CN1640970A - Polyurethane termite-proof insect-protected enclosed primping paint - Google Patents
Polyurethane termite-proof insect-protected enclosed primping paint Download PDFInfo
- Publication number
- CN1640970A CN1640970A CN 200410015514 CN200410015514A CN1640970A CN 1640970 A CN1640970 A CN 1640970A CN 200410015514 CN200410015514 CN 200410015514 CN 200410015514 A CN200410015514 A CN 200410015514A CN 1640970 A CN1640970 A CN 1640970A
- Authority
- CN
- China
- Prior art keywords
- proof
- insect
- termide
- urethane
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004814 polyurethane Substances 0.000 title abstract description 3
- 239000003973 paint Substances 0.000 title abstract 2
- 229920002635 polyurethane Polymers 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 42
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000002728 pyrethroid Substances 0.000 claims abstract description 10
- 229920000180 alkyd Polymers 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 25
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 8
- 239000005056 polyisocyanate Substances 0.000 claims description 8
- 229920001228 polyisocyanate Polymers 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- 239000004922 lacquer Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 3
- 241000256602 Isoptera Species 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 5
- 230000003405 preventing effect Effects 0.000 abstract description 5
- 239000000020 Nitrocellulose Substances 0.000 abstract description 3
- 238000010276 construction Methods 0.000 abstract description 3
- -1 nitro cellulose ester Chemical class 0.000 abstract description 3
- 229920001220 nitrocellulos Polymers 0.000 abstract description 3
- 239000000575 pesticide Substances 0.000 abstract description 2
- 241000607479 Yersinia pestis Species 0.000 abstract 3
- 238000010422 painting Methods 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000000903 blocking effect Effects 0.000 abstract 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 abstract 1
- 229940079938 nitrocellulose Drugs 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 239000003814 drug Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000005034 decoration Methods 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229940079593 drug Drugs 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003171 wood protecting agent Substances 0.000 description 1
Abstract
The termite and pest preventing blocking polyurethane base paint has in its recipe filming matter alkyd resin, modified alkyd resin or nitro cellulose ester; pyrethroid as specific pesticide, zinc stearate, butyl acetate, leveling agent and defoaming agent. It is used in painting wooden furniture, wooden floor and other wooden products to form termite and pest preventing film to inhibit the worm eating. The present invention has the advantages of high termite and pest preventing effect, good decorating effect, simple construction, etc. and is especially suitable for painting and decorating furniture and finishing house.
Description
Technical field the present invention relates to contain the solvent-borne type woodwork coating of element or organic compound insects repellant, relates in particular to a kind of urethane (PU urethane) termide-proof and insect-proof seal coat.
Background technology is present, and the timber termide-proof and insect-proof is handled mainly based on infusion method and squeegee process, is about to timber and is immersed in the solution that contains medicine, and the solution brushing that maybe will contain medicine is on wood surface.Its shortcoming is that medicine easily runs off, and duration of efficacy is short; Medicine is harmful, environmental pollution; Behind the solution of wood surface brushing medicine, influenced lacquer decorations effect to wood surface.Therefore, the termide-proof and insect-proof pesticide application technology of present timber or plank can not be applicable to the application and the decoration design for residence of modern wooden furniture.
Application number for example: 01108674 Chinese invention patent application discloses the technical scheme that name is called " termite preventing and controlling agent and uses thereof ".This scheme provides a kind of termite preventing and controlling agent.It is good fixing effect in soil, and the lasting period is long, the ground that is mainly used in termite prevention handle or be used for that brick mixes, the termite-proof harm of steel and concrete structure buildings over-ground part and ancient building.When the bamboo and wood vessel are carried out the processing of favorable moth-proof, still adopt squeegee process.Medicine easily runs off, and duration of efficacy is short, and medicine is harmful, the not fine yet solution of the shortcoming of environmental pollution.As can be seen, this control agent not too is fit to furniture woodenware termide-proof and insect-proof.
Summary of the invention the objective of the invention is to overcome above-mentioned the deficiencies in the prior art, and a kind of application of wooden furniture and termide-proof and insect-proof seal coat of decoration design for residence of can be used for is provided.
