CN1843625A - 用于烷烃临氢异构化反应的催化剂及其制备方法 - Google Patents
用于烷烃临氢异构化反应的催化剂及其制备方法 Download PDFInfo
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- CN1843625A CN1843625A CN 200510064831 CN200510064831A CN1843625A CN 1843625 A CN1843625 A CN 1843625A CN 200510064831 CN200510064831 CN 200510064831 CN 200510064831 A CN200510064831 A CN 200510064831A CN 1843625 A CN1843625 A CN 1843625A
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- catalyst
- phosphorus
- magnesium
- molecular sieve
- isomerization
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- 239000003054 catalyst Substances 0.000 title claims abstract description 64
- 150000001335 aliphatic alkanes Chemical class 0.000 title claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 title claims description 75
- 238000002360 preparation method Methods 0.000 title description 10
- 238000006317 isomerization reaction Methods 0.000 claims abstract description 38
- 239000002131 composite material Substances 0.000 claims abstract description 15
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 14
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 28
- 229910052739 hydrogen Inorganic materials 0.000 claims description 24
- 239000001257 hydrogen Substances 0.000 claims description 22
- 229910052698 phosphorus Inorganic materials 0.000 claims description 22
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 21
- 239000011574 phosphorus Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 16
- 229910000510 noble metal Inorganic materials 0.000 claims description 16
- 229910052782 aluminium Inorganic materials 0.000 claims description 15
- 229910001051 Magnalium Inorganic materials 0.000 claims description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 14
- 238000007598 dipping method Methods 0.000 claims description 14
- 239000007789 gas Substances 0.000 claims description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 12
- 239000002283 diesel fuel Substances 0.000 claims description 12
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 11
- 239000004411 aluminium Substances 0.000 claims description 10
- 230000009467 reduction Effects 0.000 claims description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 9
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 9
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 8
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical group CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 239000011777 magnesium Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 229910001593 boehmite Inorganic materials 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
- 239000003502 gasoline Substances 0.000 claims description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
- 239000010970 precious metal Substances 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229940043279 diisopropylamine Drugs 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 2
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims description 2
- 239000001273 butane Substances 0.000 claims description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims description 2
- 239000011654 magnesium acetate Substances 0.000 claims description 2
- 235000011285 magnesium acetate Nutrition 0.000 claims description 2
- 229940069446 magnesium acetate Drugs 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- 238000001308 synthesis method Methods 0.000 claims description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 3
- 230000003197 catalytic effect Effects 0.000 abstract description 5
- 229910052741 iridium Inorganic materials 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- -1 phosphor-aluminum-magnesium Chemical compound 0.000 abstract description 3
- 150000002739 metals Chemical class 0.000 abstract description 2
- 230000008602 contraction Effects 0.000 abstract 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 51
- 239000002808 molecular sieve Substances 0.000 description 24
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 20
- 239000003921 oil Substances 0.000 description 20
- 229940094933 n-dodecane Drugs 0.000 description 18
- 238000003756 stirring Methods 0.000 description 14
- 229910001220 stainless steel Inorganic materials 0.000 description 13
- 239000010935 stainless steel Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 239000000843 powder Substances 0.000 description 11
- 238000009833 condensation Methods 0.000 description 8
- 239000012188 paraffin wax Substances 0.000 description 8
- 230000005494 condensation Effects 0.000 description 7
- 239000010687 lubricating oil Substances 0.000 description 7
- 238000004587 chromatography analysis Methods 0.000 description 6
