CN1871384A - Stretchable composite fabric and clothing product therefrom - Google Patents
Stretchable composite fabric and clothing product therefrom Download PDFInfo
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- CN1871384A CN1871384A CN200480031101.XA CN200480031101A CN1871384A CN 1871384 A CN1871384 A CN 1871384A CN 200480031101 A CN200480031101 A CN 200480031101A CN 1871384 A CN1871384 A CN 1871384A
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- 239000002131 composite material Substances 0.000 title claims abstract description 133
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- 239000000835 fiber Substances 0.000 claims description 85
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- -1 polybutylene terephthalate Polymers 0.000 claims description 42
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- 238000012545 processing Methods 0.000 claims description 30
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Abstract
A stretchable composite fabric which is a woven or knitted fabric comprising composite yarns (A) formed from stretchable yarns (1) having a self elongation upon water absorption of 5 % or more and an elongation at break of 200 % or more and non-stretchable yarns (2) having a self elongation upon water absorption less than 5 % and yarns (B) containing stretchable yarns (3) having a self elongation upon water absorption of less than 5 % and an elongation at break of 30 % or more, wherein a sample taken from the fabric exhibits a ratio of L1 to L2 (L1/L2) of 0.9 or less, wherein L1 and L2 represent average lengths of yarns (1) and yarns (2) in the sample, respectively, and yarns (1) undergo self-elongation when they absorb water and undergo shrinkage when they are dried. The stretchable composite fabric can be suitably used for sport and inner wear clothes.
Description
Technical field
The present invention relates to Stretchable composite fabric and clothing item thereof.More particularly, Stretchable composite fabric that the present invention relates to and clothing item thereof, this Stretchable composite fabric is to contain the height suction from extensibility elastomeric yarn (1), the low suction from extensibility non-elastic fiber (2) and low the suction from the woven or knitted fabric of extensibility elastomeric yarn (3), by water when moistening, owing to constitute the difference of the suction of yarn from percentage elongation, produce relief pattern at fabric face, through super-dry, above-mentioned pattern disappears.
Background technology
In the past, a lot of schemes (for example patent documentation 1) of using the woven or knitted fabric of rubber-like in the purposes of sportswear and underwear etc. had been proposed.
But, if will contain the clothes purposes that the woven or knitted fabric of the elasticity of synthetic fiber and/or natural fabric is used for sportswear and underwear, then having because of skin and perspire, clothes is close to skin, produces the problem of sticky feeling.In order to eliminate described problem, for example proposed to have the fabric of double-layered structure in the patent documentation 2, wherein the inside of fabric has relief pattern.But in such fabric, its surface also forms relief pattern, and under common state (waiting moistening state because of perspiring), its clothing surface also has unnecessary relief pattern by these textile clothes, and outward appearance is not good.
In addition, for example proposed in the patent documentation 3 and 4 can the self-regulation gas permeability fabric.In the clothes that use this fabric to form, under the state of perspiring, humidity in the clothes rises, and the gas permeability that then constitutes the fabric of clothes increases, and the moisture that is stranded in the clothes is discharged to outside the clothes, stop and perspiring, temperature in the suit dried then, clothes reduces, and the gas permeability that constitutes the fabric of clothes reduces, the heat insulating ability of clothes increases, and can always keep the comfortable and easy to wear of clothes.
Proposed to make the woven or knitted fabric of above-mentioned double-decker to contain the scheme of water absorbing agent in the patent documentation 5.
But clothes in the past are with in woven or the knitted fabric, and the problem of the clothes sticky feeling that produces because of perspiration is eliminated as yet fully.
[patent documentation 1] Japanese kokai publication hei 3-174043 communique
[patent documentation 2] TOHKEMY 2003-147657 communique
[patent documentation 3] Japanese kokai publication hei 3-213518 communique
[patent documentation 4] Japanese kokai publication hei 10-77544 communique
[patent documentation 5] TOHKEMY 2002-266249 communique
Summary of the invention
The object of the present invention is to provide Stretchable composite fabric and clothing item thereof, this Stretchable composite fabric contains because of the moistening of water absorbs water from elongation, because of the dry yarn that shrinks, and integral body has elasticity.
Above-mentioned purpose realizes by Stretchable composite fabric of the present invention and clothing item thereof.
Stretchable composite fabric of the present invention is to contain different mutually at least 3 kinds of yarns (1), the woven or knitted fabric of (2) and (3), wherein,
Yarn (1) be have than higher suction from percentage elongation and 200% or above elongation at break, the high suction of rubber-like from the extensibility elastomeric yarn,
Yarn (2) is to have lower suction from percentage elongation, but does not show flexible low suction basically from the extensibility inelastic yarn,
Yarn (3) contain the lower suction of tool from percentage elongation and flexible fiber, be have 30% or the low suction of above elongation at break from the extensibility elastomeric yarn;
It is characterized in that: Yi Bian apply the load of 0.88mN/dtex, on one side with above-mentioned yarn (1), (2) and (3) be wound up into respectively on the reeled yarn frame of frame girth 1.125m, the formation winding number is 10 reeled yarn, this reeled yarn is taken off from above-mentioned reeled yarn frame, 20 ℃ of temperature, placed 24 hours in the air ambient of relative humidity 65%, carry out the state adjustment, this dry reeled yarn is applied the load of 0.0088mN/dtex, measure the long (Ld of its dry yarn, mm), this reeled yarn was soaked 5 minutes in the water of 20 ℃ of water temperatures, from water, mention then, this moistening reeled yarn is applied the load of 0.0088mN/dtex, measure the long (Lw of its moistening yarn, mm), by following formula calculate each yarn from percentage elongation
The suction of yarn is from percentage elongation (%)=(Lw-Ld)/(Ld) * 100
At this moment, above-mentioned yarn (1) have 5% or above suction from percentage elongation, above-mentioned yarn (2) and (3) have and are lower than 5% suction from percentage elongation,
Form suction from extensibility elastic composite yarn (A) by above-mentioned yarn (1) and yarn (2), above-mentioned yarn (3) is contained in the non-suction that do not show basically from extensibility in extensibility elastomeric yarn (B),
Make above-mentioned woven or knitted fabric in atmosphere, carry out dimensionally stable with 20 ℃ temperature and 65% relative humidity, from the woven or knitted fabric that has carried out this dimensionally stable, get the experiment slice of above-mentioned complex yarn (A) with 30cm length, measure above-mentioned yarn (1) and average length L 1 and the L2 of yarn (2) under 0.0088mN/dtex load in this experiment slice, at this moment, the value of L1/L2 be 0.9 or below.
In the composite fabric of the present invention, above-mentioned Stretchable composite fabric has the woven fabric tissue, in preferred in-house warp thread group of this woven fabric and/or the weft yarn group, above-mentioned suction from extensibility elastomeric yarn (A) and above-mentioned non-suction from extensibility elastomeric yarn (B) single or many alternate configurations.
In the composite fabric of the present invention, preferred above-mentioned complex yarn (A) and above-mentioned yarn (B) only constitute the side's yarn group in in-house warp thread group of above-mentioned woven fabric and the weft yarn group, and the opposing party's yarn group is by a kind or the above yarn formation different with above-mentioned yarn (B) with above-mentioned complex yarn (A).
In the composite fabric of the present invention, preferably different with above-mentioned yarn (B) with above-mentioned complex yarn (A) yarns is selected to contain many filamentary yarns with flattened and contain has 1.5dtex or following fine-titred many filamentary yarns.
In the composite fabric of the present invention, above-mentioned composite fabric has 2 layers or above multilayer tissue, one deck at least of preferred above-mentioned multilayer tissue contains above-mentioned complex yarn (A) with its gross mass 20 quality % or above containing ratio, and one deck at least of above-mentioned multilayer tissue contains above-mentioned yarn (B) with its gross mass 20 quality % or above containing ratio.
In the composite fabric of the present invention, above-mentioned high suction contained in the preferred above-mentioned complex yarn of formation (A) is selected from the polyether ester fibre that is formed by polyester elastomer from the fiber of extensibility elastomeric yarn (1), and wherein said polyester elastomer comprises the hard segment that contains the polybutylene terephthalate (PBT) block and contains the soft chain segment of polyethylene glycol block.
In the composite fabric of the present invention, preferably constitute low suction contained in the above-mentioned complex yarn (A) and be selected from polyester fiber from the fiber of extensibility inelastic yarn (2).
In the composite fabric of the present invention, the filament fiber number that preferably constitutes the fiber of above-mentioned yarn (2) is 1.5dtex or following.
In the composite fabric of the present invention, preferred above-mentioned non-suction can be except that containing above-mentioned low suction also contains other yarns (4) from extensibility elastomeric yarn (3) complex yarn from extensibility elastomeric yarn (B), at this moment, above-mentioned yarn (3) has 200% or above elongation at break, above-mentioned yarn (4) contains and does not have suction basically from extensibility and flexible fiber, when similarly measuring with above-mentioned assay method with above-mentioned complex yarn (A), the average length L 3 of the yarn (3) in the preferred above-mentioned complex yarn and the ratio L3/L4 of the average length L 4 of yarn (4) be 0.9 or below.
In the composite fabric of the present invention, preferred constitute have above-mentioned 200% or the fiber of the yarn (3) of above elongation at break be selected from the polyether ester fibre that forms by polyester elastomer, wherein said polyester elastomer comprises the hard segment that contains the polybutylene terephthalate (PBT) block and contains the soft chain segment of polyoxy butylidene glycol block.
In the composite fabric of the present invention, the fiber that preferably constitutes above-mentioned yarn (4) is selected from polyester fiber.
In the composite fabric of the present invention, by a plurality of samples of getting size 5cm * 2cm on this composite fabric, they were placed 24 hours in the air of 20 ℃ of temperature, relative humidity 65%, make a plurality of drying samples, get a plurality of samples of size 5cm * 2cm in addition again from above-mentioned composite fabric, they were soaked 5 minutes in the water of 20 ℃ of temperature, from water, mention, be clipped between a pair of filter paper, with 490N/m
2Pressure pressing 1 minute, remove and be present in interfibrous water in the sample, make a plurality of moistening samples, measure the average maximum ga(u)ge Dw of above-mentioned moistening sample and the average maximum ga(u)ge Dd of above-mentioned drying sample, measure concavo-convex rate of change by following formula,
Concavo-convex rate of change (%)=[(Dw-Dd)/(Dd)] * 100
Preferred above-mentioned concavo-convex rate of change 10% or more than.