The present invention is achieved by the following scheme:
A kind of urethane termide-proof and insect-proof seal coat is divided into first component and component B, and the weight proportion of prescription is:
The first component comprises
A. the tripolymer of the affixture of polyisocyanates and TriMethylolPropane(TMP) or polyisocyanates
Or their mixture 25～75%,
B. N-BUTYL ACETATE 25～75%;
Component B comprises
A. modified alkyd resin or Synolac or Malin's acid resin or their mixture
63～75％
B. vinyl acetic monomer 14.6～24.6%,
C. defoamer 0.06～0.40%,
D. flow agent 0.20～0.60%,
E. dispersion agent 0.10～0.30%,
F. Zinic stearas 5.10～8.10%,
G. special efficacy insect-proof agent pyrethroid or other insect-proof agent 0.50～4.00%,
H. anti-settling agent 2.50～4.50%,
I. siccative T-12 organotin is a compound 0.04～1.00%.
Polyisocyanates is meant TDI or HDI described in the first component.
N-BUTYL ACETATE is meant organic solvent or their mixtures such as vinyl acetic monomer or toluene described in the first component.
Organic solvent or their mixtures such as the also available isopropylcarbinol of vinyl acetic monomer described in the component B, dimethylbenzene.
Defoamer described in the component B is meant CFC-151 or BYK066 or moral modest 5100 or their mixture.
Flow agent described in the component B is meant KEPER-150 or BYK306 or HX-3130 or their mixture.
Dispersion agent described in the component B is meant KEPER-602 or BYK-P104S or their mixture.
Anti-settling agent described in the component B is meant 6901-21X or efka-4500 or organobentonite or their mixture.
Urethane termide-proof and insect-proof seal coat of the present invention in use first component and component B in 0.3～1: 1 ratio is mixed.
Mixed lacquer can add thinner and regulate viscosity.
The present invention mainly utilizes filmogen (Synolac, modified alkyd resin or cellulose nitrate ester), pyrethroid special efficacy insect-proof agent, Zinic stearas, N-BUTYL ACETATE, flow agent, the defoamer in the prescription, in the coating process of woodworks such as wooden furniture, timber floor, form the termide-proof and insect-proof film, thereby stop termite and of the moth erosion of other moth woodenware.Have advantages such as termide-proof and insect-proof efficient height, decorative effect are good, easy construction, can be used as the application and the decoration design for residence of modern wooden furniture.
The weight proportion of one of embodiment embodiment of the invention prescription is:
The first component:
1. the affixture of tolylene diisocyanate (TDI) and TriMethylolPropane(TMP), TDI
Tripolymer (8: 2) 45%
2. N-BUTYL ACETATE 55%
Component B:
1. Synolac 68.34%
2. N-BUTYL ACETATE 20.20%
3. defoamer BYK066 0.34%
4. flow agent BYK306 0.38%
5. dispersion agent KEPER-602 0.20%
6. Zinic stearas 6.12%
7. pyrethroid special efficacy insect-proof agent 1.00%
8. anti-settling agent 6901-21X 3.20%
9. siccative T-12 0.22%
Add up to: 100%
The weight proportion of two prescriptions of the embodiment of the invention is:
The first component:
2. the affixture of tolylene diisocyanate (TDI) and TriMethylolPropane(TMP), TDI
Tripolymer (8: 2) 25%
2. N-BUTYL ACETATE 75%
Component B:
1. Synolac 63%
2. N-BUTYL ACETATE 24.60%
3. defoamer BYK066 0.06%
4. flow agent BYK306 0.20%
5. dispersion agent KEPER-602 0.10%
6. Zinic stearas 7.10%
7. pyrethroid special efficacy insect-proof agent 1.30%
8. anti-settling agent 6901-21X 3.50%
9. siccative T-12 0.14%
Add up to: 100%
The weight proportion of three prescriptions of the embodiment of the invention is:
The first component:
1. the affixture of tolylene diisocyanate (TDI) and TriMethylolPropane(TMP), TDI
Tripolymer (8: 2) 73%
2. N-BUTYL ACETATE 27%
Component B:
1. Synolac 73%
2. N-BUTYL ACETATE 14.60%
3. defoamer BYK066 0.4%
4. flow agent BYK306 0.6%
5. dispersion agent KEPER-602 0.20%
6. Zinic stearas 5.12%
7. pyrethroid special efficacy insect-proof agent 3.00%
8. anti-settling agent 6901-21X 2.80%
9. siccative T-12 0.28%
Add up to: 100%
Production technique of the present invention is after resin, solvent and coatings additive(s) are fully disperseed, to add pyrethroid special efficacy insect-proof agent and be uniformly dispersed.