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000002199 base oil Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 229940001007 aluminium phosphate Drugs 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- MFUVDXOKPBAHMC-UHFFFAOYSA-N magnesium;dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MFUVDXOKPBAHMC-UHFFFAOYSA-N 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 238000007670 refining Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000000634 powder X-ray diffraction Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 210000004243 sweat Anatomy 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 101150003085 Pdcl gene Proteins 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- CQBLUJRVOKGWCF-UHFFFAOYSA-N [O].[AlH3] Chemical compound [O].[AlH3] CQBLUJRVOKGWCF-UHFFFAOYSA-N 0.000 description 2
- AFCIMSXHQSIHQW-UHFFFAOYSA-N [O].[P] Chemical compound [O].[P] AFCIMSXHQSIHQW-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N hydrochloric acid Substances Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910017119 AlPO Inorganic materials 0.000 description 1
- 244000275012 Sesbania cannabina Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- NNBFNNNWANBMTI-UHFFFAOYSA-M brilliant green Chemical compound OS([O-])(=O)=O.C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 NNBFNNNWANBMTI-UHFFFAOYSA-M 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
Abstract
Description
Peak No. | 2 Theta(°) | d-value | 100*I/I0 |
1234567891011 | 8.119.4713.2715.7020.4121.1422.1422.7323.2026.4128.65 | 10.90649.34396.67085.64494.35114.20284.01593.91193.83473.37493.1164 | 19541732251004068431111 |
反应温度(℃) | 220 | 240 | 260 | 280 | 300 | 320 |
正十二烷转化率(wt%)异构化选择性(wt%)异构化收率(wt%) | 40.8798.9640.44 | 62.6398.5361.71 | 82.7797.9681.08 | 92.7394.2087.34 | 95.9888.3484.79 | 98.7870.3569.49 |
实施例 | 反应温度(℃) | 正十二烷转化率(wt%) | 异构化选择性(wt%) | 异构化收率(wt%) |
23 | 330325 | 86.4690.02 | 84.4185.23 | 72.9876.88 |
200+400SN蜡下油性质 | |
凝点运动粘度(mm2.S-1)40(℃)100(℃)馏程/℃2%10%30%50%70%90%95%KK硫含量(ppm)氮含量(ppm)蜡含量(ppm) | 394.21192355392407434449472569.7 |
操作条件 | |
床层最高温度/℃反应压力/MPa空速/h-1氢油比(vol/vol) | 37012.00.5800 |
反应结果 | |
生成油液收/%(重量)>320℃基础油液收/%(重量)基础油凝点/℃运动粘度 40℃/mm2s-1 100℃粘度指数 | 94.657.8-1814.853.75148 |
650SN糠醛精制油性质 | |
凝点馏程/℃HK10%30%50%70%90%KK硫含量(ppm)氮含量(ppm)蜡含量(ppm) | 541803654945195335535955.572.3 |
操作条件 | |
床层最高温度/℃反应压力/MPa空速/h-1氢油比(vol/vol) | 38512.00.50800 |
反应结果 | |
生成油液收/%(重量)>320℃基础油液收/%(重量)基础油凝点/℃运动粘度 40℃/mm2s-1 100℃ | 98.455.3-1529.865.73 |
粘度指数 | 136 |
项目 | 直馏柴油原料 | 精制后直馏柴油 | 降凝柴油 |
密度,g/cm3凝点,℃十六烷值闭口闪点,℃流程,℃HK10%30%50%70%90%KK | 0.81309.952.897216245265287312344350 | 0.80809.759.386206239261283300343347 | 0.8055-3558.260161205.5251.5275297.5336351 |
反应温度(℃) | 260 | 280 | 300 | 320 | 340 | 360 |
正十二烷转化率(wt%)异构化选择性(wt%)异构化产率(wt%) | 37.3195.9035.78 | 63.8887.8856.14 | 79.1676.7360.74 | 88.6157.7951.20 | 92.4138.9736.01 | 94.6125.0323.68 |
反应温度(℃) | 260 | 280 | 300 | 320 | 340 | 360 |
正十二烷转化率(wt%)异构化选择性 | 54.4995.23 | 74.6293.16 | 88.1983.68 | 94.6466.46 | 96.8752.94 | 97.8734.73 |
(wt%)异构化产率(wt%) | 51.89 | 69.51 | 73.80 | 62.90 | 51.28 | 33.99 |
反应温度(℃) | 260 | 280 | 300 | 320 | 340 | 360 |
正十二烷转化率(wt%)异构化选择性(wt%)异构化产率(wt%) | 52.3996.6750.64 | 80.9594.6076.58 | 90.9889.4281.35 | 97.1376.2274.03 | 98.1662.0660.91 | 98.9144.0143.53 |
反应温度(℃) | 240 | 250 | 260 | 270 | 280 | 290 |
正十二烷转化率(wt%)异构化选择性(wt%)异构化产率(wt%) | 46.0091.2641.98 | 72.9982.5260.23 | 85.0077.3265.72 | 92.0574.6668.72 | 94.9566.3863.03 | 97.0561.9860.15 |
反应温度(℃) | 正十二烷转化率(wt%) | 异构化选择性(wt%) | 异构化产率(wt%) |
345 | 82.10 | 72.04 | 59.15 |
Claims (10)
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CNB2005100648316A CN100473462C (zh) | 2005-04-06 | 2005-04-06 | 用于烷烃临氢异构化反应的催化剂及其制备方法 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107282097A (zh) * | 2016-04-12 | 2017-10-24 | 中国石油化工股份有限公司 | 一种加氢异构催化剂及其制备方法和应用 |
CN109939729A (zh) * | 2019-04-16 | 2019-06-28 | 中国科学院上海高等研究院 | 一种Pt/SAPO-11双功能催化剂的制备方法及应用 |
CN114602548A (zh) * | 2022-01-24 | 2022-06-10 | 中国科学院上海高等研究院 | 一种金属单原子分散的烷烃异构化催化剂及其制备方法 |
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CN1098214C (zh) * | 1999-07-06 | 2003-01-08 | 中国石油化工集团公司 | 具有ael结构的磷酸硅铝分子筛及其合成方法 |
US7014827B2 (en) * | 2001-10-23 | 2006-03-21 | Machteld Maria Mertens | Synthesis of silicoaluminophosphates |
JP4248277B2 (ja) * | 2002-03-18 | 2009-04-02 | 三菱レイヨン株式会社 | イソブチレン合成用触媒 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107282097A (zh) * | 2016-04-12 | 2017-10-24 | 中国石油化工股份有限公司 | 一种加氢异构催化剂及其制备方法和应用 |
CN107282097B (zh) * | 2016-04-12 | 2019-12-27 | 中国石油化工股份有限公司 | 一种加氢异构催化剂及其制备方法和应用 |
CN109939729A (zh) * | 2019-04-16 | 2019-06-28 | 中国科学院上海高等研究院 | 一种Pt/SAPO-11双功能催化剂的制备方法及应用 |
CN114602548A (zh) * | 2022-01-24 | 2022-06-10 | 中国科学院上海高等研究院 | 一种金属单原子分散的烷烃异构化催化剂及其制备方法 |
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