In the composite fabric of the present invention, preferred above-mentioned composite fabric has the woven fabric tissue, the coverage coefficient of this woven fabric be 2500 or more than.
In the composite fabric of the present invention, preferably at least one face of this composite fabric is implemented hydrophobic processing.
In the composite fabric of the present invention, carry out air permeability when measuring by JIS L 1096-1998,6.27, A method (Fu Leizefa) in the air of 20 ℃ of temperature, relative humidity 65%, preferably this composite fabric shows 50ml/cm
2S or following air permeability.
In the composite fabric of the present invention, by JIS L 1092-1998,4. (1.1) (low hydraulic pressure hydrostatic platen press) carried out water pressure resistance when measuring, preferably this composite fabric shows 100mm H in the air of 20 ℃ of temperature, relative humidity 65%
2O or above water pressure resistance.
Dress materials of the present invention contain above-mentioned Stretchable composite fabric of the present invention, and are moistening by water, at least one surface performance concaveconvex shape.
Clothes of the present invention are to be formed by at least one part that above-mentioned dress materials of the present invention form the armpit, sidepiece, chest, back and the shoulder that are selected from clothes.
The clothes of the invention described above are preferably selected from underwear.
The clothes of the invention described above are preferably selected from sportswear.
The accompanying drawing summary
Fig. 1 is the stravismus key diagram of the shape of an example when drying of expression Stretchable composite fabric of the present invention.
Fig. 2 is the stravismus key diagram of the shape of Stretchable composite fabric when suction is moistening of presentation graphs 1.
Fig. 3 is the cross-sectional illustration figure of the shape of another example when drying of Stretchable composite fabric of the present invention.
Fig. 4 is the cross-sectional illustration figure of the shape of Stretchable composite fabric when suction is moistening of Fig. 3.
Fig. 5 is the front key diagram of an example that expression contains the clothes of Stretchable composite fabric of the present invention.
Fig. 6 is the front key diagram of another example that expression contains the clothes of Stretchable composite fabric of the present invention.
Fig. 7 is the front key diagram of another example that expression contains the clothes of Stretchable composite fabric of the present invention.
Fig. 8 is the back side key diagram of another example that expression contains the clothes of Stretchable composite fabric of the present invention.
Fig. 9 is the front key diagram of another example that expression contains the clothes of Stretchable composite fabric of the present invention.
Figure 10 is the woven fabric organization chart of an example with Stretchable composite fabric of the present invention of two layers of woven fabric tissue of latitude.
Figure 11 is the woven fabric organization chart of another example of the Stretchable composite fabric with two layers of woven fabric tissue of parallel of the present invention.
The specific embodiment
Stretchable composite fabric of the present invention is to contain in suction from least three kinds of yarns (1) different mutually aspect extensibility and/or the elasticity, the woven or knitted fabric of (2) and (3).
Yarn (1) be comprise have than higher suction from percentage elongation and flexible fiber, have 200% or the height suction of above elongation at break from the extensibility elastomeric yarn,
Yarn (2) is to comprise having lower suction from percentage elongation, but the low suction that does not show flexible fiber basically is from the extensibility inelastic yarn,
Yarn (3) be comprise have lower suction from percentage elongation and flexible fiber, have 30% or the low suction of above elongation at break from the extensibility elastomeric yarn.
Yarn (1), (2) and the suction of (3) measure by following determination experiment from extensibility: Yi Bian apply the load of 0.88mN/dtex, on one side with above-mentioned yarn (1), (2) and (3) be wound up into respectively on the reeled yarn frame of frame girth 1.125m, the formation winding number is 10 reeled yarn, this reeled yarn is taken off from above-mentioned reeled yarn frame, 20 ℃ of temperature, placed 24 hours in the air ambient of relative humidity 65%, carry out the state adjustment, this dry reeled yarn is applied the load of 0.0088mN/dtex, measure the long (Ld of its dry yarn, mm), this reeled yarn was soaked 5 minutes in the water of 20 ℃ of water temperatures, from water, mention then, this moistening reeled yarn is applied the load of 0.0088mN/dtex, measure the long (Lw of its moistening yarn, mm), by following formula calculate each yarn from percentage elongation
The suction of yarn is from percentage elongation (%)=(Lw-Ld)/(Ld) * 100
Above-mentioned yarn (1) have 5% or above suction from percentage elongation, above-mentioned yarn (2) and (3) have and are lower than 5% suction from percentage elongation.
In the Stretchable composite fabric of the present invention, form suction from extensibility elastic composite yarn (A) by above-mentioned yarn (1) and yarn (2), above-mentioned yarn (3) is contained in the non-suction that do not show basically from extensibility in extensibility elastomeric yarn (B),
Make above-mentioned woven or knitted fabric in atmosphere, carry out dimensionally stable with 20 ℃ temperature and 65% relative humidity, from the woven or knitted fabric that has carried out this dimensionally stable, get the experiment slice of above-mentioned complex yarn (A) with 30cm length, measure above-mentioned yarn (1) and average length L 1 and the L2 of yarn (2) under 0.0088mN/dtex load in this experiment slice, at this moment, the value of L1/L2 be necessary for 0.9 or below.
Composite fabric of the present invention with above-mentioned formation shows following characteristic: showing elasticity at least one direction of broadwise and warp-wise or at least one direction of row direction and wale direction, and by water when moistening, at least yarn (1) suction and elongation certainly, the shape outward appearance of fabric is changed, when it is dry, at least suction is from yarn (1) suction and the self-constriction of elongation, and the shape outward appearance of fabric is restored.
Yarn used in the present invention (1) constitutes from extensibility and flexible fiber by having high suction, the suction of yarn (1) from percentage elongation be 5% or more than, preferred 6% or more than, more preferably 8-30%.The fiber that forms described yarn (1) for example has: contain the polyether ester fibre of polyester elastomer, described polyester elastomer is a hard segment with the polybutylene terephthalate (PBT), is soft chain segment with the polyethylene glycol; Polyester hybrid resin fiber, it is that mixing contains at least a resin of polyacrylic acid slaine, polyacrylic acid and copolymer thereof, polymethylacrylic acid and copolymer thereof, polyvinyl alcohol and copolymer thereof, polyacrylamide and copolymer thereof, polyoxyethylene based polymer etc. and obtains in mylar; And the polyester fiber that obtains of 5-sulfoisophthalic acid composition copolymerization etc.Wherein, comprise and contain polybutylene terephthalate (PBT) and not only have suction from extensibility as the polyether ester fibre of the polyester elastomer of soft chain segment as hard segment, polyethylene glycol, also have the high elasticity of elongation, therefore preferably utilize this elasticity to make the structure that constitutes the elastic composite fiber.
The polybutylene terephthalate (PBT) that constitutes the hard segment of above-mentioned polyester elastomer preferably contains 70 moles of % or above mutual-phenenyl two acid bromide two alcohol ester unit at least.More preferably mutual-phenenyl two acid bromide two alcohol ester's containing ratio be 80 moles of % or more than, more preferably 90 moles of % or more than.In the sour composition of mutual-phenenyl two acid bromide two alcohol ester's structure, terephthalic acid (TPA) is a main component, also can a spot of other dicarboxylic acids composition of copolymerization, and diol component is with 1, the 4-butanediol is a main component, also can add other diol component as copolymer composition.
Above-mentioned dicarboxylic acids beyond the terephthalic acid (TPA) for example has naphthalenedicarboxylic acid, isophthalic acid, diphenyl dicarboxylic acid, biphenoxyl ethane dicarboxylic acids, beta-hydroxy ethoxybenzoic acid, P-hydroxybenzoic acid, adipic acid, decanedioic acid, 1, the dicarboxylic acids composition of aromatics such as 4-cyclohexane dicarboxylic acid, aliphatic series.In not damaging the scope that realizes the object of the invention basically, can use trifunctional such as trimellitic acid, Pyromellitic Acid or above polybasic carboxylic acid as copolymer composition.
Remove 1, the above-mentioned diol component beyond the 4-butanediol for example has: trimethylene glycol, ethylene glycol, cyclohexane-1,4-dimethanol, neopentyl glycol etc. are aliphatic, alicyclic, the diol compound of aromatics.In not damaging the scope that realizes the object of the invention basically, can also use trifunctional such as glycerine, trimethylolpropane, pentaerythrite or above polyalcohol as copolymer composition.
On the other hand, the polyethylene glycol of formation polyester elastomer soft chain segment preferably contains 70 moles of % or above oxygen ethylene glycol unit at least.The content of oxygen ethylene glycol more preferably 80 moles of % or more than, further preferred 90 moles of % or more than.In not damaging the scope that realizes the object of the invention basically, all right copolymerization propylene glycol, 1 beyond the deoxygenation ethylene glycol, 4-butanediol, glycerine etc.
The number-average molecular weight of above-mentioned polyethylene glycol preferably in the scope of 400-8000, wherein preferred especially 1000-6000.
Above-mentioned polyester elastomer for example can be prepared as follows: in the presence of ester exchange catalyst, make and contain dimethyl terephthalate (DMT), 1, the raw material of 4-butanediol and polyethylene glycol carries out ester exchange reaction, form two (ω-hydroxybutyl) terephthalate and/or oligomer, in the presence of polycondensation catalyst and stabilizing agent, carry out the melt polycondensation under the high temperature decompression then.
With weight is benchmark, and the ratio of hard segment/soft chain segment is preferably 30/70-70/30.
For example M-phthalic acid 5 sodium sulfonates are as copolymer composition if contain metal organic sulfonate in the above-mentioned polyester elastomer, and oneself extends the fiber of performance then can further to obtain having excellent suction.
Polyether ester fibre can be prepared as follows: above-mentioned polyester elastomer is melt extruded from common melt spinning spinning head, with hauling speed 300-1200m/ minute (preferred 400-980m/ minute) traction, with the 1.0-1.2 of above-mentioned hauling speed doubly the coiling draw ratio of (preferred 1.0-1.1 doubly) reel.
Above-mentioned suction is not particularly limited from the total fiber number, filament number, the long filament number that extend yarn (1), considers from style or productive rate, and preferred total fiber number is 30-300dtex, and filament number is 0.6-100dtex, and the long filament number is in the scope of 1-10 root.
