CN102101958B - Environmentally-friendly interior and exterior wall coating and preparation method and construction method thereof - Google Patents

Environmentally-friendly interior and exterior wall coating and preparation method and construction method thereof Download PDF

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CN102101958B
CN102101958B CN 201010590794 CN201010590794A CN102101958B CN 102101958 B CN102101958 B CN 102101958B CN 201010590794 CN201010590794 CN 201010590794 CN 201010590794 A CN201010590794 A CN 201010590794A CN 102101958 B CN102101958 B CN 102101958B
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boride
mass parts
environment
aqueous solution
internal
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CN102101958A (en
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侯文顺
胡英杰
刘日鑫
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Guangdong relang New Material Technology Co.,Ltd.
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Changzhou Vocational Institute of Engineering
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Abstract

The invention relates to an environmentally-friendly interior and exterior wall coating and a preparation method and a construction method thereof. The coating is prepared from the following raw materials in part by mass: 40-80 parts of aqueous solution of polyvinyl alcohol with concentration of 8-10 percent (mass), 20-40 parts of 80-120 mesh waste stone dust, 1-8 parts of aqueous solution of boride with concentration of1-3 percent (mass) and 0.05 part of mildew preventive P803. The waste stone dust is obtained by grinding and screening a waste acrylic plate. Major ingredients of the waste acrylic plate include polymethyl methacrylate, aluminum hydroxide and calcium carbonate. The preparation method is simple. During construction, the coating is coated twice, and then a borax aqueous solution with concentration of 1-3 percent (mass) is sprayed.

