CN1903930A - Flexible acrylic acid waste polyurethane water composite joint filling material and its preparation method - Google Patents
Flexible acrylic acid waste polyurethane water composite joint filling material and its preparation method Download PDFInfo
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- CN1903930A CN1903930A CN 200610029182 CN200610029182A CN1903930A CN 1903930 A CN1903930 A CN 1903930A CN 200610029182 CN200610029182 CN 200610029182 CN 200610029182 A CN200610029182 A CN 200610029182A CN 1903930 A CN1903930 A CN 1903930A
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- China
- Prior art keywords
- waste polyurethane
- acrylic acid
- filling material
- joint filling
- composite joint
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Abstract
The present invention belongs to the field of building material technology, in the concrete, it relates to a flexible acrylic acid waste polyurethane water-base composite joint-filling material and its preparation method. It is made up by using powder obtained by processing waste polyurethane material as aggregate and mixing it with the chemical raw materials of acrylic acid elastic emulsion, sodium hexametaphosphate, sodium benzoate, ethylene glycol, propylene glycol, polydimethylsiloxane, methyl cellulose, calcium carbonate and colouring agent according to a certain mixing ratio.
Description
Technical field
The invention belongs to building material technical field, be specifically related to a kind of flexible acrylic acid waste polyurethane water composite joint filling material and preparation method thereof.
Background technology
The fast development of environment protection need be called various energy-conserving and environment-protective energy saving building materials.The urethane wall heat insulation material was because its outstanding comprehensive physicochemical property more and more widely was applied to energy-conservation lagging material in recent years.Yet a large amount of polyurethane waste materials have caused new environmental pollution again, also occur new utilized industrial waste resource simultaneously; In addition, along with because a lot of novel energy-conserving building materials are applied, need a lot of supplementary material common combinations to become easy to use and the perfect performance application system.Some novel wall material of construction are often run into behind splicing seams, shrinkage joint, the employing energy-saving material outer insulation of metope and the novel building pointing fit applications that all needs such as heat insulation.The environment protection multifunctional matrix material that market is a long felt need for is functional, can joint filling.
Summary of the invention
The objective of the invention is to propose a kind ofly has adhesive ability, a kind of flexible acrylic acid waste polyurethane water composite joint filling material of better intensity and other over-all propertieies and preparation method thereof is arranged.
A kind of flexible acrylic acid waste polyurethane water composite joint filling material that the present invention proposes is that main filler aggregate raw material adds the batching composition with the depleted polyurethane material, and the heavy per-cent of its component is:
Waste polyurethane powder 25-35%
Acrylic elastic emulsion 40-45%
Sodium hexametaphosphate 99 04-0.5%
Sodium Benzoate 0.4-0.5%
Ethylene glycol 0.7-0.9%
Propylene glycol 2-3%
Polydimethylsiloxane 0.04-0.05%
Lime carbonate 15-20%
Methylcellulose gum 1.5-2%
All the other are water,
Its total amount satisfies 100%.
Among the present invention, described waste polyurethane powder directly is the 60-80 order.
Among the present invention, also can add tinting material, its add-on is the 0.06-0.1% of pointing gross weight, the color of tinting material should select for use can be as far as possible with the color of filling out building wall be same system.
The preparation method of the flexible acrylic acid waste polyurethane water composite joint filling material that the present invention proposes, concrete steps are as follows:
Take by weighing various raw materials by component ratio, earlier waste polyurethane powder and lime carbonate are mixed, as component A, again ACRYLIC EMULSION, Sodium hexametaphosphate 99, Sodium Benzoate, propylene glycol, methylcellulose gum, tinting material are mixed, as B component, then that A, B two component blending dispersion is even, at last, add polydimethylsiloxane, water, stir, promptly get desired product.
Waste polyurethane powder among the present invention is that trade wastes such as the scrap stock pulverizing of waste polyurethane goods or polyurethane building lagging material obtains, or for obtaining after the treated pulverizing of spontaneous scrap stock in the polyurethane product course of processing, be uniform fine particulate object, the rubber powder particle diameter that this pointing adopts is about 80 orders.