Have from the example of the fiber of extensibility inelastic yarn (2) about constituting the low suction that constitutes complex yarn (A) with above-mentioned yarn (1): natural fabric or cellulose-based chemical fibres such as artificial silk, acetic acid esters such as cotton, fiber crops are the synthetic fiber of the polyester, polyamide, polyacrylonitrile, polypropylene etc. of representative with polyethylene terephthalate, polytrimethylene terephtalate.Wherein, preferably use common polyester fiber.In the described low yarn (2), if filament number is 1.5dtex or following (more preferably 1.0dtex or following, preferred especially 0.1-0.8dtex) and the monofilament number be several 30 or above (more preferably 50-300 roots) of monofilament, then the water imbibition of complex yarn (A) improves, therefore complex yarn (A) suction elongation certainly easily, as a result, in the composite fabric of the present invention, easily because of moistening outward appearance, the shape performance variation that makes fabric that absorb water.
In the complex yarn (A), the yarn (1) and (2) that form this yarn must have following yarn long poor (the yarn foot is poor).Promptly, as mentioned above, woven or the knitted fabric that will contain complex yarn (A) carries out dimensionally stable in the atmosphere with 20 ℃ of temperature and 65% relative humidity, wherein said complex yarn (A) is formed by above-mentioned yarn (1) and yarn (2), from the woven or knitted fabric that has carried out this dimensionally stable, get the experiment slice of above-mentioned complex yarn (A) with 30cm length, measure above-mentioned yarn (1) and average length L 1 and the L2 of yarn (2) under 0.0088mN/dtex load in this experiment slice, at this moment, the value of L1/L2 be necessary for 0.9 or below.
The value of preferred L1/L2 is 0.9-0.2, more preferably 0.8-0.3.When the L1/L2 value is bigger than 0.9, the elasticity deficiency of gained complex yarn (A).But the L1/L2 value is littler than 0.3, and then gained complex yarn (A) is when suction is moistening, and shape, the appearance change of yarn are very few.
The preparation method of complex yarn (A) is not particularly limited, for example (drawing-off) stretches with required stretching ratio (for example 1.1-5.0 doubly) with yarn (1), around yarn (1), yarn (2) is configured to core shell structure, make yarn (1) form core, yarn (2) forms shell portion, doubling, form the complex yarn of core shell structure, carry out required slight twisting more as required, make yarn (1) elastic shrinkage by the stretching of removing above-mentioned yarn (1) then, the yarn of yarn (2) long (yarn foot) increases than the yarn of yarn (1) is long like this, the fiber of yarn (2) forms the shell portion that the fiber by bending constitutes around yarn (1), the gained complex yarn presents bulky yarn shape outward appearance.Yarn (1) can be a polyfilament yarn, can be the short staple spinning yarn also, is preferably polyfilament yarn.Yarn (2) can be a polyfilament yarn, also can be the short staple spinning yarn, preferred polyfilament yarn, and this polyfilament yarn (2) can carry out bulk processing (for example can carry out false twisting).
The yarn (1) in the complex yarn (A) and the thread count of yarn (2) are not particularly limited, and preferred thread count ratio is 1: 1, and this yarn (1) is preferably 10 with the weight ratio of yarn (2): 90-70: 30, more select 15: 85-50: 50.
When making complex yarn (A), the stretching ratio of the yarn in the said method (1) be preferably 1.1 times or more than, further preferred 1.2-5 is doubly.
The yarn (1) of elongation and the doubling step of yarn (2) can be the doubling methods, also can be interweave jet doubling method, the jet doubling method of Taslan, coat the curl any means of doubling method of doubling method, composit false twisting, the preferred employing in the yarn (1) of the elongation coating doubling method of winding yarn (2) on every side can obtain having the composite yarn of tangible core shell structure like this.
Yarn used in the present invention (B) contains requisite composition---and low suction is from extensibility elastomeric yarn (3).Yarn (3) contains and has low suction from extensibility and flexible fiber, has 30% or above elongation at break.
In the composite fabric of the present invention, in the yarn (B) employed yarn (3) be contain have 5% or following low suction from extensibility and flexible fiber and have 30% or the yarn of above elongation at break.Constitute described low suction and can be selected from flexible polyether ester fiber, elastic polyurethane fiber, elasticity parallel type conjugation polyester fiber, elasticity polytrimethylene terephtalate fiber, false twist crimping finished yarn from the fiber of extensibility elastomeric yarn (3).Above-mentioned flexible polyether ester fiber preferably use contain polybutylene terephthalate (PBT) as hard segment, contain polyoxy butylidene glycol as the polyester elastomer fiber of soft chain segment (trade mark: レ Network セ, Supreme Being people's Off ァ ィ バ (strain) make).This elastomeric fibre can use polytetramethylene glycol to replace polyethylene glycol in the manufacture method of the above-mentioned polyether ester fibre that preparation is used as yarn (1), with this composition as the formation soft chain segment.In order to make the woven or knitted fabric of target have low-permeable and/or high hydrophobicity, the filament fiber number of preferred yarn (3) is 1.5dtex or following, 1.0dtex or following more preferably, 0.1-0.8dtex more preferably, the fiber of every yarns (long filament) number be preferably 30 or more than, more preferably 50-300 root.
Yarn (B) can only be made of yarn (3), or contain yarn (3) and with the complex yarn of the different types of yarn of yarn (3) (4).When yarn (B) is complex yarn, yarn (4) can be contain have 5% or following suction from percentage elongation and show the yarn of stiff low suction from the extensibility non-elastic fiber, in this case, the elongation at break of preferred yarn (4) be 30% or more than.
In the time of will being used for yarn (3) and yarn (4) with the same experiment of the experimental technique of above-mentioned complex yarn (A), the ratio L3/L4 of the average length L 3 of the yarn (3) in the complex yarn (B) and the average length L 4 of yarn (4) be preferably 0.9 or below, 0.9-0.2 more preferably, further preferred 0.8-0.5.Use the low suction of yarn (4) use same with the fiber that constitutes yarn (2) as yarn (B), can use one or more of inelastic polyester fiber, polyamide fiber, polyacrylic fiber, polypropylene fibre, cellulose-based chemical fibre, natural fabric etc. from the extensibility inelastic yarn.
Yarn (3) in the complex yarn (B) and yarn (4) are carried out doubling, make gained complex yarn (B) performance elasticity, for example can adopt the same method of doubling method of yarn (1) and yarn (2) in the manufacturing with complex yarn (A), for example the state configuration with yarn (3) elongation becomes core, with yarn (4) doubling, around it, form shell portion, implement required yarn and handle (the jet doubling method that for example interweaves, coating doubling method, composit false twisting method etc.), the yarn (3) of elongation is replied and contraction.By this doubling method, yarn (3) is disposed at core, and the fiber of yarn (4) is in outside curve, the bulk elastomeric yarn (B) that obtains expanding.
The total fiber number of complex yarn (B) is not particularly limited, and can suitably set according to the tissue of required fabric, for example is set at 30-300dtex.Be not particularly limited for the filament fiber number of the fiber that constitutes yarn (4) and fiber (long filament) number of every yarns, in order to make the woven or knitted fabric of target have low air permeability and/or high hydrophobicity, the filament fiber number of yarn (4) is preferably 1.5dtex or following, 1.0dtex or following more preferably, further preferred 0.1-0.8dtex, the fiber of every yarns (long filament) number be preferably 30 or more than, further preferred 50-300 root.The cross sectional shape of the fiber of formation yarn (3) and yarn (4) can have circular cross-section or profiled-cross-section without limits.
Stretchable composite fabric of the present invention can have the woven fabric tissue, also can have knitted fabric tissue.
Stretchable composite fabric of the present invention has woven fabric when organizing, in in-house warp thread group of this woven fabric and/or the weft yarn group, above-mentioned suction can be wall scroll or many (preferred 2-800 bar, more preferably 5-500 bar, further preferred 10-100 bar) alternate configurations from extensibility elastomeric yarn (A) and above-mentioned non-suction from extensibility elastomeric yarn (B).
When Stretchable composite fabric of the present invention has knitted fabric tissue, in row yarn group in this knitted fabric tissue and/or the wale yarn group, above-mentioned suction can be wall scroll or many alternate configurations from extensibility elastomeric yarn (A) and above-mentioned non-suction from extensibility elastomeric yarn (B).
In the Stretchable composite fabric of the present invention, complex yarn (A) and yarn (B) alternate configurations can be the rule also can be irregular, but preferably the rule.
In the Stretchable composite fabric of the present invention, it has woven fabric when organizing, complex yarn (A) and yarn (B) only constitute the side's yarn group in in-house warp thread group of woven fabric and the weft yarn group, and other yarn group is made of one or more yarns different with yarn (B) with complex yarn (A).
Equally, in Stretchable composite fabric of the present invention, when it has knitted fabric tissue, complex yarn (A) and yarn (B) only constitute row yarn group in the knitted fabric tissue and the side's yarn group in the wale yarn group, and other yarn group is made of the yarn of one or more different with yarn (B) with complex yarn (A).
The yarn different with yarn (B) with above-mentioned complex yarn (A) is preferably selected to contain many filamentary yarns with flattened and contain has 1.5dtex or following fine-titred many filamentary yarns.These yarns not of the same race can be easily crooked.The major diameter of the flat cross section of described bendability fiber/minor axis ratio be preferably 1.2 or more than, more preferably 2-5.As mentioned above, the fiber number of fine denier fiber is preferably as above-mentioned 1.5dtex or following, more preferably 0.1-1.3dtex.As long as constituting not, the fiber of yarn of the same race satisfies above-mentioned condition, be not particularly limited, natural fabric or cellulose-based chemical fibres such as artificial silk, acetic acid esters such as cotton, fiber crops can be used, synthetic fiber by the polyester of polyethylene terephthalate, polytrimethylene terephtalate representative, polyamide, polyacrylonitrile, polypropylene etc. etc. can also be used.
Fig. 1 is the stravismus key diagram of an example when drying regime of expression Stretchable composite fabric of the present invention, and Fig. 2 is the stravismus key diagram of fabric when the water moisture state of Fig. 1.Among Fig. 1 and Fig. 2, the weft yarn in the composite fabric 1 comprises the zone 2 of containing many complex yarns (A) and the zone 3 of containing plurality of yarns (B), and zone 2 and zone 3 alternately form regularly.Among Fig. 1 that warp thread regional 2 and regional 3 is formed by identical non-suction spontaneously extensible yarn line, the thickness in the zone 2 in the fabric 1 of drying regime is d1.
