CN1899995A - 一种纳米抗菌远红外自洁净玻璃制造方法及其制品 - Google Patents
一种纳米抗菌远红外自洁净玻璃制造方法及其制品 Download PDFInfo
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- CN1899995A CN1899995A CNA2005100842369A CN200510084236A CN1899995A CN 1899995 A CN1899995 A CN 1899995A CN A2005100842369 A CNA2005100842369 A CN A2005100842369A CN 200510084236 A CN200510084236 A CN 200510084236A CN 1899995 A CN1899995 A CN 1899995A
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- 230000003115 biocidal effect Effects 0.000 title claims abstract description 42
- 239000005348 self-cleaning glass Substances 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title abstract description 11
- 239000011521 glass Substances 0.000 claims abstract description 42
- 239000000463 material Substances 0.000 claims abstract description 27
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 21
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims abstract description 12
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000004140 cleaning Methods 0.000 claims abstract description 9
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(II) oxide Inorganic materials [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 3
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 3
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 3
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 3
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052593 corundum Inorganic materials 0.000 claims abstract 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims abstract 2
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 13
- 239000011669 selenium Substances 0.000 claims description 12
- 239000004615 ingredient Substances 0.000 claims description 11
- 238000003672 processing method Methods 0.000 claims description 10
- 239000011787 zinc oxide Substances 0.000 claims description 10
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000292 calcium oxide Substances 0.000 claims description 9
- 229960004643 cupric oxide Drugs 0.000 claims description 9
- 239000000395 magnesium oxide Substances 0.000 claims description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 9
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 8
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 6
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium oxide Inorganic materials [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims description 6
- 229910052711 selenium Inorganic materials 0.000 claims description 6
