CN1831063A - Nitro-compound type termide-proof and insect-proof putty and its application - Google Patents
Nitro-compound type termide-proof and insect-proof putty and its application Download PDFInfo
- Publication number
- CN1831063A CN1831063A CN 200510024233 CN200510024233A CN1831063A CN 1831063 A CN1831063 A CN 1831063A CN 200510024233 CN200510024233 CN 200510024233 CN 200510024233 A CN200510024233 A CN 200510024233A CN 1831063 A CN1831063 A CN 1831063A
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- Prior art keywords
- proof
- insect
- termide
- parts
- putty
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000002828 nitro derivatives Chemical class 0.000 title 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 238000005034 decoration Methods 0.000 claims abstract description 7
- 229920000180 alkyd Polymers 0.000 claims abstract description 6
- 239000000020 Nitrocellulose Substances 0.000 claims description 17
- 229920001220 nitrocellulos Polymers 0.000 claims description 17
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 10
- 229920000742 Cotton Polymers 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 239000002728 pyrethroid Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 7
- 239000005892 Deltamethrin Substances 0.000 claims description 6
- 229960002483 decamethrin Drugs 0.000 claims description 6
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 239000004902 Softening Agent Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- -1 cellulose nitrate ester Chemical class 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 239000005946 Cypermethrin Substances 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 229960005424 cypermethrin Drugs 0.000 claims description 2
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 13
- 241000256602 Isoptera Species 0.000 abstract description 7
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 241001149932 Archaeognatha Species 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 239000012461 cellulose resin Substances 0.000 abstract 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 abstract 1
- 125000005245 nitryl group Chemical group [N+](=O)([O-])* 0.000 abstract 1
- 238000010422 painting Methods 0.000 abstract 1
- 239000002689 soil Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003814 drug Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- 238000002203 pretreatment Methods 0.000 description 4
- 239000012855 volatile organic compound Substances 0.000 description 4
- 230000001680 brushing effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 239000003171 wood protecting agent Substances 0.000 description 3
- 238000003556 assay Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical compound C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 238000002464 physical blending Methods 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940015367 pyrethrum Drugs 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Paints Or Removers (AREA)
Abstract
This invention discloses a termite-proof and bug-proof nitryl putty and its application. The filming matter(alkyd resin, modified alkyd resin and nitrate cellulose resin), special bug proof agent, organic expansive soil, butyl acetate and xylene are used in painting dressing process of furniture and plank floor to form termite and bug-proof putty film to prevent termite and other bristletail to erode carpentry. The advantages are high efficiency, good decoration effect, execution is convenient.
Description
Technical field
The present invention relates to a kind of solvent-borne type woodwork coating and application thereof, relate in particular to a kind of termide-proof and insect-proof nitrocellulose putty.
Background technology
At present, the timber termide-proof and insect-proof is handled mainly based on infusion method and squeegee process, is about to timber and is immersed in the solution that contains medicine, and the solution brushing that maybe will contain medicine is on wood surface, as Chinese patent 93101647.9 disclosed size putties; The MA transparent woodenware priming paint of series and the putty of the development of the single-component normal temperature quick-drying putty that document (" bonding ", 1998 the 1st phases) discloses and document (" New Building Materials ", 2002,2) report all do not have the termide-proof and insect-proof ability.Medicine easily runs off simultaneously, and duration of efficacy is short; Medicine is harmful, environmental pollution; Behind the solution of wood surface brushing medicine, influenced lacquer decorations effect to wood surface.Therefore, the termide-proof and insect-proof pesticide application technology of timber or plank can not be applicable to the substrate coating pre-treatment of modern wooden furniture and the pre-treatment of family's wood decoration finishing at present.
Summary of the invention
The technical issues that need to address of the present invention are to disclose a kind of termide-proof and insect-proof nitrocellulose putty and should have, and to overcome above-mentioned the deficiencies in the prior art, satisfy the needs of the pre-treatment of the substrate coating pre-treatment of modern wooden furniture and family's wood decoration finishing.
