EP1733102A1 - Wärmedämmverbund mit verbesserter thermostabilität und verbessertem brandverhalten - Google Patents
Wärmedämmverbund mit verbesserter thermostabilität und verbessertem brandverhaltenInfo
- Publication number
- EP1733102A1 EP1733102A1 EP05728978A EP05728978A EP1733102A1 EP 1733102 A1 EP1733102 A1 EP 1733102A1 EP 05728978 A EP05728978 A EP 05728978A EP 05728978 A EP05728978 A EP 05728978A EP 1733102 A1 EP1733102 A1 EP 1733102A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- core material
- thermal insulation
- heat
- insulation composite
- insulating core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000009413 insulation Methods 0.000 title claims abstract description 20
- 239000002131 composite material Substances 0.000 title claims abstract description 18
- 239000011162 core material Substances 0.000 claims abstract description 33
- 229910052751 metal Inorganic materials 0.000 claims abstract description 23
- 239000002184 metal Substances 0.000 claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 239000006260 foam Substances 0.000 claims description 19
- 239000000853 adhesive Substances 0.000 claims description 14
- 230000001070 adhesive effect Effects 0.000 claims description 14
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000004793 Polystyrene Substances 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 5
- 239000010959 steel Substances 0.000 claims description 5
- 239000004115 Sodium Silicate Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004795 extruded polystyrene foam Substances 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000011490 mineral wool Substances 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000011496 polyurethane foam Substances 0.000 claims 1
- 238000003860 storage Methods 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 8
- 235000019353 potassium silicate Nutrition 0.000 description 8
- 229920006248 expandable polystyrene Polymers 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229920006327 polystyrene foam Polymers 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 238000001879 gelation Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 1
- 229920005832 Basotect® Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- FWFGVMYFCODZRD-UHFFFAOYSA-N oxidanium;hydrogen sulfate Chemical class O.OS(O)(=O)=O FWFGVMYFCODZRD-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- -1 salt hydrates Chemical class 0.000 description 1
- IHQKEDIOMGYHEB-UHFFFAOYSA-M sodium dimethylarsinate Chemical class [Na+].C[As](C)([O-])=O IHQKEDIOMGYHEB-UHFFFAOYSA-M 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical class [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/92—Protection against other undesired influences or dangers
- E04B1/94—Protection against other undesired influences or dangers against fire
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/92—Protection against other undesired influences or dangers
- E04B1/94—Protection against other undesired influences or dangers against fire
- E04B1/941—Building elements specially adapted therefor
- E04B1/942—Building elements specially adapted therefor slab-shaped
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/26—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
- E04C2/284—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
- E04C2/292—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and sheet metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
- Y10T428/24496—Foamed or cellular component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249955—Void-containing component partially impregnated with adjacent component
- Y10T428/249958—Void-containing component is synthetic resin or natural rubbers
Definitions
- the invention relates to a thermal insulation composite, comprising two metal plates with a heat-insulating core material, a fire protection layer being introduced between the heat-insulating core material and at least one of the metal plates, method for its production and use for the production of storage or cooling halls.
- WO 02/064672 therefore proposes to use a polymer foam with a continuous phase made of a phenol resin and dispersed polystyrene foam particles as the core material.
- GB-A 2362586 describes a process for improving the flame retardancy of polystyrene foam blocks, in which the prefoamed polystyrene foam particles are coated with a liquid phenolic resin, which contains a flame retardant based on phosphorus or chlorine compounds, and then welded into blocks.
- a liquid phenolic resin which contains a flame retardant based on phosphorus or chlorine compounds
- flame-retardant polystyrene foam blocks can melt away over a long period of time when exposed to higher temperatures.
- DE-A 19639842 describes fire-protected composite systems made of polystyrene foam blocks which are provided on the surface with profiles, grids or nets which have been impregnated with an intumescent mass.
- the profiles, grids or nets are preferably introduced into the joints between the foam sheets.
- EP-A 0942 107 describes a flame-retardant impregnated foam body made of essentially PU foam, which is laminated with two self-adhesive films, between which an intumescent material is enclosed, and its use as a fire stopper.
- the object of the present invention was therefore to remedy the disadvantages mentioned and to find a thermal insulation composite with improved thermal stability and improved fire behavior and a process for its production. Accordingly, the thermal insulation composite described above was found.