Coating process of the present invention requires, and proportioning mixes up the termide-proof and insect-proof seal coat in accordance with regulations, uses the method for brushing and spraying with woodwork closed allround such as wooden furniture, timber floors.
Each chemical composition production firm is exemplified below among the present invention:
The affixture of polyisocyanates (as TDI, HDI) and TriMethylolPropane(TMP) (TMP) or the tripolymer of polyisocyanates or their mixture Bayer A.G.
N-BUTYL ACETATE (vinyl acetic monomer, toluene organic solvent or their mixture) the sincere solvent in Guangdong Jiangmen sky Products Co., Ltd.
Modified alkyd resin (or Synolac, Malin's acid resin or their mixture) Changxing, Guangzhou chemical industry company limited.
Vinyl acetic monomer (or isopropylcarbinol, dimethylbenzene organic solvent or their mixture) the sincere solvent in Guangdong Jiangmen sky Products Co., Ltd, Dongguan City are with boat chemical industry company limited.
Safe source trade Co., Ltd, the dark blue trade Co., Ltd in Guangzhou are engraved in defoamer (CFC-151, BYK066, moral modest 5100 or their mixture) Dongguan.
Safe source trade Co., Ltd, Guangzhou Xanadu Pentium chemical industry company limited are engraved in flow agent (KEPER-150, BYK306, HX-3130 or their mixture) Dongguan.
Safe source trade Co., Ltd is engraved in dispersion agent (KEPER-602, BYK-P104S or their mixture) Dongguan.
The fast safe Industrial Co., Ltd. in Zinic stearas Shenzhen.
Special efficacy insect-proof agent pyrethroid or the Central-South forestry institute of other insect-proof agent.
Anti-settling agent (6901-21X, efka-4500, organobentonite or their mixture) Jiangmen city pull up a horse magnificent trade Co., Ltd, Zhejiang Ward Industrial Co., Ltd..
Sea, siccative (organotin is compound such as T-12) Shenzhen Dehua worker company limited.
After testing, termide-proof and insect-proof efficient is 1 grade.Detection method GB/T18260-2000 " wood preservative is to termite toxic effect test method ".
After testing, quality and technical index and harmful substance contents are as follows:
| Sequence number | Interventions Requested | Assay | The method of inspection | |
| ??1 | Appearance of film | Surfacing, smooth | Range estimation | |
| ??2 | Time of drying (25 ℃) | Surface drying | ????15min | GB/T1728-89 (second method) |
| Do solid work | ????≤24h | GB/T1728-89 (first method) | ||
| ??3 | Sticking power | ≤ 3 grades | ????GB/T9286-1998 | |
| ??4 | Hardness (the pencil method, 72h) | ????≥H | GB/T6739-1996 (A method) | |
| ??5 | Water tolerance (25 ℃, 18h) | No change | GB/T1733-93 (first method) | |
| ??6 | Thermotolerance (60 ℃, 2h) | No change | ????GB/T1735-79 | |
| ??7 | Volatile organic compounds (VOC) | ????625g/L | ????GB18581-2001 | |
| ??8 | Benzene | Do not detect | The GB18581-2001 appendix A | |
| ??9 | Toluene and dimethylbenzene summation | ????27.5％ | The GB18581-2001 appendix A | |
| ??10 | Free toluene diisocyanate | ????0.5％ | ????GB/T18446-2001 | |
Facts have proved, the present invention mainly utilizes filmogen (Synolac, modified alkyd resin or cellulose nitrate ester), pyrethroid special efficacy insect-proof agent, Zinic stearas, N-BUTYL ACETATE, flow agent, the defoamer in the prescription, in the coating process of woodworks such as wooden furniture, timber floor, form the termide-proof and insect-proof film, thereby stop termite and of the moth erosion of other moth woodenware.Have termide-proof and insect-proof efficient height, pollute for a short time, guard time is long, advantages such as decorative effect is good, easy construction.