The component and the parts by weight of termide-proof and insect-proof nitrocellulose putty of the present invention comprise:
12～20 parts of film-forming resins
26～36 parts of organic solvents
12～20 parts of cellulose nitrate esters
1～4 part in softening agent
3～12 parts of anti-settling agents
1～4 part of Zinic stearas
0.50～3.5 part of insect-proof agent
16～28 parts of fillers
Said film-forming resin is selected from a kind of or its mixture in Synolac, modified alkyd resin or the Malin's acid resin, wherein, the product of modified alkyd resin for adopting Viscotrol C that Synolac is carried out modification can adopt the commercially available prod, as the product of Changxing, Guangzhou chemical industry company limited;
Said organic solvent is selected from a kind of or its mixture in vinyl acetic monomer, isopropylcarbinol, dimethylbenzene or the dimethylbenzene;
Said nitro-cotton 1/2s or nitro-cotton 1/4s or its mixture of being selected from, 1/2s and 1/4s refer to the cellulose nitrate ester that viscosity is 1/2 second and 1/4 second, can adopt the commercially available prod, as the product of Guangzhou northization Kai Ming trade Co., Ltd;
The preferred dimixo-octyl phthalate of said softening agent;
Said anti-settling agent is selected from organobentonite, can adopt the commercially available prod, as the pull up a horse product of magnificent trade Co., Ltd, Zhejiang Ward Industrial Co., Ltd. of Jiangmen city;
Said insect-proof agent is selected from pyrethroid, stuck gram missible oil, the white spirit of silicon or its mixture;
The preferred Deltamethrin of said pyrethroid, effective cypermethrin or tetrabromo Cyano chrysanthemate;
The chemical name of the white spirit of said silicon is 4-phenelyl [3-(4-fluoro-3-phenoxy phenyl) propyl group] dimethylsilane;
Insect-proof agent can adopt the commercially available prod, as the product of Guangdong Province Insects Research Institute, Britain Shell Co. Ltd or Japan Pyrethrum Co., Ltd;
Said filler is selected from a kind of or its mixture in talcum powder, kaolin, ground barium sulfate or the water-ground limestone, and preferred order number is 500～1500 orders.
Preferred ingredients and parts by weight are:
1. castor oil modified Synolac 16
2. vinyl acetic monomer 33
3. nitro-cotton 1/2s 15
4. dimixo-octyl phthalate 2
5. organobentonite 6
6. Zinic stearas 2
7. the pyrethroid Deltamethrin 1
8. 1000 order talcum powder 25.
The preparation method of termide-proof and insect-proof nitrocellulose putty of the present invention is foolproof, can adopt the general physical blending means, can obtain.
The using method of termide-proof and insect-proof nitrocellulose putty of the present invention is identical with conventional putty, the Coating Pretreatment and the decoration design for residence that can be used for woodworks such as wooden furniture, timber floor, behind the putty of woodwork coated putty, form the termide-proof and insect-proof film, thereby stop termite and of the moth erosion of other moth woodenware.The present invention mainly utilizes filmogen (Synolac, modified alkyd resin, Malin's acid resin or cellulose nitrate ester etc.) in the prescription, pyrethroid special efficacy insect-proof agent, Zinic stearas, N-BUTYL ACETATE, talcum powder, organobentonite etc., in the Coating Pretreatment process of woodworks such as wooden furniture, timber floor, form the termide-proof and insect-proof film, thereby stop termite and of the moth erosion of other moth woodenware.Have advantages such as termide-proof and insect-proof efficient height, decorative effect are good, easy construction, can be used as the application and the decoration design for residence of modern wooden furniture.Adopt GB/T 18260-2000 " wood preservative is to termite toxic effect test method " to detect, termide-proof and insect-proof efficient is 1 grade.
Embodiment
Embodiment 1
A kind of termide-proof and insect-proof nitro (NC) putty, its prescription is (weight proportion, unit kilogram):
1. castor oil modified Synolac 16
2. vinyl acetic monomer 33
3. nitro-cotton 1/2s 15
4. dimixo-octyl phthalate 2
5. organobentonite 6
6. Zinic stearas 2
7. the pyrethroid Deltamethrin 1
8. talcum powder (1000 order) 25
Add up to: 100.00
Production technique of the present invention is that with the above-mentioned substance blending dispersion, adding pyrethroid Deltamethrin is uniformly dispersed and gets final product.