- the metal plates of the thermal insulation composite usually consist of steel or aluminum with a thickness of 1 to 10 mm
- the heat-insulating core material can consist of polystyrene particle foam, extruded polystyrene foam sheets (XPS), polyurethane or PIR foams or mineral wool. Because of its low density, processability and long-lasting insulation properties, a heat-insulating core material made of polystyrene particle foam sheets, which can be obtained by combining pre-expanded polystyrene foam particles made of expandable polystyrene (EPS), is preferred. Polystyrene particle foam plastics with a density in the range from 10 to 50 g / l and a thickness in the range from 50 to 250 mm are preferably used.
- the fire protection layer can be applied to the molding as a laminate, plate, film, dispersion or solution.
- the thickness of the fire protection layer depends on the material used and is generally in the range from 0.1 to 50 mm, preferably in the range from 1 to 10 mm.
- a foam film made from a thermally resistant melamine resin foam (e.g. Basotect®) or a fire protection laminate made from gelled alkali silicate solution (e.g. Palusol®) is suitable.
- the heat-insulating core material is preferably coated with an intumescent material. The coating can be applied by spraying, dipping, rolling or brushing on one or more surfaces of the heat-insulating core material.
- the coating material itself is flame resistant. This protects the underlying, thermally sensitive core material from high temperatures and flame attack and maintains its structural integrity.
- the thermal insulation composite preferably contains an alkali silicate, in particular a water-containing sodium silicate, expanded graphite or expanded mica as intumescent material.
- the thermal insulation composite according to the invention can be produced by connecting two metal plates and a heat-insulating core material, a fire protection layer being introduced between the heat-insulating core material and at least one metal plate, preferably between the heat-insulating core material and both metal plates.
- a fire protection layer being introduced between the heat-insulating core material and at least one metal plate, preferably between the heat-insulating core material and both metal plates.
- commercially available machines for the production of thermal insulation bonds can be used.
- the core material is coated on at least one surface of the heat-insulating core material with an intumescent material and then glued to the metal plates. It is also possible to mix the intumescent mass with the adhesive, to put it together on the heat-insulating core material or the metal plate or to use an intumescent mass which has sufficient adhesion to the metal plate.
- One- or two-component adhesives based on polyurethane or epoxy resins can be used as adhesives.
- dispersion-based adhesives e.g. B Acrylic dispersions (Acronal®) can be used.
- the fire protection layer is wholly or partly formed by the adhesive.
- additives such as expanded graphite, water-containing sodium silicates, zinc borates, melamine compounds, metal hydroxides or metal salt hydrates or mixtures thereof are added to the adhesive.
- the proportion of additives is generally in the range from 2 to 98% by weight, preferably 40 to 90% by weight, based on the adhesive.
- processability e.g. B. when brushing or spraying, faster drying or improving the adhesive strength
- other conventional fillers can be added to the adhesive.
- the gelation takes place at room temperature, but can be accelerated at higher temperatures up to 80 ° C.
- the plates of the core material are coated on all sides or only on the broad sides later covered with a metal plate.
- the exposed corners and edges of the core material that are not covered with the metal plates can also be provided with the coating agent or by inserting mineral wool insulation wedges into the panel construction Protection of critical points, such as ends or folds, should be protected from the effects of heat or flashover.
- the foaming of the coating can also seal openings that arise and thus prevent a flashover into the core material.
- the thermal insulation composite according to the invention is preferably suitable in the building industry, for cladding facades or as so-called “structural insulation panels” for producing storage or cooling halls.
- a polystyrene particle foam sheet made of EPS (600x1000x100 mm) with a foam density of 18 g / l was coated on both sides with a 2 mm thick layer of a water glass mixture consisting of water glass solution (water content 65% by weight) mixed with water glass powder (water content 18% by weight).
- the plate obtained was provided on both sides with a 50 ⁇ m layer of PU adhesive and glued with 1 mm thick steel plates.
- the panel obtained was fastened horizontally after the adhesive had hardened and exposed to a gas flame (flame temperature> 500 ° C.) for 30 minutes from below. Over the entire test period of 30 minutes, only a small part of the EPS foam core material melted and did not catch fire.
- the foaming protective layer made of water glass largely prevented damage to the core material and the structural integrity of the panel was preserved.
- Foam density of 18 g / l was provided on both sides with a 50 ⁇ m thick layer of PU adhesive and glued with 1 mm thick steel plates.
- the panel obtained was fastened horizontally after the adhesive had hardened and exposed to a gas flame (flame temperature> 500 ° C.) for 30 minutes from below. After only 5 minutes the EPS foam core material melted and caught fire and the structural integrity of the panel was lost.