Description

A kind of environment-friendly type coating for internal and external wall and preparation method thereof and constructional method
Technical field
The present invention relates to a kind of environment-friendly type coating for internal and external wall and preparation method thereof and constructional method, more specifically say, relate to a kind of dead meal of producing acrylic sheet material of utilizing and be the environment-friendly type coating for internal and external wall of main raw material and preparation method thereof and constructional method.
Background technology
Acrylic sheet material is a kind of building decorative plates commonly used, and its staple is polymethylmethacrylate, white lake, lime carbonate.The enterprise that produces acrylic sheet material produces many wastes through regular meeting, comprising depleted acrylic sheet material.As refuse treatment, so not only environment has been polluted but also has wasted the useful matter in the acrylic sheet material at present.
Summary of the invention
First purpose of the present invention is: provide a kind of and can reduce acrylic sheet material manufacturing enterprise's waste and to the pollution and the low environment-friendly type coating for internal and external wall of cost of environment.
The technical scheme that realizes first purpose of the present invention is: a kind of environment-friendly type coating for internal and external wall, it is characterized in that it is a preparation of raw material with waste stone dust, Z 150PH, boride, mould inhibitor, and the consumption of above-mentioned each raw material is following:
Z 150PH, the aqueous solution 40~80 mass parts of 8%~20% (quality),
Waste stone dust, 80~120 orders, 20~40 mass parts,
Boride, the aqueous solution 1~8 mass parts of 1%~3% (quality),
Mould inhibitor, P803 0.05 mass parts,
Said waste stone dust is to utilize depleted acrylic sheet material, processes through pulverizing, sieving, and the staple of said acrylic sheet material is polymethylmethacrylate, white lake, lime carbonate;
Said boride is borax, boric acid or borax and boric acid;
Said mould inhibitor P803 is the mould inhibitor product grade of the Shanghai chemical ltd of nine letters.
In the above-mentioned environment-friendly type coating for internal and external wall, said boride is a borax.
In the above-mentioned environment-friendly type coating for internal and external wall, said Z 150PH is for producing discarded Z 150PH, industrial-grade polyethylene alcohol 1788, industrial-grade polyethylene alcohol 1799 or the industrial-grade polyethylene alcohol 2099 in the acrylic board material process.
In the above-mentioned environment-friendly type coating for internal and external wall, described Z 150PH is for producing the discarded Z 150PH in the acrylic board material process.
Second purpose of the present invention is: provide a kind of be convenient to operate can reduce acrylic sheet material manufacturing enterprise's waste and to the preparation method of the low environment-friendly type coating for internal and external wall of the pollution of environment and cost.
The technical scheme that realizes second purpose of the present invention is: a kind of method for preparing above-mentioned environment-friendly type coating for internal and external wall is characterized in that the prescription of environment-friendly type coating for internal and external wall is following:
Z 150PH, the aqueous solution 40~80 mass parts of 8%~20% (quality),
Waste stone dust, 80~120 orders, 20~40 mass parts,
Boride, the aqueous solution 1~8 mass parts of 1%~3% (quality),
Mould inhibitor, P803 0.05 mass parts,
Wherein waste stone dust is to utilize depleted acrylic sheet material, processes through pulverizing, sieving, and the staple of said acrylic sheet material is polymethylmethacrylate, white lake, lime carbonate;
Said boride is borax, boric acid or borax and boric acid;
Said mould inhibitor P803 is the mould inhibitor product grade of the Shanghai chemical ltd of nine letters;
Concrete preparation process is following:
1. prepare the polyvinyl alcohol water solution of 8%~20% (quality)
Polyvinyl alcohol water solution desired number difference weighing polyvinyl alcohol and water by preparation 8%~20% (quality) are heated to 75 ℃~95 ℃ with water earlier, then Z 150PH are added in the water, are stirred to Z 150PH and all dissolve, and can preserve subsequent use;