The composite fabric 1 of Fig. 1 is by water when moistening, as shown in Figure 2, in the zone 3 that forms as weft yarn with yarn (B), is non-suction from extensibility through weft yarn, and therefore the size and dimension (outward appearance) in zone 3 does not change basically.But in containing the zone 2 that complex yarn (A) forms as weft yarn, moistening by water, yarn (1) suction in the complex yarn (A), from elongation, be case of bending or around yarn (1), be wound in helical form with the yarn (2) of yarn (1) doubling, therefore yarn (2) is gone up elongation from the yarn (1) that extends along the length direction of complex yarn (A) is apparent with absorbing water, so the increase of the size of the weft direction in zone 2, is bent to form concaveconvex shape between zone 2.At this moment, the difference in height of the highest part 4 in zone 2 and lowermost portion 5 (thickness in zone 2) d2 increases than d1.The concaveconvex shape in the zone 2 when water shown in Figure 2 is moistening disappears because of dry, becomes flat condition shown in Figure 1.
In the Stretchable composite fabric of the present invention, woven fabric tissue, the number of plies are not particularly limited.For example can adopt woven tissues such as plain weave, twill, satin weave, but be not limited to these.The number of plies can be individual layer also can be 2 layers or more than.
In the Stretchable composite fabric of the present invention, the yarn long (A) of the complex yarn (A) in this fabric in the atmosphere of 20 ℃ of temperature, humidity 65%RH is represented with (LA), the yarn of yarn (B) is long with (LB) expression, and then the long difference of the yarn of LA and LB is the smaller the better, and preferred LA/LB is in the scope of 0.9-1.1.LA/LB is littler or bigger than 1.1 than 0.9, do not perspire, when dry, the fabric face performance is concavo-convex, outward appearance suffers damage.
Here, the long mensuration of yarn is undertaken by following method.At first, the sample of fabric was placed 24 hours in the atmosphere of 20 ℃ of temperature, relative humidity 65%RH, then by the small pieces (n=5) that intercept 30cm * 30cm on this sample.Then from each small pieces, respectively get a complex yarn (A) and yarn (B), measure the long LA of yarn (mm), the non-long LB of yarn (mm) of elastic composite yarns (A) from elasticity of elongation yarn (B).At this moment, the load that applies 0.0088mN/dtex (1mg/de) is measured.With (mean value of the long LA of yarn)/(mean value of the long LB of yarn) as LA/LB.Here, complex yarn that takes out from small pieces (A) and yarn (B) must be the yarns that extends along equidirectional sample.For example when the warp thread (weft yarn) of woven fabric took out complex yarn (A), another yarn (B) also must take out from warp thread (weft yarn).
As mentioned above, about making the method for LA/LB in the scope of 0.9-1.1, for example yarn (B) for example can use following method for containing non-suction when the composite yarn (B) of extensibility inelastic yarn (4).That is, during by elastomeric yarn (3) and inelastic yarn (4) preparation complex yarn (B), the draw ratio in the preparation process of elastomeric yarn (3) is influential to the boiling water shrinkage of gained complex yarn (B).Therefore, regulate the draw ratio in elastomeric yarn (3) preparation process, ratio α/β of the boiling water shrinkage α that makes complex yarn (A) and the boiling water shrinkage β of the complex yarn (B) that contains yarn (3) is in the scope of 0.9-1.1.Like this, after the boiling water treating such as composite fabric process dyeing processing, complex yarn (A) and complex yarn (B) all twisting of equal extent ground shrink (Twist Shou Shrink), both yarn length poor (Fine is poor for the yarn foot) diminishes.If because dyeing processing waits the complex yarn (A) and the long difference of yarn (B) that make in the composite fabric to increase, the fabric width that then can make composite fabric on one side at 1.4 times with interior elongation, implement the twisting typing on one side and handle, complex yarn (A) and average length (B) in the composite fabric of handling through this treatment fluid can be adjusted in the scope of 0.9-1.1 than LA/LB like this.
Humid heat treatment to 60 ℃ of fabric enforcements of the present invention or above (more preferably 65-98 ℃), the processing of then dyeing as required, preferred one side applies 1.4 times of tentering multiples with interior (more preferably 1.0-1.3 doubly) to the fabric amplitude of these damp and hot product (implement to dye to add and process semi-finished product for dyeing man-hour), carry out HEAT SETTING on one side, if carry out HEAT SETTING with tentering multiple than 1.4 times big, then the suction of the contained yarn (1) of complex yarn (A) reduces from percentage elongation, can't obtain enough concavo-convex variations that moistening-drying causes.
In the Stretchable composite fabric of the present invention, when moistening, complex yarn (A) suction is from elongation, and yarn is long elongated, and its adjacent non-yarn from elasticity of elongation yarn (B) is long constant.As a result, have only the complex yarn (A) of elongation to form crooked form in fabric, the fabric face performance is concavo-convex.Behind this fabric drying, the long invertibity of the yarn of complex yarn (A) ground restores, and shortens the concavo-convex disappearance of fabric face.
When moistening, long poor as the yarn of above-mentioned complex yarn (A) and yarn (B), the yarn of the complex yarn (A) when moistening is long for (LAw), be (LBw) so that the yarn of yarn (B) is long, and ratio Law/LBw is preferably 1.05 or above (preferably 1.1-1.3).Law/LBw is littler than 1.05 when moistening, when then perspiring the concavo-convex performance of fabric face insufficient, can not obtain the effect that good inhibition adheres to.The concavo-convex rate of change preferred 10% of this moment or more than, more preferably 100% or more than, further preferred 200% above～1000% or below.
Stretchable composite fabric of the present invention is owing to the concavo-convex variation of and the dry fabric face that produce moistening by water can be measured by following concavo-convex rate of change.
Get a plurality of samples of size 5cm * 2cm from above-mentioned composite fabric, they were placed 24 hours in the air of 20 ℃ of temperature, relative humidity 65%, make a plurality of drying samples, get a plurality of samples of size 5cm * 2cm in addition again from above-mentioned composite fabric, they were soaked 5 minutes in the water of 20 ℃ of temperature, from water, mention, be clipped between a pair of filter paper, with 490N/m
2Pressure pressing 1 minute, remove and be present in interfibrous water in the sample, make a plurality of moistening samples, measure the average maximum ga(u)ge Dw of above-mentioned moistening sample and the average maximum ga(u)ge Dd of above-mentioned drying sample, calculate concavo-convex rate of change by following formula.
Concavo-convex rate of change (%)=[(Dw-Dd)/(Dd)] * 100
The average maximum ga(u)ge Dd of drying sample and moistening sample and the following calculating of Dw: (キ one ェ Application ス company makes, model: the maximum ga(u)ge of LC-2400) measuring each sample with superelevation precise laser displacement meter with drying sample and moistening sample.5 (n=5) samples are repeated this operation, calculate average maximum ga(u)ge Dw, Dd.
Stretchable composite fabric of the present invention is because of perspire waiting when moistening, because that the suction of yarn (1) from elongation, produces on the fabric is concavo-convex, the contact area of fabric and skin reduces, and makes the moistening sticky feeling minimizing that produces because of fabric, and can promote the drying of fabric.
Complex yarn in the Stretchable composite fabric of the present invention (A) and yarn (B) on the configuration direction, its elastic extension be preferably 6% or more than, more preferably 8-30%.
Can implement hydrophobic processing, fluffing processing to Stretchable composite fabric of the present invention, ultraviolet screener is handled or carry out various processing by functional agents such as antiseptic, deodorant, insect-proof agent, light-accumulating agent, reflex reflection agent, anion propellants.
In the Stretchable composite fabric of the present invention, above-mentioned composite fabric has 2 layers or above multilayer tissue, at least the one deck that can be above-mentioned multilayer tissue contains above-mentioned complex yarn (A) with the 20 quality % or the above containing ratio of its gross mass, and one deck at least of above-mentioned multilayer tissue contains above-mentioned yarn (B) with the 20 quality % or the above containing ratio of its gross mass.
In the double-decker composite fabric of the present invention, be not particularly limited for double-deck woven or knitting form.For example can adopt the double-decker woven fabric that is called as through backed weave, filling-backed weave, dual tissue, re-organized etc. in the woven fabric usually, preferably adopt the combination of plain weave-plain weave, twill-weave-plain weave, satin weave-plain weave, satin weave-twill-weave etc.Knitted fabric can adopt 2 guides of use to comb the Ha one Off tissue of joint or 3 guide comb joints, Ha one Off ベ one ス tissue, satin weave etc.Can also be with the woven of 2 individual layers or knitted fabric heat bonding, and sew up and get, can not damage soft style but be woven or knitted into the woven or knitted fabric of above-mentioned double-deck double-decker, thereby preferably.
In the double-decker composite fabric of the present invention, woven or the knitted fabric of double-decker is made of complex yarn (A) and yarn (B), wherein one deck mainly disposes complex yarn (A), the main configuration of another layer yarn (B), the layer of main configuration complex yarn (A) is used for skin one side, the layer of main configuration yarn (B) is used to contact ambient atmos one side, and like this, the performance when perspiring of the woven or knitted surfaces of skin one side is concavo-convex.And on the woven or knitted surfaces of contact ambient atmos one side, even rain can not occur yet concavo-convex, harmless outward appearance.Like this, the method that one deck mainly disposes complex yarn (A), another layer main configuration yarn (B) for example can adopt following method: adopt the organization chart filling-backed weave shown in Figure 10 that describes in detail later, at this moment, as weft yarn, with each alternate configurations of above-mentioned complex yarn (A) and yarn (B), as warp thread, dispose non-suction from extending yarn, weave.The non-suction spontaneously extensible yarn line that uses as warp thread this moment uses the filament fiber number to be 1.5dtex or following (more preferably 1.3dtex or following, preferred especially 0.1-1.2dtex), filament (long filament) number of every yarns is the yarn of 30 or above (preferably 50-300 root), then can obtain having the composite fabric of high hydrophobicity.
Make the layer of above-mentioned main configuration non-suction spontaneously extensible yarn line (B) have water-repelling agent, then can prevent the infiltration of rainwater.Water-repelling agent can use any water-repelling agent that uses in the fibre in the past.For example, can use fluororesin is that water-repelling agent, organic siliconresin are water-repelling agent.Can only use a kind of water-repelling agent this moment, also 2 kinds or above water-repelling agent can be used in combination.When giving water-repelling agent, can be used in combination crosslinking agent, for example melamine is crosslinking agent or isocyanate-based crosslinking agent etc., and water-repelling agent is attached on the woven or knitted fabric of double-decker more firmly.