Coating process of the present invention requires, and mixes up the termide-proof and insect-proof nitrocellulose putty, with the method for brushing and blade coating with woodworks such as wooden furniture, timber floor repair comprehensively, levelling, get final product.
Adopt GB/T 18260-2000 " wood preservative is to termite toxic effect test method " to detect, the result is as follows:
| Sequence number | Interventions Requested | Assay | The method of inspection | |
| 1 | Outward appearance | There is not mechanical impurity, no skinning | ||
| 2 | Appearance of film | Surfacing, smooth | Range estimation | |
| 3 | Denseness | 8～14cm | GB/T 1749 | |
| 4 | Time of drying (25 ℃) | Surface drying | 8min | GB/T 1728-89 (second method) |
| Do solid work | ≤1h | GB/T 1728-89 (first method) | ||
| 5 | Sticking power (cross-hatching) | ≤ 2 grades | GB/T 9286-1998 | |
| 6 | Snappiness | ≤100mm | GB/T 1748 | |
| 7 | Thermotolerance (60 ℃, 2h) | No change | GB/T 1735-79 | |
| 8 | Volatile organic compounds (VOC) | ≤500g/L | GB 18581-2001 | |
| 9 | Benzene, % | Do not detect | GB 18581-2001 appendix A | |
| 10 | Toluene and dimethylbenzene summation, % | ≤15 | GB 18581-2001 appendix A | |
| 11 | The termide-proof and insect-proof ability, level | ≤ 1 grade | GB/T 18260-2000 | |
Annotate: 0 grade of expression performance is best, and 1 grade is taken second place, and 5 grades the poorest.
Embodiment 2
8 parts of Synolac, 4 parts of Malin's acid resins, 4 parts of isopropylcarbinols, 22 parts of dimethylbenzene, nitro-cotton 1/4s20 part, 1 part of dimixo-octyl phthalate, 12 parts of organobentonites, 4 parts of Zinic stearass, 1 part of the white spirit of silicon, 1.5 parts of stuck gram missible oil, 22.5 parts in kaolin 1000 orders.
The preparation method is with embodiment 1.
Adopt GB/T 18260-2000 " wood preservative is to termite toxic effect test method " to detect, the result is as follows:
| Sequence number | Interventions Requested | Assay | The method of inspection | |
| 1 | Outward appearance | There is not mechanical impurity, no skinning | ||
| 2 | Appearance of film | Surfacing, smooth | Range estimation | |
| 3 | Denseness | 8～14cm | GB/T 1749 | |
| 4 | Time of drying (25 ℃) | Surface drying | 8min | GB/T 1728-89 (second method) |
| Do solid work | ≤1h | GB/T 1728-89 (first method) | ||
| 5 | Sticking power (cross-hatching) | ≤ 2 grades | GB/T 9286-1998 | |
| 6 | Snappiness | ≤80mm | GB/T 1748 | |
| 7 | Thermotolerance (60 ℃, 2h) | No change | GB/T 1735-79 | |
| 8 | Volatile organic compounds (VOC) | ≤450g/L | GB 18581-2001 | |
| 9 | Benzene, % | Do not detect | GB 18581-2001 appendix A | |
| 10 | Toluene and dimethylbenzene summation, % | ≤15 | GB 18581-2001 appendix A | |
| 11 | The termide-proof and insect-proof ability, level | ≤ 1 grade | GB/T 18260-2000 | |
Annotate: 0 grade of expression performance is best, and 1 grade is taken second place, and 5 grades the poorest.
Claims (6)
1. a termide-proof and insect-proof nitrocellulose putty is characterized in that, component and parts by weight comprise:
12～20 parts of film-forming resins
26～36 parts of organic solvents
12～20 parts of cellulose nitrate esters
1～4 part in softening agent
3～12 parts of anti-settling agents
1～4 part of Zinic stearas
0.50～3.5 part of insect-proof agent
16～28 parts of fillers
Said film-forming resin is selected from a kind of or its mixture in Synolac, modified alkyd resin or the Malin's acid resin;
The preferred dimixo-octyl phthalate of said softening agent;
Said anti-settling agent is selected from organobentonite;
Said insect-proof agent is selected from pyrethroid (Deltamethrin, effective cypermethrin or tetrabromo Cyano chrysanthemate), stuck gram missible oil, the white spirit of silicon or its mixture.