2. prepare the boride aqueous solution of 1%~3% (quality)
Boride aqueous solution desired number by preparation 1%~3% (quality) takes by weighing boride and water respectively, earlier water is heated to 50 ℃~65 ℃, then boride is added in the water, is stirred to boride and all dissolves, and can preserve subsequent use;
3. take by weighing polyvinyl alcohol water solution 40~80 mass parts that 1. the boride aqueous solution 1~8 mass parts that 2. step prepare and step are prepared; The boride aqueous solution is joined in the polyvinyl alcohol water solution; The speed of the boride of the control adding simultaneously aqueous solution is not contained the homogeneous material of gel, leaves standstill 10~20 minutes again;
4. in the material that 3. step obtains, add 0.05 mass parts P803 mould inhibitor, stir, left standstill again 10~20 minutes;
5. 80~120 purpose waste stone dust, 20~40 mass parts are joined in the material that 4. step obtain, stirring obtains the premixing material, leaves standstill 15~20 minutes again;
6. the premixing material that 5. step is obtained is added in the colloidal mill, and discharging after 2~10 minutes is stirred in circulation, promptly processes the environment-friendly type coating for internal and external wall.
Among the preparation method of above-mentioned environment-friendly type coating for internal and external wall, said Z 150PH is for producing discarded Z 150PH, industrial-grade polyethylene alcohol 1788, industrial-grade polyethylene alcohol 1799 or the industrial-grade polyethylene alcohol 2099 in the acrylic board material process.
The 3rd purpose of the present invention is: provide a kind of can guarantee coating quality can reduce acrylic sheet material manufacturing enterprise's waste and to the constructional method of the low environment-friendly type coating for internal and external wall of the pollution of environment and cost.
The technical scheme that realizes the 3rd purpose of the present invention is: a kind of constructional method of the environment-friendly type coating for internal and external wall that makes with aforesaid method is characterized in that, at the surface of wall of new body of wall, old body of wall or the coating of haveing been friends in the past; Directly roller coating or directly spray the environment-friendly type coating for internal and external wall applies twice altogether, and the first road coat-thickness is 1~2mm; Treat after surface drying or the 24h; Apply second road again, coat-thickness is 1~2mm, treats after surface drying or the 24h; Spray the borax solution that concentration is 1%~3% (quality) again on its surface, construction finishes after the seasoning.
Technique effect of the present invention is: the environment-friendly type coating for internal and external wall of technical scheme of the present invention relatively has following advantage with existing similar coating:
1. raw material variety is few, pollution-free, cost is low
Few and the main raw material Z 150PH of the raw materials used kind of formulation for coating material of the present invention, the environmentally safe of waste stone dust own; Particularly waste stone dust is the waste from acrylic sheet material manufacturing enterprise; Not only make the contained resource of acrylic sheet material obtain utilizing and having reduced raw materials cost, reduced pollution, be particularly suitable for acrylic sheet material manufacturing enterprise and found the factory on the spot and produce coating of the present invention environment; Turn waste into wealth, directly create economic benefit for enterprise;
2. water tolerance, abrasion resistance and the alkali resistance of coating have been improved
Waste stone dust in the formulation for coating material of the present invention, its staple are polymethylmethacrylate, white lake, lime carbonate, wherein; White lake, lime carbonate are used as filler in coating, needn't allocate filler, coating process for preparation more in addition into; Z 150PH in polymethylmethacrylate and the coating can produce physics and twine; Strengthened the bonding force of filler (white lake, lime carbonate) and Z 150PH, and the boride in the coating can with Z 150PH generation crosslinking reaction, form reticulated structure; Therefore, the water tolerance of paint coatings of the present invention, abrasion resistance and alkali resistance not only meet the standard of national like product but also be improved (seeing table 1);