The pointing that the present invention proposes has good physicochemical property.Press GB through appropriate authority and detect performance such as following table:
Title | Conditioned disjunction unit | Performance |
Surface drying time | H | 2h-2.5h |
Water tolerance | 48h | The no bubble in surface, slight crack, obscission |
Alkali resistance | 48h, saturated aqua calcis | The no bubble in surface |
Abrasion resistance | 500 times | Do not have and destroy |
Adhesion strength | MPa | 0.5-0.52 |
Winter hardiness | -40C,24h | No change |
Thermotolerance | 80C,24h | No change |
Tensile strength | MPa | 1.1 |
Elongation at break | /% | 216 |
Shear bonding strength | MPa | 0.40 |
The present invention is main aggregate owing to having used the waste of waste polyurethane goods, has improved economic worth greatly, and product itself also has good physicochemical property.The available special spray gun spraying of constructing also can be scraped and be smeared, and need not that other adhesive can satisfy the joint filling requirement and cost is low.
The present invention can be used for various metopes, also can be used for slits such as post, plate fills up.Owing to be water-based environment-friendly,, do not have newly and pollute at making, construction, nontoxic, the odorlessness of prolonged application process.
Embodiment
Embodiment 1: set of dispense is such as following:
Waste polyurethane powder 80 order 280g
Acrylic elastic emulsion 400g
Sodium hexametaphosphate 99 50g
Sodium Benzoate 4g
Ethylene glycol 9g
Propylene glycol 30g
Polydimethylsiloxane 0.5g
Lime carbonate 160g
Methylcellulose gum 15g
Water 50g
Tinting material 0.06g
In the above-mentioned raw materials ratio, earlier waste polyurethane powder and lime carbonate are mixed, as component A, again ACRYLIC EMULSION, Sodium hexametaphosphate 99, Sodium Benzoate, propylene glycol, methylcellulose gum, tinting material are mixed, as B component, then that A, B two component blending dispersion is even, at last, add polydimethylsiloxane, water, stir, promptly get desired product.Its performance index are:
Time of drying: 2h
Adhesion strength: 0.53MPa
Other every indexs are ditto described.
Embodiment 2: set of dispense is such as following:
Waste polyurethane powder 60 order 260g
Acrylic elastic emulsion 400g
Sodium hexametaphosphate 99 40g
Sodium Benzoate 5g
Ethylene glycol 8g
Propylene glycol 28g
Polydimethylsiloxane 0.5g
Lime carbonate 180g
Methylcellulose gum 14.5g
Water 64g
Tinting material 0.08g
In the above-mentioned raw materials ratio, earlier waste polyurethane powder and lime carbonate are mixed, as component A, again ACRYLIC EMULSION, Sodium hexametaphosphate 99, Sodium Benzoate, propylene glycol, methylcellulose gum, tinting material are mixed, as B component, then that A, B two component blending dispersion is even, at last, add polydimethylsiloxane, water, stir, promptly get desired product.Its performance index are:
Time of drying: 2h
Adhesion strength: 0.54MPa
Other every indexs are ditto described.
Embodiment 3: set of dispense is such as following:
Waste polyurethane powder (60-80 order) 275g
Acrylic elastic emulsion 415g
Sodium hexametaphosphate 99 40g
Sodium Benzoate 4g
Ethylene glycol 9g
Propylene glycol 26g
Polydimethylsiloxane 0.4g
Lime carbonate 150g
Methylcellulose gum 14.6g
Water 64g
Tinting material 1.0g
In the above-mentioned raw materials ratio, earlier waste polyurethane powder and lime carbonate are mixed, as component A, again acrylic elastic emulsion, Sodium hexametaphosphate 99, Sodium Benzoate, propylene glycol, methylcellulose gum, tinting material are mixed, as B component, then that A, B two component blending dispersion is even, at last, add polydimethylsiloxane, water, stir, promptly get desired product.Its performance index are:
Time of drying: 2h
Adhesion strength: 0.54MPa
Other every indexs are ditto described.