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- 229960001866 silicon dioxide Drugs 0.000 claims description 3
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- 230000000593 degrading effect Effects 0.000 abstract description 2
- 238000005034 decoration Methods 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 12
- 229920000049 Carbon (fiber) Polymers 0.000 description 10
- 239000004917 carbon fiber Substances 0.000 description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 7
- 239000003242 anti bacterial agent Substances 0.000 description 7
- 229940088710 antibiotic agent Drugs 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 229910052726 zirconium Inorganic materials 0.000 description 7
- 239000011651 chromium Substances 0.000 description 6
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 229910010413 TiO 2 Inorganic materials 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 239000003570 air Substances 0.000 description 4
- 230000004927 fusion Effects 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000005543 nano-size silicon particle Substances 0.000 description 4
- 239000011858 nanopowder Substances 0.000 description 4
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 3
- 239000002134 carbon nanofiber Substances 0.000 description 3
- 238000005352 clarification Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 108010025899 gelatin film Proteins 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 208000007578 phototoxic dermatitis Diseases 0.000 description 2
- 238000000247 postprecipitation Methods 0.000 description 2
- 239000010979 ruby Substances 0.000 description 2
- 229910001750 ruby Inorganic materials 0.000 description 2
- 230000005476 size effect Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- 244000225942 Viola tricolor Species 0.000 description 1
- 235000004031 Viola x wittrockiana Nutrition 0.000 description 1
- 229910026551 ZrC Inorganic materials 0.000 description 1
- OTCHGXYCWNXDOA-UHFFFAOYSA-N [C].[Zr] Chemical compound [C].[Zr] OTCHGXYCWNXDOA-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000009686 powder production technique Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
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- C03C4/00—Compositions for glass with special properties
- C03C4/08—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths
- C03C4/082—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths for infrared absorbing glass