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Physics & Mathematics (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Electromagnetism (AREA)
- Acoustics & Sound (AREA)
- Building Environments (AREA)
- Laminated Bodies (AREA)
- Thermal Insulation (AREA)
- Refrigerator Housings (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE200410016081 DE102004016081A1 (de) | 2004-03-30 | 2004-03-30 | Wärmedämmverbund mit verbesserter Thermostabilität und verbessertem Brandverhalten |
| PCT/EP2005/003214 WO2005095728A1 (de) | 2004-03-30 | 2005-03-26 | Wärmedämmverbund mit verbesserter thermostabilität und verbessertem brandverhalten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1733102A1 true EP1733102A1 (de) | 2006-12-20 |
Family
ID=34963319
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP05728978A Withdrawn EP1733102A1 (de) | 2004-03-30 | 2005-03-26 | Wärmedämmverbund mit verbesserter thermostabilität und verbessertem brandverhalten |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20080038516A1 (zh) |
| EP (1) | EP1733102A1 (zh) |
| KR (1) | KR20070004916A (zh) |
| CN (1) | CN1934322A (zh) |
| AR (1) | AR050404A1 (zh) |
| AU (1) | AU2005229118A1 (zh) |
| BR (1) | BRPI0508977A (zh) |
| CA (1) | CA2562128A1 (zh) |
| DE (1) | DE102004016081A1 (zh) |
| MX (1) | MXPA06010475A (zh) |
| RU (1) | RU2006137945A (zh) |
| WO (1) | WO2005095728A1 (zh) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1622990B1 (en) * | 2003-05-15 | 2007-10-31 | Huntsman International Llc | Polyisocyanate-based adhesive formulation for use in sandwich panels |
| RU2470042C2 (ru) * | 2007-05-30 | 2012-12-20 | Инеос Нова Интернэшнл Са | Огнестойкий полистирол |
| DE102007034543B4 (de) * | 2007-07-20 | 2018-11-22 | Fritz Egger Gmbh & Co. Og | Verfahren und Vorrichtung zur Herstellung einer Leichtbauplatte sowie Leichtbauplatte |
| EP2207672A1 (de) | 2007-11-06 | 2010-07-21 | Basf Se | Flammschutz- und klebeschicht |
| BRPI0821290A2 (pt) * | 2007-12-19 | 2015-06-16 | Basf Se | Moldagem produzível por um processo, processo para produzir uma moldagem, painel, e, uso de uma moldagem |
| CN102007256B (zh) * | 2008-02-08 | 2012-11-21 | 3M创新有限公司 | 具有粘合剂表面的多层膨胀型防火屏障 |
| EP2307181A1 (en) * | 2008-07-24 | 2011-04-13 | Dow Global Technologies LLC | Process for manufacturing a shaped foam composite article |
| ES2320403B1 (es) * | 2008-10-22 | 2009-11-23 | Leopoldo Vicedo Uliarte | Almacen ignifugo para productos explosivos. |
| PT2456836E (pt) * | 2009-07-22 | 2015-07-30 | Basf Se | Dispersão aquosa de polímero como aglomerante para rebocos e tintas com reação ao fogo melhorada |
| KR101113577B1 (ko) * | 2009-10-01 | 2012-02-22 | 기아자동차주식회사 | 자동차용 고압 가스 연료탱크의 화재안전장치 |
| DE202009017484U1 (de) * | 2009-12-22 | 2010-03-25 | Saint-Gobain Isover G+H Ag | Dämmelement für den Brandschutz |
| EP2576175A1 (en) | 2010-05-27 | 2013-04-10 | Dow Global Technologies LLC | Method of manufacturing a shaped foam article |
| WO2012058177A1 (en) | 2010-10-29 | 2012-05-03 | Dow Global Technologies Llc | Method of forming a shaped foam laminate article |
| WO2012146577A1 (en) * | 2011-04-28 | 2012-11-01 | Ineos Styrenics International Sa | Fire retardant polystyrene |
| DE102011053560A1 (de) | 2011-06-16 | 2012-12-20 | IKJ S.à.r.l. | Brandschutzsystem sowie Brandschutztür, Brandschutz-Wandelement und Brandschutzplatte hierfür |
| WO2013115859A2 (en) * | 2011-10-25 | 2013-08-08 | B/E Aerospace, Inc. | Heat shielded composite panel |
| EP2809492B1 (de) | 2012-02-02 | 2016-04-06 | Covestro Deutschland AG | Verfahren zur kontinuierlichen herstellung eines sandwich-verbundelementes |
| EP2777926A1 (en) | 2013-03-14 | 2014-09-17 | Dow Global Technologies LLC | Panel with fire barrier |