Claims (10)
1. urethane termide-proof and insect-proof seal coat is characterized in that: lacquer is divided into first component and component B, and the weight proportion of prescription is:
The first component comprises
A. the tripolymer of the affixture of polyisocyanates and TriMethylolPropane(TMP) or polyisocyanates or their mixture 25～75%,
B. N-BUTYL ACETATE 25～75%;
Component B comprises
A. modified alkyd resin or Synolac or Malin's acid resin or their mixture
63～75％
B. vinyl acetic monomer 14.6～24.6%,
C. defoamer 0.06～0.40%,
D. flow agent 0.20～0.60%,
E. dispersion agent 0.10～0.30%,
F. Zinic stearas 5.10～8.10%,
G. special efficacy insect-proof agent pyrethroid or other insect-proof agent 0.50～4.00%,
H. anti-settling agent 2.50～4.50%,
I. siccative T-12 organotin is a compound 0.04～1.00%.
2. urethane termide-proof and insect-proof seal coat according to claim 1, it is characterized in that: described polyisocyanates is meant TDI or HDI.
3. urethane termide-proof and insect-proof seal coat according to claim 1, it is characterized in that: described N-BUTYL ACETATE is meant organic solvent or their mixtures such as vinyl acetic monomer or toluene.
4. urethane termide-proof and insect-proof seal coat according to claim 1 is characterized in that: organic solvent or their mixtures such as the also available isopropylcarbinol of vinyl acetic monomer, dimethylbenzene in the described component B.
5. urethane termide-proof and insect-proof seal coat according to claim 1 is characterized in that: defoamer is meant CFC-151 or BYK 066 or moral modest 5100 or their mixture in the described component B.
6. urethane termide-proof and insect-proof seal coat according to claim 1 is characterized in that: flow agent is meant KEPER-150 or BYK306 or HX-3130 or their mixture in the described component B.
7. urethane termide-proof and insect-proof seal coat according to claim 1 is characterized in that: dispersion agent is meant KEPER-602 or BYK-P104S or their mixture in the described component B.
8. urethane termide-proof and insect-proof seal coat according to claim 1 is characterized in that: anti-settling agent is meant 6901-21X or efka-4500 or organobentonite or their mixture in the described component B.
9. urethane termide-proof and insect-proof seal coat according to claim 1, it is characterized in that: first component and component B are in 0.3～1 during use: 1 ratio is mixed.
10. urethane termide-proof and insect-proof seal coat according to claim 9 is characterized in that: the lacquer that is mixed in proportion adds thinner and regulates viscosity.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410015514 CN1290951C (en) | 2004-02-26 | 2004-02-26 | Polyurethane termite-proof insect-protected enclosed primping paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410015514 CN1290951C (en) | 2004-02-26 | 2004-02-26 | Polyurethane termite-proof insect-protected enclosed primping paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1640970A true CN1640970A (en) | 2005-07-20 |
| CN1290951C CN1290951C (en) | 2006-12-20 |
Family
ID=34868009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410015514 Expired - Lifetime CN1290951C (en) | 2004-02-26 | 2004-02-26 | Polyurethane termite-proof insect-protected enclosed primping paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1290951C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845266A (en) * | 2009-03-24 | 2010-09-29 | 陈姣英 | Anti-blushing transparent woodwork coating and production process thereof |