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/078—Glass compositions containing silica with 40% to 90% silica, by weight containing an oxide of a divalent metal, e.g. an oxide of zinc
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- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
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- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
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Abstract
本发明公开了一种纳米抗菌自洁净玻璃制造工艺及其制品，其配方为：ZrO2、SiO2、Al2O3、Na2O、TiO2、ZnO、Fe2O3为主料，辅料为CaO、Cr2O3、CuO、MnO2、Se、Cd、CoO。可以制成各种颜色的远红外抗菌自洁净玻璃、玻璃器皿、微孔玻璃制品。本发明的远红外纳米抗菌自洁净玻璃，可以用作高档建筑玻璃、装饰玻璃等；也可制作微孔玻璃过滤器的膜基主料，还可以用其制造玻璃器皿和容器，本发明的产品具有抗菌、降解、自洁净效应。
Description
技术领域
本发明涉及纳米抗菌远红外自洁净玻璃制制工艺及其制品。
背景技术
目前具有降解污渍的自洁净玻璃，都是采用镀膜方法制造的镀膜玻璃。尚未见到具有亲光性、亲水性、能够自身发射远红外线的自洁净建筑玻璃及其制品面世。
发明内容
本发明的目的是提供一种纳米抗菌远红外自洁净玻璃的制造工艺及其制品。这种玻璃产品具有纳米尺寸效应，表面抗菌灭菌功能，再常温下能够发射5000-15000nm(纳米)远红外线，具有亲光性、亲水性，在光和水的作用下，能够自动降解玻璃表面的污渍，实现自洁净的目的。
本发明的目的是通过以下方案实现的：一种纳米抗菌远红外自洁净玻璃，可以采用化工原料，也可以利用天然矿石原料，如锆英石、长石、滑石、高岭土、锂辉石、锂云母等，按重量份百分比组分为：ZrO2(二氧化锆)0～10、SiO2(二氧化硅)0～60、Al2O3(三氧化二铝)0～80、Na2O(氧化钠)0～30、TiO2(二氧化钛)0～10、ZnO(氧化锌)0～10、Fe2O3(三氧化二铁)0～4为主料，辅料为CaO(氧化钙)0～10、MgO(氧化镁)0～12、Cr2O3(三氧化二铬)0～5、CuO(氧化铜)0～3、MnO2(二氧化锰)0～3、Se(硒)0～3、Cd(镉)0～3、CoO(氧化钴)0～3、Li2O(氧化锂)0～30、Nd2O3(氧化钕)0～6。其玻璃的制造熔制工艺方法按照常规的方法。熔化温度在1300～1600℃，将主料和辅料研磨为纳米粉体，混合-熔化-搅拌-澄清-成型-成品-检验-包装。抗菌远红外玻璃可用于建筑、装饰幕墙玻璃。
如需生产抗菌远红外玻璃粉体，则在澄清后进行水炸-粉碎-过筛，制成所需的纳米红外粉和微米纳米红外粉体产品，比陶瓷红外粉生产工艺简便，远红外玻璃粉体材料可以刮涂或印刷在纤维织物上，可代替陶瓷红外粉。
如需生产一种(空气过滤、液体过滤用)抗菌远红外自洁净微孔玻璃，工艺方法如下：第一步、制备纳米级微孔膜板，选择直径为50-80纳米碳素纤维，长度800-1000纳米，纳米碳纤维的长径比为100以上，按通透量与比重20％-40％的配比量，加入SiO2纳米溶胶，同时加入纳米ZrO2粉体与纳米碳纤维混合、强搅拌均匀后，在碳纤维外表形成凝胶膜，经过水解，沉淀后洗涤，干燥，获得纳米硅、锆、碳纤维复合体，送入真惰性气体电炉的加料装置储备-待用。第二步，将上述纳米抗菌远红外玻璃配合熔液的澄清液送入惰性气体气氛电炉，熔液温度在1350～1500℃时，在惰性气体的保护下，加入纳米硅、锆、碳纤维复合体，搅拌均匀，澄清，在惰性气体保护下经过生产线成型-成品-退火，致密孔膜玻璃在生产线退火800℃时，输出到用空气、氧气氧化处理生产线，在800-400℃时除去致密膜中的碳纤维，获得具有抗菌材料纳米锆的圆筒型直通孔道，孔壁布满有尖晶锆纳米体离子，获得纳米、抗菌、远红外、自洁净微孔净玻璃产品，产品的表面具有纳米尖晶尺寸效应、抗菌灭菌效应、远红外效应、自洁净降解。检验-包装。关键在于采用碳化锆纤维微孔膜板和应用惰性气体保护的电炉熔制及成型生产线在惰性气体气氛保护生产的工艺方法。
纳米抗菌远红外自洁净微孔玻璃，在空气净化、液体的滤清和固体分离方面有广泛的用途。
如需要生产各色远红外抗菌自洁净玻璃或各色远红外抗菌自洁净微孔玻璃，应用上述远红外抗菌自洁净玻璃的主料配方ZrO2(二氧化锆)0～10、SiO2(二氧化硅)0～60、Al2O3(三氧化二铝)0～80、Na2O(氧化钠)0～30、TiO2(二氧化钛)0～10、ZnO(氧化锌)0～10、Fe2O3(三氧化二铁)0～4为主料，配以辅料CaO(氧化钙)0～10、MgO(氧化镁)0～12、Cr2O3(三氧化二铬)0～5、CuO(氧化铜)0～3、MnO2(二氧化锰)0～3、Se(硒)0～3、Cd(镉)0～3、CoO(氧化钻)0～3、Li2O(氧化锂)0～30、Nd2O3(氧化钕)0～6为稳定剂和着色剂，选择不同的辅料组合，可以生产出颜色不同的红玻璃、蓝玻璃、绿玻璃、黄玻璃等各色远红外抗菌自洁净玻璃制品。如氧化钴和其他着色剂一起使用时可以得到希望的任何色调玻璃。例如氧化钴与铬或铜一起使用时，从纯钴蓝色，带浅绿的蓝色、蓝绿色到铬绿色。氧化钴和氧化锰一起使用，可以得到紫色、紫罗兰色和黑色。硫化镉与硒一起使用，可以得到宝石红玻璃(适合惰性气体保护气氛的电炉熔制)，硫化镉与硒也可作为硒红玻璃的着色剂；硫化镉与氧化锌一起使用，可以得到黄色玻璃；加入Nd2O3(氧化钕)3～6，可以得到美丽的紫色玻璃。