Is that the method that surface that main component forms has a water-repelling agent is not particularly limited for making in the above-mentioned double-decker composite fabric with above-mentioned non-suction from extensibility elastomeric yarn (B), method that for example can adopt flat screen print process, ROTARY SCREAM PRINTING method, roller print process, gravure roller method, touch rolling method, be undertaken by the foaming processing machine etc.
And can possess water absorbing agent to the layer that mainly disposes complex yarn (A).Water absorbing agent so long as the water absorbing agent that has a compatibility with complex yarn (A) get final product.The preferred especially water absorbent polymer that has compatibility with polyester fiber that uses.For example have: poly alkylene glycol (polyethylene glycol, polypropylene glycol etc.), make terephthalic acid (TPA) and/or M-phthalic acid and low-grade alkylidene glycol (ethylene glycol etc.) carry out block copolymerization and block copolymer of obtaining etc.At this moment, can only use a kind of water absorbing agent, perhaps 2 kinds or above water absorbing agent are used in combination.The method of giving water absorbing agent is not particularly limited, method that for example can adopt flat screen print process, ROTARY SCREAM PRINTING method, roller print process, gravure roller method, touch rolling method, be undertaken by the foaming processing machine etc.
When giving double-decker composite fabric of the present invention with water-repelling agent and water absorbing agent, its order is unqualified, can be water-repelling agent is given with non-from extending the layer that yarn (B) be a main composition, then water absorbing agent is given with complex yarn (A) be main composition layer; Or with water absorbing agent give with complex yarn (A) be main composition the layer, then water-repelling agent is given with non-from extend yarn (B) be main composition layer.Usually the former method can prevent effectively that water absorbing agent is penetrated into hydrophobic surface, is preferable methods in the practical application therefore.
In the double-decker composite fabric of the present invention, infiltrate in the fabric for preventing rainwater, preferred fabric has high density.For example when double-decker composite fabric of the present invention is woven fabric, the coverage coefficient CF of woven fabric preferably 2500 or above scope in, more preferably 3000-4500.Coverage coefficient CF is defined by following formula.
CF＝(DWp/1.1)
1/2×MWp+(DWf/1.1)
1/2×MWf
[DWp represents warp thread total fiber number (dtex), MWp represent warp thread knit density (root/3.79cm), DWf represents weft yarn total fiber number (dtex), MWf represent weft yarn knit density (root/3.79cm)].
The approximate range of above-mentioned density is: the preferred 5cc/cm of gas permeability when dry
2S or following, more preferably 0.1-3.0cc/cm
2The density of s.The preferred water pressure resistance of density is 100mm H
2O or above, more preferably 120-600mm H
2O.
Double-decker composite fabric of the present invention for example can easily prepare by following method.
At first, make yarn (2) overfeeding (surplus supply) on one side, on one side with yarn (1) doubling, perhaps the yarn (1) that contains the polyether ester elastic yarn is applied drawing-off on one side, on one side with yarn (2) doubling, with they interweave jet processing, coat processing, the composit false twisting processing etc. of curling, obtain complex yarn (A).Wherein, in order to form clear and definite core shell structure, the preferred coating processed.The draw ratio of above-mentioned drawing-off be preferably 1.1 times or more than, more preferably 1.2-5.0 doubly, i.e. 120-500%.
Then, use independent complex yarn (A) or complex yarn (A) and non-from extending yarn (B), suitably select above-mentioned woven or knitting technology weave, be woven or knitted into double-deck woven or knitted fabric.Here, complex yarn (A) has elasticity but is non-from extending yarn (B) when not having elasticity, and the complex yarn (A) that stretches by described pulling force when woven or knitting is in woven or knitting back elastic recovery, and therefore woven or knitted fabric presents the concavo-convex of curling shape.Therefore, in order to obtain to show more smooth woven or knitted fabric, non-extending yarn (B) can select independent yarn of rubber-like (3) or rubber-like complex yarn certainly.Yarn about this moment is arranged, can adopt following method: for example adopt filling-backed weave, weft yarn be with above-mentioned complex yarn (A) with non-from extend yarn (B) wall scroll alternately, wall scroll to many alternately, many to configurations such as wall scroll replace, to be that configuration is non-carry out woven method from extending yarn to warp thread; Perhaps adopt filling-backed weave, warp thread be with above-mentioned complex yarn (A) with non-from extend yarn (B) wall scroll alternately, wall scroll to many alternately, many to configurations such as wall scroll replace, to be that configuration is non-carry out woven method from extending yarn to weft yarn; Perhaps with above-mentioned complex yarn (A) with non-from extend yarn (B) wall scroll alternately, wall scroll to many alternately, many to wall scroll replace, many configuration such as replace to many, be knitted into the method for knitted fabric etc. with double-deck knitting technology weave.
Preferably double-decker composite fabric of the present invention is implemented aforesaid hydrophobic processing or suction processing.In addition, hydrophobic processing or suction first being processed and/or can also implement dyeing and finishing processing afterwards.Also can fluff processing, ultraviolet screener or give the various processing of functions such as antiseptic, deodorant, insect-proof agent, light-accumulating agent, reflex reflection agent, anion propellant.
In the double-decker composite fabric of the present invention, the complex yarn (A) that is made of suction spontaneously extensible yarn line (1) and non-suction spontaneously extensible yarn line (2) is contained in one deck at least, therefore, and when moistening, complex yarn (A) suction shows concavo-convex from elongation in woven or knitted surfaces.And when dry, the long invertibity of the yarn of elastic composite yarns (A) ground restores and shortens concavo-convex disappearance.
Shown in Figure 3 is that composite fabric 11 is the cross-sectional illustration figure of example when drying regime of double-decker woven fabric, wherein said double-decker woven fabric is made of the upper and lower, complex yarn (A) 12 from extensibility inelastic yarn (2) forms from extensibility elastomeric yarn (1) and low suction by containing suction on the upper strata, and lower floor forms by containing the yarn (B) 13 of low suction from extensibility elastomeric yarn (3).This moment, the thickness of fabric was d1.
Fig. 4 be the double-decker woven fabric of Fig. 3 by water the cross-sectional illustration figure when moistening, moistening by water, yarn (1) suction in the complex yarn (A) 12 is from elongation, its length increases, therefore the case of bending or the spiral status that are wound in yarn (1) yarn (2) on every side also are stretched, and as shown in Figure 4, the length of complex yarn (A) 12 increases, the concavo-convex increase of double-decker fabric face, its thickness d 2 becomes big than d1.If the fabric drying of moisture state shown in Figure 4 then reverts to the state of Fig. 3, the concavo-convex state on its surface reduces.
Follow the concavo-convex degree change on the composite fabric surface of above-mentioned drying-moistening-dry to represent by concavo-convex rate of change as defined above.
The concavo-convex rate of change of preferred double-decker composite fabric of the present invention be 10% or more than, more preferably 20-50%.This concavo-convex rate of change is lower than 10%, and then the clothes of being made by gained double-decker composite fabric attach skin because of perspiration when moistening, and discomfort is obvious, is not easy drying.
Composite fabric of the present invention carries out air permeability when measuring by JISL 1096-1998,6.27, A method (Fu Leizefa) in the air of 20 ℃ of temperature, relative humidity 65%, preferably show 50ml/cm
2S or following air permeability, more preferably 5-40ml/cm
2S.
In the composite fabric of the present invention, in the air of 20 ℃ of temperature, relative humidity 65% by JIS L 1092-1998,4. (1.1) (low hydraulic pressure hydrostatic platen press) carried out water pressure resistance when measuring, and preferably shows 100mm H
2O or above water pressure resistance, more preferably 120-600mmH
2O.
The present invention can provide interior decoration goods such as clothing item, bedding, curtain such as the men's clothing that uses above-mentioned double-decker composite fabric to form, women's dress, sportswear, and the vehicle seat pad wait for bus in the fibre of goods.Here, can all use above-mentioned woven or knitted fabric to make fibre, also can for example partly be used for the armpit of clothes or chest etc. and make.Use described fibre, then can prevent the infiltration of rainwater, moistening because of what perspire etc. on the other hand, make to reduce that therefore can suppress to adhere to, comfortableness improves with the contact skin area that uses this fibre place.
Dress materials of the present invention contain the Stretchable composite fabric of the invention described above, are gone up the performance concaveconvex shape by at least one surface, the moistening back of water.
Clothes of the present invention are to use the dress materials of the invention described above to form, can be being formed by dress materials of the present invention all of clothes, also can be that at least one part that is selected from armpit, sidepiece, chest, back and shoulder of clothes is formed by dress materials of the present invention.Under the latter's the situation, form by dress materials of the present invention with the health corresponding clothes part in many positions of perspiring, other parts can by outside the dress materials of the present invention, formed by the moistening material that also can not form concaveconvex shape of water on the surface.The left and right sides armpit 21 of clothes for example shown in Figure 5, shown in Figure 6 about a place or the above Stretchable composite fabric of sleeve bottom 22 and side, left and right sides portion 23, chest central part 24 shown in Figure 7, back central part shown in Figure 8 and left and right sides shoulder 26 shown in Figure 9 by the invention described above form.The gross area of the above-mentioned part that is formed by composite fabric of the present invention is preferably 500-10000cm
2, the ratio that this gross area accounts for the clothes gross area preferably in the 5-70% scope, 10-60% more preferably.This area ratio is lower than 5%, and when then clothes waited by fractional wettability because of perspiring, the concave-convex of this moistening part became effect very few to the influential effect of clothes integral body, and this area surpasses 70%, and when then moistening, the change in size of clothes integral body is excessive.
Embodiment
Further specify the present invention by embodiment.But, following embodiment not delimit the scope of the invention.Carry out following mensuration among the following embodiment.
(1) yarn in the woven or knitted fabric is when drying and the length when moistening (yarn is long)
Measure according to preceding method.
(2) suction of yarn is from the mensuration of percentage elongation
Measure according to preceding method.
(3) boiling water shrinkage of yarn
Measure according to JIS L 1013-1998,7.15 method.It is 3 that the determination test sheet is counted n.