| BE1021837B1 (nl) * | 2014-04-30 | 2016-01-21 | Es-Projects, Besloten Vennootschap Met Beperkte Aansprakelijkheid | Samenstelling van een isolatiemateriaal, werkwijze voor het vervaardigen van isolatiemateriaal en gebruik van dergelijk isolatiemateriaal |
| WO2016089543A1 (en) * | 2014-12-03 | 2016-06-09 | Albemarle Corporation | Metal composite core composition panels and process for making same |
| EP3245328B1 (en) | 2015-01-16 | 2020-10-28 | Beaulieu International Group NV | Covering for floors, walls or ceilings, and method for obtaining a covering |
| EP3245064A1 (en) | 2015-01-16 | 2017-11-22 | Beaulieu International Group NV | Covering and method for producing coverings |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3466222A (en) * | 1967-07-26 | 1969-09-09 | Lexsuco Inc | Fire retardant insulative structure and roof deck construction comprising the same |
| US4015386A (en) * | 1975-02-07 | 1977-04-05 | Clark Door Company, Inc. | Fire-retardant low temperature insulating building panel |
| US4035315A (en) * | 1976-05-03 | 1977-07-12 | Arco Polymers, Inc. | Fire-resistant styrene polymer foams |
| US4168347A (en) * | 1978-01-03 | 1979-09-18 | Arco Polymers, Inc. | Fire and heat resistant structures |
| JPS56130341A (en) * | 1980-03-19 | 1981-10-13 | Takeda Chemical Industries Ltd | Manufacture of refractory heat insulating material |
| CA1288637C (en) * | 1986-04-04 | 1991-09-10 | John S. Luckanuck | Fire resistant steel door |
| DE4318743A1 (de) * | 1993-06-05 | 1994-12-08 | Hoechst Ag | Verfahren zum Verschäumen von flammhemmend ausgerüstetem Polystyrol und Polystyrol-Formkörper |
| US5786095A (en) * | 1996-07-03 | 1998-07-28 | H.B. Fuller Licensing & Financing, Inc. | Inorganic based intumescent system |
| DE19639842C2 (de) | 1996-09-27 | 2002-04-18 | Wolman Gmbh Dr | Brandgeschütztes Verbundsystem |
| DE19809973C1 (de) | 1998-03-09 | 1999-07-01 | Salamander Ind Produkte Gmbh | Schaumstoffkörper mit flammhemmenden Eigenschaften, insbesondere für Bauzwecke |
| GB2362586B (en) | 2000-05-24 | 2003-11-12 | Prometheus Developments Ltd | Fire stable expanded polystyrene foam materials |
| AUPR309101A0 (en) | 2001-02-14 | 2001-03-08 | Styrophen International Pty Ltd | Polymeric composite foam |
| GB2405112B (en) * | 2002-06-03 | 2006-03-01 | Chong Hak Tay | A fire resistant insulation material |
-
2004
- 2004-03-30 DE DE200410016081 patent/DE102004016081A1/de not_active Withdrawn
-
2005
- 2005-03-26 MX MXPA06010475A patent/MXPA06010475A/es unknown
- 2005-03-26 KR KR1020067022506A patent/KR20070004916A/ko not_active Application Discontinuation
- 2005-03-26 EP EP05728978A patent/EP1733102A1/de not_active Withdrawn
- 2005-03-26 WO PCT/EP2005/003214 patent/WO2005095728A1/de active Application Filing
- 2005-03-26 CN CNA2005800091387A patent/CN1934322A/zh active Pending
- 2005-03-26 US US10/593,656 patent/US20080038516A1/en not_active Abandoned
- 2005-03-26 RU RU2006137945/03A patent/RU2006137945A/ru not_active Application Discontinuation
- 2005-03-26 AU AU2005229118A patent/AU2005229118A1/en not_active Abandoned
- 2005-03-26 BR BRPI0508977-8A patent/BRPI0508977A/pt not_active IP Right Cessation
- 2005-03-26 CA CA 2562128 patent/CA2562128A1/en not_active Abandoned
- 2005-03-30 AR ARP050101242 patent/AR050404A1/es unknown
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2005095728A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2562128A1 (en) | 2005-10-13 |
| AR050404A1 (es) | 2006-10-25 |
| CN1934322A (zh) | 2007-03-21 |
| KR20070004916A (ko) | 2007-01-09 |
| DE102004016081A1 (de) | 2005-10-20 |
| WO2005095728A1 (de) | 2005-10-13 |
| RU2006137945A (ru) | 2008-05-10 |
| MXPA06010475A (es) | 2007-03-27 |
| US20080038516A1 (en) | 2008-02-14 |
| BRPI0508977A (pt) | 2007-08-28 |
| AU2005229118A1 (en) | 2005-10-13 |
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