2. termide-proof and insect-proof nitrocellulose putty according to claim 1 is characterized in that, said organic solvent is selected from a kind of or its mixture in vinyl acetic monomer, isopropylcarbinol, dimethylbenzene or the dimethylbenzene.
3. termide-proof and insect-proof nitrocellulose putty according to claim 1 is characterized in that, said cellulose nitrate ester is selected from nitro-cotton 1/2s or nitro-cotton 1/4s or its mixture.
4. termide-proof and insect-proof nitrocellulose putty according to claim 1 is characterized in that, said filler is selected from a kind of or its mixture in talcum powder, kaolin, ground barium sulfate or the water-ground limestone.
5. according to each described termide-proof and insect-proof nitrocellulose putty of claim 1～4, it is characterized in that component and parts by weight are:
1. castor oil modified Synolac 16
2. vinyl acetic monomer 33
3. nitro-cotton 1/2s 15
4. dimixo-octyl phthalate 2
5. organobentonite 6
6. Zinic stearas 2
7. the pyrethroid Deltamethrin 1
8. 1000 order talcum powder 25.
6. according to the application of each described termide-proof and insect-proof nitrocellulose putty of claim 1～4, it is characterized in that, be used for the Coating Pretreatment and the decoration design for residence of woodwork.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100242336A CN100560671C (en) | 2005-03-07 | 2005-03-07 | A kind of termide-proof and insect-proof nitrocellulose putty and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100242336A CN100560671C (en) | 2005-03-07 | 2005-03-07 | A kind of termide-proof and insect-proof nitrocellulose putty and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1831063A true CN1831063A (en) | 2006-09-13 |
| CN100560671C CN100560671C (en) | 2009-11-18 |
Family
ID=36993569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100242336A Active CN100560671C (en) | 2005-03-07 | 2005-03-07 | A kind of termide-proof and insect-proof nitrocellulose putty and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100560671C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103102776A (en) * | 2013-01-22 | 2013-05-15 | 重庆市品胜涂料有限公司 | 70%-glossiness varnish and preparation method thereof |
| CN103740157A (en) * | 2013-12-27 | 2014-04-23 | 上海长润发涂料有限公司 | Oily filler |
| CN105086789A (en) * | 2015-08-05 | 2015-11-25 | 安徽岍汧漆业有限公司 | Insect expelling paint for furniture and manufacturing method thereof |
| CN105368118A (en) * | 2015-11-18 | 2016-03-02 | 广德县常丰竹木业制品有限公司 | High adhesion wood repair putty and preparation method thereof |
| CN106084971A (en) * | 2016-08-26 | 2016-11-09 | 蒋小军 | A kind of inner wall putty powder with insect protected function |
-
2005
- 2005-03-07 CN CNB2005100242336A patent/CN100560671C/en active Active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103102776A (en) * | 2013-01-22 | 2013-05-15 | 重庆市品胜涂料有限公司 | 70%-glossiness varnish and preparation method thereof |
| CN103102776B (en) * | 2013-01-22 | 2015-06-10 | 重庆市品胜涂料有限公司 | 70%-glossiness varnish and preparation method thereof |
| CN103740157A (en) * | 2013-12-27 | 2014-04-23 | 上海长润发涂料有限公司 | Oily filler |
| CN105086789A (en) * | 2015-08-05 | 2015-11-25 | 安徽岍汧漆业有限公司 | Insect expelling paint for furniture and manufacturing method thereof |
| CN105368118A (en) * | 2015-11-18 | 2016-03-02 | 广德县常丰竹木业制品有限公司 | High adhesion wood repair putty and preparation method thereof |
| CN106084971A (en) * | 2016-08-26 | 2016-11-09 | 蒋小军 | A kind of inner wall putty powder with insect protected function |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100560671C (en) | 2009-11-18 |
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