Claims (4)
1, a kind of flexible acrylic acid waste polyurethane water composite joint filling material is characterized in that with the depleted polyurethane material being that main filler aggregate raw material adds the batching composition, and the heavy per-cent of its component is:
Waste polyurethane powder 25-35%
ACRYLIC EMULSION 40-45%
Sodium hexametaphosphate 99 04-0.5%
Sodium Benzoate 0.4-0.5%
Ethylene glycol 0.7-0.9%
Propylene glycol 2-3%
Polydimethylsiloxane 0.04-0.05%
Lime carbonate 15-20%
Methylcellulose gum 1.5-2%
All the other are water,
Its total amount satisfies 100%.
2, flexible acrylic acid waste polyurethane water composite joint filling material according to claim 1 is characterized in that flexible acrylic acid waste polyurethane water composite joint filling material, it is characterized in that described waste polyurethane powder directly is the 60-80 order.
3, flexible acrylic acid waste polyurethane water composite joint filling material according to claim 1 is characterized in that also being added with tinting material, and its add-on is the 0.06-0.1% of pointing gross weight.
4, a kind of preparation method of flexible acrylic acid waste polyurethane water composite joint filling material as claimed in claim 1, concrete steps are as follows:
Take by weighing various raw materials by component ratio, earlier waste polyurethane powder and lime carbonate are mixed, as component A, again acrylic elastic emulsion, Sodium hexametaphosphate 99, Sodium Benzoate, propylene glycol, methylcellulose gum, tinting material are mixed, as B component, then that A, B two component blending dispersion is even, at last, add polydimethylsiloxane, water, stir, promptly get desired product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 200610029182 CN1903930A (en) | 2006-07-20 | 2006-07-20 | Flexible acrylic acid waste polyurethane water composite joint filling material and its preparation method |
Applications Claiming Priority (1)
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CN 200610029182 CN1903930A (en) | 2006-07-20 | 2006-07-20 | Flexible acrylic acid waste polyurethane water composite joint filling material and its preparation method |
Publications (1)
Publication Number | Publication Date |
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CN1903930A true CN1903930A (en) | 2007-01-31 |
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CN 200610029182 Pending CN1903930A (en) | 2006-07-20 | 2006-07-20 | Flexible acrylic acid waste polyurethane water composite joint filling material and its preparation method |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103881623A (en) * | 2013-11-13 | 2014-06-25 | 东南大学 | Acrylic water-based joint mixture and preparation method thereof |
CN105802550A (en) * | 2016-02-05 | 2016-07-27 | 上海鑫旺防腐保温有限公司 | High-elastic diatom waterproof glue and application thereof |
CN106084601A (en) * | 2016-07-25 | 2016-11-09 | 启东市富康箱包配件有限公司 | A kind of thermal gap filler |
CN106189021A (en) * | 2016-08-02 | 2016-12-07 | 启东市稷兵农副产品专业合作社 | A kind of flexible gap filler |
CN106318317A (en) * | 2016-07-25 | 2017-01-11 | 启东市林海制衣厂 | Flexible joint mixture |
-
2006
- 2006-07-20 CN CN 200610029182 patent/CN1903930A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103881623A (en) * | 2013-11-13 | 2014-06-25 | 东南大学 | Acrylic water-based joint mixture and preparation method thereof |
CN105802550A (en) * | 2016-02-05 | 2016-07-27 | 上海鑫旺防腐保温有限公司 | High-elastic diatom waterproof glue and application thereof |
CN106084601A (en) * | 2016-07-25 | 2016-11-09 | 启东市富康箱包配件有限公司 | A kind of thermal gap filler |
CN106318317A (en) * | 2016-07-25 | 2017-01-11 | 启东市林海制衣厂 | Flexible joint mixture |
CN106189021A (en) * | 2016-08-02 | 2016-12-07 | 启东市稷兵农副产品专业合作社 | A kind of flexible gap filler |
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