| CN101967756A (en) * | 2010-10-15 | 2011-02-09 | 江苏宝泽高分子材料股份有限公司 | Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof |
| CN102220082A (en) * | 2011-06-10 | 2011-10-19 | 东莞大宝化工制品有限公司 | Bicomponent oily polyurethane primer with low VOC (volatile organic compounds) |
| CN102504682A (en) * | 2011-11-03 | 2012-06-20 | 佛山市万正涂料有限公司 | Polyurethane paint applied to woodworking and application thereof |
| CN103409056A (en) * | 2012-12-31 | 2013-11-27 | 东莞市泰发化工有限公司 | Ultrahard transparent PU (poly urethane) paint |
| CN103897580A (en) * | 2014-03-11 | 2014-07-02 | 上海长润发涂料有限公司 | Electrostatic spraying polyurethane varnish |
| CN104031539A (en) * | 2014-06-17 | 2014-09-10 | 展辰涂料集团股份有限公司 | Electrostatic spraying priming paint |
| CN104497839A (en) * | 2014-12-11 | 2015-04-08 | 三棵树涂料股份有限公司 | PU (polyurethane) seal primer capable of highly wetting and highly infiltrating substrate and preparation method of PU seal primer |
| CN106010199A (en) * | 2016-07-28 | 2016-10-12 | 陈红旗 | Termite-proof paint for solid wood furniture |
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|---|---|---|---|---|
| CN102533084A (en) * | 2010-12-22 | 2012-07-04 | 展辰涂料集团股份有限公司 | Poly urethane (PU) polyurethane paint |
| CN103059707B (en) * | 2011-10-20 | 2015-12-02 | 展辰涂料集团股份有限公司 | A kind of polyurethane paint for melamine substrate |
| CN102504689B (en) * | 2011-11-03 | 2013-02-13 | 佛山市万正涂料有限公司 | Wood enclosing primer and application thereof |
| CN102533087B (en) * | 2011-12-16 | 2014-07-23 | 展辰涂料集团股份有限公司 | Polyurethane primer and preparation method thereof |
-
2004
- 2004-02-26 CN CN 200410015514 patent/CN1290951C/en not_active Expired - Lifetime
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845266A (en) * | 2009-03-24 | 2010-09-29 | 陈姣英 | Anti-blushing transparent woodwork coating and production process thereof |
| CN101967756A (en) * | 2010-10-15 | 2011-02-09 | 江苏宝泽高分子材料股份有限公司 | Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof |
| CN101967756B (en) * | 2010-10-15 | 2012-01-25 | 江苏宝泽高分子材料股份有限公司 | Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof |
| CN102220082A (en) * | 2011-06-10 | 2011-10-19 | 东莞大宝化工制品有限公司 | Bicomponent oily polyurethane primer with low VOC (volatile organic compounds) |
| CN102504682A (en) * | 2011-11-03 | 2012-06-20 | 佛山市万正涂料有限公司 | Polyurethane paint applied to woodworking and application thereof |
| CN103409056B (en) * | 2012-12-31 | 2016-04-27 | 东莞市泰发化工有限公司 | The transparent PU paint of a kind of ultrahard |
| CN103409056A (en) * | 2012-12-31 | 2013-11-27 | 东莞市泰发化工有限公司 | Ultrahard transparent PU (poly urethane) paint |
| CN103897580A (en) * | 2014-03-11 | 2014-07-02 | 上海长润发涂料有限公司 | Electrostatic spraying polyurethane varnish |
| CN103897580B (en) * | 2014-03-11 | 2016-11-23 | 上海长润发涂料有限公司 | A kind of electrostatic spraying polyurethane lacquer |
| CN104031539A (en) * | 2014-06-17 | 2014-09-10 | 展辰涂料集团股份有限公司 | Electrostatic spraying priming paint |
| CN104031539B (en) * | 2014-06-17 | 2016-08-31 | 展辰新材料集团股份有限公司 | A kind of electrostatic spraying priming paint |
| CN104497839A (en) * | 2014-12-11 | 2015-04-08 | 三棵树涂料股份有限公司 | PU (polyurethane) seal primer capable of highly wetting and highly infiltrating substrate and preparation method of PU seal primer |
| CN104497839B (en) * | 2014-12-11 | 2017-11-21 | 三棵树涂料股份有限公司 | It is capable of PU seal coats of high wetting Thief zone ground and preparation method thereof |
| CN106010199A (en) * | 2016-07-28 | 2016-10-12 | 陈红旗 | Termite-proof paint for solid wood furniture |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1290951C (en) | 2006-12-20 |
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