The preparation method of coating of the present invention is simple to operate, can adopt existing installation production, therefore is easy to go into operation;
Coating application technology of the present invention is easy; New and old body of wall all can use; Particularly after the coating drying, spray the borax solution that concentration is 1%~3% (quality) again, give full play to the crosslinked action of borax Z 150PH, very favourable to water tolerance, abrasion resistance and the alkali resistance that improves coating.
Embodiment
Below in conjunction with embodiment the present invention is made further specific descriptions, but be not limited to this.
Embodiment is unless otherwise indicated raw materials used, is the general raw material of coating industry, and can buys through the commercial channel.
Among the embodiment, waste stone dust (80~120 order) is taken from Guangzhou heat wave Industrial Co., Ltd.; Discarded Z 150PH is taken from Guangzhou heat wave Industrial Co., Ltd.; Mould inhibitor P803 is available from the chemical ltd of nine letters in Shanghai; All the other raw materials are commercially available technical grade.
(1) preparation environment-friendly type coating for internal and external wall
Embodiment 1
A) formulation for coating material is following:
Discarded Z 150PH, the aqueous solution of 10% (quality), 50 mass parts,
Waste stone dust, 80~120 orders, 25 mass parts,
Borax, borax solution 2 mass parts of 1% (quality),
Mould inhibitor, P803 0.05 mass parts,
B) concrete operations
1. prepare the polyvinyl alcohol water solution of 10% (quality)
Polyvinyl alcohol water solution desired number by preparation 10% (quality) takes by weighing discarded Z 150PH 10Kg and water 90Kg respectively, earlier water is heated to 75 ℃, will discard Z 150PH then and be added in the water, is stirred to Z 150PH and all dissolves, and can preserve subsequent use;
2. prepare the borax solution of 1% (quality)
Borax solution desired number by preparation 1% (quality) takes by weighing borax 1Kg and water 99Kg respectively, earlier water is heated to 65 ℃, then borax is added in the water, is stirred to borax and all dissolves, and can preserve subsequent use;
3. take by weighing polyvinyl alcohol water solution 50 mass parts that 1. borax solution 2 mass parts that 2. step prepare and step are prepared; Borax solution is joined in the polyvinyl alcohol water solution; The speed of the borax solution of control adding is not simultaneously contained the homogeneous material of gel, leaves standstill 15 minutes again;
4. in the material that 3. step obtains, add 0.05 mass parts mould inhibitor P803, stir, left standstill again 15 minutes;
5. 80~120 purpose waste stone dust, 25 mass parts are joined step and 4. make in the material, stirring obtains the premixing material, leaves standstill 20 minutes again;
6. the premixing material that 5. step is obtained is added in the colloidal mill, and discharging after 3 minutes is stirred in circulation, promptly processes the environment-friendly type coating for internal and external wall.
Embodiment 2
A) formulation for coating material is following:
Discarded Z 150PH, the aqueous solution of 12% (quality), 60 mass parts,
Waste stone dust, 80~120 orders, 35 mass parts,
Boric acid, boric acid aqueous solution 3 mass parts of 1% (quality),
Mould inhibitor, P803 0.05 mass parts,
B) concrete operations
1. prepare the polyvinyl alcohol water solution of 12% (quality)
Polyvinyl alcohol water solution desired number by preparation 12% (quality) takes by weighing discarded Z 150PH 12Kg and water 88Kg respectively, earlier water is heated to 80 ℃, will discard Z 150PH then and be added in the water, is stirred to Z 150PH and all dissolves, and can preserve subsequent use;
2. prepare the boric acid aqueous solution of 1% (quality)
Boric acid aqueous solution desired number by preparation 1% (quality) takes by weighing boric acid 1Kg and water 99Kg respectively, earlier water is heated to 60 ℃, then borax is added in the water, is stirred to boric acid and all dissolves, and can preserve subsequent use;
3. take by weighing polyvinyl alcohol water solution 60 mass parts that 1. boric acid aqueous solution 3 mass parts that 2. step prepare and step are prepared; Boric acid aqueous solution is joined in the polyvinyl alcohol water solution; The speed of the boric acid aqueous solution of control adding is not simultaneously contained the homogeneous material of gel,, left standstill again 10 minutes;