本发明的远红外纳米抗菌自洁净玻璃，是生产电热玻璃的理想原片材料。
本发明纳米抗菌远红外玻璃，可以根据其具有能够发射波长为8-15微米的远红外线，法向光谱比辐射率在0.8微米以上，这个波段的红外线，可以被人体和许多物体所吸收，能够产生一系列物理、化学、生物、纳米尺寸效应。可以广泛应用于食品、饮料、酿酒等行业的包装及用具，具有抗菌保鲜作用。对人体具有保健作用。
实施例1
纳米抗菌远红外自洁净玻璃，按重量份百0.8分比组分由ZrO2 5、SiO2 50、Al2O3 30、Na2O 15、TiO2 1、ZnO 2、Fe2O3纳米抗菌远红外自洁净玻璃、Cr2O3 1、组成为主料，辅料为CaO 1、MgO 2、CuO 1、MnO2 1、Se 0.001、Cd 0.003、CoO 0.002、Li2O 15、Nd2O3 3组成着色剂和稳定剂按照常规玻璃的熔制制造工艺方法，熔化温度在1300～1600℃，将主料和辅料研磨为纳米粉体，用氧化钴和氧化锰一起使用组成着色剂，混合-熔化-搅拌-澄清-成型-成品得到紫罗兰色的纳米抗菌自洁净玻璃产品。
实施例2
抗菌远红外自洁净微孔玻璃，工艺方法如下：制备纳米级微孔膜板，选择直径为80纳米碳素纤维，长度1000纳米，按通透量为40％的配比量，加入SiO2纳米溶胶，同时加入纳米ZrO2粉体与纳米碳纤维混合、强搅拌均匀后，在碳纤维外表形成凝胶膜，经过水解，沉淀后洗涤，干燥，获得纳米硅、锆、碳纤维复合体，送入真惰性气体电炉的加料装置储备-待用。第二步，将上述玻璃配料ZrO25、SiO250、Al2O3 30、Na2O 15、TiO2 1、ZnO 2、Fe2O3 1、Cr2O3 1、组成为主料，辅料为CaO 1、MgO 2、CuO 1、MnO2 1、Se 0.005、Cd 0.005、CoO 0.002、Li2O 15、Nd2O3 2组成着色剂和稳定剂，按照常规玻璃的熔制制造工艺方法，熔化温度在1300～1600℃，将主料和辅料研磨为纳米粉体，混合-熔化-搅拌-澄清，澄清的溶液送入惰性气体电炉，熔液温度在1400～1500℃时，在氮气的保护下，加入纳米硅、锆、碳纤维复合体，搅拌均匀，在氮气的气体保护下经过成型-成品-退火至800-300℃时，用空气、氧气氧化处理除去致密膜中的碳纤维，获得具有抗菌材料纳米锆的圆筒直通孔道，获得远红外抗菌自洁净微孔净玻璃产品。
实施例3
纳米抗菌远红外玻璃酒瓶容器，按重量份百分比组分由ZrO2 5、SiO2 50、Al2O3 30、Na2O 15、TiO2 1、ZnO 2、Fe2O3 0.9、Cr2O3 1、组成为主料，辅料为CaO 1、MgO 2、CuO 1、MnO2 1、Se 0.001、Cd 0.003、CoO 0.002、Li2O 15、Nd2O3 3组成着色剂和稳定剂按照常规玻璃的熔制制造工艺方法，熔化温度在1300～1600℃，将主料和辅料研磨为纳米粉体，用氧化钴和氧化锰一起使用组成着色剂，混合-熔化-搅拌-澄清-成型-成品得到紫罗兰色的远红外纳米抗菌玻璃酒瓶容器产品。
本发明与现有技术相比，具有发射波长为8-15微米的远红外线和纳米效应，这是普通玻璃制品不具备的，而且可生产各种颜色、透明、半透明的产品。
Claims (8)
1、一种纳米抗菌远红外自洁净玻璃，按重量份百分比组分为：ZrO2(二氧化锆)0～10、SiO2(二氧化硅)0～60、Al2O3(三氧化二铝)0～80、Na2O(氧化钠)0～30、TiO2(二氧化钛)0～10、ZnO(氧化锌)0～10、Fe2O3(三氧化二铁)0～4为主料，辅料为CaO(氧化钙)0～10、MgO(氧化镁)0～12、Cr2O3(三氧化二铬)0～5、CuO(氧化铜)0～3、MnO2(二氧化锰)0～3、Se(硒)0～3、Cd(镉)0～3、CoO(氧化钴)0～3、Li2O(氧化锂)0～30、Nd2O3(氧化钕)0～6。
2、根据权利要求1所述纳米抗菌远红外自洁净玻璃的配方，制造抗菌远红外自洁净玻璃的工艺方法。
3、根据权利要求1、2所述纳米抗菌远红外自洁净玻璃的配方，制造各种彩色的抗菌远红外自洁净玻璃的工艺方法。
4、根据权利要求1、2所述纳米抗菌远红外自洁净玻璃的配方，制造抗菌远红外自洁净微孔玻璃的工艺方法。
5、根据权利要求1所述纳米抗菌远红外自洁净玻璃的配方，制造彩色抗菌远红外自洁净微孔玻璃的工艺方法。
6、根据权利要求1所述纳米抗菌远红外自洁净玻璃的配方，制造彩色抗菌远红外自洁净微孔玻璃过滤器、过滤材料的工艺方法。
7、根据权利要求1所述纳米抗菌远红外自洁净玻璃的配方，制造抗菌远红外粉体材料的工艺方法。
8、根据权利要求1所述纳米抗菌远红外自洁净玻璃的配方，制造抗菌远红外包装玻璃容器的工艺方法。
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| CN104529157A (zh) * | 2014-12-12 | 2015-04-22 | 刘成江 | 一种原片自洁净玻璃及其制备方法 |
| CN105126255A (zh) * | 2015-07-03 | 2015-12-09 | 世泰富兴（北京）贸易有限公司 | 一种保健的水晶、玻璃工艺品及其制备方法 |
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| CN106495642B (zh) * | 2016-10-22 | 2019-02-22 | 王景沧 | 一种无需加热就能高效释放远红外线的辐射材料 |
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