(4) woven or knitted fabric is when drying and the mensuration of air permeability when moistening and air permeability rate of change
To knit or the sample of knitted fabric was placed 24 hours in the air of 20 ℃ of temperature, relative humidity 65% for test-run a machine, make a plurality of (n=5) drying sample, the sample of the above-mentioned woven or knitted fabric that will prepare in addition again soaked 5 minutes in the water of 20 ℃ of temperature, it is mentioned from water, be clipped between a pair of filter paper, with 490N/m
2Pressure pressing 1 minute, remove and be present in interfibrous water in the sample, make a plurality of moistening samples, according to JIS L 1096-1998,6.27, A method (Fu Leizefa) above-mentioned drying sample and moistening sample are carried out air permeability mensuration respectively, calculate the average air permeability of drying sample and the average air permeability of moistening sample, calculate the air permeability rate of change by following formula again.
Air permeability rate of change (%)=[(the average air permeability of moistening sample)-(the average air permeability of drying sample)]/(the average air permeability of drying sample) * 100
(5) woven or knitted fabric is when drying and the mensuration of maximum ga(u)ge when moistening and concavo-convex rate of change
Measure according to preceding method.
(6) elongation at break
Measure according to JIS L 1013-1998 percentage elongation experimental method.
(7) mensuration of coverage coefficient (CF)
Calculate by following formula.
CF＝(DWp/1.1)
1/2×MWp+(DWf/1.1)
1/2×MWf
DWp represents the warp thread total fiber number (dtex) for the test weaving thing,
MWp represent warp thread knit density (root/3.79cm),
DWf represents weft yarn total fiber number (dtex),
MWf represents that weft yarn knits density (root/3.79cm).
(8) water pressure resistance
Water pressure resistance is measured according to JIS L 1092 (B) method (the hydrostatic platen press of low hydrostatic(al) process).
(9) hydrophobicity
Hydrophobic deg carries out the mark evaluation according to the metewand of JIS L 1092 spray-on processes.
(10) water imbibition
Water imbibition is according to JIS L 1907 dripping methods, and the water droplet that mensuration drips on test film was represented by minute to the used time of minute surface areflexia.
(11) evaluation of preventing property of attaching skin (adhesion)
Worn respectively for the examination clothes by 3 experimenters, be sitting on the seat quiet 5 minutes in the environment of 35 ℃ of temperature, humidity 50%RH, 5km/ hour certain speed carries out walking movement then, estimates therebetween sense comfortable and easy to wear according to following 3 stages.
Estimate sense comfortable and easy to wear
3 do not adhere to sense, good
2 have the sense of adhesion slightly, but can use
1 adheres to sense by force, bad
Embodiment 1
To contain 49.8 weight portion polybutylene terephthalate (PBT)s as hard segment, as 50.2 parts by weight average molecular weights of soft chain segment be the polyether ester polymer of 4000 polyethylene glycol 230 ℃ of fusions, extruded with spinning head by monofilament with jetting amount 3.05g/ minute.This polymer is stretched with 705m/ minute via 2 godet rollers, (the coiling draw ratio: 1.06) reel, the height suction that obtains yarn count and be the 44dtex/1 long filament was from extensibility elastomeric yarn (1) with 750m/ minute again.This yarn (1) the fiber axis of suction when moistening to suction be 10% from percentage elongation, boiling water shrinkage is 8%, elongation at break is 816%.
Low suction is used from extensibility inelastic yarn (2) and is lower than 1% common polyethylene terephthalate multifilament (56dtex/144 long filament) from percentage elongation when moistening.
Is heart yarn with above-mentioned high suction from extensibility elastomeric yarn (1), is the shell yarn with above-mentioned low suction from extensibility inelastic yarn (2), in the draw ratio 300% (3.0 times) of heart yarn, coat under the condition of several 1000 times/m (S direction), it is implemented to coat processing, carry out doubling, make elastic composite yarns (A).
Use in addition the polyether ester elastomeric yarn (trade mark: レ Network セ, Supreme Being people's Off ァ ィ バ (strain) manufacturing, 44dtex/1 long filament, boiling water shrinkage: 24%, because of the fiber axis of the moistening generation of water to suction be lower than 1% from percentage elongation) as low suction from extensibility elastomeric yarn (3), use common polyethylene terephthalate multifilament yarn line (56dtex/144 long filament) as yarn (4).As heart yarn, as the shell yarn, under the condition of heart yarn draw ratio 30% (1.3 times), the several 1000 times/m of coating (S direction), it is implemented to coat processing with above-mentioned yarn (3), make and hang down suction from extensibility elastic composite yarns (B) with yarn (4).
Above-mentioned complex yarn (A) and above-mentioned complex yarn (B) supplied with as weft yarn weave step.Use polyethylene terephthalate multifilament yarn line (5) (84dtex/30 long filament) as warp thread.The monofilament that forms this yarn has the flattened of flatness 3.2, and in this cross sectional shape, its each side of major axis both sides respectively has three paddy portions (recess) and 4 mountain portions (protuberance).
The weft yarn that contains complex yarn (A) and complex yarn (B) and each 50 alternate picks of the warp thread that contains yarn (5) are weaved the plain cloth of 117/25.4mm of warp count, 107/25.4mm of weft count.
This plain cloth is implemented 95 ℃ * 3 minutes humid heat treatment, and the dyeing of being undertaken 120 ℃ * 45 minutes by DISPERSE DYES in liquid-flow dyeing machine is processed.Fabric after the dyeing is delivered to stenter, its fabric width is stretched to 1.1 times, implement 160 ℃ * 1 minute dry heat treatment.
The gained plain cloth shows elasticity along broadwise, and its weft direction stretch rate is 12%.Complex yarn (A) in this plain cloth weft yarn and the yarn length of complex yarn (B) when drying are 1.03 than LA/LB, are 1.15 when water is moistening, and this tabby concavo-convex rate of change is 496%.
In this plain cloth, yarn (1) is 0.42 with the average length of yarn (2) than L1/L2 in the complex yarn of weft yarn (A), and yarn (3) is 0.79 with the average length of yarn (4) than L3/LB in the complex yarn (B).
When using above-mentioned elasticity plain cloth to make sweater, sweater is perspired because of dress and is showed concaveconvex shape, and the attaching of sweater and skin is suppressed, and wearing feeling is comfortable.
The elasticity plain cloth is made in weave similarly to Example 1, dye processing, heat treatment.But warp thread adopts fine-titred polyester multifilament yarn (84dtex/72 long filament).
In the gained elasticity plain cloth, complex yarn (A) that uses as weft yarn and complex yarn (B) the yarn length when drying is 1.02 than LA/LB, is 1.14 when water is moistening, and this tabby concavo-convex rate of change is 487%.
The middle yarn (1) of complex yarn (A) that the tabby weft yarn of elasticity is contained and the average length of yarn (2) are 0.43 than L1/L2, and yarn (3) is 0.80 with the average length of yarn (4) than L3/L4 in the complex yarn (B).
The tabby weft direction stretch rate of above-mentioned elasticity is 11%.
When using above-mentioned elasticity plain cloth to make sweater, sweater is perspired because of dress and is showed concaveconvex shape, and the attaching of sweater and skin is suppressed, and wearing feeling is comfortable.
Comparative example 1
Plain cloth is made in similarly weave, dye with embodiment processing, heat treatment.But weft yarn only uses complex yarn (A).
In the gained elasticity plain cloth, the weft direction stretch rate is 10%.But moistening this elasticity plain cloth of water then along almost elongation similarly of weft direction, does not show concaveconvex shape (concavo-convex rate of change=0.5%) basically.
Use above-mentioned plain cloth to make sweater.When dress was perspired, the material of sweater did not show concaveconvex shape along weft direction stretch, therefore can not suppress the attaching of sweater and skin, the wearing feeling discomfort.
To contain 49.8 weight portion polybutylene terephthalate (PBT)s as hard segment, as 50.2 parts by weight average molecular weights of soft chain segment be the polyether ester polymer of 4000 polyethylene glycol 230 ℃ of fusions, extruded by the spinning head of regulation with jetting amount 3.05g/ minute.This polymer is stretched with 705m/ minute via 2 godet rollers, (the coiling drawing-off: 1.06) reel, the height suction that obtains the 44dtex/1 long filament was from extensibility elastomeric yarn (1) with 750m/ minute again.This yarn (1) when moistening along fiber axis to be 25% from percentage elongation, elongation at break is 816%.
As low suction spontaneously extensible yarn, prepared false twist crimping finished yarn (56dtex/144 long filament, filament fiber number 0.39dtex), this false twist crimping finished yarn be when moistening from percentage elongation be 1% or the following multifilament that contains common polyethylene terephthalate carry out common false twist crimping processing and obtain.
Above-mentioned yarn (1) and yarn (2) are delivered to the coating doubling winder, with above-mentioned yarn (1) is heart yarn, with yarn (2) is the shell yarn, in the draw ratio 120% (1.2 times) of heart yarn, coat under the condition of several 1000 times/m (S direction) and coat doubling, makes elastic composite yarns (A).
Use in addition the polyether ester elastomeric yarn (trade mark: レ Network セ, the manufacturing of Supreme Being people's Off ァ ィ バ company, 44dtex/1 long filament, boiling water absorptivity: the fiber axis when 24%, moistening to be lower than 1% from percentage elongation, elongation at break: 650%) as low suction from extensibility elastomeric yarn (3), and use polyethylene terephthalate multifilament yarn line (56dtex/144 long filament), filament fiber number: 0.39dtex, the fiber axis when moistening to being lower than 1% from percentage elongation) as low suction from extensibility inelastic yarn yarn (4).As heart yarn, as the shell yarn, deliver to the coating doubling winder with yarn (3), under the condition of heart yarn draw ratio 300% (3.0 times), the several 1000 times/m of coating (S direction), coat doubling, make elastic composite yarns (B) with yarn (4).
In addition the polyethylene terephthalate multifilament is carried out false twist crimping processing, make polyester false twist crimping finished yarn (84dtex/72 long filament, filament fiber number: 1.17dtex), polyester yarn (5) is made and twisted with the fingers to 2 these yarns on one side with 200 times/m (S direction) twisting doubling on one side.
Use above-mentioned and twist with the fingers polyester yarn (5) as warp thread, use above-mentioned complex yarn (A) and (B) as weft yarn, and each 1 alternate configurations of complex yarn (A) and complex yarn (B), by woven tissue shown in Figure 10, weave with 135/3.79cm of warp count, 215/3.79cm of weft count.This fabric is that a face mainly shows complex yarn (1), another side mainly shows the weft backed cloth of complex yarn (2).
