03-25 | Saint-Gobain Isover G+H Ag | Dämmelement für den Brandschutz |
| EP2576175A1 (en) | 2010-05-27 | 2013-04-10 | Dow Global Technologies LLC | Method of manufacturing a shaped foam article |
| WO2012058177A1 (en) | 2010-10-29 | 2012-05-03 | Dow Global Technologies Llc | Method of forming a shaped foam laminate article |
| WO2012146577A1 (en) * | 2011-04-28 | 2012-11-01 | Ineos Styrenics International Sa | Fire retardant polystyrene |
| DE102011053560A1 (de) | 2011-06-16 | 2012-12-20 | IKJ S.à.r.l. | Brandschutzsystem sowie Brandschutztür, Brandschutz-Wandelement und Brandschutzplatte hierfür |
| WO2013113734A1 (de) | 2012-02-02 | 2013-08-08 | Bayer Intellectual Property Gmbh | Verfahren zur kontinuierlichen herstellung eines sandwich-verbundelementes |
| EP2777926A1 (en) | 2013-03-14 | 2014-09-17 | Dow Global Technologies LLC | Panel with fire barrier |
| BE1021837B1 (nl) * | 2014-04-30 | 2016-01-21 | Es-Projects, Besloten Vennootschap Met Beperkte Aansprakelijkheid | Samenstelling van een isolatiemateriaal, werkwijze voor het vervaardigen van isolatiemateriaal en gebruik van dergelijk isolatiemateriaal |
| WO2016113378A1 (en) | 2015-01-16 | 2016-07-21 | Beaulieu International Group Nv | Covering for floors, walls or ceilings, and method for obtaining a covering |
| EP4056367A1 (en) | 2015-01-16 | 2022-09-14 | Beaulieu International Group NV | Covering and method for producing coverings |
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2004
- 2004-03-30 DE DE200410016081 patent/DE102004016081A1/de not_active Withdrawn
-
2005
- 2005-03-26 US US10/593,656 patent/US20080038516A1/en not_active Abandoned
- 2005-03-26 WO PCT/EP2005/003214 patent/WO2005095728A1/de active Application Filing
- 2005-03-26 BR BRPI0508977-8A patent/BRPI0508977A/pt not_active IP Right Cessation
- 2005-03-26 EP EP05728978A patent/EP1733102A1/de not_active Withdrawn
- 2005-03-26 CN CNA2005800091387A patent/CN1934322A/zh active Pending
- 2005-03-26 MX MXPA06010475A patent/MXPA06010475A/es unknown
- 2005-03-26 CA CA 2562128 patent/CA2562128A1/en not_active Abandoned
- 2005-03-26 KR KR1020067022506A patent/KR20070004916A/ko not_active Application Discontinuation
- 2005-03-26 AU AU2005229118A patent/AU2005229118A1/en not_active Abandoned
- 2005-03-26 RU RU2006137945/03A patent/RU2006137945A/ru not_active Application Discontinuation
- 2005-03-30 AR ARP050101242 patent/AR050404A1/es unknown
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| CN101835827B (zh) * | 2007-05-30 | 2014-10-22 | 英尼奥斯诺瓦国际有限公司 | 阻燃聚苯乙烯 |
| CN102007256B (zh) * | 2008-02-08 | 2012-11-21 | 3M创新有限公司 | 具有粘合剂表面的多层膨胀型防火屏障 |
| CN104010701A (zh) * | 2011-10-25 | 2014-08-27 | B/E航空公司 | 热屏蔽的复合板 |
| CN107001736A (zh) * | 2014-12-03 | 2017-08-01 | J.M.休伯有限公司 | 金属复合芯组合板及其制造工艺 |
| CN107001736B (zh) * | 2014-12-03 | 2020-02-28 | J.M.休伯有限公司 | 金属复合芯组合板及其制造工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20080038516A1 (en) | 2008-02-14 |
| AU2005229118A1 (en) | 2005-10-13 |
| CA2562128A1 (en) | 2005-10-13 |
| BRPI0508977A (pt) | 2007-08-28 |
| KR20070004916A (ko) | 2007-01-09 |
| WO2005095728A1 (de) | 2005-10-13 |
| RU2006137945A (ru) | 2008-05-10 |
| DE102004016081A1 (de) | 2005-10-20 |
| EP1733102A1 (de) | 2006-12-20 |
| AR050404A1 (es) | 2006-10-25 |
| MXPA06010475A (es) | 2007-03-27 |
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