4. in the material that 3. step obtains, add 0.05 mass parts mould inhibitor P803, stir, left standstill again 15 minutes;
5. 80~120 purpose waste stone dust, 35 mass parts are joined step and 4. make in the material, stirring obtains the premixing material, leaves standstill 15 minutes again;
6. the premixing material that 5. step is obtained is added in the colloidal mill, and discharging after 5 minutes is stirred in circulation, promptly processes the environment-friendly type coating for internal and external wall.
Embodiment 3
A) formulation for coating material is following:
The aqueous solution of industrial-grade polyethylene alcohol 1788,16% (quality), 80 mass parts,
Waste stone dust, 80~120 orders, 40 mass parts,
Borax, borax solution 3 mass parts of 2.5% (quality),
Mould inhibitor, P803 0.05 mass parts,
B) concrete operations
1. prepare the polyvinyl alcohol water solution of 16% (quality)
Polyvinyl alcohol water solution desired number by preparation 16% (quality) takes by weighing industrial-grade polyethylene alcohol 1788 16Kg and water 84Kg respectively; Earlier water is heated to 92 ℃; Then industrial-grade polyethylene alcohol 1788 is added in the water, is stirred to Z 150PH and all dissolves, can preserve subsequent use;
2. prepare the borax solution of 2.5% (quality)
Borax solution desired number by preparation 2.5% (quality) takes by weighing borax 2.5Kg and water 97.5Kg respectively, earlier water is heated to 50 ℃, then borax is added in the water, is stirred to borax and all dissolves, and can preserve subsequent use;
3. take by weighing polyvinyl alcohol water solution 80 mass parts that 1. borax solution 3 mass parts that 2. step prepare and step are prepared; Borax solution is joined in the polyvinyl alcohol water solution; The speed of the borax solution of control adding is not simultaneously contained the homogeneous material of gel, leaves standstill 15 minutes again;
4. in the material that 3. step obtains, add 0.05 mass parts P803 mould inhibitor, stir, left standstill again 15 minutes;
5. 80~120 purpose waste stone dust, 40 mass parts are joined step and 4. make in the material, stirring obtains the premixing material, leaves standstill 20 minutes again;
6. the premixing material that 5. step is obtained is added in the colloidal mill, and discharging after 7 minutes is stirred in circulation, promptly processes the environment-friendly type coating for internal and external wall.
(2) environment-friendly type coating for internal and external wall Performance Detection
Method by the national Specification of coating for internal and external wall prepares model and the coating that embodiment 1~3 makes is carried out the detection of correlated performance, and the result is listed in table 1.
Table 1
Sequence number Interventions Requested Technical requirements Assay This conclusion
1 Condition in container No lump is uniform state after the stirring Meet the requirements Qualified
2 Application property It is accessible to brush two roads Meet the requirements Qualified
3 Low-temperature stability Never degenerate Meet the requirements Qualified
4 Time of drying (surface drying), h ≤2 Through Qualified
5 Appearance of film Normally Meet the requirements Qualified
6 Contrast ratio (white and light color) ≥0.87 0.90 Qualified
7 Water-fast washing 96h is no abnormal No abnormal Qualified
8 Alkali resistance 48 h are no abnormal No abnormal Qualified
9 Abrasion resistance, inferior ≥500 2000 Premium grads
10 Contamination resistance (white and light color) ≤20 18 Qualified
11 Coating temperature-change resistance (5 circulations) No abnormal No abnormal Qualified
Annotate: the coating of embodiment 1~3 all reaches the detected result in the table 1.
(3) at surface of wall construction environment-friendly type coating for internal and external wall
At the surface of wall of new body of wall, old body of wall or the coating of haveing been friends in the past, directly roller coating or directly spray the environment-friendly type coating for internal and external wall that embodiment 1, embodiment 2 or embodiment 3 make applies twice altogether; The first road coat-thickness is 1~2mm, treats to apply second road again after surface drying or the 24h; Coat-thickness is 1~2mm; Treat after surface drying or the 24h, spray the borax solution that concentration is 2% (quality) on its surface again, construction finishes after the seasoning.