Above-mentioned fabrics is implemented 95 ℃ * 3 minutes humid heat treatment, in liquid-flow dyeing machine, carry out 120 ℃ * 45 minutes dyeing by DISPERSE DYES.By the roller print process, show mainly at the fabric after this dyeing that coating contains the hydrophobic treatments aqueous solution that 3.0 weight % fluorine are water-repelling agent (trade mark: ァ サ ヒ ガ one De AG7101, Asahi Glass (strain) are made) on the face of complex yarn (B), dry down at 120 ℃, deliver to stenter, fabric width is stretched to 1.1 times on one side, Yi Bian implement 160 ℃ * 45 seconds dried.
Gained double-decker fabric has following performance.
Gas permeability: 1.40ml/cm
2S
The water pressure resistance of the face of main performance complex yarn (B): 175mm H
2O
The hydrophobic deg of the face of main performance complex yarn (B): 5 grades
The absorption of water of the face of main performance complex yarn (A): 5.5 seconds
Concavo-convex rate of change: 25%
Sense comfortable and easy to wear: 3
Use above-mentioned double-decker fabric to make the motion overcoat and when wearing, the surface that mainly shows complex yarn (B) can prevent the infiltration of rainwater, the face that mainly shows complex yarn (B) attaching sense and airtight sense of clothes and skin when perspiring is few, and wearing feeling is comfortable.
Embodiment 4
Weave similarly to Example 3, dyeing, hydrophobic processing, heat treatment, make the double-decker fabric.But warp thread adopts the doubling yarn, (84dtex/36 long filament, filament fiber number: 2.3dtex) doubling and the twisting of carrying out 200 times/m (S direction) obtain described doubling yarn, and described polyester false twist crimping finished yarn is polyethylene terephthalate multifilament yarn line when moistening (suction be 1% or following from percentage elongation) to be carried out false twist crimping processing obtain with 2 polyester false twist crimping finished yarns.
Gained double-decker fabric has following performance.
Absorption of water without the face of hydrophobic treatments: 6.4 seconds
Concavo-convex rate of change: 22%
Sense comfortable and easy to wear: 3
Gas permeability: 5.5ml/cm
2S
Water pressure resistance through the face of hydrophobic treatments: 80mm H
2O
Make the motion overcoat and when wearing, water proofing property is poorer slightly than embodiment 1 by above-mentioned fabrics, but sense comfortable and easy to wear is good.
Weave similarly to Example 1, dyeing, hydrophobic processing and heat treatment, make the double-decker fabric.But the low suction of using in the complex yarn (A) uses from extensibility inelastic yarn (2) that (suction when moistening is from percentage elongation: 1% or following) carry out false twist crimping and handle false twist crimping finished yarn (56dtex/24 long filament, the filament fiber number: 2.3dtex) that obtains to the polyethylene terephthalate multifilament yarn line.
Gained double-decker fabric has following performance.
Gas permeability: 1.5ml/cm
2S
Water pressure resistance through the face of hydrophobic treatments: 80mm H
2O
Hydrophobicity through the face of hydrophobic treatments: 5 grades
Absorption of water without the face of hydrophobic treatments: 32 seconds
Sense comfortable and easy to wear: 2
Concavo-convex rate of change: 8%
Make the motion overcoat and when wearing, sense comfortable and easy to wear is poorer slightly than embodiment 1 by above-mentioned fabrics, but water proofing property is good.
Embodiment 6
Make complex yarn (A) similarly to Example 3.But the draw ratio of the yarn (1) in its doubling kind is changed to 300% (3 times).
Make complex yarn (B) similarly to Example 3.In addition, weave with warp thread use with embodiment 1 in use identical, (84dtex/72 long filament, filament fiber number: monofilament 1.17dtex) directly carries out the yarn that the twisting processing of 300 times/m (S direction) obtains to polyethylene terephthalate multifilament false twist crimping finished yarn.
Use above-mentioned complex yarn (A) and complex yarn (B) as weft yarn, and use above-mentioned warp thread yarn, knit tissue, weave the double-decker fabric of 188/3.79cm of warp count, 157/3.79cm of weft count according to two-fold shown in Figure 11.A face of this double-decker fabric mainly shows complex yarn (A), and another side mainly shows complex yarn (B).
Above-mentioned double-decker fabric is carried out similarly to Example 3 dyeing, hydrophobic treatments and heat treatment.
Gained double-decker fabric has following performance.
Gas permeability: 4.50ml/cm
2S
Water pressure resistance through the face of hydrophobic treatments: 120mm H
2O
Hydrophobic deg through the face of hydrophobic treatments: 5 grades
Absorption of water without the face of hydrophobic treatments: 8.2 seconds
Concavo-convex rate of change: 40%
Sense comfortable and easy to wear: 3
Use above-mentioned double-decker fabric to make the motion overcoat and when wearing, water proofing property and sense comfortable and easy to wear (anti-clothes attaches property, anti-air impermeability with skin during perspiration) are well.
Embodiment 7
Make the double-decker fabric similarly to Example 6, implement 95 ℃ * 3 minutes humid heat treatment, in liquid-flow dyeing machine, carry out 120 ℃ * 45 minutes dyeing by DISPERSE DYES.This fabric is immersed in the water absorbing agent treatment fluid that contains 5.0 weight % water absorbing agents (trade mark: YM-81, high terebinth (strain) are made), squeeze and twist, the water absorbing agent of impregnation fabric weight 120%, dry under 120 ℃ temperature, deliver to stenter, fabric width is stretched to 1.2 times on one side, Yi Bian implement 160 ℃ * 45 seconds heat treatment.
Gained double-decker fabric has following performance.
Gas permeability: 4.50ml/cm
2S
The absorption of water of the face of main performance complex yarn (A): 1.5 seconds
Concavo-convex rate of change: 40%
Sense comfortable and easy to wear: 3
Apply mechanically clothes and when wearing by above-mentioned double-decker fabric manufacturing campaign is outer, during perspiration the attaching sense of clothes and skin few, airtight sense is few, wearing feeling is comfortable.
Claims (20)
1. Stretchable composite fabric, it is to contain different mutually at least 3 kinds of yarns (1), the woven or knitted fabric of (2) and (3), wherein,
Yarn (1) comprise have than higher suction from percentage elongation and flexible fiber, be have 200% or the height suction of above elongation at break from the extensibility elastomeric yarn,
Yarn (2) be comprise have lower suction from percentage elongation but the low suction that does not show flexible fiber basically from the extensibility inelastic yarn,
Yarn (3) comprise the lower suction of tool from percentage elongation and flexible fiber, be have 30% or the low suction of above elongation at break from the extensibility elastomeric yarn;
It is characterized in that: Yi Bian apply the load of 0.88mN/dtex, on one side respectively with above-mentioned yarn (1), (2) and (3) be wound up on the reeled yarn frame of frame girth 1.125m, the formation winding number is 10 reeled yarn, this reeled yarn is taken off from above-mentioned reeled yarn frame, 20 ℃ of temperature, placed 24 hours in the air ambient of relative humidity 65%, carry out the state adjustment, this dry reeled yarn is applied the load of 0.0088mN/dtex, measure the long (Ld of this drying yarn, mm), this reeled yarn was soaked 5 minutes in the water of 20 ℃ of water temperatures, from water, mention then, this moistening reeled yarn is applied the load of 0.0088mN/dtex, measure the long (Lw of this moistening yarn, mm), by following formula calculate each yarn from percentage elongation
The suction of yarn is from percentage elongation (%)=(Lw-Ld)/(Ld) * 100
At this moment, above-mentioned yarn (1) have 5% or above suction from percentage elongation, above-mentioned yarn (2) and (3) have and are lower than 5% suction from percentage elongation,
Form suction from extensibility elastic composite yarn (A) by above-mentioned yarn (1) and yarn (2), above-mentioned yarn (3) is contained in the non-suction that do not show basically from extensibility in extensibility elastomeric yarn (B),
Make above-mentioned woven or knitted fabric in atmosphere, carry out dimensionally stable with 20 ℃ temperature and 65% relative humidity, from the woven or knitted fabric that has carried out this dimensionally stable, get the experiment slice of above-mentioned complex yarn (A) with 30cm length, measure above-mentioned yarn (1) and average length L 1 and the L2 of yarn (2) under 0.0088mN/dtex load in this experiment slice, at this moment, the value of L1/L2 be 0.9 or below.
2. the described composite fabric of claim 1, wherein above-mentioned Stretchable composite fabric has the woven fabric tissue, in in-house warp thread group of this woven fabric and/or the weft yarn group, above-mentioned suction from extensibility elastomeric yarn (A) and above-mentioned non-suction from extensibility elastomeric yarn (B) single or many alternate configurations.
3. the described composite fabric of claim 2, wherein above-mentioned complex yarn (A) and above-mentioned yarn (B) only constitute the side's yarn group in in-house warp thread group of above-mentioned woven fabric and the weft yarn group, and the opposing party's yarn group is by a kind or the above yarn formation different with above-mentioned yarn (B) with above-mentioned complex yarn (A).
4. the described composite fabric of claim 3, wherein different with above-mentioned yarn (B) with above-mentioned complex yarn (A) yarns are selected to contain many filamentary yarns with flattened and contain has 1.5dtex or following fine-titred many filamentary yarns.
5. the described composite fabric of claim 1, wherein above-mentioned composite fabric has 2 layers or above multilayer tissue, one deck at least of above-mentioned multilayer tissue contains above-mentioned complex yarn (A) with its gross mass 20 quality % or above containing ratio, and one deck at least of above-mentioned multilayer tissue contains above-mentioned yarn (B) with its gross mass 20 quality % or above containing ratio.
6. each described composite fabric among the claim 1-5, wherein constitute above-mentioned high suction contained in the above-mentioned complex yarn (A) and be selected from the polyether ester fibre that is formed by polyester elastomer from the fiber of extensibility elastomeric yarn (1), wherein said polyester elastomer comprises the hard segment that contains the polybutylene terephthalate (PBT) block and contains the soft chain segment of polyethylene glycol block.
7. each described composite fabric among the claim 1-6 wherein constitutes low suction contained in the above-mentioned complex yarn (A) and is selected from polyester fiber from the fiber of extensibility inelastic yarn (2).
8. each described composite fabric among the claim 1-7, the filament fiber number that wherein constitutes the fiber of above-mentioned yarn (2) is 1.5dtex or following.
9. each described composite fabric among the claim 1-8, wherein above-mentioned non-suction is except that containing above-mentioned low suction also contains other yarns (4) from extensibility elastomeric yarn (3) complex yarn from extensibility elastomeric yarn (B), above-mentioned yarn (3) has 200% or above elongation at break, above-mentioned yarn (4) contains and does not have suction basically from extensibility and flexible fiber, when similarly measuring with above-mentioned assay method with above-mentioned complex yarn (A), the average length L 3 of yarn in the above-mentioned complex yarn (3) and the ratio L3/L4 of the average length L 4 of yarn (4) be 0.9 or below.
10. the described composite fabric of claim 9, wherein above-mentioned formation have 200% or the fiber of the yarn (3) of above elongation at break be selected from the polyether ester fibre that forms by polyester elastomer, wherein said polyester elastomer comprises the hard segment that contains the polybutylene terephthalate (PBT) block and contains the soft chain segment of polyoxy butylidene glycol block.
11. the described composite fabric of claim 9, the fiber that wherein constitutes above-mentioned yarn (4) is selected from polyester fiber.
12. each described composite fabric among the claim 1-11, by a plurality of samples of getting size 5cm * 2cm on the above-mentioned composite fabric, they were placed 24 hours in the air of 20 ℃ of temperature, relative humidity 65%, make a plurality of drying samples, get a plurality of samples of size 5cm * 2cm in addition again from above-mentioned composite fabric, they were soaked 5 minutes in the water of 20 ℃ of temperature, from water, mention, be clipped between a pair of filter paper, with 490N/m
2Pressure pressing 1 minute, remove and be present in interfibrous water in the sample, make a plurality of moistening samples, measure the average maximum ga(u)ge Dw of above-mentioned moistening sample and the average maximum ga(u)ge Dd of above-mentioned drying sample, measure concavo-convex rate of change by following formula,
Concavo-convex rate of change (%)=[(Dw-Dd)/(Dd)] * 100
This moment above-mentioned concavo-convex rate of change be 10% or more than.
13. each described composite fabric among the claim 1-12, wherein above-mentioned composite fabric has the woven fabric tissue, the coverage coefficient of this woven fabric be 2500 or more than.
14. each described composite fabric among the claim 1-13, wherein at least one face of above-mentioned composite fabric is implemented hydrophobic processing.
15. each described composite fabric among the claim 1-14 wherein carries out air permeability when measuring by JIS L 1096-1998,6.27, A method (Fu Leizefa) in the air of 20 ℃ of temperature, relative humidity 65%, above-mentioned composite fabric shows 50ml/cm
2S or following air permeability.
16. each described composite fabric among the claim 1-15, wherein in the air of 20 ℃ of temperature, relative humidity 65% by JIS L 1092-1998,4. (1.1) (low hydraulic pressure hydrostatic platen press) carried out water pressure resistance when measuring, above-mentioned composite fabric shows 100mm H
2O or above water pressure resistance.
17. dress materials, it contains each described Stretchable composite fabric among the claim 1-15, by water moistening after, its at least one surface performance concaveconvex shape.
18. clothes, it is to be formed by at least one part that the described dress materials of claim 16 form the armpit, sidepiece, chest, back and the shoulder that are selected from clothes.
19. the described clothes of claim 18, described clothes are selected from underwear.
20. the described clothes of claim 18, described clothes are selected from sportswear.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003361984 | 2003-10-22 | ||
| JP361984/2003 | 2003-10-22 | ||
| JP147410/2004 | 2004-05-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1871384A true CN1871384A (en) | 2006-11-29 |
Family
ID=37444473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200480031101.XA Pending CN1871384A (en) | 2003-10-22 | 2004-10-18 | Stretchable composite fabric and clothing product therefrom |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1871384A (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101317698A (en) * | 2008-07-22 | 2008-12-10 | 周婉 | Swaddling clothes and production thereof |
| CN102041578A (en) * | 2010-11-16 | 2011-05-04 | 远纺工业(上海)有限公司 | Modified polyester filiform texture matter capable of extending by absorbing moisture |
| CN102302338A (en) * | 2011-08-19 | 2012-01-04 | 南通斯得福纺织装饰有限公司 | Making method for loose edge towel |
| CN102485074A (en) * | 2010-12-02 | 2012-06-06 | 东丽纤维研究所（中国）有限公司 | Clothing pressure variable leggings |
| CN103361864A (en) * | 2013-06-28 | 2013-10-23 | 江苏中新资源集团有限公司 | Soft elastic bed mattress |
| CN104246038A (en) * | 2012-04-25 | 2014-12-24 | 东丽株式会社 | Stretch fabric |
| CN104302821A (en) * | 2012-03-30 | 2015-01-21 | 英威达技术有限公司 | Stretch wovens with control yarn system |
| CN104711743A (en) * | 2013-12-12 | 2015-06-17 | 东丽纤维研究所（中国）有限公司 | Imitation silk fabric and production method thereof |
| CN107541845A (en) * | 2017-10-13 | 2018-01-05 | 江苏美恒纺织实业有限公司 | A kind of fabric and its manufacture method |
| CN107557960A (en) * | 2017-10-13 | 2018-01-09 | 江苏美恒纺织实业有限公司 | A kind of ventilation and perspiration function fabric and its manufacture method |
| CN107604510A (en) * | 2017-10-13 | 2018-01-19 | 江苏美恒纺织实业有限公司 | One kind is breathed freely and uvioresistant fabrics and its manufacture method |
| CN107740217A (en) * | 2017-10-13 | 2018-02-27 | 江苏美恒纺织实业有限公司 | A kind of multifunctional fabric and its manufacture method |
| CN108471825A (en) * | 2016-01-15 | 2018-08-31 | 耐克创新有限合伙公司 | Clothes with whole wiped area |
| CN111511970A (en) * | 2018-06-15 | 2020-08-07 | 正山国际有限公司 | Cloth with enhanced transparency of base yarn using polyester-ether block copolymer and method for manufacturing same |
| CN111699289A (en) * | 2018-02-14 | 2020-09-22 | 东丽株式会社 | Woven knitted fabric |
| CN113699640A (en) * | 2021-08-23 | 2021-11-26 | 常州科旭纺织有限公司 | Application of cellulose fiber filament in anti-cutting textile field |
| CN114059209A (en) * | 2021-12-15 | 2022-02-18 | 浙江金旗新材料科技有限公司 | Stretch yarn and stretch yarn production equipment |
| US11412796B2 (en) | 2016-11-16 | 2022-08-16 | Nike, Inc. | Garment with wipe zones |
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| CN101317698A (en) * | 2008-07-22 | 2008-12-10 | 周婉 | Swaddling clothes and production thereof |
| CN102041578B (en) * | 2010-11-16 | 2013-06-26 | 远纺工业(上海)有限公司 | Modified polyester filiform texture matter capable of extending by absorbing moisture |
| CN102041578A (en) * | 2010-11-16 | 2011-05-04 | 远纺工业(上海)有限公司 | Modified polyester filiform texture matter capable of extending by absorbing moisture |
| CN102485074A (en) * | 2010-12-02 | 2012-06-06 | 东丽纤维研究所（中国）有限公司 | Clothing pressure variable leggings |
| CN102485074B (en) * | 2010-12-02 | 2015-03-18 | 东丽纤维研究所（中国）有限公司 | Clothing pressure variable leggings |
| CN102302338A (en) * | 2011-08-19 | 2012-01-04 | 南通斯得福纺织装饰有限公司 | Making method for loose edge towel |
| CN104302821B (en) * | 2012-03-30 | 2016-08-24 | 英威达技术有限公司 | There is the stretching-machine woven fabric controlling yarn system |
| CN104302821A (en) * | 2012-03-30 | 2015-01-21 | 英威达技术有限公司 | Stretch wovens with control yarn system |
| CN104246038B (en) * | 2012-04-25 | 2016-03-30 | 东丽株式会社 | Stockinette |
| CN104246038A (en) * | 2012-04-25 | 2014-12-24 | 东丽株式会社 | Stretch fabric |
| CN103361864A (en) * | 2013-06-28 | 2013-10-23 | 江苏中新资源集团有限公司 | Soft elastic bed mattress |
| CN104711743A (en) * | 2013-12-12 | 2015-06-17 | 东丽纤维研究所（中国）有限公司 | Imitation silk fabric and production method thereof |
| CN104711743B (en) * | 2013-12-12 | 2019-03-08 | 东丽纤维研究所（中国）有限公司 | A kind of silk like fabric fabric and its production method |
| CN108471825A (en) * | 2016-01-15 | 2018-08-31 | 耐克创新有限合伙公司 | Clothes with whole wiped area |
| US11297888B2 (en) | 2016-01-15 | 2022-04-12 | Nike, Inc. | Garment with integral wipe zones |
| US11412796B2 (en) | 2016-11-16 | 2022-08-16 | Nike, Inc. | Garment with wipe zones |
| CN107541845A (en) * | 2017-10-13 | 2018-01-05 | 江苏美恒纺织实业有限公司 | A kind of fabric and its manufacture method |
| CN107740217A (en) * | 2017-10-13 | 2018-02-27 | 江苏美恒纺织实业有限公司 | A kind of multifunctional fabric and its manufacture method |
| CN107604510A (en) * | 2017-10-13 | 2018-01-19 | 江苏美恒纺织实业有限公司 | One kind is breathed freely and uvioresistant fabrics and its manufacture method |
| CN107557960A (en) * | 2017-10-13 | 2018-01-09 | 江苏美恒纺织实业有限公司 | A kind of ventilation and perspiration function fabric and its manufacture method |
| CN111699289A (en) * | 2018-02-14 | 2020-09-22 | 东丽株式会社 | Woven knitted fabric |
| CN111511970A (en) * | 2018-06-15 | 2020-08-07 | 正山国际有限公司 | Cloth with enhanced transparency of base yarn using polyester-ether block copolymer and method for manufacturing same |
| CN111511970B (en) * | 2018-06-15 | 2022-06-03 | Tkg环境材料有限公司 | Cloth with enhanced transparency of base yarn using polyester-ether block copolymer and method for manufacturing same |
| CN115244236A (en) * | 2020-12-04 | 2022-10-25 | 兴和株式会社 | High stretch fabric |
| CN115244236B (en) * | 2020-12-04 | 2024-05-10 | 兴和株式会社 | High stretch fabric |
| CN113699640A (en) * | 2021-08-23 | 2021-11-26 | 常州科旭纺织有限公司 | Application of cellulose fiber filament in anti-cutting textile field |
| CN114059209A (en) * | 2021-12-15 | 2022-02-18 | 浙江金旗新材料科技有限公司 | Stretch yarn and stretch yarn production equipment |
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