Claims (7)

1. an environment-friendly type coating for internal and external wall is characterized in that, it is a preparation of raw material with waste stone dust, Z 150PH, boride, mould inhibitor, and the consumption of above-mentioned each raw material is following:
Z 150PH, the aqueous solution 40~80 mass parts of 8%~20% quality,
Waste stone dust, 80~120 orders, 20~40 mass parts,
Boride, the aqueous solution 1~8 mass parts of 1%~3% quality,
Mould inhibitor, P803 0.05 mass parts,
Said waste stone dust is to utilize depleted acrylic sheet material, processes through pulverizing, sieving, and the staple of said acrylic sheet material is polymethylmethacrylate, white lake, lime carbonate;
Said boride is borax, boric acid or borax and boric acid;
Said mould inhibitor P803 is the mould inhibitor product grade of the Shanghai chemical ltd of nine letters.
2. environment-friendly type coating for internal and external wall according to claim 1 is characterized in that said boride is a borax.
3. environment-friendly type coating for internal and external wall according to claim 1 is characterized in that, said Z 150PH is for producing discarded Z 150PH, industrial-grade polyethylene alcohol 1788, industrial-grade polyethylene alcohol 1799 or the industrial-grade polyethylene alcohol 2099 in the acrylic board material process.
4. environment-friendly type coating for internal and external wall according to claim 3 is characterized in that, said Z 150PH is for producing the discarded Z 150PH in the acrylic board material process.
5. a method for preparing claim 1 environment-friendly type coating for internal and external wall is characterized in that, the prescription of environment-friendly type coating for internal and external wall is following:
Z 150PH, the aqueous solution 40~80 mass parts of 8%~20% quality,
Waste stone dust, 80~120 orders, 20~40 mass parts,
Boride, the aqueous solution 1~8 mass parts of 1%~3% quality,
Mould inhibitor, P803 0.05 mass parts,
Wherein waste stone dust is to utilize depleted acrylic sheet material, processes through pulverizing, sieving, and the staple of said acrylic sheet material is polymethylmethacrylate, white lake, lime carbonate;
Said boride is borax, boric acid or borax and boric acid;
Said mould inhibitor P803 is the mould inhibitor product grade of the Shanghai chemical ltd of nine letters;
Concrete preparation process is following:
1. prepare the polyvinyl alcohol water solution of 8%~20% quality
Polyvinyl alcohol water solution desired number difference weighing polyvinyl alcohol and water by preparation 8%~20% quality are heated to 75 ℃~95 ℃ with water earlier, then Z 150PH are added in the water, are stirred to Z 150PH and all dissolve, and can preserve subsequent use;
2. prepare the boride aqueous solution of 1%~3% quality
Boride aqueous solution desired number by preparation 1%~3% quality takes by weighing boride and water respectively, earlier water is heated to 50 ℃~65 ℃, then boride is added in the water, is stirred to boride and all dissolves, and can preserve subsequent use;
3. take by weighing polyvinyl alcohol water solution 40~80 mass parts that 1. the boride aqueous solution 1~8 mass parts that 2. step prepare and step are prepared; The boride aqueous solution is joined in the polyvinyl alcohol water solution; The speed of the boride of the control adding simultaneously aqueous solution is not contained the homogeneous material of gel, leaves standstill 10~20 minutes again;
4. in the material that 3. step obtains, add 0.05 mass parts P803 mould inhibitor, stir, left standstill again 10~20 minutes;
5. 80~120 purpose waste stone dust, 20~40 mass parts are joined in the material that 4. step obtain, stirring obtains the premixing material, leaves standstill 15~20 minutes again;
6. the premixing material that 5. step is obtained is added in the colloidal mill, and discharging after 2~10 minutes is stirred in circulation, promptly processes the environment-friendly type coating for internal and external wall.
6. the preparation method of environment-friendly type coating for internal and external wall according to claim 5; It is characterized in that said Z 150PH is for producing discarded Z 150PH, industrial-grade polyethylene alcohol 1788, industrial-grade polyethylene alcohol 1799 or the industrial-grade polyethylene alcohol 2099 in the acrylic board material process.
7. the constructional method of the environment-friendly type coating for internal and external wall that makes of a claim 5 is characterized in that, at the surface of wall of new body of wall, old body of wall or the coating of haveing been friends in the past; Directly roller coating or directly spray the environment-friendly type coating for internal and external wall applies twice altogether, and the first road coat-thickness is 1~2mm; Treat to apply second road again after surface drying or the 24h, coat-thickness is 1~2mm; Treat after surface drying or the 24h, spray the borax solution that concentration is 1%~3% quality on its surface again, construction finishes after the seasoning.
CN 201010590794 2010-12-16 2010-12-16 Environmentally-friendly interior and exterior wall coating and preparation method and construction method thereof Active CN102101958B (en)

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CN104497662B (en) * 2014-12-30 2016-08-31 何革兴 A kind of environment-friendlywater-based water-based paint and preparation method thereof
CN105036610A (en) * 2015-08-27 2015-11-11 苏州云舒新材料科技有限公司 External wall paint and preparation method thereof
CN106978095A (en) * 2016-12-23 2017-07-25 超卓贸易公司 A kind of covering and its covering method for decorative article
CN109838010A (en) * 2017-11-29 2019-06-04 刘岳明 Exterior walls of buildings structure
CN116535962A (en) * 2023-03-28 2023-08-04 安徽中科思沃生物科技有限公司 Quick-drying formaldehyde-free wall-fixing material and preparation process thereof

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CN1267692A (en) * 1999-03-18 2000-09-27 北京市江捷装饰工程有限责任公司 Production process and product of wall paint with natural stone powder

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Address after: 519050 No.13, Hualian 3rd road, fine chemical industry zone, Gaolan Port Economic Zone, Zhuhai City, Guangdong Province

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Address before: 519050 No.13, Hualian 3rd road, fine chemical industry zone, Gaolan Port Economic Zone, Zhuhai City, Guangdong Province

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